938S ... AXALTA COATING SYSTEMS CANADA COMPANY ...

938S          ... AXALTA COATING SYSTEMS CANADA COMPANY      ...
938S
AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
****** SECTION
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1 - Product and Company Identification ******
Supplier:
Axalta Coating Systems Canada Company
408 Fairall Street
Ajax, ON, L1S 1R6
Manufacturer:
Axalta Coating Systems, LLC
1007 Market Street, D-13111
Wilmington, DE, 19898
Telephone:
Product Information:
Medical Emergency (24 hours):
Transportation Emergency (24 hours):
(800) 387-2122
(855) 274-5698
(613) 996-6666(CANUTEC)
PRODUCT IDENTIFIER: ACTIVATOR
PRODUCT CODE:
938S
Product Use:
PAINT ADDITIVE
Prepared by:
Regulatory Affairs
Chemical Family:
Primer-Solventborne
120123
Copyright (c) 2013 Axalta Coating Systems Canada Company.
reserved.
Copies may be made only for those using
Axalta Coating Systems products.
All rights
****** SECTION 2 - Composition, Information on Ingredients ******
CAS #
Ingredient
(%)
Exposure Limits**
------------ ---------------------------------------------71-36-3
N-BUTYL ALCOHOL
10- 30
A
20.0 ppm
O 100.0 ppm
D
50.0 ppm
15 min TWA
D
25.0 ppm
8 & 12 hour TWA
110-12-3
METHYL ISOAMYL KETONE
100-41-4
ETHYLBENZENE
1330-20-7
XYLENE
7- 13
0.5-
3-
A
O
20.0 ppm
None
1.5
A
O
D
20.0 ppm
100.0 ppm
25.0 ppm
8 & 12 hour TWA
7
A
150.0 ppm
15 min STEL
100.0 ppm
100.0 ppm
A
O
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AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
****** SECTION
64742-94-5
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2 - Composition, Information on Ingredients ******
Cont'd
AROMATIC HYDROCARBON
15- 40
D
100.0 ppm
8 & 12 hour TWA
D
100.0 ppm
8 & 12 hour TWA
None
None
A
O
91-20-3
NAPHTHALENE
0.5-
1.5
A
A
O
D
98-82-8
CUMENE
79-20-9
METHYL ACETATE
0.1-
1-
1.0
A
O
50.0 ppm
50.0 ppm
Skin
5
A
250.0 ppm
15 min STEL
200.0 ppm
200.0 ppm
A
O
Not Avail
EPOXY RESIN
15.0 ppm
CEIL
Skin
10.0 ppm
Skin
10.0 ppm
0.1 ppm
8 & 12 hour TWA
40- 70
A
O
None
None
** A = ACGIH, O = OSHA, D = Dupont, TWAEV = Ontario, S = Supplier
D=Dupont Results obtained from E.I. duPont de Nemours and Company
(For additional definition of terms, see section 16)
Limits are 8-hour TWA unless otherwise specified.
****** SECTION
3 - Hazards Information ******
Emergency Overview:
WARNING! FLAMMABLE LIQUID AND VAPOR. VAPORS AND SPRAY MIST HARMFUL IF
INHALED.
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS DIZZINESS,
HEADACHE, OR NAUSEA. MAY CAUSE NOSE, THROAT, EYE AND SKIN
IRRITATION. CAN BE ABSORBED THROUGH THE SKIN.
Potential Health Effects:
Inhalation:
May cause nose and throat irritation.
May cause nervous system
depression characterized by the following progressive steps: headache,
dizziness, nausea, staggering gait, confusion, unconsciousness.
Reports have associated repeated and prolonged overexposure to
938S
AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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3 - Hazards Information ******
Cont'd
solvents with permanent brain and nervous system damage.
Ingestion:
May result in gastrointestinal distress.
Skin or eye contact:
May cause irritation or burning of the eyes. Repeated or prolonged
liquid contact may cause skin irritation with discomfort and
dermatitis.
Other Potential Health Effects in addition to those listed above:
N-BUTYL ALCOHOL
May cause abnormal blood forming function with anemia.
Liquid splashes in the eye may result in chemical burns.
ETHYLBENZENE
Is an IARC, NTP or OSHA carcinogen.
Increased susceptibility to the effects of this material may be
observed in people with preexisting disease of any of the following:
central nervous system
kidneys
liver
lungs
Recurrent overexposure may result in liver and kidney injury.
Studies in laboratory animals have shown reproductive, embryotoxic
and developmental effects.
WARNING: This chemical is known to the State of California to cause
cancer.
XYLENE
Increased susceptibility to the effects of this material may be
observed in people with preexisting disease of any of the following:
bone marrow
cardiovascular system
central nervous system
kidneys
liver
lungs
Recurrent overexposure may result in liver and kidney injury.
High exposures may produce irregular heart beats.
Canada classifies Xylene as a developmental toxin as high exposures
to xylenes in some animal studies have been reported to cause health
effects on the developing fetus/embryo. These effects were often at
levels toxic to the adult animal. The significance of these effects
to humans is not known.
Repeated or prolonged skin contact may cause: irritation dryness
cracking of the skin
AROMATIC HYDROCARBON
Laboratory studies with rats have shown that petroleum distillates
can cause kidney damage and kidney or liver tumors. These effects were
not seen in similar studies with guinea pigs, dogs, or monkeys.
Several studies evaluating petroleum workers have not shown a
significant increase of kidney damage or an increase in kidney or
liver tumors.
NAPHTHALENE
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AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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Cont'd
Is an IARC, NTP or OSHA carcinogen.
Tests in some laboratory animals demonstrate carcinogenic activity.
Increased susceptibility to the effects of this material may be
observed in people with preexisting disease of any of the following:
kidneys
liver
Recurrent overexposure may result in liver and kidney injury.
WARNING: This chemical is known to the State of California to cause
cancer.
CUMENE
WARNING: This chemical is known to the State of California to cause
cancer.
****** SECTION
4 - First Aid Measures ******
First Aid Procedures:
Inhalation:
If affected by inhalation of vapor or spray mist, move to fresh air.
If not breathing, give artificial respiration, preferably
mouth-to-mouth. If breathing difficulty persists, or occurs later,
consult a physician.
Ingestion:
In the unlikely event of ingestion, DO NOT induce vomiting.
Call a
physician immediately and have names of ingredients available.
Skin or eye:
In case of contact, immediately flush with plenty of water for at
least 15 minutes; call a physician. In case of skin contact, wash
thoroughly with soap and water. If irritation occurs, contact a
physician.
****** SECTION
5 - Firefighting Measures ******
Flash Point (Method)
Between 24 to 38 deg C
Closed Cup
Approx. flammable limits
LFL
0.8 % UFL 11.2 %
Auto ignition temperature
343.3 - 550.0 Deg C
Hazardous Combustion Products:
CO, C02, smoke, and oxides of any heavy metals that are reported in
"Composition, Information on Ingredients" section.
Extinguishing media:
Universal aqueous film-forming foam, carbon dioxide, dry chemical.
Special fire fighting procedures:
Full protective equipment, including self-contained breathing
apparatus, is recommended. Water from fog nozzles may be used to
prevent pressure build-up.
Fire & explosion hazards:
Flammable liquid. Vapor/air mixture will burn when an ignition
source is present.
938S
AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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6 - Accidental Release Measures ******
Procedures for cleaning up spills or leaks:
Ventilate area. Remove sources of ignition. Prevent skin and eye
contact and breathing of vapor.
Wear a properly fitted air-purifying respirator with organic vapor
cartridges (NIOSH approved TC-23C), eye protection, gloves and
protective clothing. Confine, remove with inert absorbent, and
dispose of properly.
****** SECTION
7 - Handling and Storage ******
Precautions to be taken in handling and storing:
Observe label precautions. Keep away from heat, sparks, flame, static
discharge and other sources of ignition. VAPORS MAY CAUSE FLASH FIRE.
Close container after each use. Ground containers when pouring.
Do not transfer contents to bottles or unlabeled containers. Wash
thoroughly after handling and before eating or smoking. Do not store
above 120 deg F.
OSHA/NFPA Storage Classification:
IC
Other precautions:
If material is a coating: do not sand, flame cut, braze or weld dry
coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation , and gloves.
****** SECTION
8 - Exposure Controls or Personal Protection ******
Engineering controls and work practices:
Ventilation:
Provide sufficient ventilation in volume and pattern to keep
contaminants below applicable exposure limits.
Personal Protective Equipment:
Recommended PPE:
Respiratory:
Do not breathe vapors or mists.
Wear a properly fitted
air-purifying respirator with organic vapor cartridges (NIOSH approved
TC-23C) and particulate filter (NIOSH TC-84A) during application and
until all vapors and spray mists are exhausted. In confined spaces,
or in situations where continuous spray operations are typical, or if
proper air-purifying respirator fit is not possible, wear a positive
pressure, supplied-air respirator (NIOSH TC-19C). In all cases,
follow respirator manufacturer s directions for respirator use. Do
not permit anyone without protection in the painting area.
Protective clothing:
Neoprene gloves and coveralls are recommended.
Eye protection:
Desirable in all industrial situations. Goggles are preferred to
prevent eye irritation.
If safety glasses are substituted, include
splash guard or side shields.
938S
AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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9 - Physical and Chemical Properties ******
Evaporation Rate
Vapor Pressure of principal solvent
Solubility of solvent in water
Vapour density (principal solvent)
Approx. Boiling range (deg C)
Approx. Freezing range (deg C)
Gallon weight (lbs/US gal)
Specific gravity
Percent volatile by volume
Percent volatile by weight
Percent solids by volume
Percent solids by weight
Odour
Appearance
Physical state
pH (waterborne systems only)
VOC* less exempt (g/l)
VOC* as packaged (g/l)
Slower than Ether
10.00 mm @ 20 Deg C
NIL
4.80
117 - 213 DEG (C)
-88
DEG (C)
7.75
0.93
49.43
45.21
50.57
54.79
Characteristic Paint Odour
semi-viscous liquid
Liquid
Not Applicable
410.1
402.5
* VOC less exempt (theoretical) and VOC as packaged (theoretical)
are based upon the VOC of the packaged material at the point of
manufacture.
****** SECTION 10 - Stability and Reactivity ******
Stability:
Stable
Incompatibility (materials to avoid):
None reasonably foreseeable
Hazardous decomposition products:
CO, C02, smoke, and oxides of any heavy metals that are reported in
"Composition, Information on Ingredients" section.
Hazardous polymerization:
Will not occur.
Sensitivity to static discharge:
Solvent vapors in air may explode if static grounding and bonding is
not used during transfer of this product.
Sensitivity to mechanical impact:
None Known
****** SECTION 11 - Toxicological Information ******
N-BUTYL ALCOHOL
Oral LD50
Dermal LD50
Inhalation LC50
790 mg/kg
3400 mg/kg
8000 ppm
METHYL ISOAMYL KETONE
Oral LD50
5700 mg/kg
Dermal LD50
16280 mg/kg
8 h
8 h
4 h
Rat
Rabbit
Rat
RTECS
RTECS
CCOHS
Rat
Guinea Pig
SUPPLIER MSDS
SUPPLIER MSDS
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AXALTA MATERIAL SAFETY DATA SHEET
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****** SECTION 11 - Toxicological Information ******
Cont'd
Inhalation LC50
Oral LOEL
Inhalation NOEL
Inhalation LOEL
3813
2000
200
1000
ppm
mg/kg
ppb
ppm
6
24
2304
2304
h
h
h
h
Rat
Rat
Rat
Rat
SUPPLIER
SUPPLIER
SUPPLIER
SUPPLIER
MSDS
MSDS
MSDS
MSDS
ETHYLBENZENE
Oral LD50
Dermal LD50
Inhalation LC50
3500 mg/kg
18 g/kg
4000 ppm
Rat
Rabbit
4 HR Rat
XYLENE
Oral LD50
Dermal LD50
Inhalation LC50
4300 mg/kg
1700 mg/kg
5000 ppm
4 h
Rat
Rabbit
Rat
AROMATIC HYDROCARBON
Oral LD50
Dermal LD50
Inhalation LC50
Inhalation LD50
13
2000
3800
580
ml/kg
mg/kg
mg/m3
ppm
Rat
Rabbit
4 HR Rat
4 h Rat
NAPHTHALENE
Oral LD50
Dermal LD50
Dermal LD50
Inhalation LC50
490
2500
20
340
mg/kg
mg/kg
g/kg
mg/m3
1 h
Rat
Rat
Rabbit
Rat
RTECS
RTECS
RTECS
RTECS
4 h
Rat
Rabbit
Rat
SUPPLIER MSDS
SUPPLIER MSDS
SUPPLIER MSDS
4 h
Rat
Rabbit
Rat
SUPPLIER MSDS
SUPPLIER MSDS
SUPPLIER MSDS
CUMENE
Oral LD50
Dermal LD50
Inhalation LC50
1400 mg/kg
10578 mg/kg
39 mg/l
METHYL ACETATE
Oral LD50
Dermal LD50
Inhalation LC50
5000 mg/kg
5000 mg/kg
16000 ppm
RTECS
RTECS
Patty's
RTECS
RTECS
RTECS
SUPPLIER
SUPPLIER
SUPPLIER
SUPPLIER
MSDS
MSDS
MSDS
MSDS
For all other ingredients, no information is available.
Key:
RTECHS CCOHS
Patty's -
Registry of Toxic Effects of Chemical Substances
Canadian Center for Occupational Health and Safety
Patty's Industrial Hygiene and Toxicology, 3rd Edition
****** SECTION 12 - Ecological Information ******
N-BUTYL ALCOHOL
1855 mg/kg
1 day
Daphnia
AQUATIC PLANTS
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AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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****** SECTION 12 - Ecological Information ******
Cont'd
1000 mg/kg
1770 mg/kg
1 day
2 days
Goldfish
Golden Orfe
FISH
FISH
METHYL ISOAMYL KETONE
560 mg/l
164 mg/l
1 day
2 days
Daphnia
Golden Orfe
AQUATIC PLANTS
FISH
ETHYLBENZENE
2 mg/l
5 mg/l
4 mg/l
48 h
72 h
96 h
INVERTEBRATES
AQUATIC PLANTS
FISH
XYLENE
22
21
10
10
24
mg/l
mg/l
mg/l
mg/l
mg/l
4
4
1
1
4
days
days
days
days
days
AROMATIC HYDROCARBON
45 mg/l
1 mg/l
96 h
48 h
NAPHTHALENE
2 mg/l
2 mg/l
48 h
96 h
Bluegill Sunfish
Fathead Minnow
Water flea
Daphnia
Goldfish
FISH
FISH
INVERTEBRATES
INVERTEBRATES
FISH
Fathead Minnow
Daphnia
FISH
INVERTEBRATES
INVERTEBRATES
FISH
CUMENE
3 mg/l
1 mg/l
3 mg/l
METHYL ACETATE
320 mg/l
96 h
24 h
72 h
4 days
Rainbow Trout
Daphnia
Green Algae
FISH
INVERTEBRATES
AQUATIC PLANTS
Fathead Minnow
FISH
****** SECTION 13 - Disposal Considerations ******
Provincial Waste Classification:
Check appropriate provincial and local waste disposal regulations
for proper classifications.
Waste disposal method:
Do not allow material to contaminate ground water systems. Incinerate
or otherwise dispose of waste material in accordance with Federal,
State, Provincial, and local requirements. Use only approved waste
management contractors. Do not incinerate in closed containers.
****** SECTION 14 - Transportation Information ******
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AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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****** SECTION 14 - Transportation Information ******
Cont'd
TDG Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
UN/NA#
Packing Group:
3
1263
III
****** SECTION 15 - Regulatory Information ******
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS contains
all the information required by the Controlled Products Regulations.
TSCA Status:
In compliance with TSCA Inventory requirements for commercial
purposes.
DSL Status:
Product is not DSL listed because one or more ingredients are not on
the DSL inventory.
OCI:
All components of the mixture
WHMIS Classification:
Class
Class
Class
Class
WHMIS symbols:
Flame
Toxic "T"
Photochemical Reactivity:
are listed with the Ontario Inventory.
B
D
D
D
Division
Division
Division
Division
2
2
2
2
Subdivision
Subdivision
Subdivision
A
A
B
53
54
60
Photochemically reactive
Other Regulatory Information:
CAS #
Ingredient
------------ ------------------------71-36-3
N-BUTYL ALCOHOL
110-12-3
METHYL ISOAMYL KETONE
100-41-4
ETHYLBENZENE
1330-20-7
XYLENE
64742-94-5
AROMATIC HYDROCARBON
91-20-3
NAPHTHALENE
98-82-8
CUMENE
79-20-9
METHYL ACETATE
Not Avail EPOXY RESIN
302
--N
N
N
N
N
N
N
N
N
EPCRA
CERCLA
TPQ/RQ 311/312 313 RQ(lbs) HAP
------ ------- --- ------- --NR
A,C,F
Y
5000
N
NR
C
N
NR
N
NR
A,C,F
Y
1000
Y
NR
A,C,F
Y
100
Y
NR
A
N
NR
N
NR
A,C,F
Y
100
Y
NR
A,C,F
Y
NR
Y
NR
A,C
N
100
N
NR
NA
N
NR
N
938S
AXALTA MATERIAL SAFETY DATA SHEET
AXALTA COATING SYSTEMS CANADA COMPANY
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****** SECTION 15 - Regulatory Information ******
Cont'd
Key:
EPCRA: Emergency Planning and Community Right-to-Know Act
(aka Title III, SARA)
302: Extremely hazardous substances
311/312 Categories:
F = Fire Hazard
A = Acute Hazard
R = Reactivity Hazard
C = Chronic Hazard
P = Pressure Related Hazard
313 Information: Section 313 Supplier Notification - The chemicals
listed above with a 'Y' in the 313 column are
subject to reporting requirements of Section 313
of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA: Comprehensive Emergency Response, Compensation and
Liability Act of 1980.
HAP = Listed as a Clean Air Act Hazardous Air Pollutant
TPQ = Threshold planning quantity
RQ = Reportable quantity
NA = not available
NR = not regulated
****** SECTION 16 - Additional Information ******
HMIS Rating:
Glossary
ACGIH
IARC
NTP
OSHA
STEL
TWA
PNOR
PNOC
of
-
H: 2
F: 3
R: 0
Terms:
American Conference of Governmental Industrial Hygienists
International Agency for Research on Cancer
National Toxicology Program
Occupational Safety and Health Administration
Short term exposure limit
Time-weighted average
Particles not otherwise regulated
Particles not otherwise classified
Notice from Axalta Coating Systems
The information on this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Approved by:
Technical Manager
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