487 - Reclaim R SDS English

487 - Reclaim R SDS English
SAFETY DATA SHEET
Reclaim R Rust/Iron Problems
Section 1. Identification
GHS product identifier
: Reclaim R Rust/Iron Problems
Other means of
identification
: Not available.
Product type
: Solid.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Supplier's details
: Betco Corporation
1001 Brown Avenue
Toledo, OH 43607
www.betco.com
888-462-3826
Emergency telephone
number (with hours of
operation)
: Chemtrec 800-424-9300 (24 Hour)
Section 2. Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
SKIN CORROSION/IRRITATION - Category 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
GHS label elements
Hazard pictograms
:
Signal word
: Danger
Hazard statements
: Harmful if swallowed or in contact with skin.
Causes severe skin burns and eye damage.
Precautionary statements
Prevention
Response
Storage
Disposal
Hazards not otherwise
classified
Date of issue/Date of revision
: Wear protective gloves: > 8 hours (breakthrough time): butyl rubber. Wear eye or face
protection: Recommended: safety glasses. Wear protective clothing. Do not eat, drink
or smoke when using this product. Wash hands thoroughly after handling.
: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water or shower. Wash contaminated clothing before reuse. Immediately call
a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water.
Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or physician.
: Store locked up.
: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: None known.
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
1/11
Reclaim R Rust/Iron Problems
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Other means of
identification
: Not available.
CAS number/other identifiers
CAS number
: Not applicable.
Product code
: 487
Ingredient name
%
CAS number
Ethanedioic acid, hydrate (1:2)
≥90
6153-56-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Ingestion
: Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
: Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
: Get medical attention immediately. Call a poison center or physician. Wash with plenty
of soap and water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for
at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
: Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: Causes serious eye damage.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: Causes severe burns. Harmful in contact with skin.
Ingestion
: Harmful if swallowed.
Over-exposure signs/symptoms
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
2/11
Reclaim R Rust/Iron Problems
Section 4. First aid measures
Eye contact
Inhalation
Skin contact
Ingestion
: Adverse symptoms may include the following:
pain
watering
redness
: No specific data.
: Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: Adverse symptoms may include the following:
stomach pains
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
Specific treatments
Protection of first-aiders
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
: No specific treatment.
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing
media
: None known.
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
: No specific fire or explosion hazard.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
3/11
Reclaim R Rust/Iron Problems
Section 6. Accidental release measures
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill
Large spill
: Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA
filter will reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
: Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not ingest. If during normal use the material presents a
respiratory hazard, use only with adequate ventilation or wear appropriate respirator.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Advice on general
occupational hygiene
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Conditions for safe storage,
including any
incompatibilities
: Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
None.
Appropriate engineering
controls
Environmental exposure
controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
Date of issue/Date of revision
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
4/11
Reclaim R Rust/Iron Problems
Section 8. Exposure controls/personal protection
Eye/face protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Recommended: safety glasses
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
Personal protective
equipment (Pictograms)
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough
time): butyl rubber
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Use a properly fitted, particulate filter respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
:
Section 9. Physical and chemical properties
Appearance
Physical state
: Solid.
Color
: White.
Odor
Odor threshold
pH
: Odorless.
: Not available.
Melting point
: Not available.
: Not available.
Boiling point
Flash point
Evaporation rate
: Not available.
: Not available.
: Not available.
Flammability (solid, gas)
: Not available.
Lower and upper explosive
(flammable) limits
: Not available.
Vapor pressure
: Not available.
Vapor density
Relative density
: Not available.
: 0.83
Solubility
: Easily soluble in the following materials: cold water and hot water.
Partition coefficient: noctanol/water
: Not available.
Auto-ignition temperature
: Not available.
Decomposition temperature
: Not available.
Viscosity
: Not available.
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
5/11
Reclaim R Rust/Iron Problems
Section 10. Stability and reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Information on the likely
routes of exposure
: Routes of entry anticipated: Oral, Dermal.
Potential acute health effects
Eye contact
: Causes serious eye damage.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: Causes severe burns. Harmful in contact with skin.
Ingestion
: Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
6/11
Reclaim R Rust/Iron Problems
Section 11. Toxicological information
Eye contact
Inhalation
Skin contact
Ingestion
: Adverse symptoms may include the following:
pain
watering
redness
: No specific data.
: Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
: Not available.
effects
Potential delayed effects
Long term exposure
Potential immediate
effects
Potential delayed effects
: Not available.
: Not available.
: Not available.
Potential chronic health effects
Not available.
General
: No known significant effects or critical hazards.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route
ATE value
Oral
Dermal
502.5 mg/kg
1105.5 mg/kg
Section 12. Ecological information
Toxicity
Not available.
Persistence and degradability
Not available.
Bioaccumulative potential
Not available.
Mobility in soil
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
7/11
Reclaim R Rust/Iron Problems
Section 12. Ecological information
Soil/water partition
coefficient (KOC)
Other adverse effects
: Not available.
: No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Section 14. Transport information
DOT
Classification
TDG
Classification
Mexico
Classification
ADR/RID
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Not regulated.
UN proper
shipping name
-
-
-
-
-
-
Transport
hazard class(es)
-
-
-
-
-
Packing group
-
-
-
-
-
-
Environmental
hazards
No.
No.
No.
No.
No.
No.
Additional
information
-
-
-
-
-
-
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
: Not available.
Section 15. Regulatory information
U.S. Federal regulations
: TSCA 8(a) CDR Exempt/Partial exemption: Not determined
All components are listed or exempted.
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances
Date of issue/Date of revision
: Not listed
: Not listed
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
8/11
Reclaim R Rust/Iron Problems
Section 15. Regulatory information
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ
: Not applicable.
SARA 311/312
Classification
: Immediate (acute) health hazard
Composition/information on ingredients
Name
%
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Ethanedioic acid, hydrate (1:2)
≥90
No.
No.
Yes.
No.
No.
State regulations
Massachusetts
: None of the components are listed.
New York
: None of the components are listed.
New Jersey
: None of the components are listed.
Pennsylvania
: The following components are listed: ETHANEDIOIC ACID, DIHYDRATE
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia
: All components are listed or exempted.
Canada
: All components are listed or exempted.
China
: All components are listed or exempted.
Europe
: Not determined.
Japan
: All components are listed or exempted.
Malaysia
: Not determined.
New Zealand
: All components are listed or exempted.
Philippines
Republic of Korea
Taiwan
: All components are listed or exempted.
: All components are listed or exempted.
: Not determined.
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
9/11
Reclaim R Rust/Iron Problems
Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health
2
Flammability
0
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Flammability
0
3
Health
0
Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification
Justification
Acute Tox. 4, H302
Acute Tox. 4, H312
Skin Corr. 1B, H314
Eye Dam. 1, H318
Calculation method
Calculation method
Calculation method
Calculation method
History
Date of printing
: 4/2/2015.
Date of issue/Date of
revision
Date of previous issue
: 4/2/2015.
Version
: 1
Key to abbreviations
References
: No previous validation.
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
: Not available.
Indicates information that has changed from previously issued version.
Notice to reader
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
10/11
Reclaim R Rust/Iron Problems
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision
: 4/2/2015.
Date of previous issue
: No previous validation.
Version
:1
11/11
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement