Sicherheitsdatenblatt Castrol Motorenoel Classic SAE 50

SAFETY DATA SHEET
dentification du produit chimique et de la personne physique ou morale responsable
e sa mise sur le marché
produit
1.
Almaredge R4
Identification of the substance/preparation and company/undertaking
FR-453352, BE-453352, NL-453352
n duProduct
produitname
Castrol
Classic
GP 50
Fluide de traitement
des
métaux. Soluble.
SDS no.
452484
eur Use of the
Castrol Industrial
- divisie
BP-Belgium
nv/sa
Automotive
engine
crankcase
lubricant.
60-62 application advice see appropriate Technical Data Sheet or consult our company
For specific
substance/preparation Uitbreidingstraat
B 2600 Berchem
representative.
Anvers
Supplier
Castrol (UK) Ltd
Belgique Wakefield House
Pipers Way
Numéro de Swindon
téléphone: +32 (0) 3/286 6210
SN3+32
1RE(0) 3/286 6220
Numéro de Wiltshire
télécopieur:
EMERGENCY
TELEPHONE
(0) 1793+44
512712
Carechem: +44
Carechem:
(0) 208 762 8322 (24 hours)
OD’
A
PPEL
NCENUMBER
E-mail address
MSDSadvice@bp.com
formation sur les composants
2.
Hazards identification
érale très raffinée, émulsifiants et additifs.
This preparation is not classified as dangerous according to Directive 1999/45/EC as amended and adapted.
mique
no CAS
Additional hazards
%
EINECS / ELINCS.
Classification
USED ENGINE OILS
Used
engine oil64742-55-8
may contain hazardous
which have the potential
to R65
cause skin cancer.
paraffiniques légers (pétrole), hydrotraités
(Huile
10 components
- 20
265-158-7
Xn;
See
Toxicological
Information,
section
11
of
this
Safety
Data
Sheet.
e très raffinée)
sections
11 andavec
12 for
more detailed information68132-47-8
on health effects and 5symptoms
and268-640-5
environmental hazards.Xi; R36/38
ras, See
tall oil,
composés
éthanolamine
- 10
amine
141-43-5
1-5
205-483-3
Xn; R20
3 . Composition/information on ingredients
Xi; R36/37/38
thylènebismorpholine
5625-90-1
1-5
227-062-3
Xn; R22
Highly refined base oil (IP 346 DMSO extract < 3%). Proprietary performance additives.
C; R34
This product does not contain any hazardous ingredients at or above regulated thresholds.
R52
-2-méthylpropanol
124-68-5
1-5
204-709-8
Xi; R36/38
R52/53
4 . First-aid measures
polyéthylèneglycol et de monooléyle
9004-98-2
1-5
500-016-2
Xi; R38, R41
C8-16,
71243-46-4
1 - 5 with a copious amount of water forXn;
R22 15 minutes. Get
Eyeéthoxylés
contact
In case of contact,
immediately flush eyes
at least
medical attention if irritation occurs.
Xi; R36/38
bamate
55406-53-6
0.1 -with
1 plenty259-627-5
Xn; R20/22
Skin3-iodo-2-propynyl
contact
In case of contact,
immediately flush skin
of water. Remove contaminated
clothing and shoes.
Xi; R41
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical
attention if irritation
N; R50
develops.
If inhaled,
remove
to fresh air. Get medical attention if symptoms appear.
on 16Inhalation
pour le texte intégral des phrases R
mentionnées
ci-dessus
Ingestion professionnelle, quand elles
Do sont
NOTdisponibles,
induce vomiting
directedà to
so by 8.
medical personnel. Never give anything by mouth to
s d'exposition
sontunless
énumérées
la do
section
Notes to physician
entification
des
dangers
an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
Treatment should in general be symptomatic and directed to relieving any effects.
. classée
Fire-fighting
measures
ation5est
dangereuse selon
la directive 1999/45/CE modifiée et adaptée.
é comme dangereux à une concentration inférieure à 75%.
Extinguishing media
Non classé comme dangereux.
physiques ou
Suitable
In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
s
Not suitable
Do not use water jet.
Irritant pour les yeux.
pour la santé
Hazardous decomposition
pourproducts
l'environnement
symptômes
Special fire-fighting
on
procedures
Decomposition products may include the following materials:
Non classé comme
dangereux.
carbon oxides
None identified.
Provoque une irritation des yeux.
Protection of fire-fighters
Fire-fighters
should peut
wear entraîner
self-contained
positive pressure
(SCBA)
and full ou
turnout
Un contact prolongé
ou répété
un déssèchement
de breathing
la peau etapparatus
provoquer
une irritation
gear.
une dermatite.
6.
Sous forme de vapeurs et d'aérosol, le produit peut occasionner l'irritation des muqueuses, des voies
Accidental release
nasales et measures
de la gorge.
provoquer
unetaken
irritation
gastro-intestinale
et laordiarrhée.
on Personal precautions L'ingestion peut
No action
shall be
involving
any personal risk
without suitable training. Evacuate surrounding
areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled
material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions
m du produit Almaredge R4
on 0.01
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform
the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Code du produit FR-453352
Date d'édition 28 Avril 2005
Format Belgique
Build 7.1.4
Product name
Version 2
Date of issue 18 September 2007
Langue FRANÇAIS
(Belgium)
Castrol Classic GP 50
Page 1 de 5
( FRENCH )
Product code 452484-GB05
Format United Kingdom
(UK)
Build 9.1.2
(United Kingdom)
Page: 1/4
Language ENGLISH
( ENGLISH )
Large spill
Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent
entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible absorbent materials, e.g.
sand, earth, vermiculite, diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilt product. Note: see section 1 for emergency
contact information and section 13 for waste disposal.
Small spill
Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
7.
Handling and storage
Handling
Wash thoroughly after handling.
Storage
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Not suitable
Prolonged exposure to elevated temperature.
8.
Exposure controls/personal protection
Ingredient name
Occupational exposure limits
Base oil - unspecified
EH40 (United Kingdom (UK)).
STEL: 10 mg/m3 15 minute(s). Form: Oil mist, mineral
TWA: 5 mg/m3 8 hour(s). Form: Oil mist, mineral
ACGIH TLVs
Base oil - unspecified
ACGIH (United States).
STEL: 10 mg/m3 15 minute(s). Form: Oil mist, mineral
TWA: 5 mg/m3 8 hour(s). Form: Oil mist, mineral
Where there are no regulatory exposure limits, for information and guidance, the ACGIH values are included.
For further information on these please consult your supplier.
Whilst specific OELs for certain components may be shown in this section, other components may be present in any mist, vapour or dust
produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.
Exposure controls
Occupational exposure
controls
Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are
close to the workstation location.
All chemicals should be assessed for their risks to health and appropriate control measures put in place to
prevent or adequately control exposure. A hierarchy of control measures exists (e.g. elimination,
substitution, general ventilation, containment, systems of work, changing the process or activity) that must
be considered before use of personal protective equipment. Personal protective equipment should
conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on selection and
appropriate standards. For further information contact your national organisation for standards.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that
all items of personal protective equipment are compatible.
Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period.
Personal protective equipment
Respiratory protection
Respiratory protective equipment is not normally required where there is adequate natural or local exhaust
ventilation to control exposure.
In case of insufficient ventilation, wear suitable respiratory equipment.
Respiratory protective equipment must be checked to ensure it fits correctly each time it is worn.
Air-filtering respirators, also called air-purifying respirators, will not be adequate under conditions of
oxygen deficiency (i.e. low oxygen concentration), and would not be considered suitable where airborne
concentrations of chemicals with a significant hazard are present. In these cases air-supplied breathing
apparatus will be required.
Provided an air-filtering/air-purifying respirator is suitable, a filter for particulates can be used for mist or
fume. Use filter type P or comparable standard. A combination filter for particles and organic gases and
vapours (boiling point >65°C) may be required if vapour or abnormal odour is also present due to high
product temperature. Use filter type AP or comparable standard.
Hand protection
Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves.
Recommended: nitrile gloves
Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace
gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.
Eye protection
Product name
Version 2
Safety glasses with side shields.
Castrol Classic GP 50
Date of issue 18 September 2007
Product code 452484-GB05
Format United Kingdom
(UK)
Build 9.1.2
(United Kingdom)
Page: 2/4
Language ENGLISH
( ENGLISH )
Skin and body
Use of protective clothing is good industrial practice.
Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that
will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin
exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant
aprons and/or impervious chemical suits and boots will be required.
9.
Physical and chemical properties
General information
Appearance
Physical state
Liquid.
Colour
Amber.
Odour
Oily.
Important health, safety and environmental information
Flash point
Closed cup: 235°C (455°F) [Pensky-Martens.]
Viscosity
Density
Kinematic: 223 mm2/s (223 cSt) at 40°C
Kinematic: 19 mm2/s (19 cSt) at 100°C
892 kg/m3 (0.892 g/cm3) at 15°C
Solubility
Insoluble in water.
Partition coefficient
(LogKow)
>3
10 . Stability and reactivity
Stability
Conditions to avoid
The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not
occur.
No specific data.
Materials to avoid
Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition
products
Combustion products may include the following:
carbon oxides
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
11 . Toxicological information
Acute toxicity
Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may
lead to dermatitis.
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause
nausea and diarrhoea.
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its
low volatility. May be harmful by inhalation if exposure to vapour, mists or fumes resulting from thermal
decomposition products occurs.
Chronic toxicity
Other chronic toxicity data
USED ENGINE OILS
Combustion products resulting from the operation of internal combustion engines contaminate engine oils
during use. Used engine oil may contain hazardous components which have the potential to cause skin
cancer. Frequent or prolonged contact with all types and makes of used engine oil must therefore be
avoided and a high standard of personal hygiene maintained.
Effects and symptoms
Eyes
No significant health hazards identified.
Inhalation
No significant health hazards identified.
Ingestion
No significant health hazards identified.
12 . Ecological information
Persistence/degradability
Inherently biodegradable.
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
This product is not expected to bioaccumulate through food chains in the environment.
Environmental hazards
Not classified as dangerous.
Other ecological information
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could
also be impaired.
Product name
Version 2
Castrol Classic GP 50
Date of issue 18 September 2007
Product code 452484-GB05
Format United Kingdom
(UK)
Build 9.1.2
(United Kingdom)
Page: 3/4
Language ENGLISH
( ENGLISH )
13 . Disposal considerations
Disposal Consideration /
Waste information
The generation of waste should be avoided or minimised wherever possible. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any
by-products should at all times comply with the requirements of environmental protection and waste
disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
Unused product
European waste catalogue
(EWC)
13 02 05* mineral-based non-chlorinated engine, gear and lubricating oils
However, deviation from the intended use and/or the presence of any potential contaminants may require
an alternative waste disposal code to be assigned by the end user.
14 . Transport information
Not classified as hazardous for transport (ADR/RID, ADNR, IMDG, ICAO/IATA)
15 . Regulatory information
Classification and labelling have been performed according to EU directives 1999/45/EC and 67/548/EEC as amended and adapted.
Label requirements
Risk phrases
This product is not classified according to the EU regulations.
Other regulations
Inventories
Europe inventory: All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory (ENCS): At least one component is not listed.
Korea inventory (KECI): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
16 . Other information
History
Date of issue
18/09/2007.
Date of previous issue
06/08/2007.
Prepared by
Product Stewardship Group
Notice to reader
Indicates information that has changed from previously issued version.
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it
is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the
data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for
the stated application or applications without seeking advice from us.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not
be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at
work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this
sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions
that should be taken.
Product name
Version 2
Castrol Classic GP 50
Date of issue 18 September 2007
Product code 452484-GB05
Format United Kingdom
(UK)
Build 9.1.2
(United Kingdom)
Page: 4/4
Language ENGLISH
( ENGLISH )