Page 1 of 8
MATERIAL SAFETY DATA SHEET
SECTION 1
MSDS #:
IC1232-0101
Product Code:
6881A
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name:
Canon Ink Tank BCI-24Black / Canon Ink Tank BCI-24Black Twin Pack
Product Code:
6881A
Distributor: Canon Australia Pty Ltd
1 Thomas Holt Drive
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
Address:
North Ryde NSW 2113
Use of the Product: Ink for Ink Jet Printer
Phone: (02) 9805-2000
Company Name:
SECTION 2
Canon Inc.
COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
Chemical Name /
Generic name
CAS # /
EC #
Weight
%
EU Symbol/
R-Phrase
USA
OSHA PEL
EU ILV
DFG MAK
Not established
Not established
ACGIH TLV
Glycerin
56-81-5 /
200-289-5
5 - 10
None / None
Diethylene glycol
111-46-6 /
203-872-2
2-6
Xn / R22
Not established
Not established
Not established
10 ppm, 44 mg/m3
Ammonium benzoate
1863-63-4 /
217-468-9
1-3
Xi / R36
Not established
Not established
Not established
Not established
Triol
Confidential
5 - 10
None / None
Not established
Not established
Not established
Not established
Water
7732-18-5 /
231-79-12
60 - 80
None / None
Not established
Not established
Not established
Not established
Date of Issue:
June 18, 2001
(as mist)
(as mist)
Total dust
TWA = 10 mg/m3
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3
Revised:
April 9, 2003
Page 2 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1232-0101
Product Code:
6881A
< Carcinogen >
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA
regulations or Annex I to Directive 67/548/EEC.
SECTION 3
HAZARDS IDENTIFICATION
EU Classification:
STATEMENT OF HAZARDOUS NATURE:
Not classified as dangerous.
Emergency Overview:
Ink tank containing black liquid ink with slight odor.
Not classified as hazardous according to the
criteria on Worksafe Australia.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Over exposure to vapor or mist may cause respiratory tract irritation, cough, dizziness, drowsiness, headache and
nausea.
Ingestion:
May cause abdominal pain, diarrhea, dizziness, drowsiness, dullness, headache, nausea and vomiting.
Eye:
May cause minimal irritation. (See SECTION 11)
Skin:
Neither irritation nor sensitization is expected. (See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
SECTION 4
FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with lukewarm, gently flowing water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None
Date of Issue:
June 18, 2001
Revised:
April 9, 2003
Page 3 of 8
MATERIAL SAFETY DATA SHEET
SECTION 5
MSDS #:
IC1232-0101
Product Code:
6881A
FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2 , water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO2 and NOx
Other Properties:
None
SECTION 6
ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.
SECTION 7
HANDLING AND STORAGE
Handling:
Use with adequate ventilation.
In case of contact, wash out the contaminated area immediately.
Storage:
Keep in a cool and dry place.
Protect from sunlight.
Keep out of the reach of children.
Specific Uses:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (See also SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Required
Respiratory Protection:
Not Required
Eye/Face Protection:
Required
Not Required
Skin Protection:
Required
Not Required
Date of Issue:
June 18, 2001
Revised:
April 9, 2003
Page 4 of 8
MATERIAL SAFETY DATA SHEET
SECTION 9
MSDS #:
IC1232-0101
Product Code:
6881A
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Black liquid
Odor:
Slight odor
pH:
7.7 - 8.3
Boiling Point/Range(°C):
Not available
Melting Point/Range(°C):
Not available
Decomposition Temperature(°C):
Not available
Flash Point(°C):
Estimate : None
Flammable (Explosive) Limits:
Not available
Autoignition Temperature(°C):
Not available
Flammability:
Neither flammable nor combustible.
Explosive Properties:
None
Oxidizing Properties:
None
Vapor Pressure :
Not available
Vapor Density :
Not available
Density / Specific Gravity:
1.04 - 1.10
Water Solubility :
Miscible
Fat Solubility :
Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%):
60 - 80
Evaporation Rate:
Not available
Viscosity (mPa s):
1.8 - 2.5
SECTION 10
STABILITY AND REACTIVITY
Stable
Unstable
Stability:
Conditions to Avoid:
None
Materials to Avoid:
Acids, bases, oxidizing materials and reducing agents
Hazardous Decomposition Products:
CO, CO2 , NOx and Ammonia
Hazardous Polymerization:
Conditions to Avoid:
Date of Issue:
June 18, 2001
May Occur
Will Not Occur
None
Revised:
April 9, 2003
Page 5 of 8
MATERIAL SAFETY DATA SHEET
SECTION 11
MSDS #:
IC1232-0101
Product Code:
6881A
TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Not available
Eye:
[Data of similar composition ink] Minimal irritant (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Skin:
[Data of similar composition ink] Non irritant (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Sensitization:
[Data of similar composition ink] Non sensitizer (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Mutagenicity:
Ames test : Negative (test strains: S.typhimurium & E.Coli)
Reproductive Toxicity:
Not available
Carcinogenicity:
Not available
Others:
Not available
Date of Issue:
June 18, 2001
Revised:
April 9, 2003
Page 6 of 8
MATERIAL SAFETY DATA SHEET
SECTION 12
ECOLOGICAL INFORMATION
Mobility:
Not available
Persistence /
Degradability:
Not available
MSDS #:
IC1232-0101
Product Code:
6881A
Bioaccumulation: Not available
Not available
Ecotoxicity:
Other Adverse Effects: Not available
SECTION 13
DISPOSAL CONSIDERATION
Method of Disposal:
Disposal should be subject to federal, state and local laws.
SECTION 14
TRANSPORT INFORMATION
UN #:
None
UN Shipping Name: None
UN Classification:
None
UN Packing Group: None
Marine Pollutant:
Yes
No
Chemical name (wt%):
Special Precautions: None
SECTION 15
REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC:
Not regulated
(EC)2037/2000: Not regulated
(EC)304/2003:
Not regulated
Others:
None
Date of Issue:
June 18, 2001
Revised:
April 9, 2003
Page 7 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1232-0101
Product Code:
6881A
< USA Information >
Information on the Label under FHSA:
Signal Word:
Not required
Hazard warning:
Not required
Safety Advice:
Not required
Hazardous Component(s):
None
SARA Title III §313:
Chemical Name
None
Weight %
California Proposition 65:
Chemical Name
None
Weight %
< Canada Information >
WHMIS Controlled Product:
Not applicable (Manufactured article)
< Australia Information >
Statement of Hazardous Nature:
Not classified as hazardous according to criteria of NOHSC.
SECTION 16
OTHER INFORMATION
<R phrase list>
R22 : Harmful if swallowed.
R36 : Irritating to eyes.
<Revised information from the previous version>
Entirely revised.
Date of Issue:
June 18, 2001
Revised:
April 9, 2003
Page 8 of 8
MATERIAL SAFETY DATA SHEET
MSDS #:
IC1232-0101
Product Code:
6881A
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EC)304/2003
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission Act 1985.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the
date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance
with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any
nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
Date of Issue:
June 18, 2001
Revised:
April 9, 2003