31538 - MSDS Sheet

31538 - MSDS Sheet
Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT - LO-VOC
* * * Section 1 - Product and Company Identification * * *
MSDS #1101E
Part Numbers: Clear -30350, 31017, 31018, 31019, 31020, 31021, 31550, 31551, 31552, 31553, 31946,
31947, 31948, 31949, 32222, 32223, 32224, 32225 Gray - 30883, 30884, 30885, 30886, 30887, 31930,
31931, 31932, 31933
Manufacturer Information
Oatey Co.
4700 West 160th Street
Cleveland, OH 44135
Phone: 216-267-7100
For Emergency First Aid call 1-877-740-5015. For chemical
transportation emergencies ONLY, call Chemtrec at 1-800-4249300. Outside the U.S. 1- 703-527-3887.
* * * Section 2 - Hazards Identification * * *
GHS Classification:
Flammable Liquids - Category 2
Acute Toxicity Oral - Category 4
Acute Toxicity Dermal - Category 4
Acute Toxicity Inhalation - Category 4
Eye Damage/Irritation - Category 2A
Carcinogenicity - Category 2
Specific Target Organ Toxicity Single Exposure - Category 3
GHS LABEL ELEMENTS
Symbol(s)
Signal Word
Danger
Hazard Statements
Highly flammable liquid and vapor.
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Causes serious eye irritation.
Contains a chemical classified by the US EPA as a suspected possible carcinogen.
May cause respiratory irritation.
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
May cause drowsiness or dizziness.
Precautionary Statements
Prevention
Keep away from heat/sparks/open flames and hot surfaces. - No smoking.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/eye protection/face protection.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing fume/gas/mist/vapors.
Use only outdoors or in a well-ventilated area.
Response
If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
contaminated clothing before reuse.
If swallowed: Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Do not induce vomiting.
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center
or doctor/physician if you feel unwell.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a poison center or doctor/physician.
If exposed or concerned Get medical advice/attention.
In case of fire: Use dry chemical, CO2, or foam to extinguish fire.
Storage
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
* * * Section 3 - Composition / Information on Ingredients * * *
CAS #
109-99-9
67-64-1
78-93-3
9002-86-2
108-94-1
112945-52-5
Component
Tetrahydrofuran
Acetone
Methyl ethyl ketone
PVC (Chloroethylene, polymer)
Cyclohexanone
Silica, amorphous, fumed, crystalline-free
Percent
30-50
10-25
10-25
12-20
10-20
1-5
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
If material gets into eyes or if fumes cause irritation, immediately flush eyes with plenty of water until chemical is
removed. If irritation persists, get medical attention immediately.
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
First Aid: Skin
Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention
if irritation develops. Remove dried cement with hand cleaner or baby oil.
First Aid: Ingestion
DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is
unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital
emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical
emergency treatment center or hospital.
First Aid: Inhalation
If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen.
Administer artificial respiration if breathing has stopped. Seek immediate medical attention.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
Highly flammable liquid and vapor. Keep away from heat and all sources of ignition including sparks, flames,
lighted cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than
air and may travel to a remote ignition source and flash back. This product contains tetrahydrofuran that may form
explosive organic peroxide when exposed to air or light or with age.
Hazardous Combustion Products
Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen
chloride.
Extinguishing Media
Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be
ineffective as an extinguishing agent.
Unsuitable Extinguishing Media
None.
Fire Fighting Equipment/Instructions
Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires
in areas where chemicals are used or stored.
* * * Section 6 - Accidental Release Measures * * *
Recovery and Neutralization
Stop leak if it can be done without risk.
Materials and Methods for Clean-Up
Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent such as sand, earth or
other noncombusting material. Put absorbent material in covered, labeled metal containers.
Emergency Measures
Isolate area. Keep unnecessary personnel away.
Personal Precautions and Protective Equipment
Personnel cleaning up the spill should wear appropriate personal protective equipment, including respirators if
vapor concentrations are high.
Environmental Precautions
Prevent liquid from entering watercourses, sewers and natural waterways.
Prevention of Secondary Hazards
None
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation
(equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep
product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas.
Keep containers closed when not in use. Other: "Empty" containers retain product residue and can be hazardous.
Follow all SDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers.
Storage Procedures
Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in
use.
Incompatibilities
Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium,
calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Component Exposure Limits
Tetrahydrofuran (109-99-9)
ACGIH:
OSHA:
NIOSH:
50 ppm TWA
100 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
200 ppm TWA; 590 mg/m3 TWA
200 ppm TWA; 590 mg/m3 TWA
250 ppm STEL; 735 mg/m3 STEL
Acetone (67-64-1)
ACGIH:
OSHA:
NIOSH:
500 ppm TWA
750 ppm STEL
1000 ppm TWA; 2400 mg/m3 TWA
250 ppm TWA; 590 mg/m3 TWA
Methyl ethyl ketone (78-93-3)
ACGIH:
OSHA:
NIOSH:
200 ppm TWA
300 ppm STEL
200 ppm TWA; 590 mg/m3 TWA
200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
PVC (Chloroethylene, polymer) (9002-86-2)
ACGIH:
1 mg/m3 TWA (respirable fraction)
Cyclohexanone (108-94-1)
ACGIH:
OSHA:
NIOSH:
20 ppm TWA
50 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
50 ppm TWA; 200 mg/m3 TWA
25 ppm TWA; 100 mg/m3 TWA
Potential for dermal absorption
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
Engineering Measures
Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below
recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosionproof or set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or
hot surfaces.
Personal Protective Equipment: Respiratory
For operations where the exposure limit may be exceeded, a NIOSH approved organic vapor respirator or
supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration,
select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use selfcontained breathing apparatus.
Personal Protective Equipment: Hands
Rubber gloves are suitable for normal use of the product. For long exposures chemical resistant gloves may be
required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact.
Personal Protective Equipment: Eyes
Safety glasses with side shields or safety goggles.
Personal Protective Equipment: Skin and Body
No additional protective equipment needed.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance:
Physical State:
Vapor Pressure:
Boiling Point:
Solubility (H2O):
Evaporation Rate:
Octanol/H2O Coeff.:
Flash Point Method:
Lower Flammability Limit
(LFL):
Auto Ignition:
Clear
Liquid
145 mmHg @ 20°C
151°F (66°C)
Negligible
(BUAC = 1) = 5.5 - 8.0
ND
CCCFP
1.8
Odor:
pH:
Vapor Density:
Melting Point:
Specific Gravity:
VOC:
Flash Point:
Upper Flammability Limit
(UFL):
Burning Rate:
Ether-like
NA
2.5
NA
0.93 +/- 0.02 @ 20°C
80-84%
14-23°F (-10 to -5°C)
11.8
ND
ND
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Hazardous Reaction Potential
Will not occur.
Conditions to Avoid
Avoid heat, sparks, flames and other sources of ignition.
Incompatible Products
Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium,
calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber.
Hazardous Decomposition Products
Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen
chloride.
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
* * * Section 11 - Toxicological Information * * *
Acute Toxicity
Component Analysis - LD50/LC50
Tetrahydrofuran (109-99-9)
Inhalation LC50 Rat 53.9 mg/L 4 h; Inhalation LC50 Rat 180 mg/L 1 h; Oral LD50 Rat 1650 mg/kg
Acetone (67-64-1)
Oral LD50 Rat 5800 mg/kg
Methyl ethyl ketone (78-93-3)
Inhalation LC50 Mouse 32 g/m3 4 h; Oral LD50 Rat 2737 mg/kg; Dermal LD50 Rabbit 6480 mg/kg
Cyclohexanone (108-94-1)
Inhalation LC50 Rat 10.7 mg/L 4 h; Inhalation LC50 Rat 8000 ppm 4 h; Oral LD50 Rat 800 mg/kg; Dermal LD50
Rabbit 948 mg/kg
Silica, amorphous, fumed, crystalline-free (112945-52-5)
Oral LD50 Rat 3160 mg/kg
Potential Health Effects: Skin Corrosion Property/Stimulativeness
May cause irritation with redness, itching and pain. Methyl ethyl ketone and cyclohexanone may be absorbed
through the skin causing effects similar to those listed under inhalation.
Potential Health Effects: Eye Critical Damage/ Stimulativeness
Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes.
May cause eye damage.
Potential Health Effects: Ingestion
Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting
can cause chemical pneumonia and lung damage. May cause kidney and liver damage.
Potential Health Effects: Inhalation
Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness,
dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system
depression, narcosis and unconsciousness. May cause kidney, liver and lung damage.
Respiratory Organs Sensitization/Skin Sensitization
This product is not reported to have any skin sensitization effects.
Generative Cell Mutagenicity
Cyclohexanone has been positive in bacterial and mammalian assays. Acetone, methyl ethyl ketone and
tetrahydrofuran are generally thought not to be mutagenic.
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
Carcinogenicity
A: General Product Information
In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on
THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while
neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could
not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse
findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review
concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential"
following exposure to THF by all routes of exposure.
B: Component Carcinogenicity
Tetrahydrofuran (109-99-9)
ACGIH:
A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
Acetone (67-64-1)
ACGIH:
A4 - Not Classifiable as a Human Carcinogen
PVC (Chloroethylene, polymer) (9002-86-2)
ACGIH:
IARC:
A4 - Not Classifiable as a Human Carcinogen
Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))
Cyclohexanone (108-94-1)
ACGIH:
IARC:
A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable))
Silica, amorphous, fumed, crystalline-free (112945-52-5)
IARC:
Monograph 68 [1997] (listed under Amorphous silica) (Group 3 (not classifiable))
Reproductive Toxicity
Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal toxicity and birth defects in
laboratory animals. Acetone and tetrahydrofuran has been found to cause adverse developmental effects only
when exposure levels cause other toxic effects to the mother.
Specified Target Organ General Toxicity: Single Exposure
May cause respiratory irritation. Inhalation of high concentrations may cause central nervous system depression,
narcosis and unconsciousness. May cause kidney, liver and lung damage.
Specified Target Organ General Toxicity: Repeated Exposure
This product is not reported to have any specific target organ toxicity repeat exposure effects.
Aspiration Respiratory Organs Hazard
Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney
and liver damage.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
This product is not expected to be toxic to aquatic organisms.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Tetrahydrofuran (109-99-9)
Test & Species
Conditions
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
96 Hr LC50 Pimephales promelas
1970-2360 mg/L
[flow-through]
2700-3600 mg/L
[static]
5930 mg/L
96 Hr LC50 Pimephales promelas
24 Hr EC50 Daphnia magna
Acetone (67-64-1)
Test & Species
Conditions
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Pimephales promelas
4.74 - 6.33 mL/L
6210 - 8120 mg/L
[static]
8300 mg/L
10294 - 17704 mg/L
[Static]
12600 - 12700 mg/L
96 Hr LC50 Lepomis macrochirus
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna
Methyl ethyl ketone (78-93-3)
Test & Species
Conditions
96 Hr LC50 Pimephales promelas
3130-3320 mg/L
[flow-through]
>520 mg/L
5091 mg/L
4025 - 6440 mg/L
[Static]
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna
Cyclohexanone (108-94-1)
Test & Species
Conditions
96 Hr LC50 Pimephales promelas
481-578 mg/L [flowthrough]
8.9 mg/L
20 mg/L
800 mg/L
96 Hr LC50 Pimephales promelas
96 Hr EC50 Chlorella vulgaris
24 Hr EC50 Daphnia magna
Persistence/Degradability
No information available for the product.
Bioaccumulation
No information available for the product.
Mobility in Soil
No information available for the product.
* * * Section 13 - Disposal Considerations * * *
Waste Disposal Instructions
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging
Dispose of contents/container in accordance with local/regional/national/international regulations.
* * * Section 14 - Transportation Information * * *
DOT Information
For Greater than 1 liter (0.3 gal):
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
Shipping Name: Adhesives
UN #: 1133 Hazard Class: 3 Packing Group: II
Required Label(s): Flammable Liquid
For Less than 1 liter (0.3 gal):
Shipping Name: Consumer Commodity, ORM-D
IMDG Information
For Greater than 1 liter (0.3 gal):
Shipping Name: Adhesives
UN #: 1133 Hazard Class: 3 Packing Group: II
Required Label(s): Flammable Liquid
For Less than 1 liter (0.3 gal):
Shipping Name: Adhesives
UN #: 1133 Hazard Class: 3 Packing Group: II
Required Label(s): None (Limited Quantities are expected from labeling)
* * * Section 15 - Regulatory Information * * *
Regulatory Information
US Federal Regulations
Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Tetrahydrofuran (109-99-9)
CERCLA:
1000 lb final RQ; 454 kg final RQ
Acetone (67-64-1)
CERCLA:
5000 lb final RQ; 2270 kg final RQ
Methyl ethyl ketone (78-93-3)
CERCLA:
5000 lb final RQ; 2270 kg final RQ
Cyclohexanone (108-94-1)
CERCLA:
5000 lb final RQ; 2270 kg final RQ
State Regulations
Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component
Tetrahydrofuran
Acetone
Methyl ethyl ketone
PVC (Chloroethylene, polymer)
Cyclohexanone
CAS
109-99-9
67-64-1
78-93-3
9002-86-2
108-94-1
CA
Yes
Yes
Yes
No
Yes
MA
Yes
Yes
Yes
No
Yes
MN
Yes
Yes
Yes
No
Yes
NJ
Yes
Yes
Yes
Yes
Yes
PA
Yes
Yes
Yes
No
Yes
RI
No
No
No
No
No
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Material Name: OATEY PVC MEDIUM CLEAR or GRAY CEMENT – LO-VOC
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
CAS #
Minimum Concentration
Component
Tetrahydrofuran
Acetone
Methyl ethyl ketone
Cyclohexanone
109-99-9
67-64-1
78-93-3
108-94-1
1%
1%
1%
0.1 %
Additional Regulatory Information
A: General Product Information
This product contains trace amounts of chemicals known to the State of California to cause cancer. Under normal
use conditions, exposure to these chemicals at levels above the State of California "No Significant Risk Level"
(NSRL) are unlikely. The use of proper personal protective equipment (PPE) and ventilation guidelines noted in
Section 8 will minimize exposure to these chemicals.
B: Component Analysis - Inventory
Component
Tetrahydrofuran
Acetone
Methyl ethyl ketone
PVC (Chloroethylene, polymer)
Cyclohexanone
Silica, amorphous, fumed, crystalline-free
CAS #
109-99-9
67-64-1
78-93-3
9002-86-2
108-94-1
112945-52-5
TSCA
Yes
Yes
Yes
Yes
Yes
No
CAN
DSL
DSL
DSL
DSL
DSL
DSL
EEC
EINECS
EINECS
EINECS
ELINCS
EINECS
No
* * * Section 16 - Other Information * * *
Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference
of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety
and Health Administration., NJTSR = New Jersey Trade Secret Registry.
Literature References
None
Other Information
NFPA and HMIS:
NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None
HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the
best of our knowledge. However, we cannot give any guarantees regarding information from other sources, and
expressly do not make warranties, nor assume any liability for its use.
End of Sheet
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Issue Date 06/06/12
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Print Date: 9/27/2012
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