Page 1 of 8
MATERIAL SAFETY DATA SHEET
SECTION 1
Product Name:
Product Code:
MSDS #:
IC1233-0202
Product Code:
6882A
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Canon Ink Tank BCI-24Color / Canon Ink Tank BCI-24Color Twin Pack
6882A
Distributor: Canon Australia Pty Ltd
1 Thomas Holt Drive
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
Address:
North Ryde NSW 2113
Use of the Product: Ink for Ink Jet Printer
Phone: (02) 9805-2000
Company Name:
Canon Inc.
SECTION 2
COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
Chemical Name /
Generic name
CAS # /
EC #
Weight
%
Glycerin
56-81-5 /
200-289-5
5 - 10
None / None
Ethylene glycol
(Contained in cyan and
magenta ink)
107-21-1 /
203-473-3
2-6
Xn / R22
Not established
(aerosol)
Ceiling =
100 mg/m3
Diethylene glycol
111-46-6 /
203-872-2
2-6
Xn / R22
Not established
Not established
Not established
10 ppm, 44 mg/m3
Copper,
[29H,31H-phthalocyaninato(2-)N29,N30,N31,N32]-,
aminosulfonyl sulfo derivs.,
sodium salts
(Contained only in cyan ink)
90295-11-7 /
291-001-7
2-6
Xi / R41
Not established
Not established
Not established
Copper and its
compounds
Inhalable fraction
1.0 mg/m3
Isopropyl alcohol
67-63-0 /
200-661-7
1-3
F / R11
Xi / R36
R67
Not established
200 ppm,
500 mg/m3
Quinoline derivative
(Contained only in
magenta ink)
Confidential
1-3
Xi / R36
Not established
Not established
Not established
Not established
Triazine derivative
(Contained only in
magenta ink)
Confidential
1-3
Xi / R36
R52/53
Not established
Not established
Not established
Not established
Ammonia derivative
Confidential
5 - 10
None / None
Not established
Not established
Not established
Not established
Lactam
(Contained in cyan and
yellow ink)
Confidential
2-6
None / None
Not established
Not established
Not established
Not established
Water
7732-18-5 /
231-791-2
55 - 75
None / None
Not established
Not established
Not established
Not established
Date of Issue:
June 18, 2001
EU Symbol/
R-Phrase
USA
OSHA PEL
ACGIH TLV
(as mist)
(as mist)
Total dust
TWA = 10 mg/m3
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3
EU ILV
DFG MAK
Not established
Not established
TWA = 20 ppm, 10 ppm, 26 mg/m3
52 mg/m3
STEL = 40 ppm,
104 mg/m3
TWA = 400 ppm, TWA = 200 ppm,
980 mg/m3
492 mg/m3
STEL = 400 ppm,
984 mg/m3
Revised:
December 25, 2003
Page 2 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1233-0202
Product Code:
6882A
< Carcinogen >
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA
regulations or Annex I to Directive 67/548/EEC.
SECTION 3
HAZARDS IDENTIFICATION
EU Classification:
STATEMENT OF HAZARDOUS NATURE:
Not classified as dangerous.
Emergency Overview:
A set of three colors ink tanks. (Cyan, Magenta and Yellow)
All the ink is liquid mixture with slight odor.
Not classified as hazardous according to the
criteria on Worksafe Australia.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Over exposure to vapor or mist may cause respiratory tract irritation, cough, dizziness, drowsiness, headache and
nausea.
Ingestion:
May cause abdominal pain, diarrhea, dizziness, drowsiness, dullness, headache, nausea and vomiting.
Eye:
May cause minimal irritation. (See SECTION 11)
Skin:
May cause mild irritation and no sensitization. (See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
SECTION 4
FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with lukewarm, gently flowing water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None
Date of Issue:
June 18, 2001
Revised:
December 25, 2003
Page 3 of 8
MATERIAL SAFETY DATA SHEET
SECTION 5
MSDS #:
IC1233-0202
Product Code:
6882A
FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2, water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO2 and NOx
Other Properties:
None
SECTION 6
ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.
SECTION 7
HANDLING AND STORAGE
Handling:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
In case of contact, wash out the contaminated area immediately.
Storage:
Keep in a cool and dry place. Protect from sunlight.
Keep away from heat and flame.
Keep out of the reach of children.
Specific Uses:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (See also SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Required
Respiratory Protection:
Not Required
Eye/Face Protection:
Required
Not Required
Skin Protection:
Required
Not Required
Date of Issue:
June 18, 2001
Revised:
December 25, 2003
Page 4 of 8
MATERIAL SAFETY DATA SHEET
SECTION 9
MSDS #:
IC1233-0202
Product Code:
6882A
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Cyan, magenta and yellow liquid
Odor:
Slight odor
pH:
8.0 - 10.0
Boiling Point/Range(°C):
Not available
Melting Point/Range(°C):
Not available
Decomposition Temperature(°C):
Not available
Flash Point(°C):
Estimate: 55 - 57 (Tag. Closed Cup. Combustion is not sustainable.)
Flammable (Explosive) Limits:
Not available
Autoignition Temperature(°C):
Not available
Flammability:
Classified as "combustible liquid" under OSHA-HCS.
Not classified as "flammable" or "combustible" under FHSA.
Not classified as "flammable" under 1999/45/EC.
Explosive Properties:
None
Oxidizing Properties:
None
Vapor Pressure :
Not available
Vapor Density :
Not available
Density / Specific Gravity:
1.04 - 1.10
Water Solubility :
Miscible
Fat Solubility :
Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%):
55 - 75
Evaporation Rate:
Not available
Viscosity (mPa s):
1.9 - 2.6
SECTION 10
STABILITY AND REACTIVITY
Stable
Unstable
Stability:
Conditions to Avoid:
None
Materials to Avoid:
Acids, bases, oxidizing materials and reducing agents
Hazardous Decomposition Products:
CO, CO2, NOx and Ammonia
Hazardous Polymerization:
None
Conditions to Avoid:
Date of Issue:
May Occur
Will Not Occur
June 18, 2001
Revised:
December 25, 2003
Page 5 of 8
MATERIAL SAFETY DATA SHEET
SECTION 11
MSDS #:
IC1233-0202
Product Code:
6882A
TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Cyan and Magenta: [Data of similar composition ink] Estimated LD 50 > 2500 mg/kg (rat)
OECD Guidelines No.423 (1996)
96/54/EC Method B1 tris
Yellow: Not available
Eye:
All colors: [Data of similar composition ink] Minimal irritant (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Skin:
All colors: [Data of similar composition ink] Mild irritant (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Sensitization:
All colors: [Data of similar composition ink] Non-sensitizer (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Mutagenicity:
Ames test:
All colors: Negative (test strains: S. typhimurium & E. Coli)
Chromosome aberration test:
Magenta: Negative (test strains: Human peripheral blood lymphocytes)
Cyan and Yellow: Not available
Reproductive Toxicity:
Not available
Carcinogenicity:
Not available
Others:
Not available
Date of Issue:
June 18, 2001
Revised:
December 25, 2003
Page 6 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1233-0202
Product Code:
6882A
SECTION 12
ECOLOGICAL INFORMATION
Not available
Mobility:
Persistence
Not available
/ Degradability:
Not available
Bioaccumulation:
Ecotoxicity:
Not available
Not available
Other Adverse Effects:
SECTION 13
DISPOSAL CONSIDERATION
Method of Disposal:
Disposal should be subject to federal, state and local laws.
SECTION 14
UN #:
TRANSPORT INFORMATION
None
UN Shipping Name: None
UN Classification:
None
UN Packing Group: None
Marine Pollutant:
Yes
No
Chemical name (wt%):
Special Precautions: None
SECTION 15
REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC:
Not regulated
(EC)2037/2000: Not regulated
(EC)304/2003:
Not regulated
Others:
None
Date of Issue:
June 18, 2001
Revised:
December 25, 2003
Page 7 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1233-0202
Product Code:
6882A
< USA Information >
Information on the Label
Signal Word:
under FHSA:
Not required
Hazard warning:
Not required
Safety Advice:
Not required
Hazardous Component(s):
None
SARA Title III §313:
Chemical Name
"Ethylene glycol" (107-21-1) (Contained in cyan and magenta ink)
"Copper Compounds" (Contained only in cyan ink)
(as Cu)
Weight %
2-6
2-6
(< 0.35)
California Proposition 65:
Chemical Name
None
< Canada Information >
WHMIS Controlled Product:
Weight %
Not applicable (Manufactured article)
< Australia Information >
Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC.
SECTION 16
OTHER INFORMATION
<R phrase list>
R11: Highly flammable.
R22: Harmful if swallowed.
R36: Irritating to eyes.
R41: Risk of serious damage to eyes.
R67: Vapours may cause drowsiness and dizziness.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
<Revised information from the previous version>
Section 2, 7, 9 and 11
Date of Issue:
June 18, 2001
Revised:
December 25, 2003
Page 8 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1233-0202
Product Code:
6882A
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EC)304/2003
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatz-Konzentration) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
STEL: Short Term Exposure Limit.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the
date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance
with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any
nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
Date of Issue:
June 18, 2001
Revised:
December 25, 2003