Lanier Worldwide, Inc. 2300 Parklake Dr., N. E. Atlanta, GA 30345-2979 Emergency Telephone: (800) 526-4371 MATERIAL SAFETY DATA SHEET Section 1: Chemical Product and Company Information Identity: Product ID: Synonyms & Common Names: Toner for 1210, 1240, 1260, 1205 491-0282 MSDS No. Issued: Supersedes: Date: Prepared by: Toner for Lanier 1210, 1240, 1260, 1205 Fax Uses: Approved by: European Contact: Lanier 1210, 1240, 1260, 1205 Fax Chemical Formula: Mixture FX-071 02/06/2004 08/12/2002 02/06/2004 Lanier Worldwide, Inc. EH&S Department (770) 496-9500 Larry Choskey, Manager, EH&S Lanier Worldwide, Inc., Manager, Safety & Environment, Walter Fricke, Im Taubental D-41468 Neuss, Germany +49-2131-387-177 Section 2: Composition / Information on Ingredients PERCENT CAS No. EXPOSURE LIMITS Polyester resin Carbon black > 85 1–5 Confidential 1333-86-4 Polyolefin wax 1–5 Organic pigment 1–5 Quaternary ammonium salt 1–5 *PEL as the product: 15mg/m3 (total dust), 5mg/m3 (respirable dust) *TLV as the product: 10mg/m3 (total dust), 5mg/m3 (respirable dust) Confidential Confidential Confidential Not listed 3.5 mg/m3, 3.5 mg/m3 6 mg/m3 Not listed Not listed Not listed SOURCE n/a OSHA TWA, ACGIH TLV MAK N/a N/a N/a Section 3: Hazards Identification HMIS Rating: FLAMMABILITY = 1 REACTIVITY = 0 HEALTH = 1 SPECIAL = none Health Hazards (Acute, Chronic, Immediate and Potential): Minimum irritation to respiratory tract may occur as with exposure to any nontoxic dust. May cause gasping if inhaled. Inhalation should be avoided. May cause temporary eye discomfort. Health Hazards of Long Term exposure (Chronic): A manufacturer sponsored chronic inhalation study in rats using a special test toner revealed there were no lung changes at all in the lowest exposure level (1mg/m3), the most relevant level to potential human exposures. A very slight degree of fibrosis was noted in 25% of the animals at the middle exposure level (4mg/m3), while a slight degree of fibrosis was observed at the highest exposure level (16mg/m3) in all animals. These findings are attributed to “Lung Overloading”, a generic response to excessive amount of any dust retained in the lungs for a prolonged interval. The special test toner was ten times more respirable than commercially available toner to comply with EPA testing protocol and would not function properly in Xerographic equipment. Carbon Black is listed on the IARC Monograph and the Massachusetts Substance List. The IARC has evaluated the evidence for the carcinogenicity of Carbon Black as inadequate to determine a carcinogenic risk for humans. This product contains no known hazardous materials as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200. Section 4: First Aid Measures Inhalation: Remove to fresh air if effects occur. Get medical attention if needed. Eye Contact: Skin Contact: Wash with soap and water. Ingestion: In case of contact, immediately flush eyes with water for 5 minutes. Get medical attention if needed. Dilute stomach contents with several glasses of water. Get medical attention. Section 5: Fire Fighting Measures Suitable extinguishing media: CO2, dry chemical, foam or water. Extinguishing media which may not be used for safety reasons: none Explosion limits: n/a This material will burn in case of fire. The decomposition products are CO, CO2, and No x. Avoid inhalation of smoke. Special protective equipment for fire fighters: none LEL: n/a UEL: n/a MATERIAL SAFETY DATA SHEET Page 2 of FX-071 Section 6: Accidental Release Measures Spill / leak Procedures: If spilled, sweep up using an approved toner vacuum with a 0.5 micron filter or smaller, such as the Atrix AAA Toner Vacuum or 3M Toner Vacuum. Use of a vacuum cleaner not rated for toner particles, could result in a fire or personal injury. Remove residue with soap and cold water. Miscellaneous: Keep product out of sewers and watercourses. Personal protection: Avoid inhalation of dust. Section 7: Handling and Storage Special Handling: Special Storage: Cleanse skin after contact before breaks or meals, and end of workday. Avoid direct sunlight. Keep out of reach of children. Store in a cool, dry place. Section 8: Exposure Control and Personal Protection Information: Ventilation: Local exhaust Respiratory Protection: Nuisance dust respirator. Eye Protection: Safety goggles. Hand Protection: none required under normal use. Skin Protection: Gloves. Section 9: Physical and Chemical Properties CHARACTERISTICS: Appearance: Form: Odor: Solubility in Water: Specific gravity: Black Powder Faint odor Negligible 1.2 Melting point: Vapor pressure: Vapor density: Evaporation rate: Ignition temp. 120 - 130ºC n/a n/a n/a 450ºC Section 10: Stability and Reactivity Conditions to avoid: Electronic discharge or throwing into fire Materials to avoid: Oxidizing materials Hazardous decomposition products: CO and CO2 and other decomposition products when burned. Stability: Stable Section 11: Toxicological Information: Acute oral toxicity (rat) LD50: Over 5.0 g/kg Mutagenicity: Ames Test result: Negative Skin sensitizer: None indicated (Guinea-pig) Acute Inhalation: LC50 (4H) is in excess of 0.74 g/m3 (rat) Dermal: LD50 Over 2.0 g/kg (rat) Eye Irritation: Not an irritant (rabbit) Section 12: Environmental / Ecological Information Mobility: No data is available on the adverse effects of this material on the environment. Persistence/Degradability: No data is available on the adverse effects of this material on the environment. Bioaccumulation: No data is available on the adverse effects of this material on the environment. Ecotoxicity: Behavior in Sewage works: No data is available on the adverse effects of this material on the environment. Aquatic Toxicity: No data is available on the adverse effects of this material on the environment. Ecological Data (EC) Csb Value (EC): No data is available on the adverse effects of this material on the environment. AOX-Remark (EC): No data is available on the adverse effects of this material on the environment. BsB5 Value (EC): No data is available on the adverse effects of this material on the environment. Significant Components (EC): Not applicable Section 13: Disposal Consideration Used Toner should be disposed of under conditions that meet all federal, state and local environmental regulations. Disposal regulations vary from locality to locality; therefore consult your local Lanier office or the EPA to determine the proper method for disposal. Section 14: Transportation Information Special Precautions : None International Transport Information: UN Classification number: None DOT Identification number: None Information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. On the basis of the data available to us, this product is not a dangerous substance. One should, however, observe the usual precautionary measures for dealing with chemicals. MATERIAL SAFETY DATA SHEET Page 3 of FX-071 Domestic Transportation : n/a Land RID(EC): None ADR(EC): None Inland Waterways ADNR (Rhine R.): None Sea: IMDG: None Air: ICAO-TI: None IATA-DGR: None Section 15: Regulatory Information OSHA Hazard Communication Standard, 29 CFR 1910.1200: Not regulated TSCA: All chemical substances in this product comply with all applicable rules or orders under TSCA RCRA, 40 CFR 261: Not regulated NTP Annual Report on Carcinogens: Not listed as a NTP carcinogen IARC: See Section 11 California Proposition 65: Neither toner, nor any of its components, are listed as chemicals known to the state of California to cause cancer. Controlled Products Regulations (Canada): This product has been classified in accordance with the hazard criteria of the CPR. Other State Regulations: Carbon Black is listed in the New Jersey Right To Know List, Pennsylvania Hazardous Substance List and Massachusetts Substance List. U.S. / Canada Label Standards: LOW HAZARD FOR RECOMMENDED HANDLING. Minimize dust generation and accumulation. Use with adequate ventilation. EU Information Label Information according to Directives 67/548 EEC & 88/379 EEC: Symbol & Indication: Not required Risk Phase: Not required Safety Advice Phase: Not required EEC Directive (76/548 EEC, 79/831, 92/32 EEC): All chemical substances in this product comply with all applicable rules or order under EEC Directive. Section 16: Miscellaneous Information Notice: Judgments as to the suitability of information contained herein for purchaser’s purposes are the purchaser’s responsibility. Therefore, although reasonable care has been taken in the preparation of such information, Lanier Worldwide, Inc. extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser’s intended purposes or for consequences of its use. All materials may present unknown hazards and should be used with caution. Although certain hazards are described within, we do not guarantee that these are the only hazards, which exist. References: IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risks of Chemical to Humans, Vol. 65, Printing Processes and Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp. 149-261. H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J.C. MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991). Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats, Fundamental and Applied Toxicology 17, pp 280-299. Abbreviations: (1) OSHA PEL ; Permissible Exposure Limit under Occupational Safety and Health Administration. (USA) (2) ACGIH TLV; Threshold Limit Value under American Conference of Governmental Industrial Hygienists. (USA) (3) (4) (5) (6) (7) (8) DFG-MAK; Maximale Arbeitsplatzkonzentrationen under Deutsche Forschungsgemeinschaft. TWA; Time Weighted Average. IARC; International Agency for Research on Cancer. NTP; National Toxicology Program. (USA) NIOSH; National Institute for Occupational Safety and Health. (USA) DOT; Department of Transportation. (USA) Information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. On the basis of the data available to us, this product is not a dangerous substance. One should, however, observe the usual precautionary measures for dealing with chemicals.