Groundwater and Drinking Water Results

March 1, 2016
Jeannette DeBartolomeo
Environmental Compliance Specialist
MDE-OCP
1800 Washington Blvd.
Suite 620
Baltimore, MD 21230
RE:
Groundwater and Drinking Water Results
Calvert Citgo (Former Alger County Store)
2815 North East Road, North East, MD
2802 Northeast Road (Harrison Residence)
2794 Northeast Road (O’Brien’s Residence)
North East, Maryland 21901
Facility No. 5678
REPSG Project Reference No. 005977.130.01
Dear Ms. DeBartolomeo,
Attached please find the groundwater results and drinking water results for the Calvert Citgo Site located
at 2815 Northeast Road (case NO.: 1992-2616-CE) as well as the drinking water results for the O’Brien
and Harrison Residences, located at 2802 and 2794 Northeast Road in Northeast Maryland related to case
NO.: 1992-2616-CE. These results are for the January 2016 groundwater and drinking water events. As
requested, tabulated groundwater level data collected for the most recent four quarters of sampling, is also
included in this packet.
The results of the drinking water analysis are compared against the drinking water standards set by the
U.S. Environmental Protection Agency (USEPA), which sets legal limits that certain compounds in
drinking water should meet in order to be protective of human health. Not all compounds analyzed for in
drinking water samples have standards set by the USEPA. Moving forward, MTBE for which no standard
is set by the EPA, will be compared against the MDE’s recommended control level of 20 parts per billion.
If you have any questions or concerns, please do not hesitate to contact our office at 215-729-3220.
Sincerely,
Suzanne Shourds
Project Manager
React Environmental Professional Services Group, Inc
enclosures
Commercial Property
(Vacant)
Commercial Property
(Real Estate Office)
2802 Northeast Rd.
Residence
Gasoline UST Field
(One 8,000-gallon and
one 12,000-gallon UST)
ND
YL A
M AR TE 2 7 2
ROU
Kerosene Pump
Convenience
Store
Diesel
Fuel Pump
Island
2794 Northeast Rd.
Residence
Diesel/Kerosene UST
(12,000-gallon)
Approximate Location
of Septic Tank
Gasoline
Fuel Pump
Island
NE )
LA 272
ER T E
AK O U
QU D R
L
(O
BRICK
MEETINGHOUSE
ROAD
MARYLAND
ROUTE 272
QUAKER LANE
(OLD ROUTE 272)
Figure 2: Site Diagram
Site Boundary
PROJECT NAME: CALVERT CITGO
PROJECT ADDRESS: 2815 NORTH EAST ROAD, NORTH EAST, MD
MAP SCALE:
0
20
40
PROJECT NUMBER: 005977
1 inch = 100 feet
80
120
160
Feet
DATE: DECEMBER 2010
¨
MW-003R
MW-004
MW-003
MP-002
MW-010
MP-001
MW-007
MW-008
!
A
!
A
!
A
MW-008D
!
!
!
A
MW-010D
! A
!
A
!
!A
A
!A
!
A
MW-009D
!A
!
A
MW-005R
ND
YLA
MAR TE 272
RO U
MW-005
!
A
MW-001
MW-009
! A
!
A
!
A
MW-001R
MW-002
MW-006
NE )
LA 272
ER TE
AK OU
QU D R
L
(O
BRICK
MEETINGHOUSE
ROAD
MARYLAND
ROUTE 272
QUAKER LANE
(OLD ROUTE 272)
Monitoring Well Locations
A
!
!
A
Lost/Abandoned Monitoring Well
Leak Detection Wells
Monitoring Well
PROJECT NAME: CALVERT CITGO
!
?
Potable Well
Off-Site Bulding
Kerosene Pump
Site Boundary
Diesel Pump
PROJECT ADDRESS: 2815 NORTH EAST ROAD, NORTH EAST, MD
MAP SCALE:
0
15
30
1 inch = 75 feet
60
90
PROJECT NUMBER: 005977
120
Feet
DATE: MAY 2014
Septic Tank
¨
2
R
MW-003R
(401.3)
Gasoline UST Field
(One 8,000-gallon and
one 12,000-gallon UST)
MW-004
(LOST)
MW-003
(400.7)
MP-001
(408.2)
MP-002
(408.1)
MW-007
(400.9)
!
A
MW-005R
(399.9)
!
401
!
!
A
MW-005
(399.6)
.5
400
400
!
A
!
A
!
!A
A
MW-010D
(398.6)
9
39
!A
!
A
.5
! A
!
A
9
39
39
!A
!
A
Convenience
Store
MW-010
(398.7)
!
A
!
A
! A
!
A
MW-008D
(401.4)
MW-001
(397.8)
MW-008
(399.5)
MW-001R
(399.4)
MW-002
(398.6)
ND
YLA
MAR TE 272
RO U
NE )
LA 272
ER TE
AK OU
QU D R
L
(O
MW-006
(399.2)
Groundwater Directional Flow
GROUNDWATER CONTOUR MAP (January 19-21, 2016)
MW-001 Site ID
(176.01) Groundwater Elevation (feet above datum)
!
A
A
!
Monitoring Well
!
?
Lost/Abandoned Monitoring Well
Leak Detection Wells
Potable Well
Off-Site Bulding
Kerosene Pump
Site Boundary
Diesel Pump
PROJECT NAME: CALVERT CITGO
PROJECT ADDRESS: 2815 NORTH EAST ROAD, NORTH EAST, MD
MAP SCALE:
0
15
30
1 inch = 75 feet
60
90
PROJECT NUMBER: 005977
120
Feet
2794 North
Residence
MW-009D
(396.7)
8. 5
8
39
!
?
MW-009
(397.8)
DATE: JANUARY 2016
Groundwater Depth Interpolation Method: Local Polynomial Interpolation (Order of Polynomial: 1, Exploratory Trend Surface Analysis: 40)
Septic Tank
¨
MW-003R
(401.3)
Gasoline UST Field
(One 8,000-gallon and
one 12,000-gallon UST)
MW-004
(LOST)
MW-003
(400.7)
MP-001
(408.2)
MP-002
(408.1)
MW-010
(398.7)
MW-010D
(398.6)
MW-007
(400.9)
!
A
!
A
!
A
MW-005R
(399.9)
!
!
.8
.6
! A
!
A
!
?
!
A
MW-008D
(401.4)
!
A
ND
YLA
MAR TE 272
RO U
NE )
LA 272
ER TE
AK OU
QU D R
L
(O
Groundwater Directional Flow
GROUNDWATER CONTOUR MAP (Jan. 19-21, 2016; "D" Wells Only)
MW-001 Site ID
(176.01) Groundwater Elevation (feet above datum)
!
A
A
!
Monitoring Well
!
?
Lost/Abandoned Monitoring Well
Leak Detection Wells
PROJECT NAME: CALVERT CITGO
PROJECT ADDRESS: 2815 NORTH EAST ROAD, NORTH EAST, MD
MAP SCALE:
15
30
1 inch = 75 feet
60
90
PROJECT NUMBER: 005977
120
Feet
MW-009
(397.8)
MW-002
(398.6)
MW-001R
(399.4)
0
MW-009D
(396.7)
MW-008
(399.5)
MW-001
(397.8)
MW-006
(399.2)
39
7
!A
!
A
Convenience
Store
2794 North
Residence
39
7
39
9
40
0
!A
!
A
39
8
40
1
!
!A
A
.4
MW-005
(399.6)
! A
!
A
.2
!
A
DATE: JANUARY 2016
Groundwater Depth Interpolation Method: Radial Basis Function (Kernal Function: Completely Regularized Spline)
Potable Well
Off-Site Bulding
Kerosene Pump
Site Boundary
Diesel Pump
Septic Tank
¨
MP-002
Benzene [5]: 1290 [1Q 2015]
Methyl chloride [19]: 494 [1Q 2015]
Methyl tert-butyl ether [20]: 26.8 [1Q 2015]
Toluene [1000]: 3950 [1Q 2015]
MW-003R
Benzene [5]: 31.6 [1Q 2015]
Ethylbenzene [700]: 21.1 [1Q 2015]
Methyl tert-butyl ether [20]: 2.5 [1Q 2015]
Toluene [1000]: 25.9 [1Q 2015]
MP-001
Benzene [5]: 2030 [1Q 2015]
Methyl chloride [19]: 367 [1Q 2015]
Methyl tert-butyl ether [20]: 105 [1Q 2015]
Toluene [1000]: 6260 [1Q 2015]
MW-007
Benzene [5]: 509 [1Q 2015]
Ethylbenzene [700]: 293 [1Q 2015]
Methyl chloride [19]: 30.1 [1Q 2015]
Methyl tert-butyl ether [20]: 6.8 [1Q 2015]
Toluene [1000]: 5380 [1Q 2015]
MW-003
Benzene [5]: 115 [1Q 2015]
Ethylbenzene [700]: 986 [1Q 2015]
Methyl chloride [19]: 20.9J [1Q 2015]
Methyl tert-butyl ether [20]: 19J [1Q 2015]
Toluene [1000]: 320 [1Q 2015]
MW-004
!
A
!
A
!
A
! Concrete
A
Pad
Landscaped
Area
MW-005
Benzene [5]: 236 [1Q 2015]
Ethylbenzene [700]: 1690 [1Q 2015]
Methyl chloride [19]: 73.2 [1Q 2015]
Methyl tert-butyl ether [20]: 9.5J [1Q 2015]
Toluene [1000]: 10200 [1Q 2015]
!
A
!
A
!
!A
A
ND
Y LA
MAR TE 272
R OU
MW-005R
Benzene [5]: 4100 [1Q 2015]
Ethylbenzene [700]: 1320 [1Q 2015]
Methyl chloride [19]: 18J [1Q 2015]
Toluene [1000]: 21200 [1Q 2015]
Drive
Area
!A
!
A
Kerosene Pump
! A
!
A
MW-010
1,2-Dichloroethane [5]: 197 [1Q 2015]
Benzene [5]: 33.6 [1Q 2015]
Methyl tert-butyl ether [20]: 196 [1Q 2015]
Toluene [1000]: 2.9J [1Q 2015]
Pump Island
Canopy
!A
!
A
Convenience
Store
MW-001
Benzene [5]: 97.6 [1Q 2015]
Ethylbenzene [700]: 4.4 [1Q 2015]
Methyl tert-butyl ether [20]: 0.47J [1Q 2015]
Toluene [1000]: 17.6 [1Q 2015]
! A
!
A
!
?
!
A
DW-001
MW-001R
1,2-Dichloroethane [5]: 129 [1Q 2015]
Benzene [5]: 40.8 [1Q 2015]
Ethylbenzene [700]: 1.9J [1Q 2015]
Methyl tert-butyl ether [20]: 295 [1Q 2015]
Toluene [1000]: 10.4 [1Q 2015]
!
A
MW-010D
A
1,2-Dichloroethane [5]: 12.6 [1Q 2015]
Benzene [5]: 2.1 [1Q 2015]
Ethylbenzene [700]: 0.5J [1Q 2015]
Methyl tert-butyl ether [20]: 85.6 [1Q 2015]
Toluene [1000]: 4.6 [1Q 2015]
Diesel
Fuel Pump
Island
MW-009D
1,2-Dichloroethane [5]: 26.6 [1Q 2015]
Methyl tert-butyl ether [20]: 840 [1Q 2015]
Toluene [1000]: 4.6J [1Q 2015]
A
MW-009
Methyl tert-butyl ether [20]: 0.34J [1Q 2015]
Toluene [1000]: 0.85J [1Q 2015]
!
Diesel/Kerosene UST
(12,000-gallon)
A
MW-008D
Benzene [5]: 0.58J [1Q 2015]
Methyl chloride [19]: 0.32J [1Q 2015]
Toluene [1000]: 0.6J [1Q 2015]
Landscaped
Area
NE )
L A 2 72
ER E
A K UT
QU D R O
L
(O
MW-006
Benzene [5]: 1.3 [1Q 2015]
Ethylbenzene [700]: 2.1 [1Q 2015]
Methyl tert-butyl ether [20]: 0.74J [1Q 2015]
Toluene [1000]: 22.8 [1Q 2015]
MW-008
1,2-Dichloroethane [5]: 6.1 [1Q 2015]
Benzene [5]: 366 [1Q 2015]
Ethylbenzene [700]: 40.6 [1Q 2015]
Methyl tert-butyl ether [20]: 545 [1Q 2015]
Toluene [1000]: 10.2 [1Q 2015]
MW-002
Benzene [5]: 19 [1Q 2015]
Methyl tert-butyl ether [20]: 10.2 [1Q 2015]
GROUNDWATER CONTAMINANT DISTRIBUTION MAP (January 19-21, 2016)
LABEL LEGEND:
Concentration (ppb)
PROJECT NAME:
MAP SCALE: 1 inch = 50 feet
0 12.5 25
50
75
100
Feet
CALVERT CITGO
PROJECT ADDRESS:
2815 NORTH EAST ROAD, NORTH EAST, MD
DATE:
JANUARY 2016
PROJECT NUMBER:
005977
!
A
!
A
!
?
Leak Detection Wells
Kerosene Pump
Site Features
Monitoring Well
Septic Tank
Yard Boundary
Lost/Abandoned Monitoring Well
Potable Well
Diesel Pump
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Off-Site Bulding
Site Boundary
Buildings
Grassline
Tank Field
Roads
Sidewalk
Sample Date
B-017
Toluene (100): 270 [2Q 2004] / ND [3Q 2004]
Groundwater Cleanup
Standard (ppb)
ND - Concentration Not Detected Above Laboratory Reporting Limits
Exceedences of the Regulatory Standard Printed in bold
¨
<Table Name>
Fluid Levels Summary
Calvert Citgo 2815 Northeast Rd North East, Maryland
Well
MC* Unit
Ref. Elev.
Measure
Dry
REPSG Project No.: 005977
Water Depth Water Elev. Corrected Depth Corrected Elev. Depth of Well
Sample Dates: 04/27/2015-01/21/2016
LNAPL
Thickness
DNAPL
Thickness
Remark
2015 [Fourth Quarter]
Sample Date: 10/20/2015
MP-002
M
ft
416.0
Y
N
10.46
405.5
10.46
405.5
12.16
-
-
-
-
MW-003
M
ft
415.2
Y
N
16.84
398.4
16.84
398.4
31.54
-
-
-
-
MW-003R
M
ft
415.5
Y
N
19.39
396.1
19.39
396.1
25.03
-
-
-
-
MW-007
M
ft
416.9
Y
N
18.15
398.7
18.15
398.7
28.68
-
-
-
-
MW-009
M
ft
415.0
Y
N
18.80
396.2
18.80
396.2
30.14
-
-
-
-
MW-009D
M
ft
415.0
Y
N
19.30
395.7
19.30
395.7
66.69
-
-
-
-
MW-010
M
ft
415.1
Y
N
12.24
402.9
12.24
402.9
17.85
-
-
-
-
MW-010D
M
ft
415.1
Y
N
18.25
396.9
18.25
396.9
68.83
-
-
-
-
Sample Date: 10/21/2015
MP-001
M
ft
415.6
Y
N
9.990
405.6
9.990
405.6
12.66
-
-
-
-
MW-001
M
ft
415.6
Y
N
17.84
397.7
17.84
397.7
29.89
-
-
-
-
MW-001R
M
ft
415.2
Y
N
17.49
397.7
17.49
397.7
42.84
-
-
-
-
MW-005
M
ft
416.0
Y
N
17.90
398.1
17.90
398.1
29.97
-
-
-
-
MW-005R
M
ft
415.7
Y
N
17.59
398.1
17.59
398.1
25.07
-
-
-
-
MW-006
M
ft
415.7
Y
N
18.01
397.6
18.01
397.6
30.46
-
-
-
-
Sample Date: 10/22/2015
MW-002
M
ft
414.6
Y
N
17.65
397.0
17.65
397.0
29.36
-
-
-
-
MW-008
M
ft
415.6
Y
N
17.64
397.9
17.64
397.9
27.65
-
-
-
-
MW-008D
M
ft
415.4
Y
N
16.45
399.0
16.45
399.0
146.8
-
-
-
-
2015 [Second Quarter]
Sample Date: 04/27/2015
MP-001
M
ft
415.6
Y
N
4.910
410.6
4.910
410.6
11.71
-
-
-
-
MP-002
M
ft
416.0
Y
N
5.430
410.6
5.430
410.6
12.24
-
-
-
-
MW-002
M
ft
414.6
Y
N
15.42
399.2
15.42
399.2
31.52
-
-
-
-
MW-003
M
ft
415.2
Y
N
13.50
401.7
13.50
401.7
31.31
-
-
-
-
MW-003R
M
ft
415.5
Y
N
13.25
402.2
13.25
402.2
24.90
-
-
-
-
MW-005
M
ft
416.0
Y
N
15.34
400.7
15.34
400.7
29.80
-
-
-
-
Print Date: 03/01/2016
* Measurement Code: "M" = Measured; “N” = Not Measured; “MP” = Pre-Recovery Measurement; “MR” = Post-Recovery Measurement; “NF” = Not Found; “O” = Obstructed.
Page 1
of
4
<Table Name>
Fluid Levels Summary
Calvert Citgo 2815 Northeast Rd North East, Maryland
Well
MC* Unit
Ref. Elev.
Measure
Dry
REPSG Project No.: 005977
Water Depth Water Elev. Corrected Depth Corrected Elev. Depth of Well
Sample Dates: 04/27/2015-01/21/2016
LNAPL
Thickness
DNAPL
Thickness
Remark
2015 [Second Quarter]
Sample Date: 04/27/2015
MW-005R
M
ft
415.7
Y
N
15.12
400.6
15.12
400.6
25.07
-
-
-
-
MW-006
M
ft
415.7
Y
N
15.82
399.8
15.82
399.8
30.34
-
-
-
-
MW-007
M
ft
416.9
Y
N
15.94
400.9
15.94
400.9
28.69
-
-
-
-
415.4
Y
N
13.46
402.0
13.46
402.0
144.0
-
-
-
-
Sample Date: 04/28/2015
MW-008D
M
ft
Sample Date: 04/29/2015
MW-001
M
ft
415.6
Y
N
15.51
400.0
15.51
400.0
28.70
-
-
-
-
MW-001R
M
ft
415.2
Y
N
15.74
399.5
15.74
399.5
42.81
-
-
-
-
MW-009
M
ft
415.0
Y
N
16.82
398.2
16.82
398.2
30.16
-
-
-
-
MW-010
M
ft
415.1
Y
N
15.94
399.2
15.94
399.2
30.09
-
-
-
-
Sample Date: 05/01/2015
MW-008
M
ft
415.6
Y
N
16.01
399.5
16.01
399.5
72.93
-
-
-
-
MW-009D
M
ft
415.0
Y
N
16.79
398.2
16.79
398.2
67.90
-
-
-
-
MW-010D
M
ft
415.1
Y
N
15.72
399.4
15.72
399.4
69.28
-
-
-
-
2015 [Third Quarter]
Sample Date: 07/13/2015
MP-001
M
ft
415.6
Y
N
5.350
410.2
5.350
410.2
11.81
-
-
-
-
MP-002
M
ft
416.0
Y
N
5.710
410.3
5.710
410.3
12.28
-
-
-
-
MW-003
M
ft
415.2
Y
N
13.15
402.1
13.15
402.1
31.50
-
-
-
-
MW-003R
M
ft
415.5
Y
N
12.85
402.6
12.85
402.6
25.10
-
-
-
-
MW-005
M
ft
416.0
Y
N
14.94
401.1
14.94
401.1
29.90
-
-
-
-
MW-005R
M
ft
415.7
Y
N
14.55
401.2
14.55
401.2
25.09
-
-
-
-
MW-006
M
ft
415.7
Y
N
15.26
400.4
15.26
400.4
30.42
-
-
-
-
MW-007
M
ft
416.9
Y
N
14.45
402.4
14.45
402.4
28.75
-
-
-
-
415.6
Y
N
15.34
400.2
15.34
400.2
28.69
-
-
-
-
Sample Date: 07/14/2015
MW-001
M
ft
Print Date: 03/01/2016
* Measurement Code: "M" = Measured; “N” = Not Measured; “MP” = Pre-Recovery Measurement; “MR” = Post-Recovery Measurement; “NF” = Not Found; “O” = Obstructed.
Page 2
of
4
<Table Name>
Fluid Levels Summary
Calvert Citgo 2815 Northeast Rd North East, Maryland
Well
MC* Unit
Ref. Elev.
Measure
Dry
REPSG Project No.: 005977
Sample Dates: 04/27/2015-01/21/2016
Water Depth Water Elev. Corrected Depth Corrected Elev. Depth of Well
LNAPL
Thickness
DNAPL
Thickness
Remark
2015 [Third Quarter]
Sample Date: 07/14/2015
MW-001R
M
ft
415.2
Y
N
14.76
400.5
14.76
400.5
42.80
-
-
-
-
MW-002
M
ft
414.6
Y
N
14.72
399.9
14.72
399.9
31.49
-
-
-
-
MW-008
M
ft
415.6
Y
N
15.80
399.8
15.80
399.8
72.00
-
-
-
-
MW-009
M
ft
415.0
Y
N
16.80
398.2
16.80
398.2
30.06
-
-
-
-
Sample Date: 07/15/2015
MW-008D
M
ft
415.4
Y
N
13.11
402.3
13.11
402.3
140.0
-
-
-
-
MW-009D
M
ft
415.0
Y
N
16.80
398.2
16.80
398.2
67.00
-
-
-
-
MW-010
M
ft
415.1
Y
N
15.79
399.4
15.79
399.4
30.10
-
-
-
-
MW-010D
M
ft
415.1
Y
N
15.56
399.5
15.56
399.5
68.00
-
-
-
-
2016 [First Quarter]
Sample Date: 01/19/2016
MP-001
M
ft
415.6
Y
N
7.380
408.2
7.380
408.2
11.34
-
-
-
-
MP-002
M
ft
416.0
Y
N
7.920
408.1
7.920
408.1
12.15
-
-
-
-
MW-003
M
ft
415.2
Y
N
14.52
400.7
14.52
400.7
31.40
-
-
-
-
MW-003R
M
ft
415.5
Y
N
14.14
401.3
14.14
401.3
25.16
-
-
-
-
MW-005
M
ft
416.0
Y
N
16.40
399.6
16.40
399.6
29.88
-
-
-
-
MW-005R
M
ft
415.7
Y
N
15.78
399.9
15.78
399.9
25.33
-
-
-
-
MW-006
M
ft
415.7
Y
N
16.43
399.2
16.43
399.2
30.43
-
-
-
-
MW-007
M
ft
416.9
Y
N
16.03
400.9
16.03
400.9
28.74
-
-
-
-
MW-008
M
ft
415.6
Y
N
16.10
399.5
16.10
399.5
72.03
-
-
-
-
MW-008D
M
ft
415.4
Y
N
14.04
401.4
14.04
401.4
-
-
-
-
-
Sample Date: 01/20/2016
MW-001
M
ft
415.6
Y
N
17.75
397.8
17.75
397.8
28.66
-
-
-
-
MW-001R
M
ft
415.2
Y
N
15.84
399.4
15.84
399.4
26.98
-
-
-
-
MW-002
M
ft
414.6
Y
N
16.02
398.6
16.02
398.6
31.46
-
-
-
-
MW-009
M
ft
415.0
Y
N
17.19
397.8
17.19
397.8
30.09
-
-
-
-
MW-009D
M
ft
415.0
Y
N
18.26
396.7
18.26
396.7
66.58
-
-
-
-
Print Date: 03/01/2016
* Measurement Code: "M" = Measured; “N” = Not Measured; “MP” = Pre-Recovery Measurement; “MR” = Post-Recovery Measurement; “NF” = Not Found; “O” = Obstructed.
Page 3
of
4
<Table Name>
Fluid Levels Summary
Calvert Citgo 2815 Northeast Rd North East, Maryland
Well
MC* Unit
Ref. Elev.
Measure
Dry
REPSG Project No.: 005977
Water Depth Water Elev. Corrected Depth Corrected Elev. Depth of Well
Sample Dates: 04/27/2015-01/21/2016
LNAPL
Thickness
DNAPL
Thickness
Remark
2016 [First Quarter]
Sample Date: 01/21/2016
MW-010
M
ft
415.1
Y
N
16.47
398.7
16.47
398.7
30.03
-
-
-
-
MW-010D
M
ft
415.1
Y
N
16.52
398.6
16.52
398.6
67.89
-
-
-
-
Print Date: 03/01/2016
* Measurement Code: "M" = Measured; “N” = Not Measured; “MP” = Pre-Recovery Measurement; “MR” = Post-Recovery Measurement; “NF” = Not Found; “O” = Obstructed.
Page 4
of
4
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
MP-001
MP-002
MW-001
MW-001R
MW-002
01/19/2016
01/19/2016
01/20/2016
01/20/2016
01/20/2016
0
0
0
0
0
MW-003
01/19/2016
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------DBCP
ug/l
0.2
<30U#
<7.5U#
<1.5U#
<1.5U#
<1.5U#
<30U#
Dichlorofluoromethane
ug/l
**
<7.4U
<1.9U
<0.37U
<0.37U
<0.37U
<7.4U
Tert-Amyl Methyl Ether
ug/l
**
<4U
<1U
<0.2U
<0.2U
<0.2U
<4U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1,1-trichloroethane
ug/l
200
<4.4U
<1.1U
<0.22U
<0.22U
<0.22U
<4.4U
1,1,2,2-Tetrachloroethane
ug/l
0.053
<6.8U#
<1.7U#
<0.34U#
<0.34U#
<0.34U#
<6.8U#
1,1,2-Trichloroethane
ug/l
5
<6.6U#
<1.7U
<0.33U
<0.33U
<0.33U
<6.6U#
1,1-Dichloroethane
ug/l
90
<5.6U
<1.4U
<0.28U
<0.28U
<0.28U
<5.6U
1,1-Dichloroethylene
ug/l
7
<5.8U
<1.5U
<0.29U
<0.29U
<0.29U
<5.8U
1,2-Dibromoethane
ug/l
0.05
<5.6U#
<1.4U#
<0.28U#
<0.28U#
<0.28U#
<5.6U#
1,2-Dichloroethane
ug/l
5
33.7
<1.6U
0.72J
47.1
<0.32U
<6.4U#
1,2-Dichloropropane
ug/l
5
<4.8U
<1.2U
<0.24U
0.33J
<0.24U
<4.8U
2-Hexanone
ug/l
**
<26U
<6.5U
<1.3U
<1.3U
<1.3U
<26U
Acetone
ug/l
550
<62U
<15.5U
<3.1U
<3.1U
<3.1U
<62U
Benzene
ug/l
5
<4.6U
1290
110
62.5
24.3
1310
Bromodichloromethane
ug/l
80
<5.4U
<1.4U
<0.27U
<0.27U
<0.27U
<5.4U
Bromoform
ug/l
80
<8U
<2U
<0.4U
<0.4U
<0.4U
<8U
Carbon disulfide
ug/l
100
<4.6U
<1.2U
<0.23U
<0.23U
<0.23U
<4.6U
Carbon tetrachloride
ug/l
5
<6.2U#
<1.6U
<0.31U
<0.31U
<0.31U
<6.2U#
Print Date: 02/01/2016
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
MP-001
MP-002
MW-001
MW-001R
MW-002
01/19/2016
01/19/2016
01/20/2016
01/20/2016
01/20/2016
MW-003
0
0
0
0
0
0
<3.8U
<0.95U
<0.19U
<0.19U
<0.19U
<3.8U
01/19/2016
Chlorobenzene
ug/l
Chlorobromomethane
ug/l
**
<6.4U
<1.6U
<0.32U
<0.32U
<0.32U
<6.4U
Chloroethane
ug/l
3.6
<6.6U#
<1.7U
<0.33U
0.36J
<0.33U
<6.6U#
Chloroform
ug/l
80
11.1J
<1.1U
<0.21U
<0.21U
<0.21U
15.3J
cis-1,2-Dichloroethylene
ug/l
70
<6.4U
<1.6U
<0.32U
<0.32U
<0.32U
<6.4U
cis-1,3-Dichloropropene
ug/l
0.44
<6.2U#
<1.6U#
<0.31U
<0.31U
<0.31U
<6.2U#
Dibromochloromethane
ug/l
80
<9U
<2.3U
<0.45U
<0.45U
<0.45U
<9U
Dichlorodifluoromethane
ug/l
**
<6.6U
<1.7U
<0.33U
<0.33U
<0.33U
<6.6U
Ethyl tert-butyl ether
ug/l
**
<3.8U
<0.95U
<0.19U
<0.19U
<0.19U
<3.8U
Ethylbenzene
ug/l
700
11.2J
<1.7U
4.4
1.9
<0.34U
<6.8U
Isopropyl Ether
ug/l
**
<5U
13.7
0.74J
6.6
<0.25U
29.4
m/p-xylene
ug/l
**
51.6
591
13.8
5
0.87J
681
Methyl bromide
ug/l
0.85
<7.8U#
<2U#
<0.39U
<0.39U
<0.39U
<7.8U#
Methyl chloride
ug/l
19
<6.2U
<1.6U
1.3
1.5
<0.31U
<6.2U
Methyl ethyl ketone
ug/l
700
<36U
<9U
<1.8U
<1.8U
<1.8U
<36U
Methyl isobutylketone (MIBK)
ug/l
630
<30U
<7.5U
<1.5U
<1.5U
<1.5U
<30U
Methyl tert-butyl ether
ug/l
20
1060
5.4
0.99J
15.2
16.2
18.6J
Methylene chloride
ug/l
5
<9U#
<2.3U
<0.45U
<0.45U
<0.45U
<9U#
o-Xylene
ug/l
**
14.2J
255
3.9
2.7
0.55J
272
Styrene
ug/l
100
<4.8U
<1.2U
<0.24U
<0.24U
<0.24U
<4.8U
Tert-Amyl alcohol
ug/l
**
196J
1080
267
1210
<6.6U
1030
100
Print Date: 02/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
MP-001
MP-002
MW-001
MW-001R
MW-002
01/19/2016
01/19/2016
01/20/2016
01/20/2016
01/20/2016
MW-003
0
0
0
0
0
0
<5.8U
<1.5U
<0.29U
<0.29U
<0.29U
<5.8U
01/19/2016
Tert-Amyl Ethyl Ether
ug/l
**
tert-Butylalcohol
ug/l
**
7050
588
32.8
290
21.4
491
Tetrachloroethylene
ug/l
5
<7U#
<1.8U
<0.35U
<0.35U
<0.35U
<7U#
Toluene
ug/l
1000
10.1J
5910
2.7
4.7
<0.23U
365
trans-1,2-Di-chloroethylene
ug/l
100
<5.2U
<1.3U
<0.26U
<0.26U
<0.26U
<5.2U
trans-1,3-Dichloropropene
ug/l
0.44
<5.8U#
<1.5U#
<0.29U
<0.29U
<0.29U
<5.8U#
Trichloroethylene
ug/l
5
<6.6U#
<1.7U
<0.33U
<0.33U
<0.33U
<6.6U#
Vinyl chloride
ug/l
2
<6U#
<1.5U
<0.3U
<0.3U
<0.3U
<6U#
Xylene (total)
ug/l
10000
65.8
846
17.7
7.7
1.4J
953
Constituent
Unit
*Standard
Location:
MW-003R
MW-005
MW-005R
MW-006
MW-007
Date:
01/19/2016
01/19/2016
01/19/2016
01/19/2016
01/19/2016
0
0
0
0
0
Depth (ft):
MW-008
01/19/2016
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------DBCP
ug/l
0.2
<1.5U#
<150U#
<150U#
<1.5U#
<150U#
<7.5U#
Dichlorofluoromethane
ug/l
**
<0.37U
<37U
<37U
<0.37U
<37U
<1.9U
Tert-Amyl Methyl Ether
ug/l
**
<0.2U
<20U
<20U
<0.2U
<20U
<1U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1,1-trichloroethane
ug/l
200
<0.22U
<22U
<22U
<0.22U
<22U
<1.1U
1,1,2,2-Tetrachloroethane
ug/l
0.053
<0.34U#
<34U#
<34U#
<0.34U#
<34U#
<1.7U#
Print Date: 02/01/2016
Page 3
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
MW-003R
MW-005
MW-005R
MW-006
MW-007
Date:
01/19/2016
01/19/2016
01/19/2016
01/19/2016
01/19/2016
0
0
0
0
0
0
<33U#
<33U#
<0.33U
<33U#
<1.7U
<1.4U
Depth (ft):
MW-008
01/19/2016
1,1,2-Trichloroethane
ug/l
5
<0.33U
1,1-Dichloroethane
ug/l
90
<0.28U
<28U
<28U
<0.28U
<28U
1,1-Dichloroethylene
ug/l
7
<0.29U
<29U#
<29U#
<0.29U
<29U#
<1.5U
1,2-Dibromoethane
ug/l
0.05
<0.28U#
<28U#
<28U#
<0.28U#
<28U#
<1.4U#
1,2-Dichloroethane
ug/l
5
<0.32U
<32U#
<32U#
<0.32U
<32U#
<1.6U
1,2-Dichloropropane
ug/l
5
<0.24U
<24U#
<24U#
<0.24U
<24U#
<1.2U
2-Hexanone
ug/l
**
<1.3U
<130U
<130U
<1.3U
<130U
<6.5U
Acetone
ug/l
550
<3.1U
<310U
<310U
<3.1U
<310U
<15.5U
Benzene
ug/l
5
82.9
263
2550
0.3J
180
61.3
Bromodichloromethane
ug/l
80
<0.27U
<27U
<27U
<0.27U
<27U
<1.4U
Bromoform
ug/l
80
<0.4U
<40U
<40U
<0.4U
<40U
<2U
Carbon disulfide
ug/l
100
<0.23U
<23U
<23U
<0.23U
<23U
<1.2U
Carbon tetrachloride
ug/l
5
<0.31U
<31U#
<31U#
<0.31U
<31U#
<1.6U
Chlorobenzene
ug/l
100
<0.19U
<19U
<19U
1.4
<19U
<0.95U
Chlorobromomethane
ug/l
**
<0.32U
<32U
<32U
<0.32U
<32U
<1.6U
Chloroethane
ug/l
3.6
<0.33U
<33U#
<33U#
<0.33U
<33U#
<1.7U
Chloroform
ug/l
80
<0.21U
63.8J
73J
<0.21U
56.2J
4.9J
cis-1,2-Dichloroethylene
ug/l
70
<0.32U
<32U
<32U
<0.32U
<32U
<1.6U
cis-1,3-Dichloropropene
ug/l
0.44
<0.31U
<31U#
<31U#
<0.31U
<31U#
<1.6U#
Dibromochloromethane
ug/l
80
<0.45U
<45U
<45U
<0.45U
<45U
<2.3U
Dichlorodifluoromethane
ug/l
**
<0.33U
<33U
<33U
<0.33U
<33U
<1.7U
Print Date: 02/01/2016
Page 4
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
MW-003R
MW-005
MW-005R
MW-006
MW-007
Date:
01/19/2016
01/19/2016
01/19/2016
01/19/2016
01/19/2016
0
0
0
0
0
0
<0.19U
<19U
<19U
<0.19U
<19U
1.6J
Depth (ft):
MW-008
01/19/2016
Ethyl tert-butyl ether
ug/l
**
Ethylbenzene
ug/l
700
8.4
2310
1400
2.1
336
8
Isopropyl Ether
ug/l
**
28.1
34.5J
<25U
<0.25U
<25U
6.5
m/p-xylene
ug/l
**
27.6
7780
5150
9.9
596
9.9J
Methyl bromide
ug/l
0.85
<0.39U
<39U#
<39U#
<0.39U
<39U#
<2U#
Methyl chloride
ug/l
19
<0.31U
<31U#
<31U#
<0.31U
<31U#
9.1
Methyl ethyl ketone
ug/l
700
<1.8U
<180U
<180U
<1.8U
<180U
<9U
Methyl isobutylketone (MIBK)
ug/l
630
<1.5U
<150U
<150U
<1.5U
<150U
<7.5U
Methyl tert-butyl ether
ug/l
20
24.4
48.6J
38.7J
0.95J
<33U#
222
Methylene chloride
ug/l
5
<0.45U
<45U#
<45U#
0.57J
65.8J
<2.3U
o-Xylene
ug/l
**
6.6
2970
2310
3
517
4.1J
Styrene
ug/l
100
<0.24U
<24U
<24U
<0.24U
<24U
<1.2U
Tert-Amyl alcohol
ug/l
**
224
<660U
<660U
<6.6U
<660U
217
Tert-Amyl Ethyl Ether
ug/l
**
<0.29U
<29U
<29U
<0.29U
<29U
<1.5U
tert-Butylalcohol
ug/l
**
132
<220U
330J
<2.2U
<220U
122
Tetrachloroethylene
ug/l
5
<0.35U
<35U#
<35U#
<0.35U
<35U#
<1.8U
Toluene
ug/l
1000
6.5
4290
10900
0.62J
4510
5.7
trans-1,2-Di-chloroethylene
ug/l
100
<0.26U
<26U
<26U
<0.26U
<26U
<1.3U
trans-1,3-Dichloropropene
ug/l
0.44
<0.29U
<29U#
<29U#
<0.29U
<29U#
<1.5U#
Trichloroethylene
ug/l
5
<0.33U
<33U#
<33U#
<0.33U
<33U#
<1.7U
Vinyl chloride
ug/l
2
<0.3U
<30U#
<30U#
<0.3U
<30U#
<1.5U
Print Date: 02/01/2016
Page 5
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
MW-003R
MW-005
MW-005R
MW-006
MW-007
Date:
01/19/2016
01/19/2016
01/19/2016
01/19/2016
01/19/2016
0
0
0
0
0
0
34.2
10700
7470
12.9
1110
14J
Depth (ft):
Xylene (total)
Constituent
ug/l
Unit
10000
*Standard
Location:
MW-008D
MW-009
MW-009D
MW-010
Date:
01/19/2016
01/20/2016
01/20/2016
01/21/2016
0
0
0
0
Depth (ft):
MW-008
01/19/2016
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------DBCP
ug/l
0.2
<1.5U#
<1.5U#
<30U#
<7.5U#
Dichlorofluoromethane
ug/l
**
<0.37U
<0.37U
<7.4U
<1.9U
Tert-Amyl Methyl Ether
ug/l
**
<0.2U
<0.2U
<4U
<1U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1,1-trichloroethane
ug/l
200
<0.22U
<0.22U
<4.4U
<1.1U
1,1,2,2-Tetrachloroethane
ug/l
0.053
<0.34U#
<0.34U#
<6.8U#
<1.7U#
1,1,2-Trichloroethane
ug/l
5
<0.33U
<0.33U
<6.6U#
<1.7U
1,1-Dichloroethane
ug/l
90
<0.28U
<0.28U
<5.6U
<1.4U
1,1-Dichloroethylene
ug/l
7
<0.29U
<0.29U
<5.8U
<1.5U
1,2-Dibromoethane
ug/l
0.05
<0.28U#
<0.28U#
<5.6U#
<1.4U#
1,2-Dichloroethane
ug/l
5
<0.32U
<0.32U
<6.4U#
248
1,2-Dichloropropane
ug/l
5
<0.24U
<0.24U
<4.8U
<1.2U
2-Hexanone
ug/l
**
<1.3U
<1.3U
<26U
<6.5U
Acetone
ug/l
550
6.4J
<3.1U
<62U
<15.5U
Print Date: 02/01/2016
Page 6
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
MW-008D
MW-009
MW-009D
MW-010
Date:
01/19/2016
01/20/2016
01/20/2016
01/21/2016
0
0
0
0
Depth (ft):
Benzene
ug/l
5
0.4J
<0.23U
127
26.8
Bromodichloromethane
ug/l
80
<0.27U
<0.27U
<5.4U
<1.4U
Bromoform
ug/l
80
<0.4U
<0.4U
<8U
<2U
Carbon disulfide
ug/l
100
<0.23U
<0.23U
<4.6U
<1.2U
Carbon tetrachloride
ug/l
5
<0.31U
<0.31U
<6.2U#
<1.6U
Chlorobenzene
ug/l
100
<0.19U
<0.19U
<3.8U
<0.95U
Chlorobromomethane
ug/l
**
<0.32U
<0.32U
<6.4U
<1.6U
Chloroethane
ug/l
3.6
<0.33U
<0.33U
<6.6U#
<1.7U
Chloroform
ug/l
80
<0.21U
<0.21U
15.4J
<1.1U
cis-1,2-Dichloroethylene
ug/l
70
<0.32U
<0.32U
<6.4U
<1.6U
cis-1,3-Dichloropropene
ug/l
0.44
<0.31U
<0.31U
<6.2U#
<1.6U#
Dibromochloromethane
ug/l
80
<0.45U
<0.45U
<9U
<2.3U
Dichlorodifluoromethane
ug/l
**
<0.33U
<0.33U
<6.6U
<1.7U
Ethyl tert-butyl ether
ug/l
**
<0.19U
<0.19U
<3.8U
<0.95U
Ethylbenzene
ug/l
700
<0.34U
<0.34U
1050
<1.7U
Isopropyl Ether
ug/l
**
<0.25U
<0.25U
14.9J
30.1
m/p-xylene
ug/l
**
<0.52U
<0.52U
4400
10
Methyl bromide
ug/l
0.85
<0.39U
<0.39U
<7.8U#
<2U#
Methyl chloride
ug/l
19
0.48J
<0.31U
<6.2U
<1.6U
Methyl ethyl ketone
ug/l
700
<1.8U
<1.8U
<36U
<9U
Methyl isobutylketone (MIBK)
ug/l
630
<1.5U
<1.5U
<30U
<7.5U
Print Date: 02/01/2016
Page 7
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 01/19/2016-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Voluntary Cleanup Program (VCP): Generic Numeric Cleanup Standards for Groundwater for Type I & II Aquifers, Tables 1 and 2 (March 2008).
Constituent
Unit
*Standard
Location:
MW-008D
MW-009
MW-009D
MW-010
Date:
01/19/2016
01/20/2016
01/20/2016
01/21/2016
0
0
0
0
20
<0.33U
0.75J
11.2J
254
Depth (ft):
Methyl tert-butyl ether
ug/l
Methylene chloride
ug/l
5
<0.45U
<0.45U
<9U#
<2.3U
o-Xylene
ug/l
**
<0.33U
<0.33U
1180
<1.7U
Styrene
ug/l
100
<0.24U
<0.24U
<4.8U
<1.2U
Tert-Amyl alcohol
ug/l
**
<6.6U
<6.6U
<132U
7170E
Tert-Amyl Ethyl Ether
ug/l
**
<0.29U
<0.29U
<5.8U
<1.5U
tert-Butylalcohol
ug/l
**
<2.2U
<2.2U
57.4J
1440
Tetrachloroethylene
ug/l
5
<0.35U
<0.35U
<7U#
<1.8U
Toluene
ug/l
1000
0.55J
<0.23U
391
18.2
trans-1,2-Di-chloroethylene
ug/l
100
<0.26U
<0.26U
<5.2U
<1.3U
trans-1,3-Dichloropropene
ug/l
0.44
<0.29U
<0.29U
<5.8U#
<1.5U#
Trichloroethylene
ug/l
5
<0.33U
<0.33U
<6.6U#
<1.7U
Vinyl chloride
ug/l
2
<0.3U
<0.3U
<6U#
<1.5U
Xylene (total)
ug/l
10000
<0.66U
<0.66U
5580
10J
Print Date: 02/01/2016
Page 8
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
January 29, 2016
Mr. James Manuel
REPSG
6901 Kingsessing Avenue
Philadelphia, PA 19142
Certificate of Analysis
Project Name:
Purchase Order:
2016-CALVERT CITGO
11789
Workorder:
2120204
Workorder ID: 2016-CALVERT CITGO/5977
Dear Mr. Manuel:
Enclosed are the analytical results for samples received by the laboratory on Friday, January 22, 2016.
The ALS Environmental laboratory in Middletown, Pennsylvania is a National Environmental Laboratory
Accreditation Program (NELAP) accredited laboratory and as such, certifies that all applicable test results meet the
requirements of NELAP.
If you have any questions regarding this certificate of analysis, please contact Ms. Susan J Scherer (Project
Coordinator) at (717) 944-5541.
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program and any
applicable state requirements. The test results meet requirements of the current NELAP standards or state
requirements, where applicable. For a specific list of accredited analytes, refer to the certifications section of the
ALS website at www.alsglobal.com/en/Our-Services/Life-Sciences/Environmental/Downloads.
This laboratory report may not be reproduced, except in full, without the written approval of ALS Environmental.
ALS Spring City: 10 Riverside Drive, Spring City, PA 19475 610-948-4903
CC: Ms. Natalie Griffith , Ms. S Shourds
This page is included as part of the Analytical Report and
Ms. Susan J Scherer
Project Coordinator
must be retained as a permanent record thereof.
Page 1 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
SAMPLE SUMMARY
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID
Sample ID
Matrix
Date Collected
Date Received
Collected By
2120204001
MP-001
Ground Water
1/19/2016 12:45
1/22/2016 20:35
Collected by Client
2120204002
MW-005R
Ground Water
1/19/2016 13:25
1/22/2016 20:35
Collected by Client
2120204003
MW-008
Ground Water
1/19/2016 13:40
1/22/2016 20:35
Collected by Client
2120204004
MW-008D
Ground Water
1/19/2016 14:20
1/22/2016 20:35
Collected by Client
2120204005
MW-005
Ground Water
1/19/2016 14:25
1/22/2016 20:35
Collected by Client
2120204006
MW-006
Ground Water
1/19/2016 14:36
1/22/2016 20:35
Collected by Client
2120204007
MW-001R
Ground Water
1/20/2016 10:53
1/22/2016 20:35
Collected by Client
2120204008
DUP-001
Ground Water
1/20/2016 00:00
1/22/2016 20:35
Collected by Client
2120204009
FB-001
Ground Water
1/19/2016 14:47
1/22/2016 20:35
Collected by Client
2120204010
TB-001
Ground Water
1/19/2016 00:00
1/22/2016 20:35
Collected by Client
2120204011
MW-010
Ground Water
1/21/2016 13:02
1/22/2016 20:35
Collected by Client
2120204012
MW-010D
Ground Water
1/21/2016 12:12
1/22/2016 20:35
Collected by Client
2120204013
MW-007
Ground Water
1/19/2016 11:10
1/22/2016 20:35
Collected by Client
2120204014
MW-003R
Ground Water
1/19/2016 11:30
1/22/2016 20:35
Collected by Client
2120204015
MP-002
Ground Water
1/19/2016 11:55
1/22/2016 20:35
Collected by Client
2120204016
MW-003
Ground Water
1/19/2016 12:30
1/22/2016 20:35
Collected by Client
2120204017
MW-001
Ground Water
1/20/2016 11:45
1/22/2016 20:35
Collected by Client
2120204018
MW-002
Ground Water
1/20/2016 13:00
1/22/2016 20:35
Collected by Client
2120204019
FB-002
Ground Water
1/20/2016 13:40
1/22/2016 20:35
Collected by Client
2120204020
MW-009D
Ground Water
1/20/2016 14:00
1/22/2016 20:35
Collected by Client
2120204021
MW-009
Ground Water
1/20/2016 14:45
1/22/2016 20:35
Collected by Client
2120204022
FB-003
Ground Water
1/21/2016 12:15
1/22/2016 20:35
Collected by Client
Page 2 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
SAMPLE SUMMARY
Workorder: 2120204 2016-CALVERT CITGO/5977
Notes
-- Samples collected by ALS personnel are done so in accordance with the procedures set forth in the ALS Field Sampling Plan (20 Field Services Sampling Plan).
-- All Waste Water analyses comply with methodology requirements of 40 CFR Part 136.
-- All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141.
-- Unless otherwise noted, all quantitative results for soils are reported on a dry weight basis.
-- The Chain of Custody document is included as part of this report.
-- All Library Search analytes should be regarded as tentative identifications based on the presumptive evidence of the mass spectra.
Concentrations reported are estimated values.
-- Parameters identified as "analyze immediately" require analysis within 15 minutes of collection. Any "analyze immediately" parameters
not listed under the header "Field Parameters" are preformed in the laboratory and are therefore analyzed out of hold time.
-- Method references listed on this report beginning with the prefix “S” followed by a method number (such as S2310B-97)
refer to methods from “Standard Methods for the Examination of Water and Wastewater”.
Standard Acronyms/Flags
J
Indicates an estimated value between the Method Detection Limit (MDL) and the Practical Quantitation Limit (PQL) for the analyte
U
Indicates that the analyte was Not Detected (ND)
N
Indicates presumptive evidence of the presence of a compound
MDL
Method Detection Limit
PQL
Practical Quantitation Limit
RDL
Reporting Detection Limit
ND
Not Detected - indicates that the analyte was Not Detected at the RDL
Cntr
Analysis was performed using this container
RegLmt Regulatory Limit
LCS
Laboratory Control Sample
MS
Matrix Spike
MSD
Matrix Spike Duplicate
DUP
Sample Duplicate
%Rec
Percent Recovery
RPD
Relative Percent Difference
LOD
DoD Limit of Detection
LOQ
DoD Limit of Quantitation
DL
DoD Detection Limit
I
Indicates reported value is greater than or equal to the Method Detection Limit (MDL) but less than the Report Detection Limit (RDL)
(S)
Surrogate Compound
NC
Not Calculated
*
Result outside of QC limits
Page 3 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
PROJECT SUMMARY
Workorder: 2120204 2016-CALVERT CITGO/5977
Sample Comments
Lab ID: 2120204001
Sample ID: MP-001
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204002
Sample ID: MW-005R
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204003
Sample ID: MW-008
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204005
Sample ID: MW-005
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204011
Sample ID: MW-010
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204013
Sample ID: MW-007
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204015
Sample ID: MP-002
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Methods for the analysis of volatile organics require that the sample be preserved to a pH less than 2 using HCl. This sample had a
pH greater than 2 when received by the lab.
Lab ID: 2120204016
Sample ID: MW-003
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204020
Sample ID: MW-009D
Sample Type: SAMPLE
The GCMS volatiles analysis was performed at a dilution due to the level of target compounds.
Lab ID: 2120204021
Sample ID: MW-009
Sample Type: SAMPLE
In the 8260 analysis, several compounds were recovered outside quality control criteria in the matrix spike and matrix spike
duplicate of this sample.
Page 4 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204001
Date Collected: 1/19/2016 12:45
Sample ID:
MP-001
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
20.0
200
20.0
20.0
20.0
20.0
20.0
20.0
200
200
20.0
20.0
20.0
20.0
20.0
20.0
20.0
140
62.0
4.0
132
5.8
4.6
6.4
5.4
8.0
7.8
36.0
44.0
4.6
6.2
3.8
9.0
6.6
4.2
6.2
30.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
100
20.0
100
5.6
6.6
5.6
6.4
5.8
6.4
5.2
7.4
4.8
6.2
5.8
5.0
3.8
6.8
26.0
6.6
30.0
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
196J
ND
ND
ND
ND
ND
ND
ND
7050
ND
ND
ND
ND
ND
11.1J
ND
ND
ND
ND
ND
33.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.2J
ND
1060
ND
J
J
J
Page 5 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204001
Date Collected: 1/19/2016 12:45
Sample ID:
MP-001
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
10.1J
65.8
ND
ND
ND
ND
14.2J
51.6
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
96.3
95.9
83.1
107
Flag
J
J
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
20.0
60.0
20.0
20.0
20.0
20.0
20.0
40.0
9.0
4.8
6.8
7.0
4.6
13.2
4.4
6.6
6.6
6.0
6.6
10.4
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
1/27/16 09:03
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 6 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204002
Date Collected: 1/19/2016 13:25
Sample ID:
MW-005R
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1000
100
1000
100
100
100
100
100
100
1000
1000
100
100
100
100
100
100
100
700
310
20.0
660
29.0
23.0
32.0
27.0
40.0
39.0
180
220
23.0
31.0
19.0
45.0
33.0
21.0
31.0
150
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
100
100
100
100
100
100
100
100
100
500
100
500
28.0
33.0
28.0
32.0
29.0
32.0
26.0
37.0
24.0
31.0
29.0
25.0
19.0
34.0
130
33.0
150
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
ND
ND
2550
ND
ND
ND
ND
ND
330J
ND
ND
ND
ND
ND
73.0J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1400
ND
38.7J
ND
J
J
J
Page 7 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204002
Date Collected: 1/19/2016 13:25
Sample ID:
MW-005R
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
10900
7470
ND
ND
ND
ND
2310
5150
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
95.1
100
82.8
105
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
300
100
100
100
100
100
200
45.0
24.0
34.0
35.0
23.0
66.0
22.0
33.0
33.0
30.0
33.0
52.0
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
1/27/16 05:57
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 8 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204003
Date Collected: 1/19/2016 13:40
Sample ID:
MW-008
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50.0
5.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
50.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
35.0
15.5
1.0
33.0
1.5
1.2
1.6
1.4
2.0
2.0
9.0
11.0
1.2
1.6
0.95
2.3
1.7
1.1
1.6
7.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25.0
5.0
25.0
1.4
1.7
1.4
1.6
1.5
1.6
1.3
1.9
1.2
1.6
1.5
1.3
0.95
1.7
6.5
1.7
7.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
217
ND
61.3
ND
ND
ND
ND
ND
122
ND
ND
ND
ND
ND
4.9J
9.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.5
1.6J
8.0
ND
222
ND
1
J
J
Page 9 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204003
Date Collected: 1/19/2016 13:40
Sample ID:
MW-008
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
5.7
14.0J
ND
ND
ND
ND
4.1J
9.9J
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
95.8
101
84.1
107
Flag
J
J
J
Flag
Units
RDL
MDL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
15.0
5.0
5.0
5.0
5.0
5.0
10.0
2.3
1.2
1.7
1.8
1.2
3.3
1.1
1.7
1.7
1.5
1.7
2.6
Units
%
%
%
%
Method
Matrix:
Prepared By
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
1/27/16 20:45
DD
DD
DD
DD
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 10 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204004
Date Collected: 1/19/2016 14:20
Sample ID:
MW-008D
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
6.4J
ND
ND
ND
0.40J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.48J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
J
J
2
1
Page 11 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204004
Date Collected: 1/19/2016 14:20
Sample ID:
MW-008D
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
0.55J
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
101
100
89.2
95.5
Flag
J
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
1/27/16 02:47
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 12 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204005
Date Collected: 1/19/2016 14:25
Sample ID:
MW-005
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1000
100
1000
100
100
100
100
100
100
1000
1000
100
100
100
100
100
100
100
700
310
20.0
660
29.0
23.0
32.0
27.0
40.0
39.0
180
220
23.0
31.0
19.0
45.0
33.0
21.0
31.0
150
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
100
100
100
100
100
100
100
100
100
500
100
500
28.0
33.0
28.0
32.0
29.0
32.0
26.0
37.0
24.0
31.0
29.0
25.0
19.0
34.0
130
33.0
150
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
ND
ND
263
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
63.8J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
34.5J
ND
2310
ND
48.6J
ND
J
J
J
Page 13 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204005
Date Collected: 1/19/2016 14:25
Sample ID:
MW-005
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
4290
10700
ND
ND
ND
ND
2970
7780
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
92.2
99.5
83.9
107
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
300
100
100
100
100
100
200
45.0
24.0
34.0
35.0
23.0
66.0
22.0
33.0
33.0
30.0
33.0
52.0
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
1/27/16 06:21
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 14 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204006
Date Collected: 1/19/2016 14:36
Sample ID:
MW-006
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
ND
ND
0.30J
ND
ND
ND
ND
ND
ND
ND
ND
1.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.1
ND
0.95J
ND
J
1
J
Page 15 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204006
Date Collected: 1/19/2016 14:36
Sample ID:
MW-006
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
0.57J
ND
ND
ND
0.62J
12.9
ND
ND
ND
ND
3.0
9.9
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
93.6
96.1
81.4
106
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
J
Flag
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
1/27/16 03:38
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 16 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204007
Date Collected: 1/20/2016 10:53
Sample ID:
MW-001R
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
500
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
330
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/28/16 04:57
1/28/16 04:57
1/27/16 07:30
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
1210
ND
62.5
ND
ND
ND
ND
ND
290
ND
ND
ND
ND
0.36J
ND
1.5
ND
ND
ND
ND
47.1
ND
ND
ND
ND
0.33J
ND
ND
6.6
ND
1.9
ND
15.2
ND
J
J
Page 17 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204007
Date Collected: 1/20/2016 10:53
Sample ID:
MW-001R
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
4.7
7.7
ND
ND
ND
ND
2.7
5.0
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
Toluene-d8 (S)
97.2
94.3
101
104
85.1
85.3
108
102
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
%
%
%
%
Limits
Method
62 - 133
62 - 133
79 - 114
79 - 114
78 - 116
78 - 116
76 - 127
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
1/28/16 04:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
Analyzed
By
Cntr
1/28/16 04:57
1/27/16 07:30
1/27/16 07:30
1/28/16 04:57
1/27/16 07:30
1/28/16 04:57
1/27/16 07:30
1/28/16 04:57
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
A
A
B
A
B
A
B
Ms. Susan J Scherer
Project Coordinator
Page 18 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204008
Date Collected: 1/20/2016 00:00
Sample ID:
DUP-001
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50.0
5.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
50.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
35.0
15.5
1.0
33.0
1.5
1.2
1.6
1.4
2.0
2.0
9.0
11.0
1.2
1.6
0.95
2.3
1.7
1.1
1.6
7.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25.0
5.0
25.0
1.4
1.7
1.4
1.6
1.5
1.6
1.3
1.9
1.2
1.6
1.5
1.3
0.95
1.7
6.5
1.7
7.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
1330
ND
64.9
ND
ND
ND
ND
ND
298
1.4J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
41.7
ND
ND
ND
ND
ND
ND
ND
6.3
ND
2.5J
ND
16.6
ND
J
J
Page 19 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204008
Date Collected: 1/20/2016 00:00
Sample ID:
DUP-001
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
5.5
9.8J
ND
ND
ND
ND
3.5J
6.3J
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
94.5
96.7
87.9
90.5
Flag
J
J
J
Flag
Units
RDL
MDL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
15.0
5.0
5.0
5.0
5.0
5.0
10.0
2.3
1.2
1.7
1.8
1.2
3.3
1.1
1.7
1.7
1.5
1.7
2.6
Units
%
%
%
%
Method
Matrix:
Prepared By
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Prepared
By
Ground Water
Analyzed
By
Cntr
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
Analyzed
By
Cntr
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
1/29/16 01:02
CJG
CJG
CJG
CJG
B
B
B
B
Ms. Susan J Scherer
Project Coordinator
Page 20 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204009
Date Collected: 1/19/2016 14:47
Sample ID:
FB-001
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
11.8
ND
ND
ND
ND
ND
ND
ND
ND
10.2
ND
ND
ND
ND
ND
ND
ND
0.43J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
J
Page 21 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204009
Date Collected: 1/19/2016 14:47
Sample ID:
FB-001
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
100
99.2
88
94.2
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
1/27/16 03:09
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 22 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204010
Date Collected: 1/19/2016 00:00
Sample ID:
TB-001
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
9.9J
ND
ND
ND
ND
ND
ND
ND
ND
5.7J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.64J
ND
ND
ND
J
J
Page 23 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204010
Date Collected: 1/19/2016 00:00
Sample ID:
TB-001
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
94.8
98.5
82.3
107
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
1/27/16 03:15
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 24 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204011
Date Collected: 1/21/2016 13:02
Sample ID:
MW-010
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
7170
ND
26.8
ND
ND
ND
ND
ND
1440
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50.0
5.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
50.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
35.0
15.5
1.0
33.0
1.5
1.2
1.6
1.4
2.0
2.0
9.0
11.0
1.2
1.6
0.95
2.3
1.7
1.1
1.6
7.5
ND
ND
ND
248
ND
ND
ND
ND
ND
ND
ND
30.1
ND
ND
ND
254
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25.0
5.0
25.0
1.4
1.7
1.4
1.6
1.5
1.6
1.3
1.9
1.2
1.6
1.5
1.3
0.95
1.7
6.5
1.7
7.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Page 25 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204011
Date Collected: 1/21/2016 13:02
Sample ID:
MW-010
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
18.2
10.0J
ND
ND
ND
ND
ND
10.0
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
102
100
80.4
111
Flag
J
Flag
Units
RDL
MDL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
15.0
5.0
5.0
5.0
5.0
5.0
10.0
2.3
1.2
1.7
1.8
1.2
3.3
1.1
1.7
1.7
1.5
1.7
2.6
Units
%
%
%
%
Method
Matrix:
Prepared By
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
1/27/16 09:49
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 26 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204012
Date Collected: 1/21/2016 12:12
Sample ID:
MW-010D
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
264
ND
0.29J
ND
ND
ND
ND
ND
94.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
14.0
ND
ND
ND
ND
ND
ND
ND
3.9
ND
0.34J
ND
144
ND
J
J
Page 27 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204012
Date Collected: 1/21/2016 12:12
Sample ID:
MW-010D
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
0.50J
ND
ND
ND
1.7
1.8J
ND
ND
ND
ND
0.60J
1.2J
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
97.2
101
81.7
108
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
J
J
J
Flag
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
1/27/16 04:01
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 28 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204013
Date Collected: 1/19/2016 11:10
Sample ID:
MW-007
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1000
100
1000
100
100
100
100
100
100
1000
1000
100
100
100
100
100
100
100
700
310
20.0
660
29.0
23.0
32.0
27.0
40.0
39.0
180
220
23.0
31.0
19.0
45.0
33.0
21.0
31.0
150
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
100
100
100
100
100
100
100
100
100
500
100
500
28.0
33.0
28.0
32.0
29.0
32.0
26.0
37.0
24.0
31.0
29.0
25.0
19.0
34.0
130
33.0
150
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
ND
ND
180
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
56.2J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
336
ND
ND
ND
J
Page 29 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204013
Date Collected: 1/19/2016 11:10
Sample ID:
MW-007
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
65.8J
ND
ND
ND
4510
1110
ND
ND
ND
ND
517
596
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
94
99.1
84.3
107
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
100
100
100
100
100
300
100
100
100
100
100
200
45.0
24.0
34.0
35.0
23.0
66.0
22.0
33.0
33.0
30.0
33.0
52.0
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Flag
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
1/27/16 06:44
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 30 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204014
Date Collected: 1/19/2016 11:30
Sample ID:
MW-003R
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
224
ND
82.9
ND
ND
ND
ND
ND
132
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
28.1
ND
8.4
ND
24.4
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Page 31 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204014
Date Collected: 1/19/2016 11:30
Sample ID:
MW-003R
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
6.5
34.2
ND
ND
ND
ND
6.6
27.6
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
94.6
97.7
83
111
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
1/27/16 04:24
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 32 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204015
Date Collected: 1/19/2016 11:55
Sample ID:
MP-002
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
1080
ND
1290
ND
ND
ND
ND
ND
588
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50.0
5.0
50.0
5.0
100
5.0
5.0
5.0
5.0
50.0
50.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
35.0
15.5
1.0
33.0
1.5
23.0
1.6
1.4
2.0
2.0
9.0
11.0
1.2
1.6
0.95
2.3
1.7
1.1
1.6
7.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
13.7
ND
ND
ND
5.4
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
25.0
5.0
25.0
1.4
1.7
1.4
1.6
1.5
1.6
1.3
1.9
1.2
1.6
1.5
1.3
0.95
1.7
6.5
1.7
7.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/28/16 05:42
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Page 33 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204015
Date Collected: 1/19/2016 11:55
Sample ID:
MP-002
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
5910
846
ND
ND
ND
ND
255
591
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
Toluene-d8 (S)
91.8
92.5
101
103
86.3
85.2
112
97.5
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
5.0
5.0
5.0
100
15.0
5.0
5.0
5.0
5.0
5.0
10.0
2.3
1.2
1.7
1.8
23.0
3.3
1.1
1.7
1.7
1.5
1.7
2.6
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
%
%
%
%
Limits
Method
62 - 133
62 - 133
79 - 114
79 - 114
78 - 116
78 - 116
76 - 127
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/28/16 05:42
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
1/27/16 09:26
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
B
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 09:26
1/28/16 05:42
1/28/16 05:42
1/27/16 09:26
1/27/16 09:26
1/28/16 05:42
1/27/16 09:26
1/28/16 05:42
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
B
B
A
A
B
A
B
Ms. Susan J Scherer
Project Coordinator
Page 34 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204016
Date Collected: 1/19/2016 12:30
Sample ID:
MW-003
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
20.0
200
20.0
20.0
20.0
20.0
20.0
20.0
200
200
20.0
20.0
20.0
20.0
20.0
20.0
20.0
140
62.0
4.0
132
5.8
4.6
6.4
5.4
8.0
7.8
36.0
44.0
4.6
6.2
3.8
9.0
6.6
4.2
6.2
30.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
100
20.0
100
5.6
6.6
5.6
6.4
5.8
6.4
5.2
7.4
4.8
6.2
5.8
5.0
3.8
6.8
26.0
6.6
30.0
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
1030
ND
1310
ND
ND
ND
ND
ND
491
ND
ND
ND
ND
ND
15.3J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
29.4
ND
ND
ND
18.6J
ND
J
J
Page 35 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204016
Date Collected: 1/19/2016 12:30
Sample ID:
MW-003
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
365
953
ND
ND
ND
ND
272
681
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
Toluene-d8 (S)
93.3
91.1
105
103
82.7
90.5
108
98.9
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
100
60.0
20.0
20.0
20.0
20.0
20.0
40.0
9.0
4.8
6.8
7.0
23.0
13.2
4.4
6.6
6.6
6.0
6.6
10.4
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
%
%
%
%
Limits
Method
62 - 133
62 - 133
79 - 114
79 - 114
78 - 116
78 - 116
76 - 127
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/28/16 06:05
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
1/27/16 08:16
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
B
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 08:16
1/28/16 06:05
1/28/16 06:05
1/27/16 08:16
1/27/16 08:16
1/28/16 06:05
1/27/16 08:16
1/28/16 06:05
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
B
B
A
A
B
A
B
Ms. Susan J Scherer
Project Coordinator
Page 36 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204017
Date Collected: 1/20/2016 11:45
Sample ID:
MW-001
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
267
ND
110
ND
ND
ND
ND
ND
32.8
ND
ND
ND
ND
ND
ND
1.3
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ND
ND
ND
0.72J
ND
ND
ND
ND
ND
ND
ND
0.74J
ND
4.4
ND
0.99J
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
J
J
J
Page 37 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204017
Date Collected: 1/20/2016 11:45
Sample ID:
MW-001
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
2.7
17.7
ND
ND
ND
ND
3.9
13.8
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
90.3
100
90.3
98.1
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
B
B
B
B
B
B
B
B
B
B
B
B
Analyzed
By
Cntr
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
1/28/16 05:19
CJG
CJG
CJG
CJG
B
B
B
B
Ms. Susan J Scherer
Project Coordinator
Page 38 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204018
Date Collected: 1/20/2016 13:00
Sample ID:
MW-002
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
ND
ND
24.3
ND
ND
ND
ND
ND
21.4
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.2
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Page 39 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204018
Date Collected: 1/20/2016 13:00
Sample ID:
MW-002
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
1.4J
ND
ND
ND
ND
0.55J
0.87J
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
96.3
96.4
85.5
107
Flag
J
J
J
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
1/27/16 04:48
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 40 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204019
Date Collected: 1/20/2016 13:40
Sample ID:
FB-002
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
11.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.93J
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
J
Page 41 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204019
Date Collected: 1/20/2016 13:40
Sample ID:
FB-002
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
94.5
97.4
81.9
107
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
1/27/16 02:52
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 42 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204020
Date Collected: 1/20/2016 14:00
Sample ID:
MW-009D
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
200
20.0
200
20.0
20.0
20.0
20.0
20.0
20.0
200
200
20.0
20.0
20.0
20.0
20.0
20.0
20.0
140
62.0
4.0
132
5.8
4.6
6.4
5.4
8.0
7.8
36.0
44.0
4.6
6.2
3.8
9.0
6.6
4.2
6.2
30.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
100
20.0
100
5.6
6.6
5.6
6.4
5.8
6.4
5.2
7.4
4.8
6.2
5.8
5.0
3.8
6.8
26.0
6.6
30.0
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
ND
ND
ND
ND
127
ND
ND
ND
ND
ND
57.4J
ND
ND
ND
ND
ND
15.4J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
14.9J
ND
1050
ND
11.2J
ND
J
J
J
J
Page 43 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204020
Date Collected: 1/20/2016 14:00
Sample ID:
MW-009D
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
391
5580
ND
ND
ND
ND
1180
4400
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
96.1
96.9
83.6
106
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20.0
20.0
20.0
20.0
20.0
60.0
20.0
20.0
20.0
20.0
20.0
40.0
9.0
4.8
6.8
7.0
4.6
13.2
4.4
6.6
6.6
6.0
6.6
10.4
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
1/27/16 08:39
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 44 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204021
Date Collected: 1/20/2016 14:45
Sample ID:
MW-009
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.75J
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Results
Flag
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
J
Page 45 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204021
Date Collected: 1/20/2016 14:45
Sample ID:
MW-009
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
96.7
97.2
84.3
108
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
CJG
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
1/27/16 05:11
CJG
CJG
CJG
CJG
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 46 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204022
Date Collected: 1/21/2016 12:15
Sample ID:
FB-003
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
7.0
3.1
0.20
6.6
0.29
0.23
0.32
0.27
0.40
0.39
1.8
2.2
0.23
0.31
0.19
0.45
0.33
0.21
0.31
1.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
0.28
0.33
0.28
0.32
0.29
0.32
0.26
0.37
0.24
0.31
0.29
0.25
0.19
0.34
1.3
0.33
1.5
Matrix:
Prepared By
Ground Water
Analyzed
By
Cntr
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl tert-butyl ether
Ethylbenzene
2-Hexanone
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
12.3
ND
ND
ND
ND
ND
ND
ND
ND
5.7J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.91J
ND
ND
ND
1
J
J
Page 47 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120204 2016-CALVERT CITGO/5977
Lab ID:
2120204022
Date Collected: 1/21/2016 12:15
Sample ID:
FB-003
Date Received: 1/22/2016 20:35
Parameters
Results
Methylene Chloride
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Total Xylenes
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
99.8
98.1
86.3
107
Flag
Flag
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1.0
1.0
1.0
1.0
1.0
3.0
1.0
1.0
1.0
1.0
1.0
2.0
0.45
0.24
0.34
0.35
0.23
0.66
0.22
0.33
0.33
0.30
0.33
0.52
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Units
%
%
%
%
Limits
Method
62 - 133
79 - 114
78 - 116
76 - 127
SW846 8260B
SW846 8260B
SW846 8260B
SW846 8260B
Matrix:
Prepared By
Prepared
By
Ground Water
Analyzed
By
Cntr
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
DD
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
1/27/16 14:59
DD
DD
DD
DD
A
A
A
A
Ms. Susan J Scherer
Project Coordinator
Page 48 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
PARAMETER QUALIFIERS
Lab ID
#
Sample ID
Analytical Method
Analyte
2120204003
1
MW-008
SW846 8260B
tert-Amyl Alcohol
The QC sample type LCS for method SW846 8260B was outside the control limits for the analyte tert-Amyl Alcohol. The % Recovery was
reported as 65.5 and the control limits were 70 to 130.
2120204004
1
MW-008D
SW846 8260B
Dichlorofluoromethane
The QC sample type MS for method SW846 8260B was outside the control limits for the analyte Dichlorofluoromethane. The % Recovery was
reported as 125 and the control limits were 4 to 121.
2120204004
2
MW-008D
SW846 8260B
trans-1,2-Dichloroethene
The QC sample type MS for method SW846 8260B was outside the control limits for the analyte trans-1,2-Dichloroethene. The % Recovery was
reported as 129 and the control limits were 71 to 122.
2120204006
1
MW-006
SW846 8260B
Chlorobenzene
The QC sample type LCS for method SW846 8260B was outside the control limits for the analyte Chlorobenzene. The % Recovery was reported
as 123 and the control limits were 85 to 117.
2120204022
1
FB-003
SW846 8260B
tert-Amyl Alcohol
The QC sample type LCS for method SW846 8260B was outside the control limits for the analyte tert-Amyl Alcohol. The % Recovery was
reported as 65.5 and the control limits were 70 to 130.
Page 49 of 52
Report ID: 2120204 - 1/29/2016
DL ID - 29657, QC - 0
Friday, January 29, 2016 6:18:31 PM
Page 50 of 52
Friday, January 29, 2016 6:18:31 PM
Page 51 of 52
Friday, January 29, 2016 6:18:31 PM
Page 52 of 52
Calvert Citgo
2815 NE Road, North East MD
Drinking Water Results
Pre-Filtration
Sample ID
Sample date
Compound
DW-001
DW-001
DW-001
DW-001
4/28/2015
7/15/2015
10/21/2015
1/21/2016
EPA Std.
Unit
1,2-Dichloroethane
5
ug/l
1.1
1.2
2.7
ND
1,4-Dioxane
**
ug/l
ND
ND
ND
ND
Acetone
**
ug/l
9.1
ND
7.7
3.2
Isopropyl Ether
**
ug/l
0.9
0.86
1.4
0.59
Methyl chloride
**
ug/l
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
8.8
ND
ND
ND
Methyl tert-butyl ether
**
ug/l
22.6
36.5
114
19
Tert-Amyl Methyl Ether
**
ug/l
0.22
ND
ND
0.27
tert-Butylalcohol
**
ug/l
12.8
7.7
14.2
11
1000
ug/l
ND
ND
ND
ND
Toluene
Mid-Filtration
Compound
Sample ID
DW-001A
DW-001A
DW-001A
DW-001A
Sample date
4/28/2015
7/15/2015
10/21/2015
1/21/2016
EPA Std.
Unit
Acetone
**
ug/l
10.3
5.2
11.9
2.3
Methyl ethyl ketone
**
ug/l
7.4
ND
ND
ND
Methyl tert-butyl ether
**
ug/l
ND
ND
ND
ND
Methacrylonitrile
**
ug/l
ND
ND
0.27
ND
Naphthalene
**
ug/l
0.16
ND
ND
ND
n-Hexane
**
ug/l
0.58
ND
0.65
ND
tert-Butylalcohol
**
ug/l
10.3
6.3
5.9
5.7
Post-Filtration
Compound
EPA Std.
Sample ID
DW-001B
DW-001B
DW-001B
DW-001B
Sample date
4/28/2015
7/15/2015
10/21/2015
1/21/2016
Unit
Acetone
**
ug/l
10.9
3.9
15.2
3.4
Isopropanol
**
ug/l
ND
ND
ND
11.2
Methyl ethyl ketone
**
ug/l
8.6
ND
ND
ND
Methyl iodide
**
ug/l
ND
ND
ND
0.26
n-Hexane
**
ug/l
ND
ND
0.38
ND
tert-Butylalcohol
**
ug/l
12
9.9
ND
7.1
REPSG Project Reference No. 005977.130.01
Related to MDE Case No. 1992‐2616‐CE
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
January 26, 2016
Ms. Natalie Griffith
REPSG
6901 Kingsessing Ave
Suite 201
Philadelphia, PA 19142
Certificate of Analysis
Project Name:
Purchase Order:
2016-CALVERT CITGO
11790
Workorder:
2120213
Workorder ID: 2016-CALVERT CITGO/5977
Dear Ms. Griffith:
Enclosed are the analytical results for samples received by the laboratory on Friday, January 22, 2016.
The ALS Environmental laboratory in Middletown, Pennsylvania is a National Environmental Laboratory
Accreditation Program (NELAP) accredited laboratory and as such, certifies that all applicable test results meet the
requirements of NELAP.
If you have any questions regarding this certificate of analysis, please contact Ms. Susan J Scherer (Project
Coordinator) at (717) 944-5541.
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program and any
applicable state requirements. The test results meet requirements of the current NELAP standards or state
requirements, where applicable. For a specific list of accredited analytes, refer to the certifications section of the
ALS website at www.alsglobal.com/en/Our-Services/Life-Sciences/Environmental/Downloads.
This laboratory report may not be reproduced, except in full, without the written approval of ALS Environmental.
ALS Spring City: 10 Riverside Drive, Spring City, PA 19475 610-948-4903
CC: Ms. S Shourds , Mr. James Manuel
This page is included as part of the Analytical Report and
Ms. Susan J Scherer
Project Coordinator
must be retained as a permanent record thereof.
Page 1 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
SAMPLE SUMMARY
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID
Sample ID
Matrix
Date Collected
Date Received
Collected By
2120213001
DW-001B
Water
1/21/2016 09:45
1/22/2016 20:35
Collected by Client
2120213002
DW-001A
Water
1/21/2016 09:50
1/22/2016 20:35
Collected by Client
2120213003
DW-001
Water
1/21/2016 09:55
1/22/2016 20:35
Collected by Client
Notes
-- Samples collected by ALS personnel are done so in accordance with the procedures set forth in the ALS Field Sampling Plan (20 Field Services Sampling Plan).
-- All Waste Water analyses comply with methodology requirements of 40 CFR Part 136.
-- All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141.
-- Unless otherwise noted, all quantitative results for soils are reported on a dry weight basis.
-- The Chain of Custody document is included as part of this report.
-- All Library Search analytes should be regarded as tentative identifications based on the presumptive evidence of the mass spectra.
Concentrations reported are estimated values.
-- Parameters identified as "analyze immediately" require analysis within 15 minutes of collection. Any "analyze immediately" parameters
not listed under the header "Field Parameters" are preformed in the laboratory and are therefore analyzed out of hold time.
-- Method references listed on this report beginning with the prefix “S” followed by a method number (such as S2310B-97)
refer to methods from “Standard Methods for the Examination of Water and Wastewater”.
Standard Acronyms/Flags
J
Indicates an estimated value between the Method Detection Limit (MDL) and the Practical Quantitation Limit (PQL) for the analyte
U
Indicates that the analyte was Not Detected (ND)
N
Indicates presumptive evidence of the presence of a compound
MDL
Method Detection Limit
PQL
Practical Quantitation Limit
RDL
Reporting Detection Limit
ND
Not Detected - indicates that the analyte was Not Detected at the RDL
Cntr
Analysis was performed using this container
RegLmt Regulatory Limit
LCS
Laboratory Control Sample
MS
Matrix Spike
MSD
Matrix Spike Duplicate
DUP
Sample Duplicate
%Rec
Percent Recovery
RPD
Relative Percent Difference
LOD
DoD Limit of Detection
LOQ
DoD Limit of Quantitation
DL
DoD Detection Limit
I
Indicates reported value is greater than or equal to the Method Detection Limit (MDL) but less than the Report Detection Limit (RDL)
(S)
Surrogate Compound
NC
Not Calculated
*
Result outside of QC limits
Page 2 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213001
Date Collected: 1/21/2016 09:45
Sample ID:
DW-001B
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
5.0
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
1.4
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3.4J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page 3 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213001
Date Collected: 1/21/2016 09:45
Sample ID:
DW-001B
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.26J
11.2J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Flag
J
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 4 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213001
Date Collected: 1/21/2016 09:45
Sample ID:
DW-001B
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
107
117
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
1/25/16 15:13
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
EPA 524.2
EPA 524.2
1/25/16 15:13
1/25/16 15:13
TMP
TMP
A
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 5 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213002
Date Collected: 1/21/2016 09:50
Sample ID:
DW-001A
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
5.0
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
1.4
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
2.3J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page 6 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213002
Date Collected: 1/21/2016 09:50
Sample ID:
DW-001A
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 7 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213002
Date Collected: 1/21/2016 09:50
Sample ID:
DW-001A
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
91.9
96.6
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
1/25/16 15:35
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
EPA 524.2
EPA 524.2
1/25/16 15:35
1/25/16 15:35
TMP
TMP
A
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 8 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213003
Date Collected: 1/21/2016 09:55
Sample ID:
DW-001
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
5.0
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
1.4
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3.2J
ND
0.27J
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
J
Page 9 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213003
Date Collected: 1/21/2016 09:55
Sample ID:
DW-001
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.59
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
19.0
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 10 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120213 2016-CALVERT CITGO/5977
Lab ID:
2120213003
Date Collected: 1/21/2016 09:55
Sample ID:
DW-001
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
91.1
95.9
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
1/25/16 15:58
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
EPA 524.2
EPA 524.2
1/25/16 15:58
1/25/16 15:58
TMP
TMP
A
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 11 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
PARAMETER QUALIFIERS
Lab ID
#
Sample ID
Analytical Method
Analyte
2120213001
1
DW-001B
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120213002
1
DW-001A
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120213003
1
DW-001
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
Page 12 of 13
Report ID: 2120213 - 1/26/2016
DL ID - 29440, QC - 0
Tuesday, January 26, 2016 6:10:43 PM
Page 13 of 13
Calvert Citgo
2794 NE Road, North East MD
Drinking Water Results
Pre-Filtration
Compound
Sample ID
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
DW-004C
DW-004C
DW-004C
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out) 10/22/2015
DW-004C
DW-004C
DW-004C
11/18/2015
12/16/2015
1/21/2016
EPA Std.
Unit
1,1-Dichloroethane
5
ug/l
ND
0.13
0.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
1,2-Dichloroethane
5
ug/l
9.7
16.6
15.6
12.2
11.8
10.7
9.6
ND
12.2
12.1
11.3
13.3
1,4-Dioxane
**
ug/l
ND
ND
4.2
2.3
ND
ND
ND
ND
ND
ND
ND
ND
2-Nitropropane
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
21.6
ND
ND
14.6
Benzene
5
ug/l
ND
0.082
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Carbon disulfide
**
ug/l
ND
ND
ND
ND
0.23
ND
ND
ND
ND
ND
ND
ND
Cymene
**
ug/l
ND
0.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Diethyl ether
**
ug/l
0.23
0.37
0.39
0.27
0.23
ND
ND
ND
0.21
ND
0.3
ND
Isopropyl benzene
**
ug/l
ND
0.15
0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
Isopropyl ether
**
ug/l
5.6
ND
ND
ND
ND
ND
4
3.8
5.7
7
5.8
6.2
m-Dichlorobenzene
**
ug/l
ND
ND
0.15
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl chloride
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.1
ND
ND
Methyl ethyl ketone
**
ug/l
5
8.7
8.2
4.1
ND
ND
4.4
ND
1.8
ND
ND
11.7
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34
Methyl tert-butyl ether
20
ug/l
472
780
549
596
548
521
401
343
490
430
462
431
p-Dichlorobenzene
**
ug/l
ND
0.13
0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
sec-Butylbenzene
**
ug/l
0.53
ND
0.16
ND
0.1
ND
ND
ND
ND
ND
0.1
ND
Tert-Amyl alcohol
**
ug/l
ND
202
ND
ND
166
143
ND
ND
ND
ND
ND
ND
Tert-Amyl Methyl Ether
**
ug/l
ND
ND
3.9
3
3.2
ND
2.6
2.2
3.2
3
3.7
3.5
tert-Butylalcohol
**
ug/l
4520
7880
5380
4510
5530
5270
4450
3180
5030
4470
4320
3520
Tetrahydrofuran
**
ug/l
ND
ND
ND
0.95
1.2
ND
ND
0.97
ND
ND
ND
ND
Toluene
**
ug/l
ND
0.15
ND
ND
ND
ND
0.12
0.12
ND
ND
ND
ND
Sample ID
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
11/18/2015
12/16/2015
1/21/2016
Mid-Carbon 1
Compound
DW-004I
DW-004I
DW-004I
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out) 10/22/2015
EPA Std.
Unit
1,4-Dioxane
**
ug/l
ND
ND
ND
2.4
2.4
ND
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
ND
ND
10.5
ND
ND
ND
ND
ND
ND
ND
ND
11.3
Methyl bromide
**
ug/l
0.17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
6
8.6
8.1
4.9
ND
ND
3.4
ND
ND
ND
ND
12.9
253
Methyl tert-butyl ether
20
ug/l
118
302
282
410
366
381
367
67.1
137
211
226
Tert-Amyl alcohol
**
ug/l
114
121
199
ND
165
131
ND
ND
ND
ND
ND
ND
Tert-Amyl Methyl Ether
**
ug/l
ND
0.17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3520
tert-Butylalcohol
**
ug/l
4380
7930
5770
6380
5590
5790
4590
4130
4740
4270
4460
Tetrahydrofuran
**
ug/l
5.7
ND
6.4
4.7
2.6
2.6
3.8
3.6
2.9
5.2
ND
2.3
1000
ug/l
ND
0.13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sample ID
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
11/18/2015
12/16/2015
1/21/2016
Toluene
Mid-Carbon 2
Compound
DW-004J
DW-004J
DW-004J
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out) 10/22/2015
EPA Std.
Unit
1,4-Dioxane
**
ug/l
ND
ND
2.9
3.7
ND
ND
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
7.7
17.1
12.7
7.9
4.6
ND
ND
7.6
ND
ND
ND
10.3
Methyl bromide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
5.8
7.8
9.4
4.9
ND
ND
4.4
ND
ND
ND
ND
12
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.23
0.54
Methyl tert-butyl ether
20
ug/l
0.2
0.68
2.1
5.9
11.8
28.4
74.1
20
0.62
0.33
ND
n-Butylbenzne
**
ug/l
ND
ND
ND
ND
ND
ND
0.26
ND
ND
ND
ND
ND
n-Hexane
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Tert-Amyl alcohol
**
ug/l
13.2
18.2
24.8
34.6
71
85.5
95.3
ND
ND
ND
ND
ND
tert-Butylalcohol
**
ug/l
4660
7410
5770
6630
4920
5820
4200
1530
5220
4300
4180
3560
ND
trans-1,4-Dichloro-2-butene
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Tetrahydrofuran
**
ug/l
5.5
5.8
6.4
6.8
5.6
6.4
7.2
1.85
1.8
5.4
6
4
1000
ug/l
ND
0.22
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sample ID
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
11/18/2015
12/16/2015
1/21/2016
Toluene
Post-Carbon
Compound
DW-004K
DW-004K
DW-004K
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out) 10/22/2015
EPA Std.
Unit
1,4-Dioxane
**
ug/l
ND
ND
2.2
2.8
ND
ND
ND
ND
ND
ND
ND
ND
2-Hexanone
**
ug/l
ND
ND
ND
ND
3.1
ND
ND
ND
ND
ND
ND
ND
10.4
Acetone
**
ug/l
4.9
20.2
7.2
7.9
ND
ND
6.6
9.5
ND
ND
ND
n-Hexane
**
ug/l
ND
ND
ND
ND
0.78
ND
ND
ND
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
5.6
8.9
5.7
7
ND
ND
4.6
ND
ND
ND
ND
11.6
Methyl tert-butyl ether
20
ug/l
ND
ND
ND
ND
ND
ND
0.35
0.12
0.3
ND
0.65
0.18
Methylene chloride
5
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Tert-Amyl alcohol
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.2
ND
tert-Butylalcohol
**
ug/l
4130
7030
5080
5910
5570
5170
4830
5220
4400
5080
4480
3240
Tetrahydrofuran
Toluene
**
ug/l
5.1
ND
6.4
6.8
7.1
7.9
8.3
8.9
7.5
8.9
4.5
6.3
1000
ug/l
ND
0.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
REPSG Project Reference No. 005977.130.01
Related to MDE Case No. 1992‐2616‐CE
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004C (Pre-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004C_Post
DW-004C_Pre
DW-004C
DW-004C
DW-004C
DW-004C
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------2-Nitropropane
ug/l
**
Chlorine
ug/l
4000
<0.8U
<0.8U
<0.8U
<0.8U
<0.8U
-
-
-
-
<9U
Methyl iodide
ug/l
Tert-Amyl Methyl Ether
ug/l
<0.8U
-
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
**
2.2
2.6
<0.15U
<0.15U
3.9
3
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1-Dichloroethane
ug/l
**
<0.11U
<0.11U
<0.11U
0.13J
0.11J
<0.11U
1,2-Dichloroethane
ug/l
5
<0.15U
9.6
9.7
16.6
15.6
12.2
1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
4.2
2.3J
Acetone
ug/l
**
<2.2U
<2.2U
<2.2U
<2.2U
<2.2U
<2.2U
Benzene
ug/l
5
<0.07U
<0.07U
<0.07U
0.082J
<0.07U
<0.07U
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Chlorobenzene
ug/l
100
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Cymene
ug/l
**
<0.11U
<0.11U
<0.11U
0.11J
<0.11U
<0.11U
Diethyl ether
ug/l
**
<0.21U
<0.21U
0.23J
0.37J
0.39J
0.27J
Isopropyl benzene
ug/l
**
<0.14U
<0.14U
<0.14U
0.15J
0.14J
<0.14U
Isopropyl Ether
ug/l
**
3.8
4
5.6
<0.21U
<0.21U
<0.21U
Methyl chloride
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Methyl ethyl ketone
ug/l
**
<1.3U
4.4
5
8.7
8.2
4.1
Print Date: 03/01/2016
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004C (Pre-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-004C_Post
DW-004C_Pre
DW-004C
DW-004C
DW-004C
DW-004C
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
20
343
401
472
780
549
596
<0.32U
Date:
Depth (ft):
Methyl tert-butyl ether
ug/l
Methylene chloride
ug/l
5
<0.32U
<0.32U
<0.32U
<0.32U
<0.32U
sec-Butylbenzene
ug/l
**
<0.1U
<0.1U
0.53
<0.1U
0.16J
<0.1U
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
<80U
202
<160U
<160U
tert-Butylalcohol
ug/l
**
3180
4450
4520
7880
5380
4510
Tetrahydrofuran
ug/l
**
0.97J
<0.81U
<0.81U
<0.81U
<0.81U
0.95J
Toluene
ug/l
1000
0.13J
0.12J
<0.12U
0.15J
<0.12U
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Hexachlorobutadiene
ug/l
**
<0.24U
<0.24U
<0.24U
<0.24U
<0.24U
<0.24U
m-Dichlorobenzene
ug/l
**
<0.11U
<0.11U
<0.11U
<0.11U
0.15J
<0.11U
o-Dichlorobenzene
ug/l
600
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
p-Dichlorobenzene
ug/l
75
<0.11U
<0.11U
<0.11U
0.13J
0.14J
<0.11U
Constituent
Unit
*Standard
Location:
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
Date:
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------2-Nitropropane
ug/l
**
Chlorine
ug/l
4000
<0.8U
<0.8U
<0.8U
<0.8U
<0.8U
<0.8U
-
<9U
<9U
-
-
<9U
Print Date: 03/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004C (Pre-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
Date:
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
01/21/2016
0
0
Depth (ft):
0
0
0
0
Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
0.34J
Tert-Amyl Methyl Ether
ug/l
**
3.2
<0.15U
3.2
3
3.7
3.5
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1-Dichloroethane
ug/l
**
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
1,2-Dichloroethane
ug/l
5
11.8
10.7
12.2
12.1
11.3
13.3
1,4-Dioxane
ug/l
**
<1.5U
<1.5U
<4U
<4U
<4U
<4U
Acetone
ug/l
**
<2.2U
<2.2U
21.6
<2.2U
<2.2U
14.6
Benzene
ug/l
5
<0.07U
<0.07U
<0.07U
<0.07U
<0.07U
<0.07U
Carbon disulfide
ug/l
**
0.23J
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Chlorobenzene
ug/l
100
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Cymene
ug/l
**
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
Diethyl ether
ug/l
**
0.23J
<0.21U
0.21J
<0.21U
0.3J
<0.21U
Isopropyl benzene
ug/l
**
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Isopropyl Ether
ug/l
**
<0.21U
<0.21U
5.7
7
5.8
6.2
Methyl chloride
ug/l
**
<0.22U
<0.22U
<0.22U
1.1
<0.22U
<0.22U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
1.8J
<1.3U
<1.3U
11.7
Methyl tert-butyl ether
ug/l
20
548
521
490
430
462
431
Methylene chloride
ug/l
5
<0.32U
<0.32U
<0.32U
<0.32U
<0.32U
<0.32U
sec-Butylbenzene
ug/l
**
0.1J
<0.1U
<0.1U
<0.1U
0.1J
<0.1U
Tert-Amyl alcohol
ug/l
**
166
143
<160U
<80U
<160U
<1.6U
Print Date: 03/01/2016
Page 3
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004C (Pre-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
DW-004C
Date:
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
0
5530
5270
5030
4470
4230
3520
Depth (ft):
tert-Butylalcohol
ug/l
**
Tetrahydrofuran
ug/l
**
Toluene
ug/l
1000
1.2J
<0.81U
<0.81U
<0.81U
<0.81U
<0.81U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Hexachlorobutadiene
ug/l
**
<0.24U
<0.24U
<0.24U
<0.24U
<0.24U
m-Dichlorobenzene
ug/l
**
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
o-Dichlorobenzene
ug/l
600
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
p-Dichlorobenzene
ug/l
75
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
<0.11U
Print Date: 03/01/2016
<0.24U
Page 4
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004J (Mid-Carbon 2;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004I_Post
DW-004I_Pre
DW-004I
DW-004I
DW-004I
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
0
0
0
0
0
DW-004I
05/21/2015
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
<1.5U
2.4J
Acetone
ug/l
**
<2.2U
<2.2U
<2.2U
<2.2U
10.5
<2.2U
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
0.17J
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
3.4
6
8.6
8.1
4.9
Methyl tert-butyl ether
ug/l
20
67.1
367
118
302
282
410
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
114
121
199J
<160U
tert-Butylalcohol
ug/l
**
4130
4590
4380
7930
5590
6380
Tetrahydrofuran
ug/l
**
3.6
3.8
5.7
<0.81U
4.9
4.7
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
0.13J
<0.12U
<0.12U
trans-1,2-Di-chloroethylene
ug/l
100
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
0
0
0
0
0
Print Date: 03/01/2016
DW-004I
01/21/2016
0
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004J (Mid-Carbon 2;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004I
DW-004I
DW-004I
DW-004I
DW-004I
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
0
0
0
0
0
DW-004I
01/21/2016
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
2.4J
<1.5U
<4U
<4U
<4U
<4U
Acetone
ug/l
**
<2.2U
<2.2U
<2.2U
<2.2U
<2.2U
11.3
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
12.9
Methyl tert-butyl ether
ug/l
20
366
381
137
211
226
253
Tert-Amyl alcohol
ug/l
**
165
131
<160U
<80U
<160U
<1.6U
tert-Butylalcohol
ug/l
**
5590
5790
4740
4270
4460
3520
Tetrahydrofuran
ug/l
**
2.6
2.6
2.9
5.2
<0.81U
2.3J
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
trans-1,2-Di-chloroethylene
ug/l
100
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Print Date: 03/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004J (Mid-Carbon 2;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004J_Post
DW-004J_Pre
DW-004J
DW-004J
DW-004J
DW-004J
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
2.9J
Acetone
ug/l
**
7.6
<2.2U
7.7
17.1
12.7
7.9
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
4.4
5.8
7.8
9.4
4.9
Methyl tert-butyl ether
ug/l
20
20
74.1
0.2J
0.68
2.1
5.9
Tert-Amyl alcohol
ug/l
**
<1.6U
95.3
13.2
18.2
24.8
34.6
tert-Butylalcohol
ug/l
**
1530
4200
4660
7410
5770
6630
Tetrahydrofuran
ug/l
**
1.8J
7.2
5.5
5.8
6.4
6.8
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
0.22J
<0.12U
<0.12U
trans-1,2-Di-chloroethylene
ug/l
100
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
3.7J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Print Date: 03/01/2016
0
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004J (Mid-Carbon 2;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
DW-004J
06/23/2015
07/15/2015
10/22/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
0.23J
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<1.5U
<1.5U
<4U
<4U
<4U
<4U
Acetone
ug/l
**
4.6J
<2.2U
<2.2U
<2.2U
<2.2U
10.3
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
12
Methyl tert-butyl ether
ug/l
20
11.8
28.4
0.62
0.33J
<9U
0.54
Tert-Amyl alcohol
ug/l
**
71
85.5
<1.6U
<1.6U
<1.6U
<1.6U
tert-Butylalcohol
ug/l
**
4920
5820
5220
4300
4180
3560
Tetrahydrofuran
ug/l
**
5.6
6.4
1.8J
5.4
6
4
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
trans-1,2-Di-chloroethylene
ug/l
100
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Print Date: 03/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004K (Post-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-004K_Post
DW-004K_Pre
DW-004K
DW-004K
DW-004K
DW-004K
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------n-Hexane
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
2.2J
2.8J
2-Hexanone
ug/l
**
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
Acetone
ug/l
**
9.5
6.6
4.9J
20.2
7.2
5.8
Methyl ethyl ketone
ug/l
**
<1.3U
4.6
5.6
8.9
5.7
7
Methyl tert-butyl ether
ug/l
20
0.12J
0.35J
<0.09U
<0.09U
<0.09U
<0.09U
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
<1.6U
<1.6U
<1.6U
<1.6U
tert-Butylalcohol
ug/l
**
5220
4830
4130
7030
5080
5910
Tetrahydrofuran
ug/l
**
8.9
8.3
5.1
<0.81U
7.7
6.8
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
0.16J
<0.12U
<0.12U
Constituent
Unit
*Standard
Location:
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------n-Hexane
ug/l
**
0.78J
Print Date: 03/01/2016
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-004K (Post-Filtration;
2794 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
DW-004K
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
0
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<1.5U
<1.5U
<4U
<4U
<4U
<4U
2-Hexanone
ug/l
**
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
Acetone
ug/l
**
3.1J
<2.2U
<2.2U
<2.2U
<2.2U
10.4
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
11.6
Methyl tert-butyl ether
ug/l
20
<0.09U
<0.09U
0.3J
<0.09U
0.65
0.18J
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
<1.6U
<1.6U
9.2
<1.6U
tert-Butylalcohol
ug/l
**
5570
5170
4400
5080
4480
3240
Tetrahydrofuran
ug/l
**
7.1
7.9
7.5
8.9
4.5
6.3
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Print Date: 03/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
January 28, 2016
Ms. Natalie Griffith
REPSG
6901 Kingsessing Ave
Suite 201
Philadelphia, PA 19142
Certificate of Analysis
Project Name:
Purchase Order:
2016-CALVERT CITGO
11791
Workorder:
2120211
Workorder ID: 2015-CALVERT CITGO/5977
Dear Ms. Griffith:
Enclosed are the analytical results for samples received by the laboratory on Friday, January 22, 2016.
The ALS Environmental laboratory in Middletown, Pennsylvania is a National Environmental Laboratory
Accreditation Program (NELAP) accredited laboratory and as such, certifies that all applicable test results meet the
requirements of NELAP.
If you have any questions regarding this certificate of analysis, please contact Ms. Susan J Scherer (Project
Coordinator) at (717) 944-5541.
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program and any
applicable state requirements. The test results meet requirements of the current NELAP standards or state
requirements, where applicable. For a specific list of accredited analytes, refer to the certifications section of the
ALS website at www.alsglobal.com/en/Our-Services/Life-Sciences/Environmental/Downloads.
This laboratory report may not be reproduced, except in full, without the written approval of ALS Environmental.
ALS Spring City: 10 Riverside Drive, Spring City, PA 19475 610-948-4903
CC: Ms. S Shourds , Mr. James Manuel
This page is included as part of the Analytical Report and
Ms. Susan J Scherer
Project Coordinator
must be retained as a permanent record thereof.
Page 1 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
SAMPLE SUMMARY
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID
Sample ID
Matrix
Date Collected
Date Received
Collected By
2120211001
DW-004K
Water
1/21/2016 10:10
1/22/2016 20:35
Collected by Client
2120211002
DW-004J
Water
1/21/2016 10:15
1/22/2016 20:35
Collected by Client
2120211003
DW-004I
Water
1/21/2016 10:20
1/22/2016 20:35
Collected by Client
2120211004
DW-004C
Water
1/21/2016 10:25
1/22/2016 20:35
Collected by Client
Notes
-- Samples collected by ALS personnel are done so in accordance with the procedures set forth in the ALS Field Sampling Plan (20 Field Services Sampling Plan).
-- All Waste Water analyses comply with methodology requirements of 40 CFR Part 136.
-- All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141.
-- Unless otherwise noted, all quantitative results for soils are reported on a dry weight basis.
-- The Chain of Custody document is included as part of this report.
-- All Library Search analytes should be regarded as tentative identifications based on the presumptive evidence of the mass spectra.
Concentrations reported are estimated values.
-- Parameters identified as "analyze immediately" require analysis within 15 minutes of collection. Any "analyze immediately" parameters
not listed under the header "Field Parameters" are preformed in the laboratory and are therefore analyzed out of hold time.
-- Method references listed on this report beginning with the prefix “S” followed by a method number (such as S2310B-97)
refer to methods from “Standard Methods for the Examination of Water and Wastewater”.
Standard Acronyms/Flags
J
Indicates an estimated value between the Method Detection Limit (MDL) and the Practical Quantitation Limit (PQL) for the analyte
U
Indicates that the analyte was Not Detected (ND)
N
Indicates presumptive evidence of the presence of a compound
MDL
Method Detection Limit
PQL
Practical Quantitation Limit
RDL
Reporting Detection Limit
ND
Not Detected - indicates that the analyte was Not Detected at the RDL
Cntr
Analysis was performed using this container
RegLmt Regulatory Limit
LCS
Laboratory Control Sample
MS
Matrix Spike
MSD
Matrix Spike Duplicate
DUP
Sample Duplicate
%Rec
Percent Recovery
RPD
Relative Percent Difference
LOD
DoD Limit of Detection
LOQ
DoD Limit of Quantitation
DL
DoD Detection Limit
I
Indicates reported value is greater than or equal to the Method Detection Limit (MDL) but less than the Report Detection Limit (RDL)
(S)
Surrogate Compound
NC
Not Calculated
*
Result outside of QC limits
Page 2 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211001
Date Collected: 1/21/2016 10:10
Sample ID:
DW-004K
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
10.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.6
3240
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
500
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
140
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/27/16 18:46
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 3 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211001
Date Collected: 1/21/2016 10:10
Sample ID:
DW-004K
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.18J
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 4 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211001
Date Collected: 1/21/2016 10:10
Sample ID:
DW-004K
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
6.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
88.9
78.3
79.5
95
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
1/25/16 17:49
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:49
1/27/16 18:46
1/27/16 18:46
1/25/16 17:49
TMP
TMP
TMP
TMP
A
B
B
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 5 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211002
Date Collected: 1/21/2016 10:15
Sample ID:
DW-004J
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
10.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
12.0
3560
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
500
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
140
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/27/16 19:08
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 6 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211002
Date Collected: 1/21/2016 10:15
Sample ID:
DW-004J
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.23J
ND
ND
ND
ND
ND
ND
0.54
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 7 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211002
Date Collected: 1/21/2016 10:15
Sample ID:
DW-004J
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
4.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
94
78.8
81.8
108
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
1/25/16 18:11
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:11
1/27/16 19:08
1/27/16 19:08
1/25/16 18:11
TMP
TMP
TMP
TMP
A
B
B
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 8 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211003
Date Collected: 1/21/2016 10:20
Sample ID:
DW-004I
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
11.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
12.9
3520
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
250
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
70.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/27/16 19:30
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 9 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211003
Date Collected: 1/21/2016 10:20
Sample ID:
DW-004I
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
253
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
25.0
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
4.5
0.56
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/27/16 19:30
1/25/16 18:33
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 10 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211003
Date Collected: 1/21/2016 10:20
Sample ID:
DW-004I
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
2.3J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
84.3
87.3
93.7
84.1
%
%
%
%
ND
mg/L
Flag
J
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
1/25/16 18:33
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/27/16 19:30
1/25/16 18:33
1/25/16 18:33
1/27/16 19:30
TMP
TMP
TMP
TMP
B
A
A
B
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 11 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211004
Date Collected: 1/21/2016 10:25
Sample ID:
DW-004C
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
14.6
ND
3.5
ND
ND
ND
ND
ND
ND
ND
ND
11.7
3520
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
250
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
70.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/27/16 19:52
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 12 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211004
Date Collected: 1/21/2016 10:25
Sample ID:
DW-004C
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
13.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34J
ND
ND
ND
ND
ND
ND
431
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
25.0
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
4.5
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/27/16 19:52
1/25/16 18:55
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 13 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120211 2015-CALVERT CITGO/5977
Lab ID:
2120211004
Date Collected: 1/21/2016 10:25
Sample ID:
DW-004C
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
95.1
80.7
94.4
82.5
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
1/25/16 18:55
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 18:55
1/27/16 19:52
1/25/16 18:55
1/27/16 19:52
TMP
TMP
TMP
TMP
A
B
A
B
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 14 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
PARAMETER QUALIFIERS
Lab ID
#
Sample ID
Analytical Method
Analyte
2120211001
1
DW-004K
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120211002
1
DW-004J
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120211003
1
DW-004I
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120211004
1
DW-004C
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
Page 15 of 16
Report ID: 2120211 - 1/28/2016
DL ID - 29589, QC - 0
Thursday, January 28, 2016 6:15:54 PM
Page 16 of 16
Calvert Citgo
2802 NE Road, North East MD
Drinking Water Results
Pre-Filtration
Compound
1,1-Dichloroethane
Sample ID
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
0.37
EPA Std.
DW-005A
DW-005A
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out)
DW-005A
DW-005A
DW-005A
DW-005A
10/20/2015
11/18/2015
12/16/2015
1/21/2016
ND
0.21
Unit
**
ug/l
0.24
0.49
0.33
0.32J
ND
0.24
1,2-Dichloroethane
5
ug/l
1.2
1.3
1.5
0.49
0.63
ND
0.83
3.1
4.7
3.9
2.7
2.1
1,2,4-Trichlorobenzene
70
ug/l
0.2
ND
ND
ND
ND
ND
ND
0.23
ND
0.23
ND
ND
ND
ND
ND
1,4-Dioxane
**
ug/l
11
ND
ND
3.5
1.8J
ND
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
4.4
16.1
15.7
8.4
15.3
61.5
21.2
ND
58.1
21.8
ND
17.3
Benzene
5
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Bromodichloromethane
**
ug/l
ND
ND
5.1
1.1
4.7
ND
0.98
ND
ND
ND
ND
ND
Bromoform
**
ug/l
ND
ND
ND
0.31
1.2
ND
0.27
ND
ND
ND
ND
ND
Carbon disulfide
**
ug/l
ND
ND
ND
ND
0.33
32.3
ND
ND
ND
ND
ND
ND
Chlorine
**
ug/l
ND
ND
110
ND
ND
ND
ND
ND
ND
ND
ND
ND
Chlorobenzene
**
ug/l
ND
ND
ND
ND
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
Chloroethane
**
ug/l
ND
ND
ND
0.33
ND
ND
ND
ND
ND
ND
Chloroform
**
ug/l
0.28
ND
46.4
4.3
23
ND
6.6
0.55
ND
ND
0.22
ND
Dibromochloromethane
**
ug/l
ND
ND
1.3
0.81
3.1
ND
0.49
ND
ND
ND
ND
ND
Diethyl ether
**
ug/l
0.22
0.75
0.58
0.62
0.41
ND
0.4
ND
0.5
ND
0.46
ND
Isopropyl Ether
**
ug/l
0.49
1.7
2.1
0.64
0.45
ND
0.36
1.1
2.3
2.6
1.9
1.8
Methyl bromide
**
ug/l
0.2
ND
ND
ND
0.13
ND
0.14
ND
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
4.7
7.8
10.4
5.9
ND
ND
ND
2
ND
ND
ND
3.8
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.27
Methyl tert-butyl ether
20
ug/l
17.7
132
189
52.9
48.9
48.3
27.1
136
324
239
234
170
Naphthalene
**
ug/l
0.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-Butylbenzene
**
ug/l
0.68
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
p-Dichlorobenzene
75
ug/l
0.12
0.11
0.2
ND
ND
ND
0.15
ND
ND
ND
0.13
ND
sec-Butylbenzene
**
ug/l
0.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Tert-Amyl alcohol
**
ug/l
ND
12.1
24
5.6
ND
ND
ND
ND
56
53.8
64.7
ND
Tert-Amyl Methyl Ether
**
ug/l
ND
1.4
2
ND
ND
ND
ND
1.7
3.6
2.7
3
2.2
tert-Butylalcohol
**
ug/l
5.9
245
313
59.2
20.9
ND
17.9
857
1320
814
656
260
Tetrahydrofuran
Toluene
**
ug/l
7.9
ND
ND
ND
283
166
172
ND
ND
ND
ND
ND
1000
ug/l
ND
ND
0.74
ND
0.23
ND
ND
ND
ND
ND
ND
ND
Sample ID
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
10/20/2015
11/18/2015
12/16/2015
1/21/2016
Mid-Carbon 1
Compound
EPA Std.
DW-005I
DW-005I
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out)
Unit
1,2,3-Trichlorobenzene
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1,2,4-Trichlorobenzene
70
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-Hexanone
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1,4-Dioxane
**
ug/l
ND
3.1
ND
ND
3.8
51.8
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
4.4
17.6
10.1
5.1
3
ND
4
8.5
16.1
ND
ND
4
Methyl bromide
**
ug/l
0.24
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.16
ND
Methyl ethyl ketone
**
4.7
ND
ND
ND
ND
ND
ND
ND
Methyl tert-butyl ether
20
ug/l
ND
ND
ND
ND
0.18
ND
0.11
0.14
0.2
0.23
0.88
1.8
n-Hexane
**
ug/l
ND
ND
ND
ND
1.2
ND
ND
ND
ND
ND
ND
ND
Naphthalene
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Tert-Amyl alcohol
ug/l
7.6
6
ND
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
tert-Butylalcohol
**
ug/l
681
1050
998
1270
1200
1330
954
49.9
1330
1080
987
327
Tetrahydrofuran
**
ug/l
5.2
5.2
3.7
5.5
81.5
ND
73.6
1.1
ND
ND
ND
ND
1000
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sample ID
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
Sample date
2/13/2015
3/18/2015
4/28/2015
5/21/2015
6/23/2015
7/15/2015
10/20/2015
11/18/2015
12/16/2015
1/21/2016
ND
Toluene
**
5.7
ND
Mid-Carbon 2
Compound
DW-005J
DW-005J
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out)
EPA Std.
Unit
1,4-Dioxane
**
ug/l
ND
ND
ND
3.8
2.8
ND
ND
ND
ND
ND
ND
Acetone
**
ug/l
6.7
11
10
ND
ND
ND
ND
7.6
20.3
ND
ND
5.7
Carbon disulfide
**
ug/l
ND
0.23
0.29
ND
0.41
0.27
0.41
0.63
ND
ND
ND
ND
Methyl bromide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.1
ND
Methyl ethyl ketone
**
ug/l
5.5
9.4
7.5
5
2.5
ND
ND
3.2
ND
ND
ND
ND
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.29
Methyl tert-butyl ether
20
ug/l
ND
ND
ND
0.13
ND
ND
ND
0.12
0.19
0.23
0.63
0.64
n-Hexane
**
ug/l
ND
ND
ND
ND
1
ND
ND
ND
ND
ND
ND
ND
Pentachloroethane
**
ug/l
1.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
496
tert-Butylalcohol
**
ug/l
686
1020
1100
1000
1340
1230
1050
739
646
908
1060
Tetrahydrofuran
**
ug/l
10.4
11.8
11.7
13.5
57.4
35.7
181
9.2
13.1
9.3
8.3
5.3
1000
ug/l
ND
0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DW-005K
DW-005K
DW-005K
DW-005K
Toluene
Post-Carbon
Sample ID
Sample date
Compound
EPA Std.
2/13/2015
3/18/2015
4/28/2015
5/21/2015
DW-005K
6/23/2015
DW-005K
7/15/2015
DW-005K
DW-005K
9/2/2015 (Pre- 9/2/2015
Carbon
(Post-Carbon
Change Out) Change Out)
DW-005K
DW-005K
DW-005K
DW-005K
10/20/2015
11/18/2015
12/16/2015
1/21/2016
Unit
1,2,4-Trichlorobenzene
70
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1,4-Dioxane
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
9.7
ND
ND
ND
Acetone
ug/l
6.2
17.4
8.1
4.6
3.9
6.2
6.8
Carbon disulfide
**
ug/l
0.27
0.56
0.4
0.44
0.29
0.69
0.67
ND
ND
ND
ND
ND
Chloroform
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.31
ND
Isopropanol
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl bromide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Methyl ethyl ketone
**
ug/l
4.3
7.9
5.7
5.3
ND
ND
ND
ND
ND
ND
ND
ND
Methyl iodide
**
ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.29
Methyl tert-butyl ether
20
ug/l
0.62
0.36
0.71
0.15
1.2
2.6
n-Butylbenzene
**
ug/l
0.65
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
tert-Butylalcohol
**
ug/l
18.6
33.4
8.4
9.9
16.7
9.1
43.6
10.8
469
764
1200
706
Tetrahydrofuran
Toluene
**
2
7.6
ND
ND
ND
ND
ND
ND
ND
4
ND
ND
**
ug/l
ND
ND
13.5
2.1
33.9
299
246
2.1
2.1
3.6
ND
10.5
1000
ug/l
ND
0.13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
REPSG Project Reference No. 005977.130.01
Related to MDE Case No. 1992‐2616‐CE
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005A (Pre-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005A_Post
DW-005A_Pre
DW-005A
DW-005A
DW-005A
DW-005A
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Chlorine
ug/l
4000
Methyl iodide
ug/l
**
-
-
-
-
110
-
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1-Dichloroethane
ug/l
**
0.23J
0.24J
0.24J
0.37J
0.49J
0.33J
1,2-Dichloroethane
ug/l
5
3.1
0.83
1.2
1.3
1.5
0.49J
1,4-Dioxane
ug/l
**
<4U
<4U
11
<1.5U
<1.5U
3.5J
Acetone
ug/l
**
<2.2U
21.2
4.4J
16.1
15.7
8.4
Benzene
ug/l
5
<0.07U
<0.07U
<0.07U
<0.07U
<0.07U
<0.07U
Bromodichloromethane
ug/l
**
<0.22U
0.98
<0.22U
<0.22U
5.1
1.1
Bromoform
ug/l
**
<0.23U
0.27J
<0.23U
<0.23U
<0.23U
0.31J
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Chlorobenzene
ug/l
100
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Chloroethane
ug/l
**
<0.24U
<0.24U
<0.24U
<0.24U
<0.24U
<0.24U
Chloroform
ug/l
**
0.55
6.6
0.28J
<0.19U
46.4
4.3
Dibromochloromethane
ug/l
**
<0.18U
0.49J
<0.18U
<0.18U
1.3
0.81
Diethyl ether
ug/l
**
<0.21U
0.4J
0.22J
0.75
0.58
0.62
Isopropyl benzene
ug/l
**
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Isopropyl Ether
ug/l
**
1.1
0.36J
0.49J
1.7
2.1
0.64
Print Date: 03/01/2016
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005A (Pre-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005A_Post
DW-005A_Pre
DW-005A
DW-005A
DW-005A
DW-005A
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Methyl bromide
ug/l
**
<0.13U
0.14J
0.2J
<0.13U
<0.13U
<0.13U
Methyl chloride
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Methyl ethyl ketone
ug/l
**
2J
<1.3U
4.7
7.8
10.4
5.9
Methyl tert-butyl ether
ug/l
20
136
27.1
17.7
132
189
52.9
Methylene chloride
ug/l
5
<0.32U
<0.32U
<0.32U
<0.32U
<0.32U
<0.32U
n-Butylbenzene
ug/l
**
<0.13U
<0.13U
0.68
<0.13U
<0.13U
<0.13U
sec-Butylbenzene
ug/l
**
<0.1U
<0.1U
0.5J
<0.1U
<0.1U
<0.1U
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
<1.6U
12.1
24
5.6
Tert-Amyl Ethyl Ether
ug/l
**
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Tetrahydrofuran
ug/l
**
<0.81U
172
7.9
<0.81U
<0.81U
<0.81U
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
0.74
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,4-Trichlorobenzene
ug/l
70
<0.14U
<0.14U
0.2J
<0.14U
<0.14U
Naphthalene
ug/l
**
<0.15U
<0.15U
0.2J
<0.15U
<0.15U
<0.15U
p-Dichlorobenzene
ug/l
75
<0.11U
0.15J
0.12J
0.11J
0.2J
<0.11U
Constituent
Unit
*Standard
<0.14U
Location:
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
Print Date: 03/01/2016
0
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005A (Pre-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Chlorine
ug/l
4000
Methyl iodide
ug/l
**
-
<9U
<9U
-
-
<9U
<0.19U
<3.8U
<0.19U
<0.19U
<0.19U
0.27J
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,1-Dichloroethane
ug/l
**
0.32J
<2.2U
0.23J
<0.11U
0.21J
1,2-Dichloroethane
ug/l
5
0.63
<3U
4.7
3.9
2.7
<0.11U
2.1
1,4-Dioxane
ug/l
**
1.8J
<30U
<4U
<4U
<4U
<4U
Acetone
ug/l
**
15.3
61.5J
58.1
21.8
<2.2U
17.3
Benzene
ug/l
5
<0.07U
<1.4U
<0.07U
<0.07U
<0.07U
<0.07U
Bromodichloromethane
ug/l
**
4.7
<4.4U
<0.22U
<0.22U
<0.22U
<0.22U
Bromoform
ug/l
**
1.2
<4.6U
<0.23U
<0.23U
<0.23U
<0.23U
Carbon disulfide
ug/l
**
0.33J
<4.2U
<0.21U
<0.21U
<0.21U
<0.21U
Chlorobenzene
ug/l
100
0.23J
<2.8U
<0.14U
<0.14U
<0.14U
<0.14U
Chloroethane
ug/l
**
0.33J
<4.8U
<0.24U
<0.24U
<0.24U
<0.24U
Chloroform
ug/l
**
23
32.3
<0.19U
<0.19U
0.22J
<0.19U
Dibromochloromethane
ug/l
**
3.1
<3.6U
<0.18U
<0.18U
<0.18U
<0.18U
Diethyl ether
ug/l
**
0.41J
<4.2U
0.5
<0.21U
0.46J
<0.21U
Isopropyl benzene
ug/l
**
<0.14U
<2.8U
<0.14U
<0.14U
<0.14U
<0.14U
Isopropyl Ether
ug/l
**
0.45J
<4.2U
2.3
2.6
1.9
1.8
Methyl bromide
ug/l
**
0.13J
<2.6U
0.16J
<0.13U
<0.13U
<0.13U
Print Date: 03/01/2016
Page 3
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005A (Pre-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
DW-005A
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
Depth (ft):
0
0
0
0
Methyl chloride
ug/l
**
<0.22U
<4.4U
<0.22U
<0.22U
<0.22U
<0.22U
Methyl ethyl ketone
ug/l
**
<1.3U
<26U
<1.3U
<1.3U
<1.3U
3.8
Methyl tert-butyl ether
ug/l
20
48.9
48.3
324
239
234
170
Methylene chloride
ug/l
5
<0.32U
<6.4U#
<0.32U
<0.32U
<0.32U
<0.32U
n-Butylbenzene
ug/l
**
<0.13U
<2.6U
<0.13U
<0.13U
<0.13U
<0.13U
sec-Butylbenzene
ug/l
**
<0.1U
<2U
<0.1U
<0.1U
<0.1U
<0.1U
Tert-Amyl alcohol
ug/l
**
<1.6U
<32U
56
53.8
64.7
<1.6U
Tert-Amyl Ethyl Ether
ug/l
**
<0.12U
<2.4U
<0.12U
<0.12U
<0.12U
<0.12U
Tetrahydrofuran
ug/l
**
Toluene
ug/l
1000
283
166
<0.81U
<0.81U
<0.81U
<0.81U
0.23J
<2.4U
<0.12U
<0.12U
<0.12U
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,4-Trichlorobenzene
ug/l
70
<0.14U
<2.8U
<0.14U
<0.14U
<0.14U
Naphthalene
ug/l
**
<0.15U
<3U
<0.15U
<0.15U
<0.15U
<0.15U
p-Dichlorobenzene
ug/l
75
<0.11U
<2.2U
0.15J
<0.11U
0.13J
<0.11U
Print Date: 03/01/2016
<0.14U
Page 4
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005I (Mid-Carbon 1;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005I_Post
DW-005I_Pre
DW-005I
DW-005I
DW-005I
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
0
0
0
0
0
DW-005I
05/21/2015
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------n-Hexane
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,3-Trichlorobenzene
ug/l
**
<0.23U
<0.23U
<0.23U
<0.23U
<0.23U
1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
3.1J
<1.5U
<0.23U
<1.5U
2-Hexanone
ug/l
**
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
<0.82U
Carbon disulfide
ug/l
**
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
0.24J
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
5.7
7.6
6
4.7
Methyl tert-butyl ether
ug/l
20
0.14J
0.11J
<0.09U
<0.09U
<0.09U
<0.09U
Tert-Amyl alcohol
ug/l
**
<1.6U
<1.6U
<1.6U
<1.6U
<1.6U
<1.6U
Tetrahydrofuran
ug/l
**
Toluene
ug/l
1000
1.1J
73.6
5.2
5.2
3.7
5.5
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,4-Trichlorobenzene
ug/l
70
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
<0.14U
Naphthalene
ug/l
**
<0.15U
<0.15U
<0.15U
<0.15U
<0.15U
<0.15U
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
Constituent
Unit
*Standard
Location:
Print Date: 03/01/2016
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005I (Mid-Carbon 1;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005I
DW-005I
DW-005I
DW-005I
DW-005I
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
0
0
0
0
0
DW-005I
01/21/2016
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------n-Hexane
ug/l
**
1.2J
<4.4U
<0.22U
<0.22U
<0.22U
<0.22U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,3-Trichlorobenzene
ug/l
**
<0.23U
<4.6U
<0.23U
<0.23U
<0.23U
1,4-Dioxane
ug/l
**
3.8J
51.8J
<4U
<4U
<4U
<0.23U
<4U
2-Hexanone
ug/l
**
<0.82U
<16.4U
<0.82U
<0.82U
<0.82U
<0.82U
Carbon disulfide
ug/l
**
<0.21U
<4.2U
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<2.6U
<0.13U
<0.13U
0.16J
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<26U
<1.3U
<1.3U
<1.3U
<1.3U
Methyl tert-butyl ether
ug/l
20
0.18J
<1.8U
0.2J
0.23J
0.88
1.8
Tert-Amyl alcohol
ug/l
**
<1.6U
<32U
<1.6U
<1.6U
<1.6U
<1.6U
Tetrahydrofuran
ug/l
**
81.5
<16.2U
<0.81U
<0.81U
<0.81U
<0.81U
Toluene
ug/l
1000
<0.12U
<2.4U
<0.12U
<0.12U
<0.12U
<0.12U
Volatile/Semi-Volatile Organic Compounds (V/SVOCs) ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,2,4-Trichlorobenzene
ug/l
70
<0.14U
<2.8U
<0.14U
<0.14U
<0.14U
<0.14U
Naphthalene
ug/l
**
<0.15U
<3U
<0.15U
<0.15U
<0.15U
<0.15U
Print Date: 03/01/2016
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005J (Mid-Carbon 2;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005J_Post
DW-005J_Pre
DW-005J
DW-005J
DW-005J
DW-005J
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
n-Hexane
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Pentachloroethane
ug/l
**
<0.23U
<0.23U
1.1
<0.23U
<0.23U
<0.23U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
<1.5U
Acetone
ug/l
**
7.6
<2.2U
6.7
11
10
3.8J
Carbon disulfide
ug/l
**
0.63
0.41J
<0.21U
0.23J
0.29J
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
3.2
<1.3U
5.5
9.4
7.5
5
Methyl tert-butyl ether
ug/l
20
0.12J
<0.09U
<0.09U
<0.09U
<0.09U
0.13J
tert-Butylalcohol
ug/l
**
739
1050
686
1020
1100
1000
Tetrahydrofuran
ug/l
**
9.2
181
10.4
11.8
11.7
13.5
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
0.14J
<0.12U
<0.12U
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
1.7J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Print Date: 03/01/2016
0
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005J (Mid-Carbon 2;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
DW-005J
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
1.1
0.29J
n-Hexane
ug/l
**
1J
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Pentachloroethane
ug/l
**
<0.23U
<0.23U
<0.23U
<0.23U
<0.23U
<0.23U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
2.8J
<1.5U
<4U
<4U
<4U
Acetone
ug/l
**
<2.2U
<2.2U
20.3
<2.2U
<2.2U
5.7
Carbon disulfide
ug/l
**
0.41J
0.27J
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
2.5J
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
Methyl tert-butyl ether
ug/l
20
<0.09U
<0.09U
0.19J
0.23J
0.63
0.64
tert-Butylalcohol
ug/l
**
1340
1230
646
908
1060
496
Tetrahydrofuran
ug/l
**
57.4
35.7
13.1
9.3
8.3
5.3
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Print Date: 03/01/2016
<4U
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005K (Post-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
Date:
Depth (ft):
DW-005K_Post
DW-005K_Pre
DW-005K
DW-005K
DW-005K
DW-005K
09/02/2015
09/02/2015
02/13/2015
03/18/2015
04/28/2015
05/21/2015
0
0
0
0
0
0
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Isopropanol
ug/l
**
<3.9U
<3.9U
<3.9U
<3.9U
<3.9U
<3.9U
Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
n-Hexane
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<4U
<4U
<1.5U
<1.5U
<1.5U
Acetone
ug/l
**
7.6
6.8
6.2
17.4
8.1
4.6J
Carbon disulfide
ug/l
**
<0.21U
0.67
0.27J
0.56
0.4J
0.44J
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
4.3
7.9
5.7
5.3
Methyl tert-butyl ether
ug/l
20
<0.09U
2
0.62
0.36J
0.71
0.15J
n-Butylbenzene
ug/l
**
<0.13U
<0.13U
0.65
<0.13U
<0.13U
<0.13U
tert-Butylalcohol
ug/l
**
10.8
43.6
18.6
33.4
8.4
9.9
Tetrahydrofuran
ug/l
**
2.1J
246
<0.81U
<0.81U
13.5
2.1J
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
0.13J
<0.12U
<0.12U
Constituent
Unit
*Standard
<1.5U
Location:
DW-005K
DW-005K
DW-005K
DW-005K
DW-005K
DW-005K
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
0
0
0
0
0
Depth (ft):
Print Date: 03/01/2016
0
Page 1
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
Last Twelve Months of Results for Compounds Known to Have Detections in Sample DW-005K (Post-Filtration;
2802 NE Rd.)
Analytical Chemistry Report
Calvert Citgo 2815 Northeast Rd North East, Maryland
Matrix: Water
Sample Dates: 02/13/2015-01/21/2016
Project No.: 005977
Regulatory Standard*:
Maryland Department of the Environment (MDE) Modified Drinking Water Standards. Based on EPA National Primary Drinking Water Standards: Office of Water (June 2003) and the most conservative of EPA Drinking Water Advisory levels: Office of Water (April 2012).
Constituent
Unit
*Standard
Location:
DW-005K
DW-005K
DW-005K
DW-005K
DW-005K
DW-005K
Date:
06/23/2015
07/15/2015
10/20/2015
11/18/2015
12/16/2015
01/21/2016
Not Otherwise Specified -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Isopropanol
ug/l
**
<3.9U
<3.9U
<3.9U
<3.9U
<3.9U
Methyl iodide
ug/l
**
<0.19U
<0.19U
<0.19U
<0.19U
<0.19U
<3.9U
0.25J
n-Hexane
ug/l
**
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
<0.22U
Volatile Organic Compounds (VOCs) ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------1,4-Dioxane
ug/l
**
<1.5U
<1.5U
<4U
<4U
<4U
Acetone
ug/l
**
3.9J
6.2
9.7
<2.2U
<2.2U
4J
Carbon disulfide
ug/l
**
0.29J
0.69
<0.21U
<0.21U
<0.21U
<0.21U
Methyl bromide
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
Methyl ethyl ketone
ug/l
**
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
<1.3U
Methyl tert-butyl ether
ug/l
20
1.2
2.6
<0.09U
<0.09U
<0.09U
<0.09U
n-Butylbenzene
ug/l
**
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
<0.13U
tert-Butylalcohol
ug/l
**
16.7
9.1
469
764
1200
706
Tetrahydrofuran
ug/l
**
33.9
299
2.1J
3.6
<0.81U
10.5
Toluene
ug/l
1000
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
<0.12U
Print Date: 03/01/2016
<4U
Page 2
** No Applicable Regulatory Standard
Exceedences of the regulatory standard are printed in bold. # = Reporting limit exceeds regulatory standard. NOC = Not of Concern.
QUALIFIERS: U = Constituent not detected above Method Detection Limit (MDL). J = Estimated Value. < = Indicates that the reported concentration is the Method Detection Limit (MDL). D = Compound identified at a secondary dilution factor. B = Analyte reported
in associated field or trip blank. N = Tentatively Identified Compound (TIC). Y = Tentatively Identified Compound (TIC) also identified in Method Blank. E = Reported result is over instrument calibration range. This result is an estimate; the true result may be higher. C =
Calibration verification recovery was above the method control limit for this analyte. Analyte not detected, data not impacted. F1 = MS and/or MSD Recovery is outside acceptable limits.
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
January 28, 2016
Ms. Natalie Griffith
REPSG
6901 Kingsessing Ave
Suite 201
Philadelphia, PA 19142
Certificate of Analysis
Project Name:
Purchase Order:
2016-CALVERT CITGO
11806
Workorder:
2120209
Workorder ID: 2016-CALVERT CITGO/5977
Dear Ms. Griffith:
Enclosed are the analytical results for samples received by the laboratory on Friday, January 22, 2016.
The ALS Environmental laboratory in Middletown, Pennsylvania is a National Environmental Laboratory
Accreditation Program (NELAP) accredited laboratory and as such, certifies that all applicable test results meet the
requirements of NELAP.
If you have any questions regarding this certificate of analysis, please contact Ms. Susan J Scherer (Project
Coordinator) at (717) 944-5541.
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program and any
applicable state requirements. The test results meet requirements of the current NELAP standards or state
requirements, where applicable. For a specific list of accredited analytes, refer to the certifications section of the
ALS website at www.alsglobal.com/en/Our-Services/Life-Sciences/Environmental/Downloads.
This laboratory report may not be reproduced, except in full, without the written approval of ALS Environmental.
ALS Spring City: 10 Riverside Drive, Spring City, PA 19475 610-948-4903
CC: Ms. S Shourds , Mr. James Manuel
This page is included as part of the Analytical Report and
Ms. Susan J Scherer
Project Coordinator
must be retained as a permanent record thereof.
Page 1 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
SAMPLE SUMMARY
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID
Sample ID
Matrix
Date Collected
Date Received
Collected By
2120209001
DW-005K
Water
1/21/2016 10:40
1/22/2016 20:35
Collected by Client
2120209002
DW-005J
Water
1/21/2016 10:45
1/22/2016 20:35
Collected by Client
2120209003
DW-005I
Water
1/21/2016 10:50
1/22/2016 20:35
Collected by Client
2120209004
DW-005A
Water
1/21/2016 10:55
1/22/2016 20:35
Collected by Client
Notes
-- Samples collected by ALS personnel are done so in accordance with the procedures set forth in the ALS Field Sampling Plan (20 Field Services Sampling Plan).
-- All Waste Water analyses comply with methodology requirements of 40 CFR Part 136.
-- All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141.
-- Unless otherwise noted, all quantitative results for soils are reported on a dry weight basis.
-- The Chain of Custody document is included as part of this report.
-- All Library Search analytes should be regarded as tentative identifications based on the presumptive evidence of the mass spectra.
Concentrations reported are estimated values.
-- Parameters identified as "analyze immediately" require analysis within 15 minutes of collection. Any "analyze immediately" parameters
not listed under the header "Field Parameters" are preformed in the laboratory and are therefore analyzed out of hold time.
-- Method references listed on this report beginning with the prefix “S” followed by a method number (such as S2310B-97)
refer to methods from “Standard Methods for the Examination of Water and Wastewater”.
Standard Acronyms/Flags
J
Indicates an estimated value between the Method Detection Limit (MDL) and the Practical Quantitation Limit (PQL) for the analyte
U
Indicates that the analyte was Not Detected (ND)
N
Indicates presumptive evidence of the presence of a compound
MDL
Method Detection Limit
PQL
Practical Quantitation Limit
RDL
Reporting Detection Limit
ND
Not Detected - indicates that the analyte was Not Detected at the RDL
Cntr
Analysis was performed using this container
RegLmt Regulatory Limit
LCS
Laboratory Control Sample
MS
Matrix Spike
MSD
Matrix Spike Duplicate
DUP
Sample Duplicate
%Rec
Percent Recovery
RPD
Relative Percent Difference
LOD
DoD Limit of Detection
LOQ
DoD Limit of Quantitation
DL
DoD Detection Limit
I
Indicates reported value is greater than or equal to the Method Detection Limit (MDL) but less than the Report Detection Limit (RDL)
(S)
Surrogate Compound
NC
Not Calculated
*
Result outside of QC limits
Page 2 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209001
Date Collected: 1/21/2016 10:40
Sample ID:
DW-005K
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
100
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
28.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/27/16 17:17
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
4.0J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
706
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page 3 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209001
Date Collected: 1/21/2016 10:40
Sample ID:
DW-005K
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.25J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 4 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209001
Date Collected: 1/21/2016 10:40
Sample ID:
DW-005K
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
10.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
90.5
82.4
95.9
83.6
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
1/25/16 16:20
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:20
1/27/16 17:17
1/25/16 16:20
1/27/16 17:17
TMP
TMP
TMP
TMP
A
B
A
B
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 5 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209002
Date Collected: 1/21/2016 10:45
Sample ID:
DW-005J
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
5.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
496
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
100
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
28.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/27/16 17:39
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 6 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209002
Date Collected: 1/21/2016 10:45
Sample ID:
DW-005J
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.29J
ND
ND
ND
ND
ND
ND
0.64
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 7 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209002
Date Collected: 1/21/2016 10:45
Sample ID:
DW-005J
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
5.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
81.2
91.3
99.2
80.6
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
1/25/16 16:42
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/27/16 17:39
1/25/16 16:42
1/25/16 16:42
1/27/16 17:39
TMP
TMP
TMP
TMP
B
A
A
B
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 8 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209003
Date Collected: 1/21/2016 10:50
Sample ID:
DW-005I
Date Received: 1/22/2016 20:35
Parameters
Results
Flag
Units
RDL
MDL
Method
J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
50.0
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
14.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/27/16 18:02
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
4.0J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
327
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page 9 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209003
Date Collected: 1/21/2016 10:50
Sample ID:
DW-005I
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.8
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
0.50
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
0.090
0.56
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 10 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209003
Date Collected: 1/21/2016 10:50
Sample ID:
DW-005I
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
88.8
80.8
82.6
95
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
1/25/16 17:04
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:04
1/27/16 18:02
1/27/16 18:02
1/25/16 17:04
TMP
TMP
TMP
TMP
A
B
B
A
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 11 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209004
Date Collected: 1/21/2016 10:55
Sample ID:
DW-005A
Date Received: 1/22/2016 20:35
Parameters
Units
RDL
MDL
Method
17.3
ND
2.2
ND
ND
ND
ND
ND
ND
ND
ND
3.8
260
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
5.0
2.5
0.50
5.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.5
100
0.50
0.50
0.50
0.50
0.50
2.5
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.2
0.88
0.15
1.6
0.12
0.070
0.19
0.20
0.22
0.23
0.13
1.3
28.0
0.13
0.24
0.10
0.21
0.20
0.88
0.14
0.28
0.18
0.24
0.19
0.22
0.17
0.23
0.16
0.23
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
1.0
12.5
0.50
0.50
0.50
0.15
0.24
0.27
2.2
0.13
0.11
0.11
Results
Flag
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/27/16 18:24
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
VOLATILE ORGANICS
Acetone
Acrylonitrile
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Ethylether
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
tert-Butyl Alcohol
n-Butylbenzene
tert-Butylbenzene
sec-Butylbenzene
Carbon Disulfide
Carbon Tetrachloride
Chloroacetonitrile
Chlorobenzene
1-Chlorobutane
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3-Chloro-1-propene
o-Chlorotoluene
p-Chlorotoluene
1,2-Dibromo-3chloropropane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,1-Dichloro-2-Propanone
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Page 12 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209004
Date Collected: 1/21/2016 10:55
Sample ID:
DW-005A
Date Received: 1/22/2016 20:35
Parameters
Results
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Dichlorofluoromethane
1,3-Dichloropropane
2,2-Dichloropropane
1,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,3-Dichloropropene, Total
Diisopropyl ether
1,4-Dioxane
Ethyl Ether
Ethyl Methacrylate
Ethyl tert-butyl ether
Ethylbenzene
Hexachlorobutadiene
Hexachloroethane
Hexane
2-Hexanone
Iodomethane
Isopropyl Alcohol
Isopropylbenzene
p-Isopropyltoluene
Methacrylonitrile
Methyl methacrylate
Methyl acrylate
Methyl t-Butyl Ether
4-Methyl-2Pentanone(MIBK)
Methylene Chloride
Naphthalene
Nitrobenzene
2-Nitropropane
Pentachloroethane
ND
ND
2.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.27J
ND
ND
ND
ND
ND
ND
170
ND
ND
ND
ND
ND
ND
Flag
J
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
4.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
2.5
0.50
25.0
0.50
0.50
1.0
0.50
1.0
10.0
2.5
0.22
0.11
0.15
0.22
0.19
0.19
0.21
0.14
0.18
0.19
0.24
0.15
0.10
0.23
0.21
4.0
0.21
0.16
0.19
0.18
0.24
0.32
0.22
0.82
0.19
3.9
0.14
0.11
0.23
0.20
0.21
1.8
0.56
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
5.0
2.5
0.50
0.32
0.15
1.8
0.80
0.23
Matrix:
Prepared By
Water
Analyzed
By
Cntr
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/27/16 18:24
1/25/16 17:27
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
Page 13 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
ANALYTICAL RESULTS
Workorder: 2120209 2016-CALVERT CITGO/5977
Lab ID:
2120209004
Date Collected: 1/21/2016 10:55
Sample ID:
DW-005A
Date Received: 1/22/2016 20:35
Units
RDL
MDL
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2.5
0.50
0.50
0.50
0.50
0.50
2.5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.70
0.10
0.11
0.22
0.13
0.17
0.81
0.12
0.27
0.23
0.14
0.15
0.20
0.21
0.18
0.28
0.11
0.11
0.22
0.23
0.12
0.21
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
Parameters
Results
Propionitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
Total Xylenes
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Acetate
Vinyl Chloride
o-Xylene
mp-Xylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Surrogate Recoveries
Results
1,2-Dichlorobenzene-d4 (S)
1,2-Dichlorobenzene-d4 (S)
4-Bromofluorobenzene (S)
4-Bromofluorobenzene (S)
90.5
85.2
97.8
82.6
%
%
%
%
ND
mg/L
Flag
1
Flag
Units
Matrix:
Prepared By
Prepared
By
Water
Analyzed
By
Cntr
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
1/25/16 17:27
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
TMP
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Analyzed
By
Cntr
Limits
Method
70 - 130
70 - 130
70 - 130
70 - 130
EPA 524.2
EPA 524.2
EPA 524.2
EPA 524.2
1/25/16 17:27
1/27/16 18:24
1/25/16 17:27
1/27/16 18:24
TMP
TMP
TMP
TMP
A
B
A
B
S4500ClG-00
1/22/16 23:43
MSA
D
WET CHEMISTRY
Chlorine, Total Residual
0.10
0.009
Ms. Susan J Scherer
Project Coordinator
Page 14 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
NELAP Certifications: NJ PA010 , NY 11759 , PA 22-293 DoD ELAP: A2LA 0818.01
State Certifications: DE ID 11 , MA PA0102 , MD 128 , VA 460157 , WV 343
PARAMETER QUALIFIERS
Lab ID
#
Sample ID
Analytical Method
Analyte
2120209001
1
DW-005K
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120209002
1
DW-005J
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120209003
1
DW-005I
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
2120209004
1
DW-005A
EPA 524.2
Vinyl Acetate
The QC sample type LCS for method EPA 524.2 was outside the control limits for the analyte Vinyl Acetate. The % Recovery was reported as
62.3 and the control limits were 70 to 130.
Page 15 of 16
Report ID: 2120209 - 1/28/2016
DL ID - 29589, QC - 0
Thursday, January 28, 2016 6:14:44 PM
Page 16 of 16