2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
Product Name : Print Cartridge SP1000E (Black toner) SDS Number : 413196
Date Prepared : 01/09/2005 Date Modified : 10/07/2017 Date : 02/11/2017
Safety Data Sheet (ISO form)
1.Product and Company Identification
Product Name
General Use
SDS Number
Company Name
Department
Address
Telephone Number
Telefax Number
E-mail
:Print Cartridge SP1000E (Black toner)
:The Image Formation of Printing Machine or Copier
:413196
:Ricoh Company,Ltd.
:Safety Engineering Department, Quality Management Division
:146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007 Japan
:055-920-1470, Japan
:055-920-1479, Japan
:msdsinfo@nts.ricoh.co.jp
2.Compo regulation (EC) No 1272/2008 sition/Information on Ingredients
Substance or Preparation
Preparation
Chemical Nature
Ingredients
Chemical Formula
Polyester Resin
CAS.No.
Confidential
Contents(%)
Confidential
30-70
1317-61-9
<30
Confidential
<20
C
1333-86-4
<5
Wax
Not Identified
8015-86-9
<5
Silica
O2Si
7631-86-9
<5
Magnetite
Fe3O4
Styrene-acrylic Resin
Confidential
Carbon Black
This product does not contain any of the following substances as ingredients.
Cadmium, Hexavalent Chromium, Mercury, Lead, Polybrominated biphenyls (PBB), Polybrominated diphenyl
ethers (PBDE), SVHC (substances of very high concern: published by ECHA).
And if it contains any impurities, it does not exceed any of the thresholds of RoHS.
Hazardous Ingredients Information
Chemical Name : Carbon Black
CAS Number
OSHA Z-Tables (USA)
NTP (USA)
Symbol (EU)
DFG-MAK
California Proposition 65 (USA)
: 1333-86-4
: 3.5mg/m3
: Not listed
: Not listed
: III 3B
: Listed
EEC Number
ACGIH-TLV
IARC Monographs
R-Phrase (EU)
OELs-TWA (Australia)
: 215-609-9
: 3.5mg/m3
: Group 2B
: Not listed
: 3.0mg/m3
3.Hazards Identification
The Most Important Hazards
Adverse Human Health Effects
There are no significant hazards expected with intended use.
Environmental Effects
There are no significant hazards expected with intended use.
Physical and Chemical Hazards
There are no significant hazards expected with intended use.
Specific Hazards
Dust explosion (like most finely grained organic powders)
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
1/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
Main Symptoms
Acute Inhalation Toxicity
Exposure to excessive amount of dust may cause physical irritation to respiratory tract.
Acute Oral Toxicity
Low acute toxicity in animal experiment.
Acute Eye Irritation
May cause slight transient irritation.
Acute Skin Irritation
May be non-irritant.
Sensitization
From test no apparent significant hazards are expected . (Only few cases reported on incidental allergyrelated conjunctivitis or dermatitis.)
Chronic Effect
Slight pulmonary fibrosis has been reported in rats upon chronic inhalation exposure to a toner at 4mg/m3
every day for 2 years. No pulmonary change was found at 1mg/m3. These findings show that exposure to
excessive amounts of powder may cause damage to lungs. However, normal use and handling of this
product as intended, does not result in inhalation of excessive amounts of powder.
Carcinogenicity
Carbon black contained in this product is classified to Group 2B of IARC as the result of inhalation test in
use of rat.
But oral/skin test does not show carcinogenicity.
The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test in use
of rat.
The Classification of The Chemical Product
This preparation is not classified as dangerous according to Regulation (EC) No 1272/2008.
4.First-Aid Measures
Inhalation
Remove from exposure into fresh air and rinse mouth with water. Seek medical advice.
Skin Contact
Wash thoroughly with soapy water.
Eye Contact
Flush with a large amount of water until particles are removed. Seek medical advice.
Ingestion
Drink several glasses of water to dilute ingested toner. Seek medical advice.
Notes to a physician
Not applicable
5.Fire-Fighting Measures
Extinguishing Media
CO2,dry chemicals,foam or water.
Extinguishing Media to Avoid
Not applicable.
Specific Hazards
Can form explosive dust-air mixtures when finely dispersed in air.
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
2/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
Specific Method
No special fire protecting method is required. Sprinkling or fire extinguishers can be used.
Protection of Fire-fighters
Wear gloves, glasses, a mask if necessary.
6.Accidental Release Measures
Personal Precautions
Do not breathe in dust.
Environment Precautions
Do not flush into sewers or watercourses.
Methods for Cleaning Up
Confirm there is no source of fire and if there is a source, remove it. Sweep up spilled powder slowly and
clean remainder with wet cloth.
7.Handling and Storage
Handling
Technical Measures/Precautions
Not applicable
Safe Handling Advice
Do not handle in areas where there is wind or draught, this may cause dust to get into eyes.
Avoid breathing in dust.
Storage
Technical Measures
Not applicable
Storage Conditions
Keep out of reach of children.
Store in dry, well-ventilated area, to maintain quality the temperature should not exceed 35degrees
centigrade for a long time. Avoid direct sunlight.
Packaging Material
Not applicable
Specific Use(s)
Image formation in printing machines or copiers.
8.Exposure Controls/Personal Protection
Technical Measures
Use adequate ventilation. None required with intended use.
Control Parameters
USA OSHA PEL (TWA)
: 15mg/m3 (Total dust)
5.0mg/m3 (Respirable fraction)
ACGIH TLV (TWA)
: 10mg/m3 (Inhalable fraction)
3.0mg/m3 (Respirable fraction)
DFG MAK
: 4.0mg/m3 (Total dust)
1.5mg/m3 (Respirable fraction)
Personal Protection
Respiratory Protections
None required in normal use. If the limit of exposure concentration is exceeded, use authorised respirator.
Hand Protection
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
3/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
Use vinyl or rubber gloves if necessary.
Eye Protection
Put on goggles if necessary.
Skin and Body Protection
Wear chemical-resistant apron or other impervious clothing if necessary.
Hygiene Measures
Wash hands after handling.
9.Physical and Chemical Properties
Appearance
Physical State
Form
Colour
Odour
:
:
:
:
Solid
Powder
Black
Slightly plastic odour
Information
pH : Not applicable
Specific Temperatures/Temperature Ranges at Which Changes in Physical State Occur
Boiling Point (degrees centigrade) : Not applicable
Melting Point (degrees centigrade) : (Softening point) Approx.110
Decomposition Temperature (degrees centigrade)
Flash Point (degrees centigrade)
Explosion Properties (degrees centigrade)
Vapor Pressure (Pa)
: Not applicable
Vapor Density(AIR=1) : Not applicable
Density (g/cm3)
: 1.45
: Not available
: Not applicable
: This product is considered a nonexplosive material under
normal use.
Measuring Temp (degrees centigrade) : 25
Solubility
Water Solubility (g/L)
: Insoluble
Chloroform Solubility (g/L)
: Slightly soluble
Octanol/Water Partition Coefficient
Not available
Other Information
Flammability
Viscosity (Pa・s)
Volatile (%)
: Not flammable
: Not applicable
: 0.2 or below
10.Stability and Reactivity
Stability
Stable
Hazardous Reaction
Dust explosion, like most finely grained organic powders.
Conditions to Avoid
Not applicable in normal use.
Materials to Avoid
Not applicable in normal use.
Hazardous Decomposition Products
Decomposition products will not occur.
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
4/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
11.Toxicological Information
Acute Toxicity
Acute Oral Toxicity (LD50) :
5000 or over [mg/kg] (Rat) (The acute lethal oral dose to rats of JX Toner was demonstrated to be greater than
5000 mg/kg bodyweight.)
Acute Dermal Toxicity :
Not available
Acute Inhalation Toxicity :
Not available
Local effects
Acute Skin Irritation(PII) :
Non-irritant (Rabbit) (PII=0.0)
Acute Eye Irritation :
Not available (Ingredients are not classified as dangerous according to Regulation (EC) No 1272/2008.)
Sensitization
Acute Allergenic Effects :
0 % (Marmot) (Did not produce evidence of skin sensitisation.)
Specific Effects
Carcinogenicity :
Carbon black contained in this product is classified to Group 2B of IARC as the result of inhalation test in use
of rat.
But oral/skin test does not show carcinogenicity.
The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test in use of
rat.
Mutagenicity : Negative (Ames test)
Reproduction Toxicity : Does not contain substances listed as hazardous to reproductive health.
12.Ecological Information
Mobility
Persistence/Degradability
Bioaccumulation
: No data are available on any adverse effects on the environment.
: Not available
: Not available
Ecotoxicity
Acute Toxicity for Fish (LC50)
Acute Toxicity for Daphnia (EC50)
Algae Inhibition Test (IC50)
: Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/96hr
: Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/48hr
: Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/72hr
13.Disposal Consideration
General information:
Dispose of waste and residues in accordance with local authority requirements.
Disposal methods:
Disposal recommendations are based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal. Confirm disposal procedures with
local regulations.
Precautions:
Do not throw the toner cartridge or toner into an open flame. Hot toner may scatter and cause burns or other
damage.
14.Transport Information
International Regulations
Land Transport
RID/ADR
: Not applicable
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
5/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
DOT 49 CFR
: Not applicable
ADNR
: Not applicable
Sea Transport
IMDG Code
: Not applicable
Air Transport
ICAO-TI/IATA-DGR : Not applicable
The UN Classification Number
: Not applicable
Class
: Not applicable
Specific Precautionary Transport Measures and conditions
Avoid direct sunlight in quality.
15.Regulatory Information
Regulations
EU Information
Information on the label (Regulation (EC) No 1272/2008)
Symbols &
: Not required
Indications
R-Phrase
: Not required
S-Phrase
: Not required
Special Precautions under regulation (EC) No 1272/2008 Annex II : Not required
Regulation (EC) No 1907/2006 annex XVII
This product complies with applicable rules and regulations under Regulation (EC) No 1907/2006 annex
XVII.
304/2003/EC
Not regulated
US Information
Information on the label : Not required
TSCA (Toxic Substances Control Act) :
This toner complies with all applicable rules and regulations under TSCA.
SARA Title III
313 Reportable Ingredients : Not regulated
California Proposition 65 : Not regulated
Canada Information
WHMIS Controlled product : Not a controlled product
16.Other Information
NFPA Hazard Rating: National Fire Protection Agency (USA)
Health ; 1, Flammability ; 1, Reactivity ; 0
HMIS Rating : The National Paint and Coating Association (USA)
Health ; 1, Flammability ; 1, Reactivity ; 0
Literature References :
ANSI Z400.1-1993
ISO 11014-1
IARC (1996) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.65, Printing
Process and Printing Inks, Carbon Black and Some Nitro Compounds", Lyon, pp149-261
H. Muhle, B. Bellman, O. Creutzenberg, C. Dasenbrock, H. Emst, R. Kilpper, J.C. MacKenzie, P. Morrow, U. Mohr, S.
Takenaka and R. Mermelstein(1991) "Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats"
Fundamental and Applied Toxicology 17, pp 280-299
IARC (2008) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.93"
NIOSH CURRENT INTELLIGENCE BULLETIN "Evaluation of Health Hazard and Recommendation for
Occupational Exposure to Titanium Dioxide DRAFT"
ACGIH-TLV
: Threshold Limit Values for Chemical Substances and Physical Agents and
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
6/7
2017-11-02
Ricoh Company,Ltd. 413196 Print Cartridge SP1000E (Black toner)
Biological Exposure Indices
: US Department of Labor, 29CFR Part 1910 , Tables Z-1, Z-2, and Z-3
: US Department of Health and Human Services National Toxicology Program
Annual Report on Carcinogens
DFG-MAK
DFG List of MAK and BAT Value
Symbol (EC)
: Regulation (EC)No.1272/2008
91/155/ EEC
: EU Directive 91/155/ EEC
1272/2008
: Regulation (EC) No 1272/2008
CLP (EC)No.1272/2008
: Regulation (EC)No.1272/2008 of the European Parliamant and of the Council of 16
December 2008 on classification, labelling and packaging of substances and
mixtures,amending and repealing Directive Regulation (EC) No 1272/2008, and
amending Regulation (EC)No. 1907/2006
EC 304/2003
: Regulation (EC) No 304/2003 of the European Parliament and of the Council of 28
January 2003 concerning the export and import of dangerous chemicals
WHMIS Controlled product : Canada Workplace Hazardous Information System
OELs-TWA (Australia)
: Guidance Note on the Interpretation of Exposure Standards for Atmospheric
Contaminants in the Occupational Environment [NOHSC: 3008 (1995)]
OSHA Z-Tables
NTP (USA)
Abbreviations :
OSHA PEL
ACGIH-TLV
SVHC
ECHA
DFG-MAK
RoHS
PEL (Permissible Exposure Limit) under Occupational Safety and Health Act
TLV (Threshold Limit Values) under American Conference of Governmental Industrial
Hygienists
(EC)No.1907/2006:Council Regulation concerning the Registration, Evaluation, Authorization
and Restriction of Chemicals
Substances of Very High Concern
The European Chemicals Agency
MAK (Maximale Arbeitsplatz Konzentrationen) by Deutsche Forschungs Gemeinschaft
Restriction of the use of certain Hazardous Substances in Electrical and Electronic Equipment
TWA
IARC
NTP
WHMIS
NOHSC
Time Weighted Average
nternational Agency for Research on Cancer
National Toxicology Program
Workplace Hazardous Information System
National Occupational Health and Safety Commission Act 1985
REACH
Disclaimer :
This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge
of RICOH COMPANY, LTD.
It relates only to the specific material designated herein, and does not relate to use in combination with any other
material or process.
RICOH COMPANY, LTD assumes no legal responsibility for use or reliance upon this information.
https://www2.notes.ricoh.co.jp/ecology/msds.nsf/MSDSSearchforName_e/D7BB1FADCD509D524925818400127F71?OpenDocument
7/7
Download PDF
Similar pages