SAFETY DATA SHEET Green Klean Green Klean Chlorinated Sanitizing Crystals

SAFETY DATA SHEET Green Klean Green Klean Chlorinated Sanitizing Crystals
Green Klean
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
1. Identification of the substance & the company
Chemical name
Sodium dichloroisocyanurate,dihydrate
Synonym(s)
Sodium dichlor; Sodium dichloroisocyanurate,dihydrate; Sodium
dichloro-s-triazinetrione dihydrate; CDB Granuals; Troclosene sodium,
dihydrate CDB 56
Chemical formula
NaCl 2(NCO) 3 x2H 2O
Chemical family
Chloroisocyanurate
Molecular weight
256
Type of product and use
Disinfectant, sanitizer, bactericide, and algaecide for industrial recirculating water
cooling towers, air washers and evaporative condensers, sewage treatment, food
contact surfaces, laundry and egg sanitizing, and drinking water disinfection (as
supporting by WHO and as per NSF/ANSI Standard 60).
Supplier
SOP Green Klean
615 Industrial Drive, Suite D
Cary, Illinois 60013
USA
Phone Number: 1-815- 479-0460
Emergency Telephone
Chemtrec: (800) 424-9300
Medical: (800) 420-9236
2. Hazards identification
GHS classification
Acute Tox. 4, H302 Harmful if swallowed
Eye Irrit. 2, H319 Causes serious eye irritation
STOT SE 3, H335 May cause respiratory irritation
Aquatic Acute 1, H400 - Very toxic to aquatic life
Aquatic Chronic 1, H410 - Very toxic to aquatic life with long lasting effects
Labels and other form of warning
Symbol(s)
{ Page 1 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Signal Word
WARNING
Hazard statements
H302 - Harmful if swallowed
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H410 - Very toxic to aquatic life with long lasting effects
EUH031 - Contact with acids liberates toxic gas
Precautionary statements
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P264 - Wash hands thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or
doctor/physician if you feel unwell. Rinse mouth.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P405 - Store locked up
P501 - Dispose of contents/container in accordance with national and international
regulations
NFPA Ratings (Scale 0-4)
Health = 2, Fire = 0, Reactivity = 1. Special Hazard Warning: OXIDIZER.
HMIS Ratings (Scale 0-4)
Health = 3, Fire = 0, Reactivity = 1.
{ Page 2 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
3. Composition / information on ingredients
Components
SODIUM DICHLOROISO CYANURATE,
DIHYDRATE
SODIUM CHLORIDE
CAS No.
51580-86-0
Weight %
99-100
7647-14-5
0-1
4. First-aid measures
Eye contact
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call
a poison control center or doctor for treatment advice.
Skin contact
Take off contaminated clothing. Rinse skin immediately with plenty of water for
15-20 minutes. Call a poison control center or doctor for treatment advice. Get
medical attention immediately.
Inhalation
Move person to fresh air. If person is not breathing, call 911 or an ambulance,
then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a
poison control center or doctor for further treatment advice.
Ingestion
Call poison control center, or doctor immediately for treatment advice.
Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by the poison control center or doctor.
Do not give anything by mouth to an unconscious person.
Most important symptoms and effects, acute or delayed
- Eye Contact
Severe irritation and/or burns can occur following eye exposure. Contact may
cause impairment of vision and corneal damage.
- Skin contact
Dermal exposure can cause severe irritation and/or burns characterized by
redness, swelling and scab formation.
Prolonged skin exposure may cause permanent damage.
- Inhalation
Irritating to the nose, mouth, throat and lungs.
It may also cause burns to the respiratory tract with the production of lung edema
that can result in shortness of breath, wheezing, choking, chest pain, and
impairment of lung function.
Inhalation of high concentrations can result in permanent lung damage from the
corrosive action of the lung.
{ Page 3 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Irritation and/or burns can occur to the entire gastrointestinal tract, including the
- Ingestion
stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal
pain, bleeding and/or tissue ulceration.
Ingestion causes severe damage to the gastrointestinal tract with the potential to
cause perforation.
Note to physician
Probable mucosal damage may contraindicate the use of gastric lavage.
No specific antidote.
Treat symptomatically and supportively.
In case of ingestion DO NOT induce vomiting.
5. Fire - fighting measures
Suitable extinguishing media
Water.
Extinguishing media not to be
used
Do not use dry chemical extinguisher containing ammonia compounds.
Unusual fire and explosion
hazards
Fire fighting procedure
When heated to decomposition, may release poisonous and corrosive fumes of
nitrogen trichloride, chlorine and CO.
Cool containers with water spray. Fire fighters should wear full protective clothing
and self-contained breathing apparatus (SCBA) in positive pressure mode. On
small fires, use water spray or fog. On large fires, use heavy deluge or fog
streams. Flooding amounts of water may be required before extinguishment can
be accomplished.
6. Accidental release measures
Personal precautions
For small spills in a well-ventilated areas, wear a NIOSH approved half-face or full
face tight fitting respirator or a loose fitting powered air purifying respirator
equipped with chlorine cartridges. Chemical goggles should be worn when using a
half-face respirator. In addition to respiratory protection, wear coveralls, chemical
resistant gloves, chemical resistant footwear; and chemical resistant headgear for
overhead exposure. For clean-up of large spills, or small dry spills in confined
areas, wear full-face respirator with chlorine cartridges or a positive pressure
supplied air respirator. Additionally, body protection should be impervious clothing
covering entire body to prevent personal contact with material. CAUTION Protection concerns must also address the following: If this material becomes
damp/wet or contaminated in a container, the formation of nitrogen trichloride gas
may occur and an explosive condition may exist.
{ Page 4 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Hazardous concentrations in air may be found in local spill area and immediately
Methods for cleaning up
downwind. If spill material is still dry, do not put water directly on this product as a
gas evolution may occur.
Environmental precautions
- Soil
Do not contaminate spill material with any organic materials, ammonia, ammonium
salts or urea. Clean up all spill material with clean, dry dedicated equipment and
place in a clean dry container.
- Water
This material is heavier than and soluble in water. Stop flow of material into water
as soon as possible. Begin monitoring for available chlorine and pH immediately.
- Air
Vapors may be suppressed by the use of water fog.
7. Handling and storage
Handling
Do not take internally. Avoid contact with skin, eyes, and clothing. Upon contact
with skin or eyes, wash off with water.
Storage
Store in a dry, cool, well-ventilated area. away from incompatible materials (see
"materials to avoid"). Do not store at temperatures above 60°C/140°F. Product has
an indefinite shelf-life limitation.
8. Exposure controls / personal protection
Exposure Limits :
Components
SODIUM DICHLOROISO CYANURATE,
DIHYDRATE
51580-86-0
SODIUM CHLORIDE
7647-14-5
Ventilation requirements
ACGIH-TLV Data
Not determined
OSHA (PEL) Data
Not determined
Not determined
Not determined
Use local exhaust ventilation to minimize dust and chlorine levels where industrial
use occurs. Otherwise, ensure good general ventilation.
Personal protective equipment:
When dusty conditions are encountered, wear a NIOSH/OSHA full-face respirator
- Respiratory protection
with chlorine cartridges for protection againts chlorine gas and dust/mist pre-filter.
Neoprene gloves (0.67 mm)
- Hand protection
Use chemical safety glasses to avoid eye contact. Where industrial use occurs,
- Eye protection
chemical goggles may be required.
{ Page 5 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Impervious body covering clothes, boots and neoprene apron
- Skin and body protection
Hygiene measures
Do not eat, smoke or drink where material is handled, processed or stored. Wash
hands thoroughly after handling and before eating or smoking. Safety shower and
eye bath should be provided.
9. Physical and chemical properties
Appearance
Odor
Odor threshold
pH
Melting point/range
Boiling point/range
Flash point
Evaporation rate (ether=1)
Flammability (solid, gas)
Flammable/Explosion limits
Vapor pressure
Vapor density
Density
Solubility:
- Solubility in water
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidising properties
Particle size
White granules or tablet-form product
Mild chlorine-like.
Not determined
Not determined
Not applicable
Not applicable
Not applicable
Not applicable under standard conditions
Not determined
Not determined
Not applicable under standard conditions
Not applicable under standard conditions
tap density= 0.974 g/mL
pour density= 1.083 g/mL
24-25 g/100g
LogP - -0.0056 (estimated)
Not self-ignitable
Begins to lose 1 mole water at approximately 50°C; second mole water at 95°C;
Decomposes at 240-250°C
Not applicable
Not determined
Not oxidising
Non- inhalable
10. Stability and reactivity
Reactivity
Stability
Possibility of hazardous
reactions
Conditions to avoid
Begins to lose one mole of water at approximately 50°C.
Stable under normal conditions
If this material becomes damp/wet or contaminated in a container, the formation of
nitrogen trichloride gas may occur and an explosive condition may exist.
Heating above decomposition temperature. Do not package in paper or cardboard.
{ Page 6 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Organic materials, reducing agents, nitrogen containing materials, other oxidizers,
Materials to avoid
acids, bases, oils, grease, sawdust, dry fire extinguishers containing
monoammonium compounds.
Nitrogen trichloride, chlorine, carbon monoxide
Hazardous decomposition
products
11. Toxicological information
Likely Routes of Exposure
Skin
Inhalation
Ingestion
Eye contact
Acute toxicity:
- Rat oral LD50
1671 mg/kg
- Rat dermal LD50
>5000 mg/kg
- Dermal irritation (rabbit)
Severe irritant
- Eye irritation (rabbit)
Severe irritant
Dermal sensitization
Not a sensitizer
Immediately Dangerous to Life
or Health (IDLH)
No level has been established for the components or the product itself.
Chronic toxicity
Chronic inhalation exposure may cause impairment of lung function and
permanent lung damage.
Mutagenicity
Not mutagenic in five Salmonella strains with or without metabolic activation.
Carcinogenicity
Not classified by IARC, OSHA, EPA.
Not included in NTP 13th Report on Carcinogens
Reproductive toxicity
Sodium dichloroisocyanuric acid when given orally to pregnant mice from day 6 to
day 15 of gestation, did not induce any significant teratogenic effects.
{ Page 7 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
12. Ecological information
Aquatic toxicity :
- 96 Hour-LC50, Fish
0.22 mg/l (rainbow trout)
0.28 mg/l (bluegill sunfish)
- 48 hour-LC50, Daphnia magna 0.2 mg/l
Avian toxicity:
- Oral LD50, Bobwhite quail
- Oral LD50, Mallard duck
730 mg/kg
3300 mg/kg
- Dietary LC50, Mallard duck
- Dietary LC50, Bobwhite quail
>10,000 ppm
>10,000 ppm
Persistence and degradability
Not readily biodegradable. Rapidly hydrolyses in water into Cyanuric acid
Bioaccumulative potential
Not expected to bioaccumulate
Mobility in soil
The degradation product, Cyanuric acid, is weakly adsorbed to and highly mobile
in all soils
13. Disposal considerations
Waste disposal
Care must be taken to prevent environmental contamination from the use of this
material. Observe all federal, state and local environmental regulations when
disposing of this material.
Disposal of Packaging
Empty containers should be disposed of in accordance with all applicable laws
and regulations
{ Page 8 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
14. Transportation information
DOT
NOT REGULATED FOR ROAD TRANSPORTATION
For Vessel only:
UN No. 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s
(Sodium Dichloroisocyanurate,dihydrate)
Class: 9 - Miscellaneous Hazardous Materials
Labels: 9
Marking: Marine Pollutant
Packing Group: III
Note: Certain shipping modes or package sizes may have exceptions from the
transport regulations and may be classified as Consumer Commodity and Limited
Quantity. The classification provided may not reflect those exceptions and may not
apply to all shipping modes or package sizes.
IMDG
UN No. 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s
(Sodium Dichloroisocyanurate,dihydrate)
Class: 9 - Miscellaneous Dangerous Substances and Articles
Labels: 9
Mark: MARINE POLLUTANT
Packing Group: III
ICAO/IATA
UN No. 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s
(Sodium Dichloroisocyanurate,dihydrate)
Class: 9
Hazard label(s): Miscellaneous
Packing group: III
Marking: Environmentally hazardous
{ Page 9 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
15. Regulatory information
USA
All the components of this substance are listed on or are exempt from the
inventory
This product is registered under FIFRA
- EPA Registration no.
69470-20-91038
DANGER
- Emergency overview in
accordance to EPA Master Label Hazards to humans and domestic animals
Corrosive
Causes irreversible eye damage
May be fatal if inhaled
Harmful if swallowed or absorbed through skin
Strong oxidizing agent
This pesticide is toxic to fish and aquatic organisms.
- SARA (311, 312)
This product is categorized as an immediate health hazard, and fire and reactivity
physical hazard
- Massachusetts Right-to-Know Listed
Hazardous Substances list
- Pennsylvania Right-to-Know Listed
Hazardous Substances list
- California-Prop 65
This product does not contain any ingredient known to the State of California to
cause cancer or reproductive toxicity as listed under the State drinking Water and
Toxic Enforcement Act of 1986.
- Waste Classifications
If this product becomes a waste as defined under 40 CFR 261, it may meet the
criteria of a hazardous waste. Please check with all federal, state and local
regulations to determine if this product meets the definition of a hazardous waste
listed under 40 CFR 262.11.
EU
Reported in EINECS
Japan
ENCS no. (5)-1043
ISHL no. (5)-1043
Australia
Listed in AICS
New Zealand Inventory
Listed in NZIoC
China
{ Page 10 of 11 }
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________
Product name
Green Klean Chlorinated Sanitizing Crystals
AS_2007QDIN_GK1
Product id
03/11/2015
Revision date
Revision: 1
________________________________________________________________________________________
Listed
- China inventory
Listed in PICCS
Philippines
16. Other information
Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith
and believed to be correct as of the date hereof, SOP Green Klean makes no representations as to the completeness
or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own
determination as to its safety and suitability for their purposes prior to use. In no event will SOP Green Klean be
responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANT ABILITY, FITNESS
FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO
INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Prepared by
North America Regulatory Affairs
ICL-IP America Inc.
95 MacCorkle Ave.,S.W.
South Charleston,WV 25303, USA
Phone number:(304)746-3000
Prepared for
SOP Green Klean
615 Industrial Drive; Ste. D
Cary, IL 60013
Tel: (815) 479-0460
End of safety data sheet
{ Page 11 of 11 }
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