81-0158RK-02

81-0158RK-02
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifier
●
Product Name
Product Code
●
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–
0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas
balance
MSDS No. 50200
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)
●
Calibration of industrial gas devices
1.3 Details of the supplier of the safety data sheet
Manufacturer
●
Air Liquide
Telephone (General)
●
2700 Post Oak Blvd.
Houston, TX 77056
United States
www.us.airliquide.com
713-624-8000
Telephone (Technical)
●
713-896-2896 - EHS Telephone
1.4 Emergency telephone number
Manufacturer
●
800-424-9300 - CHEMTREC
Section 2: Hazards Identification
EU/EEC
According to EU Directive 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]
According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP
●
DSD/DPD
●
Compressed Gas - H280
Reproductive Toxicity 1A - H360D
Specific Target Organ Toxicity Repeated Exposure 2 - H373
Harmful (Xn)
Substances Toxic To Reproduction - Category 1
R20, R61
2.2 Label Elements
CLP
DANGER
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 1 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
●
H280 - Contains gas under pressure; may explode if heated
H360D - May damage the unborn child.
H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention
●
Response
●
Storage/Disposal
●
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P220 - Keep/Store away from clothing and other combustible materials.
P260 - Do not breathe dust, fume, gas, mist, vapours and/or spray.
P281 - Use personal protective equipment as required.
P285 - In case of inadequate ventilation wear respiratory protection.
P370+P376 - In case of fire: Stop leak if safe to do so.
P309+P311 - IF exposed or if you feel unwell: Call a POISON CENTER or
doctor/physician.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P410+P403 - Protect from sunlight. Store in a well-ventilated place.
P405 - Store locked up.
P501 - Dispose of content and/or container in accordance with local, regional,
national, and/or international regulations.
DSD/DPD
Risk phrases
●
Safety phrases
●
R20 - Harmful by inhalation.
R61 - May cause harm to the unborn child.
S9 - Keep container in a well ventilated place
S17 - Keep away from combustible material.
S36 - Wear suitable protective clothing.
S53 - Avoid exposure - obtain special instructions before use.
2.3 Other Hazards
CLP
●
DSD/DPD
●
According to Regulation (EC) No. 1272/2008 (CLP) this material is considered
hazardous.
According to European Directive 1999/45/EC this preparation is considered
dangerous.
UN GHS
According to Third Revised Edition
2.1 Classification of the substance or mixture
UN GHS
●
Compressed Gas - H280
Reproductive Toxicity 1A - H360
2.2 Label elements
UN GHS
DANGER
●
H280 - Contains gas under pressure; may explode if heated
H360 - May damage fertility or the unborn child.
Precautionary statements
Prevention
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
●
P201
P202
P220
P281
- Obtain special instructions before use.
- Do not handle until all safety precautions have been read and understood.
- Keep/Store away from clothing and other combustible materials.
- Use personal protective equipment as required.
Page 2 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Response
●
Storage/Disposal
●
P370+P376 - In case of fire: Stop leak if safe to do so.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P410+P403 - Protect from sunlight. Store in a well-ventilated place.
P405 - Store locked up.
P501 - Dispose of content and/or container in accordance with local, regional,
national, and/or international regulations.
●
According to the Globally Harmonized System for Classification and Labeling (GHS)
this product is considered hazardous.
2.3 Other hazards
UN GHS
United States (US)
According to OSHA 29 CFR 1910.1200 HCS
2.1 Classification of the substance or mixture
OSHA HCS
●
Compressed Gas
●
Not required
●
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
Standard), this product is considered hazardous.
2.2 Label elements
OSHA HCS
2.3 Other hazards
OSHA HCS
Canada
According to WHMIS
2.1 Classification of the substance or mixture
WHMIS
●
Compressed Gas - A
Very Toxic - D1A
Other Toxic Effects - D2A
2.2 Label elements
WHMIS
●
Compressed Gas - A
Very Toxic - D1A
Other Toxic Effects - D2A
2.3 Other hazards
WHMIS
●
In Canada, the product mentioned above is considered hazardous under the
Workplace Hazardous Materials Information System (WHMIS).
2.4 Other information
●
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Note: This SDS has been developed for various gas mixtures with the composition of
components within the ranges listed in Section 3(Composition/Information on
Ingredients). All classifications provided are based on the highest end of the range
provided for each component. Refer to the product label for information on the actual
composition of the product.
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Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
NFPA
Section 3 - Composition/Information on Ingredients
3.1 Substances
●
Material does not meet the criteria of a substance according to United Nations
Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
Material does not meet the criteria of a substance in accordance with Regulation (EC)
No 1272/2008.
3.2 Mixtures
Hazardous Components
Chemical Name
Identifiers
%(weight)
Nitrogen
CAS:7727-37-9
UN:UN1066
EINECS:231783-9
74.475% TO
99.997%
Oxygen
CAS:7782-44-7
EC
Number:231956-9
UN:UN1072
0.0015% TO
23.5%
Carbon
monoxide
CAS:630-08-0
EC
Number:211128-3
UN:UN1016
Isobutane
CAS:75-28-5
EC
Number:200857-2
UN:UN1969
Hydrogen
sulfide
CAS:7783-06-4
EC
Number:231977-3
UN:UN1053
LD50/LC50
NDA
Classifications According to
Regulation/Directive
UN GHS: Press. Gas - Comp
EU DSD/DPD: Not Classified
EU CLP: Self Classified - Press. Gas - Comp,
H280
Comments
NDA
NDA
UN GHS: Ox. Gas 1
EU DSD/DPD:Annex I - O; R8
EU CLP: Annex VI - Ox. Gas 1, H270; Press. Gas
- Comp, H280
NDA
0.0005% TO
1%
Inhalation-Rat LC50 ∙
1807 ppm 4 Hour(s)
UN GHS: Acute Tox. 3 (Inhalation); Flam. Gas 1;
Repr. 1A; Press. Gas - Comp;
EU DSD/DPD: Annex I - F+; R12 T; R23 R48/23
Repr.Cat.1; R61
EU CLP: Annex VI - Flam. Gas 1, H220; Press.
Gas - Comp; Acute Tox. 3*, H331; Repr. 1A,
H360D; STOT RE 1, H372;
NDA
0% TO 1%
Inhalation-Rat LC50 ∙
658000 mg/m³ 4
Hour(s)
UN GHS: Flam. Gas 1; Press. Gas - Comp
EU DSD/DPD: Annex I - F+; R12
EU CLP: Annex VI - Flam. Gas 1, H220; Press.
Gas - Comp;
NDA
Inhalation-Rat LC50 ∙
444 ppm
UN GHS:Acute Tox. 2 (Inhalation); Flam. Gas 1;
Press. Gas - Comp
EU DSD/DPD: Annex I - F+; R12 T+; R26 N; R50
EU CLP: Annex VI - Flam. Gas 1, H220; Press.
Gas - Comp; Acute Tox 2*, H300; Aquatic Acute
1, H400;
NDA
0.001% TO
0.025%
Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
●
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. If not breathing, give artificial respiration. If
Page 4 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Skin
●
Eye
●
Ingestion
●
signs/symptoms continue, get medical attention.
In case of contact, immediately flush with plenty of water for at least 15 minutes. Take
off contaminated clothing. If irritation develops and persists, get medical attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion is not considered a potential route of exposure.
4.2 Most important symptoms and effects, both acute and delayed
●
Refer to Section 11 - Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician
●
Treat symptoms and eliminate over-exposure. Hyperbaric oxygen is the most efficient
antidote to Carbon Monoxide poisoning, the optimum range being 2-2.5 atm. A special
mask, or, preferably, a compression chamber to utilize oxygen at these pressures is
required. Avoid administering stimulant drugs. Be observant for initial signs of
pulmonary edema in the event of severe inhalation over-exposures.
4.4 Other information
●
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO
THIS GAS MIXTURE WITHOUT ADEQUATE PERSONAL PROTECTIVE
EQUIPMENT. At a minimum, Self-Contained Breathing Apparatus must be worn.
Victim(s) who experience any adverse effect after over-exposure to this gas mixture
must be taken for medical attention. Rescuers should be taken for medical attention if
necessary. Take a copy of the label and the MSDS to physician or other health
professional with victim(s).
Section 5 - Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media
Unsuitable Extinguishing
Media
●
Non-flammable gas mixture. Use extinguishing media appropriate for surrounding fire.
●
No data available
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion
Hazards
Hazardous Combustion
Products
●
●
This gas mixture contains toxic gases, Hydrogen Sulfide and Carbon Monoxide, and
presents a health hazard to firefighters. This gas mixture is not flammable; however,
containers, when involved in fire, may rupture or burst in the heat of the fire.
No data available
5.3 Advice for firefighters
●
Structural firefighters' protective clothing will only provide limited protection.
Wear positive pressure self-contained breathing apparatus (SCBA).
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
●
Emergency Procedures
●
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Wear appropriate personal protective equipment. See section 8 for more information.
Due to the small size and content of the cylinder, an accidental release of this gas
mixture presents significantly less risk of over-exposure to Hydrogen Sulfide and
Carbon Monoxide, the toxic components of this gas mixture, and other safety hazards
related to the remaining components of this gas mixture, than a similar release from a
larger cylinder. In the event of a release in which the atmosphere is unknown, and in
which other chemicals are potentially involved, evacuate immediate area. Such
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Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a leak, clear the affected area,
protect people, and respond with trained personnel.
6.2 Environmental precautions
●
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Containment/Clean-up
Measures
●
Allow the gas mixture to dissipate.
If necessary, monitor the surrounding area (and the original area of the release) for
concentrations of component gases.
Concentrations of component gases must be below any exposure limits listed in
Section 8 and Oxygen levels must be above 19.5% before non-emergency personnel
are allowed to re-enter area.
6.4 Reference to other sections
●
Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
Considerations.
Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling
●
Use good safety and industrial hygiene practices. Use only with adequate ventilation.
Be aware of any signs of dizziness or fatigue, especially if work is done in a poorly
ventilated area; exposures to fatal concentrations of this gas mixture could occur
without any significant warning symptoms, due to olfactory fatigue or oxygen
deficiency. Cylinders should be firmly secured to prevent falling or being knocked-over.
Do not attempt to repair, adjust, or in any other way modify cylinders. If there is a
malfunction or another type of operational problem, contact nearest distributor
immediately.
7.2 Conditions for safe storage, including any incompatibilities
Storage
●
Cylinders should be stored in dry, well-ventilated areas away from sources of heat,
ignition and direct sunlight. Do not allow area where cylinders are stored to exceed
52°C (125°F). Cylinders must be protected from the environment, and preferably kept
at room temperature (approximately 21°C (70°F). Cylinders should be firmly secured
to prevent falling or being knocked-over. Protect cylinders against physical damage.
Store locked up.
7.3 Specific end use(s)
●
Refer to Section 1.2 - Relevant identified uses.
Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Exposure Limits/Guidelines
Result
TWAs
Isobutane
(75-28-5)
ACGIH
Canada Ontario
1000 ppm TWA
800 ppm TWA (listed
(listed under Aliphatic
under Aliphatic
hydrocarbon gases:
hydrocarbon gases)
Alkane C1-4)
Canada Quebec
Not established
China
Not established
Not established
4000 ppm Peak
(listed under Butane);
9600 mg/m3 Peak
(listed under Butane)
Ceilings Not established
Not established
Not established
Not established
MAKs
Not established
Not established
Not established
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Not established
Page 6 of 20
Germany DFG
1000 ppm TWA MAK;
2400 mg/m3 TWA
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
MAK
Carbon monoxide
(630-08-0)
Ceilings Not established
Not established
Not established
20 mg/m3 Ceiling
[MAC] (high altitude
area, 2000-3000m);
15 mg/m3 Ceiling
[MAC] (high altitude
area, >3000m)
STELs
Not established
100 ppm STEL
200 ppm STEV; 230
mg/m3 STEV
30 mg/m3 STEL (not
in high altitude area)
Not established
TWAs
25 ppm TWA
25 ppm TWA
35 ppm TWAEV; 40
mg/m3 TWAEV
20 mg/m3 TWA (not
in high altitude area)
Not established
MAKs
Not established
Not established
Not established
Not established
30 ppm TWA MAK;
35 mg/m3 TWA MAK
Ceilings Not established
Not established
Not established
10 mg/m3 Ceiling
[MAC]
10 ppm Peak; 14.2
mg/m3 Peak
STELs
5 ppm STEL
15 ppm STEL
15 ppm STEV; 21
mg/m3 STEV
Not established
Not established
TWAs
1 ppm TWA
10 ppm TWA
10 ppm TWAEV; 14
mg/m3 TWAEV
Not established
Not established
MAKs
Not established
Not established
Not established
Not established
5 ppm TWA MAK; 7.1
mg/m3 TWA MAK
Hydrogen sulfide
(7783-06-4)
60 ppm Peak; 70
mg/m3 Peak
Exposure Limits/Guidelines (Con't.)
Isobutane
(75-28-5)
Result
Germany TRGS
TWAs
1000 ppm TWA AGW
(exposure factor 4);
2400 mg/m3 TWA
AGW (exposure factor
4)
800 ppm TWA; 1900
mg/m3 TWA
Not established
Not established
TWAs
30 ppm TWA AGW
(The risk of damage to
the embryo or fetus
cannot be excluded
even when AGW and
BGW values are
observed, exposure
factor 1); 35 mg/m3
TWA AGW (The risk of
damage to the embryo
or fetus cannot be
excluded even when
AGW and BGW values
are observed,
exposure factor 1)
35 ppm TWA; 40
mg/m3 TWA
50 ppm TWA; 55
mg/m3 TWA
25 ppm PEL; 29 mg/m3
PEL
Ceilings Not established
200 ppm Ceiling; 229
mg/m3 Ceiling
Not established
Not established
STELs
Not established
Not established
15 ppm STEL; 21
mg/m3 STEL
Carbon monoxide
(630-08-0)
Not established
NIOSH
OSHA
Singapore
5 ppm TWA AGW (The
risk of damage to the
embryo or fetus can be
excluded when AGW
and BGW values are
observed, exposure
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
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Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Hydrogen sulfide
(7783-06-4)
TWAs
factor 2); 7.1 mg/m3
TWA AGW (The risk of
damage to the embryo
or fetus can be
excluded when AGW
and BGW values are
observed, exposure
factor 2)
Ceilings Not established
Not established
Not established
10 ppm PEL; 14 mg/m3
PEL
10 ppm Ceiling (10
min); 15 mg/m3 Ceiling
(10 min)
20 ppm Ceiling
Not established
8.2 Exposure controls
Engineering
Measures/Controls
●
Adequate ventilation systems as needed to control concentrations of airborne
contaminants below applicable threshold limit values. If this gas mixture is used in a
poorly-ventilated area, install automatic monitoring equipment to detect the levels of
component gases.
Personal Protective Equipment
Pictograms
●
Respiratory
●
Eye/Face
●
Skin/Body
●
Environmental Exposure
Controls
●
In case of insufficient ventilation, wear suitable respiratory equipment. Follow the
OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure
limits are exceeded or symptoms are experienced.
Wear safety glasses.
Wear protective gloves leather gloves when handling cylinders; chemically resistant
gloves when using this gas mixture and clothing .
Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways.
Key to abbreviations
American Conference of Governmental Industrial
ACGIH =
Hygiene
MSHA = Mine Safety and Health Administration
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration
Maximale Arbeitsplatz Konzentration is the maximum
MAK =
permissible concentration
Permissible Exposure Level determined by the Occupational Safety
and Health Administration (OSHA)
STEL = Short Term Exposure Limits are based on 15-minute exposures
STEV = Short Term Exposure Value
TWAEV = Time-Weighted Average Exposure Value
PEL
=
TWA
= Time-Weighted Averages are based on 8h/day, 40h/week exposures
Section 9 - Physical and Chemical Properties
9.1 Information on Physical and Chemical Properties
Material Description
Physical Form
Gas
Appearance/Description
Gas mixture, colorless gas, which
has a rotten egg-like odor, due to
the presence of Hydrogen Sulfide.
Color
Colorless
Odor
Rotten-egg
Taste
No data available
Particulate Type
Not relevant
Particulate Size
Not relevant
Aerosol Type
Not relevant
Odor Threshold
0.13 ppm
Hydrogen sulfide
Physical and Chemical
Properties
No data available
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 8 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
General Properties
Boiling Point
-320.4 F(-195.7778 C)
Nitrogen
Melting Point
-345.8 F(-209.8889 C)
Nitrogen
Decomposition Temperature
No data available
Heat of Decomposition
No data available
pH
No data available
Specific Gravity/Relative
Density
No data available
Density
0.072 lb(s)/ft³
Nitrogen
Bulk Density
No data available
Water Solubility
0.023
(vol/vol) Nitrogen
Solvent Solubility
No data available
Viscosity
Not relevant
Explosive Properties
No data available
Oxidizing Properties:
Not an oxidizing gas.
Volatility
Vapor Pressure
Not relevant
Vapor Density
0.967 Air=1
Nitrogen
Evaporation Rate
Not relevant
VOC (Wt.)
No data available
VOC (Vol.)
No data available
Volatiles (Wt.)
No data available
Volatiles (Vol.)
No data available
UEL
Not relevant
Flammability
Flash Point
Not relevant
LEL
Not relevant
Autoignition
Not relevant
Self-Accelerating
Decomposition Temperature
(SADT)
No data available
Heat of Combustion (ΔHc)
No data available
Burning Time
No data available
Flame Duration
No data available
Flame Height
No data available
Flame Extension
No data available
Ignition Distance
No data available
Flammability (solid, gas)
No data available
Half-Life
No data available
Octanol/Water Partition
coefficient
No data available
Coefficient of water/oil
distribution
Not relevant
Bioaccumulation Factor
No data available
Bioconcentration Factor
No data available
Biochemical Oxygen Demand
BOD/BOD5
No data available
Chemical Oxygen Demand
No data available
Persistence
No data available
Degradation
No data available
Environmental
9.2 Other Information
●
No additional physical and chemical parameters noted.
Section 10: Stability and Reactivity
10.1 Reactivity
●
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 9 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
●
Stable under normal temperatures and pressures.
10.3 Possibility of hazardous reactions
●
Hazardous polymerization will not occur.
●
Excess heat. Incompatible materials.
10.4 Conditions to avoid
10.5 Incompatible materials
●
Oxidizers Titanium, Lithium.
10.6 Hazardous decomposition products
●
Sulfur oxide.
Section 11 - Toxicological Information
11.1 Information on toxicological effects
Component Name
CAS
Data
Oxygen (0.0015% TO 23.5%)
7782-44-7
Acute Toxicity: ihl-rat TCLo:95 pph/7D-C;
Reproductive: ihl-rat TCLo:10 pph/9H (22D preg)
Carbon monoxide (0.0005% TO 1%)
630-08-0
Acute Toxicity: ihl-rat LC50:1807 ppm/4H;
Reproductive: ihl-rat TCLo:103 mg/m3 (1-22D preg)
Isobutane (0% TO 1%)
75-28-5
Acute Toxicity: ihl-rat LC50:658000 mg/m3/4H
Hydrogen sulfide (0.001% TO 0.025%)
7783-06-4
Acute Toxicity: ihl-rat LC50:444 ppm; skn-rbt TDLo:1000 mg/m3/2H;
Irritation: eye-hmn 0.000125 ppm/5H;
Reproductive: ihl-rat TCLo:10 mg/m3 (48D pre/1-22D preg)
GHS Properties
Classification
Acute toxicity
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Skin corrosion/Irritation
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Serious eye damage/Irritation
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Skin sensitization
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Respiratory sensitization
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Aspiration Hazard
EU/CLP • Not relevant
UN GHS • Not relevant
Carcinogenicity
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Germ Cell Mutagenicity
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Toxicity for Reproduction
EU/CLP • Toxic to Reproduction 1A
UN GHS • Toxic to Reproduction 1A
STOT-SE
EU/CLP • Classification criteria not met
UN GHS • Classification criteria not met
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 10 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
EU/CLP • Specific Target Organ Toxicity Repeated Exposure 2
STOT-RE
Route(s) of entry/exposure
UN GHS • Classification criteria not met
●
Inhalation, Skin, Eye, Ingestion
Potential Health Effects
Inhalation
Acute (Immediate)
●
Chronic (Delayed)
●
A potential health hazard associated with this gas mixture is the inhalation of
Hydrogen Sulfide, a component of this gas mixture. Such over-exposures may occur if
this gas mixture is used in a confined space or other poorly-ventilated area. Overexposures to Hydrogen Sulfide can cause dizziness, headache, nausea, respiratory
arrest, coma, or unconsciousness. Continuous inhalation of low concentrations of
Hydrogen Sulfide may cause olfactory fatigue, so that the odor is no longer an
effective warning of the presence of this gas. Inhalation over-exposures to
atmospheres containing more than the Threshold Limit Value of Carbon Monoxide (25
ppm), another component of this gas mixture, can result in serious health
consequences. Carbon Monoxide is classified as a chemical asphyxiant, producing a
toxic action by combining with the hemoglobin of the blood and replacing the available
oxygen. Through this replacement, the body is deprived of the required oxygen, and
asphyxiation occurs. Since the affinity of Carbon Monoxide for hemoglobin is about
200-300 times that of oxygen, only a small amount of Carbon Monoxide will cause a
toxic reaction to occur. Carbon Monoxide exposures in excess of 50 ppm will produce
symptoms of poisoning if breathed for a sufficiently long time. If this gas mixture is
released in a small, poorly ventilated area (i.e. an enclosed or confined space),
symptoms which may develop include the following: bright red lips and fingernails,
headache progessing to heart palpitations, staggering, confusion, nausea, dizziness
and unconsciousness with higher concentration exposures. For exposures greater
than 2500 ppm there is potential for collapse and death before warning symptoms are
experienced.
Chronic exposure to oxygen-deficient atmospheres (below 18% oxygen in air) may
affect the heart and nervous system.
Skin
Acute (Immediate)
●
Hydrogen Sulfide, a component of this gas mixture, may be irritating to the skin.
Chronic (Delayed)
●
No data available
Eye
Acute (Immediate)
●
Chronic (Delayed)
●
May cause mild irritation. Inflammation and irritation of the eyes can occur at very low
airborne concentration of Hydrogen Sulfide (less than 10 ppm). Exposure over several
hours may result in “gas eyes” or “sore eyes” with symptoms of scratchiness,
irritation, tearing and burning. Above 50 ppm of Hydrogen Sulfide, there is an intense
tearing, blurring of vision, and pain when looking at light. Over-exposed individuals may
see rings around bright lights. Most symptoms disappear when exposure ceases.
However, in serious cases, the eye can be permanently damaged.
No data available
Acute (Immediate)
●
Under normal conditions of use, no health effects are expected.
Chronic (Delayed)
●
No data available
Ingestion
Mutagenic Effects
●
Carcinogenic Effects
●
Reproductive Effects
●
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
The components of this gas mixture are not reported to cause mutagenic effects in
humans.
The components of this gas mixture are not found on the following lists: FEDERAL
OSHA Z LIST, NTP and IARC; therefore, they are not considered to be, nor suspected
to be, cancer-causing agents by these agencies.
The Carbon Monoxide component of this gas mixture which exists up to 1%, can
cause teratogenic effects in humans. Severe exposure to Carbon Monoxide during
pregnancy has caused adverse effects and the death of the fetus. In general, maternal
symptoms are an indicator of the potential risk to the fetus since Carbon Monoxide is
toxic to the mother before it is toxic to the fetus.
Page 11 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Section 12 - Ecological Information
12.1 Toxicity
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025%
Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
Dosage
Species
Duration
Exposure
Conditions
Results
Comments
0.0071 to
0.55 mg/L
Fish: Fathead minnow
96 Day(s)
LC50
NDA
Hydrogen Sulfide
component
0.009 to
0.014 mg/L
Fish: Bluegill
96 Hour(s)
LC50
NDA
Hydrogen sulfide
component
12.2 Persistence and degradability
●
Material data lacking.
12.3 Bioaccumulative potential
●
Material data lacking.
●
Material data lacking.
12.4 Mobility in Soil
12.5 Results of PBT and vPvB assessment
●
PBT and vPvB assessment has not been conducted.
12.6 Other adverse effects
●
No evidence is currently available on this gas mixture’s effects on plant, animal or
aquatic life. Hydrogen Sulfide and Carbon Monoxide, components of this gas mixture,
can be deadly to exposed animal life, producing symptoms similar to those
experienced by humans. This gas mixture may also be harmful to plant life. The
presence of more than a trace of the Carbon Monoxide component of this gas mixture
is a hazard to fish.
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste
●
Packaging waste
●
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
Section 14 - Transport Information
14.1 UN
number
14.2 UN proper shipping
name
14.3 Transport
hazard class(es)
14.4 Packing
group
14.5 Environmental
hazards
DOT
UN1956
Compressed gas, n.o.s (Oxygen,
Nitrogen)
2.2
NDA
NDA
TDG
UN1956
COMPRESSED GAS, N.O.S.
(Oxygen, Nitrogen)
2.2
NDA
NDA
IMO/IMDG
UN1956
COMPRESSED GAS, N.O.S.
(OXYGEN, NITROGEN)
2.2
NDA
NDA
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 12 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
IATA/ICAO
Compressed Gas, n.o.s. (Oxygen,
Nitrogen)
UN1956
14.6 Special precautions for
user
14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
●
●
2.2
NDA
NDA
Cylinders should be transported in a secure position, in a well-ventilated vehicle. The
transportation of compressed gas cylinders in automobiles or in closed-body vehicles
can present serious safety hazards. If transporting these cylinders in vehicles, ensure
these cylinders are not exposed to extremely high temperatures (as may occur in an
enclosed vehicle on a hot day). Additionally, the vehicle should be well-ventilated
during transportation.
This product is provided only in non-bulk containers.
Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
SARA Hazard Classifications
●
Acute, Pressure(Sudden Release of)
State Right To Know
MA
NJ
PA
Nitrogen
Component
7727-37-9
CAS
Yes
Yes
Yes
Oxygen
7782-44-7
Yes
Yes
Yes
Carbon monoxide
630-08-0
Yes
Yes
Yes
Isobutane
75-28-5
Yes
Yes
Yes
Hydrogen sulfide
7783-06-4
Yes
Yes
Yes
Inventory
Component
CAS
Canada DSL
Canada NDSL
China
EU EINECS
EU ELNICS
Nitrogen
7727-37-9
Yes
No
Yes
Yes
No
Oxygen
7782-44-7
Yes
No
Yes
Yes
No
Carbon monoxide
630-08-0
Yes
No
Yes
Yes
No
Isobutane
75-28-5
Yes
No
Yes
Yes
No
Hydrogen sulfide
7783-06-4
Yes
No
Yes
Yes
No
Inventory (Con't.)
Korea KECL
TSCA
Nitrogen
Component
7727-37-9
CAS
Japan ENCS
No
Yes
Yes
Oxygen
7782-44-7
No
Yes
Yes
Carbon monoxide
630-08-0
Yes
Yes
Yes
Isobutane
75-28-5
Yes
Yes
Yes
Hydrogen sulfide
7783-06-4
Yes
Yes
Yes
Australia
Labor
Australia - Work Health and Safety Regulations - Hazardous Substances Requiring Health Monitoring
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 13 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
Not Listed
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Australia - High Volume Industrial Chemicals List
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
0.001% TO 0.025%
0.0005% TO 1%
● Oxygen
● Isobutane
● Nitrogen
0.0015% TO 23.5%
Not Listed
0% TO 1%
Not Listed
74.475% TO 99.997% Not Listed
7782-44-7
75-28-5
7727-37-9
Not Listed
Not Listed
Australia - List of Designated Hazardous Substances - Classification
● Hydrogen sulfide
7783-06-4
0.001% TO 0.025%
F+, T+, N R12, R26, R50
● Carbon monoxide 630-08-0
● Oxygen
7782-44-7
● Isobutane
75-28-5
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
F+, T Repr.Cat.1 R12, R61, R23, R48/23
O R8
F+ Carc.Cat.1, Muta.Cat.2 R12, R45, R46 (containing >=0.1% Butadiene)
● Nitrogen
74.475% TO 99.997% Not Listed
7727-37-9
Environment
Australia - National Pollutant Inventory (NPI) Substance List
● Hydrogen
sulfide
7783-06-4 0.001% TO 0.025%
● Carbon
monoxide
630-08-0
● Oxygen
7782-44-7 0.0015% TO 23.5%
● Isobutane
● Nitrogen
75-28-5
0% TO 1%
Not Listed
7727-37-9 74.475% TO 99.997% 15 tonne/yr Threshold category 3 (total)
0.0005% TO 1%
10 tonne/yr Threshold category 1
10 tonne/yr Threshold category 1; 400 tonne/yr Threshold category 2a; 1 tonne/h
Threshold category 2a; 2000 tonne/yr Threshold category 2b; 60000 MWH Threshold
category 2b; 20 MW Threshold category 2b
Not Listed
Australia - Ozone Protection Act - Scheduled Substances
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Australia - Priority Existing Chemical Program
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
● Oxygen
7782-44-7
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
Not Listed
Not Listed
Not Listed
Page 14 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
● Isobutane
75-28-5
0% TO 1%
● Nitrogen
7727-37-9
74.475% TO 99.997% Not Listed
Not Listed
Canada
Labor
Canada - WHMIS - Classifications of Substances
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
A, B1, D1A, D2B
A, B1, D1A, D2A
A, C
A, B1 (listed under Methyl-2 propane)
A
Canada - WHMIS - Ingredient Disclosure List
● Hydrogen sulfide
7783-06-4
0.001% TO 0.025%
1%
● Carbon monoxide 630-08-0
● Oxygen
7782-44-7
● Isobutane
75-28-5
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
0.1 %
Not Listed
Not Listed
● Nitrogen
74.475% TO 99.997% Not Listed
7727-37-9
Environment
Canada - CEPA - Priority Substances List
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Europe
Other
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Classification
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
F+; R12 T+; R26 N; R50
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
F+; R12 T; R23-48/23 Repr.Cat.1; R61
O; R8
F+; R12
Not Listed
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Concentration Limits
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
0.001% TO 0.025%
0.0005% TO 1%
Not Listed
Not Listed
Page 15 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
● Oxygen
7782-44-7
0.0015% TO 23.5%
● Isobutane
● Nitrogen
75-28-5
7727-37-9
0% TO 1%
Not Listed
74.475% TO 99.997% Not Listed
Not Listed
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Labelling
●
●
●
●
Hydrogen sulfide 7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
● Nitrogen
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
7727-37-9
F+ T+ N R:12-26-50 S:(1/2)-9-16-36-38-45-61
F+ T R:61-12-23-48/23 S:53-45
O R:8 S:(2)-17
F+ R:12 S:(2)-9-16
74.475% TO 99.997% Not Listed
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Notes - Substances and Preparations
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
Not Listed
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
E
Not Listed
C
Not Listed
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Safety Phrases
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
S:(1/2)-9-16-36-38-45-61
S:53-45
S:(2)-17
S:(2)-9-16
Not Listed
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
0.001% TO 0.025%
0.0005% TO 1%
Hazard Class = 2.3 (2.1) UN1053
Hazard Class = 2.3 (2.1) UN1016
● Oxygen
● Isobutane
● Nitrogen
0.0015% TO 23.5%
Hazard Class = 2.2 (5.1) UN1072; Hazard Class = 2.2 (5.1) UN1073
0% TO 1%
Hazard Class = 2.1 UN1969
74.475% TO 99.997% Hazard Class = 2.2 UN1066; Hazard Class = 2.2 UN1977
Mexico
Other
Mexico - Hazard Classifications
7782-44-7
75-28-5
7727-37-9
Mexico - Regulated Substances
● Hydrogen sulfide
●
●
●
●
7783-06-4 0.001% TO 0.025%
Carbon monoxide 630-08-0 0.0005% TO 1%
Oxygen
7782-44-7 0.0015% TO 23.5%
Isobutane
75-28-5
0% TO 1%
Nitrogen
7727-37-9 74.475% TO 99.997%
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
UN1053
UN1016
UN1072; UN1073
UN1969
UN1066; UN1977
Page 16 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
United States
Labor
U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
1500 lb TQ
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - OSHA - Specifically Regulated Chemicals
●
●
●
●
Hydrogen sulfide 7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
● Nitrogen
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
Not Listed
Not Listed
Not Listed
Not Listed
74.475% TO 99.997% Not Listed
Environment
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
Not Listed
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
100 lb final RQ; 45.4 kg final RQ
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 17 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
100 lb EPCRA RQ
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
500 lb TPQ
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
1.0 % de minimis concentration
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - RCRA (Resource Conservation & Recovery Act) - Hazardous Constituents - Appendix VIII to 40 CFR 261
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
waste number U135
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - California - Proposition 65 - Developmental Toxicity
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
0.001% TO 0.025%
0.0005% TO 1%
Not Listed
developmental toxicity, initial date 7/1/89
Page 18 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
● Oxygen
7782-44-7
0.0015% TO 23.5%
● Isobutane
● Nitrogen
75-28-5
7727-37-9
0% TO 1%
Not Listed
74.475% TO 99.997% Not Listed
Not Listed
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)
●
●
●
●
Hydrogen sulfide 7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
● Nitrogen
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
Not Listed
Not Listed
Not Listed
Not Listed
74.475% TO 99.997% Not Listed
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
Not Listed
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
0.001% TO 0.025%
Not Listed
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
United States - Pennsylvania
Labor
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
● Hydrogen sulfide
●
●
●
●
7783-06-4
Carbon monoxide 630-08-0
Oxygen
7782-44-7
Isobutane
75-28-5
Nitrogen
7727-37-9
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
Not Listed
0% TO 1%
Not Listed
74.475% TO 99.997% Not Listed
Page 19 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
0.0015–23.5% Oxygen; 0.0005–1.0% Carbon Monoxide; 0.001–0.025% Hydrogen Sulfide; 0–1% Isobutane; Nitrogen Gas balance
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances
●
●
●
●
●
Hydrogen sulfide
Carbon monoxide
Oxygen
Isobutane
Nitrogen
7783-06-4
630-08-0
7782-44-7
75-28-5
7727-37-9
0.001% TO 0.025%
0.0005% TO 1%
0.0015% TO 23.5%
0% TO 1%
74.475% TO 99.997%
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
United States - Rhode Island
Labor
U.S. - Rhode Island - Hazardous Substance List
● Hydrogen sulfide 7783-06-4
● Carbon monoxide 630-08-0
0.001% TO 0.025%
0.0005% TO 1%
● Oxygen
● Isobutane
● Nitrogen
0.0015% TO 23.5%
Flammable
0% TO 1%
Not Listed
74.475% TO 99.997% Flammable
7782-44-7
75-28-5
7727-37-9
Toxic; Flammable
Toxic
15.2 Chemical Safety Assessment
●
No Chemical Safety Assessment has been carried out.
Section 16 - Other Information
Relevant Phrases (code & full text)
● H220 - Extremely flammable gas
H270 - May cause or intensify fire; oxidizer
H300 - Fatal if swallowed
H331 - Toxic if inhaled
H372 - Causes damage to organs through prolonged or repeated exposure.
H400 - Very toxic to aquatic life
R8 - Contact with combustible material may cause fire.
R12 - Extremely flammable.
R23 - Toxic by inhalation.
R26 - Very toxic by inhalation.
R48/23 - Toxic: danger of serious damage to health by prolonged exposure through
inhalation.
R50 - Very toxic to aquatic organisms.
Last Revision Date
● 08/May/2012
Preparation Date
Disclaimer/Statement of
Liability
●
●
08/May/2012
To the best of Air Liquide's knowledge, the information contained herein is reliable and
accurate as of this date; however, accuracy, suitability or completeness are not
guaranteed and no warranties of any type, either express or implied, are provided. The
information contained herein relates only to this specific product. If this gas mixture is
combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.
Key to abbreviations
NDA = No data available
Preparation Date: 08/May/2012
Revision Date: 08/May/2012
Page 20 of 20
Format: EU CLP/REACH Language: English (US)
OSHA, WHMIS, UN GHS, EU DSD/DPD, EU CLP
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