SU100 M

SU100 M
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 1 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
1.
Product and Company
Company Identification
Product Name
: SU100 Magenta
Order No.
: SU100-M-60
Ver.
:1
General Use
: Ink jet printing ink
Product Description
: UV / solvent Inkjet Ink
MSDS Number
:031-37U03MC
Manufacture
Company Name
: Mimaki Engineering Co., Ltd
Address
: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan
Telephone No.
: +81-268-64-2413
Importer/Distributor Established in USA
Company Name
: MIMAKI USA. INC.
Address
: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A
Telephone No.
: 1-678-730-0100
Emergency Telephone No.
2.
: +81-268-64-2413
Hazard Identification
WHMIS Statement
: This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.
CANADIAN WHMIS SYMBOLS
WHMIS Hazard Class
: B3 Combustible liquid
: D2B Toxic materials
Emergency Overview
: May be harmful if swallowed, inhaled, or absorbed through skin
May produce an allergic reaction
May cause skin irritation and/or dermatitis
Potential Health Effects
Inhalation
: May be harmful if inhaled.
Eye Contact
: May cause irritation.
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 2 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
Skin Contact
: May be harmful in contact with skin. Repeated or prolonged skin
contact may cause allergic reactions with susceptible persons.
Ingestion
: May be harmful if swallowed. May cause additional affects as listed
under "Inhalation".
Chronic Effects
Chronic toxicity
: Repeated contact may cause allergic reactions in very susceptible
persons. Avoid repeated exposure.
Aggravated Medical
: Allergies. Skin disorders. Respiratory disorders.
Conditions
Interactions with Other
: Irritants. Sensitizers. Epoxies.
Chemicals
Potential Environmental
: See Section 12 for additional Ecological Information.
Effects
HMIS Rating (scale 0 – 4)
Health = 2*
NFPA Rating (scale 0 – 4)
Health = 2
2*
Flammability= 2
Health
Physical Hazard = 1
2 Flammability
Stability =1
Personal protection = B
1 Physical Hazard
Special =
B
2
Flammability = 2
2
1
Personal protection
*Indicates a chronic health hazard.
3.
Composition / Information On Ingredients
No
Chemical Name
Wt%
CAS No.
1
Diethylene glycol diethyl ether
40-60%
112-36-7
2
Butyrolactone
10-20%
96-48-0
3
2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone
1-5%
106797-53-9
4
phenylbis(2,4,6-trimethylbenzoyl)-phosphine oxide
1-5%
162881-26-7
5
Pentaerythritol tetraacrylate
1-5%
4986-89-4
4.
First Aid Measures
Measures
Inhalation
: Move to fresh air. If symptoms persist, call a physician.
Eye Contact
: Rinse immediately with plenty of water, also under the eyelids, for
at least 15 minutes. If symptoms persist, call a physician.
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 3 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
Skin Contact
: Wash off immediately with plenty of water for at least 15 minutes. If
skin irritation persists, call a physician. Wash off immediately with
soap and plenty of water.
Ingestion
: Do NOT induce vomiting. Drink plenty of water. Immediate medical
attention is not required. Rinse mouth.
Note To Physician
5.
: May cause sensitization of susceptible persons.
Fire Fighting Measures
Measures
Flammable Properties
: Not flammable.
Extinguishing Media
: Use CO2, dry chemical, or foam.
Fire Fighting
: Wear full fire-fighting turn-out gear (full bunker gear) and
Instructions
respiratory protection (self-contained breathing apparatus).
Hazardous Combustion
: Nitrogen oxides (NOx). Carbon oxides.
Products
Explosion Data
Sensitivity to Mechanical
: none
Impact
Sensitivity to Static
: Yes
Discharge
Specific hazards arising
: Thermal decomposition can lead to release of irritating gases and
from the chemical
vapors. In the event of fire and/or explosion do not breathe fumes.
May cause sensitization by inhalation and skin contact.
Protective Equipment
: As in any fire, wear self-contained breathing apparatus
and Precautions for
pressure-demand, MSHA/NIOSH (approved or equivalent) and full
Firefighters
protective gear.
6.
Accidental Release Measures
Measures
Personal Precautions
: Use personal protective equipment. Avoid contact with the skin and
the eyes. Remove all sources of ignition.
Environmental
: Prevent entry into waterways, sewers, basements or confined areas.
precautions
Do not flush into surface water or sanitary sewer system.
Methods for Containment
: Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
: Soak up with inert absorbent material. Pick up and transfer to
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 4 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
properly labeled containers. After cleaning, flush away traces with
water. Prevent product from entering drains.
7.
Handling And
And Storage
Handling
: Ensure adequate ventilation. Wear personal protective equipment.
Storage
: Keep out of the reach of children. Keep container tightly closed. Keep
away from heat and sources of ignition. Keep containers tightly closed
in a cool, well-ventilated place.
8.
Exposure Controls / Personal Protection
Exposure Controls
Occupational Exposure Controls
Engineering Controls
: Showers
Eyewash stations
Ventilation systems
Personal Protection
Respiratory Protection
: If exposure limits are exceeded or irritation is experienced,
NIOSH/MSHA approved respiratory protection should be worn.
Positive-pressure supplied air respirators may be required for
high airborne contaminant concentrations. Respiratory
protection must be provided in accordance with current local
regulations.
Hand Protection
: Wear protective gloves.
Eye Protection
: Tightly fitting safety goggles.
Skin Protection
: Wear protective clothing.
Hygiene measures
: When using, do not eat, drink or smoke. Remove and wash
contaminated clothing before re-use.
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
9.
Physical And
And Chemical Properties
Appearance
- Physical state
: liquid
- Color
: Magenta
Odor
: Slight glycol ether
pH
: No data available
Boiling Point / Boiling Range
: > 212 °F
Melting Point / Melting Range
: No data available
Flash Point
: > 194 °F
Auto ignition temperature
: No data available
Explosive Properties
: No data available
Oxidizing Properties
: No data available
Vapor Pressure
: 0.48 mm/Hg @ 20 C
Weight per Gallon (lbs)
: 8.57
Water solubility
: Partially insoluble
Viscosity
: No data available
Vapor density
: Heavier than air
Evaporation Rate
: No data available
Density
: No data available
EPA VOC (g/l)
: No data available
VOC Content of Material
: 711 grams per liter
VOC Content of Coating less Water and
: 711 grams per liter
Exempt Solvents
10. Stability
tability And Reactivity
Reactivity
Conditions To Avoid
: Extremes of temperature and direct sunlight.
Stability
: Stable under recommended storage conditions.
Materials To Avoid
: Strong oxidizing agents, strong acids, and strong bases.
Hazardous Reactions/
: Carbon oxides. Nitrogen oxides (NOx).
Decomposition Products
Hazardous
Polymerization
: No information available.
Page 5 of 9
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 6 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
11. Toxicological
oxicological Information
Acute Toxicity
: There is no data available for this product
Chronic Toxicity
: Repeated contact may cause allergic reactions in very susceptible
persons. Avoid repeated exposure.
Component Information
Chemical Name
LD50 Oral
LD50 Dermal
LC50
Inhalation
Diethylene glycol diethyl ether
4970 mg/kg ( Rat )
Butyrolactone
1540 mg/kg ( Rat )
6700 µL/kg ( Rabbit )
2.68 mg/L
( Rat ) 4 h
2-hydroxy-1-[4-(2-hydroxyethoxy)p
4082 mg/kg ( Rat )
henyl]-2-methyl-1-propanone
Carcinogenicity
: The table below indicates whether each agency has listed any
ingredient as a carcinogen
Chemical Name
ACGIH
Butyrolactone
IARC
NTP
Group 3
ACGIH: (American Conference of Governmental Industrial Hygienists)
A1 - Known Human Carcinogen
A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
A4 - Not Classifiable as a Human Carcinogen
IARC: (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Group 1 - Carcinogenic to Humans
Group 2A - Probably Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
NTP: (National
(National Toxicity Program)
Known - Known Carcinogen
Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen
OSHA: (Occupational Safety & Health Administration)
X - Present
OSHA
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 7 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
12. Ecological Information
Information
Handling is noted because it might influence the environment when
leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the
river, and the drain ditch.
Ecotoxicity
: The environmental impact of this product has not been fully
investigated.
Chemical Name
Octonol Water Partition Coefficient (log pow)
Butyrolactone
-0.566
13. Disposal Considerations
Considerations
Waste Disposal Methods
: Dispose of in accordance with federal, state, and local regulations.
Contaminated packaging
: Do not re-use empty containers.
US EPA Waste Number
: U220
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Us Department of Transportation (DOT)
: Not regulated
Sea Transport (IMDG)
: Not regulated
Air Transport (ICAO/IATA)
: Not regulated
TDG
: Not regulated
MEX
: Not regulated
ADR/RID
: Not regulated
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 8 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
ADN
: Not regulated
15. Regulatory Information
OSHA Status
: This product is NOT considered hazardous under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
TSCA Status
: The ingredients below are listed.
Diethylene glycol diethyl ether
Butyrolactone
2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone
Phenylbis(2,4,6-trimethylbenzoyl)-phosphine oxide
Pentaerythritol tetraacrylate
: Not Applicable
CERCLA
Reportable Quantity
(40 CFR 117, 302)
SARA TitleⅢ
Section 302
: Not Applicable
(40 CFR 355)
Section 311/312 (40 CFR 370)
Acute Health Hazard
Yes
Chronic Health Hazard
Yes
Fire Hazard
Yes
Sudden Release of Pressure Hazard
no
Reactive Hazard
Yes
Section 313 (40 CFR 372)
Chemical Name
SARA 313 - Threshold Values %
Diethylene glycol diethyl ether
1.0
California
: This product contains the following Proposition 65 chemicals
Proposition 65
Chemical Name
California Prop. 65
toluene
Developmental Female Reproductive
Product Name: SU100 Magenta
MSDS No.031-37U03MC
First issue: 2012/06/14
Material Safety Data Sheets
Page 9 of 9
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
U.S. State Right-to-Know Regulations
Chemical
Massachusetts
New Jersey
Pennsylvania
Illinois
×
×
×
×
×
×
Rhode Island
Name
Diethylene
glycol
diethylether
×
toluene
Others
×
: Please refer to any other federal, state and local regulations.
16. Other Information
Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use in
combination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon this
information.
Revision history
Version
Date
Content
1.0
2012/06/14
First issue
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