Ethylene Oxide

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MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 1

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

Danger

M

M

SECTION 1. Identification of the substance/mixture and of the company/undertaking

M

1.1. Product identifier

Trade name

SDS Nr

Chemical formula

: Ethylene oxide

: AL069

: C2H4O

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Use

: Industrial and professional. Perform risk assessment prior to use.

Test gas / Calibration gas. Laboratory use Contact supplier for more uses information

: Analytical reagent. Fumigant. Industrial applications. Manufacturing. Steriliser.

1.3. Details of the supplier of the safety data sheet

Company identification : Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road

Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

1.4. Emergency telephone number

Emergency telephone number : 1800 812 588

SECTION 2. Hazards identification

2.1. Classification of the substance or mixture

Hazard Class and Category Code Regulation EC 1272/2008 (CLP)

R Phrase(s)

• Health hazards

• Physical hazards

: R12 : Extremely flammable. - R23 : Toxic by inhalation. - R36/37/38 : Irritating to eyes, respiratory system and skin. - R45 : May cause cancer. - R46 : May cause heritable genetic damage.

: Acute toxicity, Inhalation - Category 3 - Danger - (CLP : Acute Tox. 3) - H331

Skin irritation - Category 2 - Warning - (CLP : Skin Irrit. 2) - H315

Eye irritation - Category 2A - Warning - (CLP : Eye Irrit. 2) - H319

Germ cell mutagenicity - Category 1B - Danger - (CLP : Muta. 1B) - H340

Carcinogenicity - Category 1B - Danger - (CLP : Carc. 1B) - H350

Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 -

Warning - (CLP : STOT SE 3) - H335

: Flammable gases - Category 1 - Danger - (CLP : Flam. Gas 1) - H220

Gases under pressure - Liquefied gas - Warning - (CLP : Press. Gas) - H280

Classification EC 67/548 or EC 1999/45

: F+; R12

Carc. Cat. 2; R45

Muta. Cat. 2; R46

T; R23

Xi; R36/37/38

2.2. Label elements

Labelling Regulation EC 1272/2008 (CLP)

• Hazard pictograms M M M M

In case of emergency : 1800 812 588 Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 2

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 2. Hazards identification (continued)

• Hazard pictograms code

• Signal word

• Hazard statements

• Precautionary statements

- Prevention

- Response

- Storage

2.3. Other hazards

: GHS06 - GHS02 - GHS08 - GHS04

: Danger

: H220 - Extremely flammable gas.

H280 - Contains gas under pressure; may explode if heated.

H331 - Toxic if inhaled.

H350 - May cause cancer.

H340 - May cause genetic defects.

H319 - Causes serious eye irritation.

H315 - Causes skin irritation.

H335 - May cause respiratory irritation.

: P260 - Do not breathe gas, vapours.

P280 - Wear protective gloves, protective clothing, eye protection, face protection.

P210 - Keep away from heat, sparks, open flames or hot surfaces. – No smoking.

P202 - Do not handle until all safety precautions have been read and understood.

: P304+P340+P315 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice / attention.

P305+P351+P338+P315 - IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice / attention.

P308+P313 - If exposed or concerned : get medical advice.

P302+P352 - IF ON SKIN : Wash with plenty of soap and water.

P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

P381 - Eliminate all ignition sources if safe to do so.

P332+P313 - If skin irritation occurs : Get medical advice.

: P403 - Store in a well-ventilated place.

P405 - Store locked up.

: None.

SECTION 3. Composition/information on ingredients

3.1. Substance / 3.2. Mixture

Substance.

Substance name

Ethylene oxide :

Contents CAS No

75-21-8

EC No

200-849-9

Annex No

603-023-00-X * 2

Classification

F+; R12

R6

Carc. Cat. 2; R45

Muta. Cat. 2; R46

T; R23

Xi; R36/37/38

----------------------------------

Flam. Gas 1 (H220)

Acute Tox. 3 (H331)

Carc. 1B (H350)

Muta. 1B (H340)

Eye irrit 2 (H319)

Skin Irrit. 2 (H315)

STOT SE 3 (H335)

Liq. Gas (H280)

Expl. (EUH006)

Contains no other components or impurities which will influence the classification of the product.

* 1: Listed in Annex IV / V REACH, exempted from registration.

* 2: Registration deadline not expired.

* 3: Registration not required: Substance manufactured or imported < 1t/y

Full text of R-phrases see chapter 16. Full text of H-statements see chapter 16

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 3

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 4. First aid measures

4.1. Description of first aid measures

First aid measures

- Inhalation

- Skin/eye contact

- Skin contact

- Eye contact

- Ingestion

: Toxic if inhaled.

In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/ consciousness. Victim may not be aware of asphyxiation.

In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of co-ordination.

Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

: Remove contaminated clothing.

Obtain medical assistance.

Immediately flush eyes thoroughly with water for at least 15 minutes.

May cause chemical burns to skin and cornea (with temporary disturbance to vision).

: Remove contaminated clothing. Drench affected area with water for at least 15 minutes.

: Immediately flush eyes thoroughly with water for at least 15 minutes.

: Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

: May cause irritation to cornea (with temporary disturbance to vision).

May cause irritation to skin.

Irritation to the respiratory tract.

Refer to section 11.

4.3. Indication of any immediate medical attention and special treatment needed

: Obtain medical assistance.

SECTION 5. Fire-fighting measures

5.1. Extinguishing media

Extinguishing media

- Suitable extinguishing media : All known extinguishants can be used.

5.2. Special hazards arising from the substance or mixture

Specific hazards

Hazardous combustion products

5.3. Advice for fire-fighters

: The decomposition temperature of ethylene oxide is 1060oF (571oC). This reaction is highly exothermic with the temperature rising from 1060oF (571oC) to 2190oF (1199oC) in only 2 milliseconds.

Exposure to fire may cause containers to rupture/explode.

: Incomplete combustion may form carbon monoxide.

Specific methods : If possible, stop flow of product.

Coordinate fire measure to the surrounding fire. Cool endangered containers with water spray jet from a protected position. Do not empty contaminated fire water into drains.

Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous/explosive re-ignition may occur. Extinguish any other fire.

Move away from the container and cool with water from a protected position.

Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing.

fighters Use self-contained breathing apparatus.

Flammable class : Extremely flammable.

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 4

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions

: Try to stop release.

: Evacuate area.

Use self-contained breathing apparatus and chemically protective clothing.

Eliminate ignition sources.

Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe.

Ensure adequate air ventilation.

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Clean up methods

: None.

: Ventilate area.

Keep area evacuated and free from ignition sources until any spilled liquid has evaporated. (

Ground free from frost).

Hose down area with water.

Wash contaminated equipment or sites of leaks with copious quantities of water.

6.4. Reference to other sections

: None.

: Try to stop release.

Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

Reduce vapour with fog or fine water spray.

: See also sections 8 and 13.

SECTION 7. Handling and storage

7.1. Precautions for safe handling

Safe use of the product

Safe handling of the gas receptacle

Handling

: Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt.

Only experienced and properly instructed persons should handle gases under pressure.

The product must be handled in accordance with good industrial hygiene and safety procedures.

Do not smoke while handling product.

Ensure the complete gas system was (or is regularily) checked for leaks before use.

: Refer to supplier's container handling instructions.

Do not allow backfeed into the container.

Protect cylinders from physical damage; do not drag, roll, slide or drop.

When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders.

Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use.

If user experiences any difficulty operating cylinder valve discontinue use and contact supplier.

Never attempt to repair or modify container valves or safety relief devices.

Damaged valves should be reported immediately to the supplier.

Keep container valve outlets clean and free from contaminates particularly oil and water.

Replace valve outlet caps or plugs and container caps where supplied as soon as container is disconnected from equipment.

Close container valve after each use and when empty, even if still connected to equipment.

Never attempt to transfer gases from one cylinder/container to another.

Never use direct flame or electrical heating devices to raise the pressure of a container.

Do not remove or deface labels provided by the supplier for the identification of the cylinder contents.

: Take precautionary measures against static discharge.

Suck back of water into the container must be prevented.

Purge air from system before introducing gas.

Do not allow backfeed into the container.

Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt.

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 5

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 7. Handling and storage (continued)

Keep away from ignition sources (including static discharges).

Refer to supplier's container handling instructions.

7.2. Conditions for safe storage, including any incompatibilities

Storage

: Keep away from combustible materials.

Keep container below 50°C in a well ventilated plac e.

Observe all regulations and local requirements regarding storage of containers.

Containers should not be stored in conditions likely to encourage corrosion.

Containers should be stored in the vertical position and properly secured to prevent toppling.

Stored containers should be periodically checked for general condition and leakage.

Container valve guards or caps should be in place.

Store containers in location free from fire risk and away from sources of heat and ignition.

: Segregate from oxidant gases and other oxidants in store.

Keep container below 50°C in a well ventilated plac e.

7.3. Specific end use(s)

: None.

SECTION 8. Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Ethylene oxide : Value 8h (CZ) [mg/m3] : 1

: Value 15min. (CZ) [mg/m3] : 3

: Grænserværdier (DK) (ppm) : 0.84

: TLV© -TWA [ppm] : 1

: LTEL - UK [ppm] : 5

: VLE - France [ppm] : 5

: VME - France [ppm] : 1

: AGW (8h) - Germany [mg/m³] TRGS 900 : 1

: AGW (8h) - Germany [ppm] TRGS 900 : 2

: Exceeding factor AGW - Germany TRGS 900 : 4

: NGV - [ppm] : 1

: NGV - [mg/m³] : 2

: KTV - [ppm] : 5

: KTV - [mg/m³] : 5

: Grænserværdier (DK) (ppm) : 1

: HTP-värden (FI) - 8 H - [ppm] : 1

: HTP-värden (FI) - 8 H - [mg/m³] : 1.8

: Grænserværdier (DK) : 1.8

: GV Value Limit (Norway) [ppm] : 1

: 8-Hour TWA (PL) (NDS) (mg/m³) : 1

: 15-Minute STEL (PL)(NDSCh) (mg/m³) : 3

: TLV-TWA (Belgium) (ppm) : 1

: None available.

: None available.

DNEL: Derived no effect level

PNEC: Predicted no effect concentration

8.2. Exposure controls

8.2.1. Appropriate engineering controls

: Systems under pressure shoud be regularily checked for leakages.

Alarm detectors should be used when toxic gases may be released.

Ensure exposure is below occupational exposure limits (where available).

Provide adequate general and local exhaust ventilation.

Consider work permit system e.g. for maintenance activities.

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 6

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 8. Exposure controls/personal protection (continued)

8.2.2. Individual protection measures, : A risk assessment should be conducted and documented in each work area to assess the e.g. personal protective equipment risks related to the use of the product and to select the PPE that matches the relevant risk.

The following recommendations should be considered.

Wear safety glasses with side shields

Wear leather safety gloves and safety shoes when handling cylinders.

Keep suitable chemically resistant protective clothing readily available for emergency use.

Keep self contained breathing apparatus readily available for emergency use.

Personal protection

8.2.3. Environmental exposure controls

: Keep suitable chemically resistant protective clothing readily available for emergency use.

Keep self contained breathing apparatus readily available for emergency use.

Do not smoke while handling product.

Ensure adequate ventilation.

Protect eyes, face and skin from liquid splashes.

: Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment.

SECTION 9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance

- Physical state at 20°C / 101.3kPa

- Colour

Odour

Odour threshold pH value

Molar mass [g/mol]

Melting point [°C]

Boiling point [°C]

Critical temperature [°C]

Flash point [°C]

Evaporation rate (ether=1)

Flammability range [vol% in air]

Vapour pressure [20°C]

: Liquefied gas.

: Colourless.

: Ethereal. Poor warning properties at low concentrations.

: Odour threshold is subjective and inadequate to warn for overexposure.

: Not applicable for gas-mixtures.

: Not applicable for gases and gas-mixtures.

: -112

: 10.4

: 196

: Not applicable for gas-mixtures.

: Not applicable for gas-mixtures.

: 3 to 100

: Not applicable.

1.4 bar

Relative density, gas (air=1)

Relative density, liquid (water=1)

: 1.5

: 0.89

Solubility in water [mg/l] : No reliable data available.

Partition coefficient n-octanol/water : Not applicable for gas-mixtures.

Auto-ignition temperature [°C]

Viscosity at 20°C [mPa.s]

Explosive Properties

: 440

: Not applicable.

: Not applicable.

9.2. Other information

Other data

Molecular weight

: Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level.

: 44

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 7

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 10. Stability and reactivity

10.1. Reactivity

Stability and reactivity

: No reactivity hazard other than the effects described in sub-sections below.

: Can form explosive mixture with air.

May decompose violently at high temperature and/or pressure or in the presence of a catalyst.

May polymerise.

Inhibitor usually added.

May react violently with oxidants.

Containers are commonly pressurised to 5-7 bars with nitrogen.

10.2. Chemical stability

: Stable under normal conditions.

10.3. Possibility of hazardous reactions

: Hazardous Polymerization may occur in the presence of catalysts suxh as pure iron, aluminium oxide, or anhydrous chlorides of iron, aluminium or tin.

10.4. Conditions to avoid

: Do no expose to temperatures exceeding 50°C/ 122°F .

10.5. Incompatible materials

: caustic soda, hydrated lime (quicklime), magnesium chloride, ammonia, alcohols and amines.

Metals other than stainless steel or nickel will cause polymerization or decomposition

10.6. Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11. Toxicological information

11.1. Information on toxicological effects

Toxicity information

Acute toxicity

Rat inhalation LC50 [ppm/4h]

LC50 [ppm/1h]

Skin corrosion/irritation

: May cause irritation to the respiratory tract.

Damage to red blood cells (haemolytic poison).

May have carcinogenic effect.

: No known toxicological effects from this product.

: • Ethylene oxide : 1450

: 2900

: Irritation to skin .

Serious eye damage/irritation

Respiratory or skin sensitisation

: Irritation to eyes.

: No known effects from this product.

Carcinogenicity

Germ cell mutagenicity

: No known effects from this product.

: May have mutagenic effect.

Toxic for reproduction : Fertility : No known effects from this product.

Toxic for reproduction : unborn child : No known effects from this product.

STOT-single exposure

STOT-repeated exposure

Aspiration hazard

: Irritation to the respiratory tract.

: No known effects from this product.

: Not applicable for gases and gas-mixtures.

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 8

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 12. Ecological information

12.1. Toxicity

: No data available.

12.2. Persistence - degradability

: No data available.

12.3. Bioaccumulative potential

12.6. Other adverse effects

Ecological effects information

: No data available.

12.4. Mobility in soil

: No data available.

12.5. Results of PBT and vPvB assessment

: No data available.

: No known ecological damage caused by this product.

May cause pH changes in aqueous ecological systems.

SECTION 13. Disposal considerations

13.1. Waste treatment methods

General

: Do not discharge into any place where its accumulation could be dangerous.

Avoid discharge to atmosphere.

Refer to the code of practice of EIGA (Doc. 30/10 “Disposal of Gases, downloadable at http:// www.eiga.org) for more guidance on suitable disposal methods

Ensure that the emission levels from local regulations or operating permits are not exceeded.

Contact supplier if guidance is required.

: Do not discharge into areas where there is a risk of forming an explosive mixture with air.

Waste gas should be flared through a suitable burner with flash back arrestor.

Do not discharge into any place where its accumulation could be dangerous.

Avoid discharge to atmosphere.

Contact supplier if guidance is required.

13.2. Additional information

: None.

SECTION 14. Transport information

UN number

Labelling ADR, IMDG, IATA

: 1040 o

ó

: 2.3 : Toxic gas.

2.1 : flammable gas.

Land transport (ADR/RID)

H.I. nr

UN proper shipping name

Transport hazard class(es)

Classification code

Packing Instruction(s)

Tunnel Restriction

: 263

: ETHYLENE OXIDE

: 2

: 2 TF

: P200

: B/D Tank carriage: Passage forbidden through tunnels of category B, C, D

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 9

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 14. Transport information (continued)

HAZCHEM - Emergency Action Code : 2PE

: 2 = Fine water spray.

P = Risk of violent reaction or explosion. Recommended personal protective equipment :

Liquid-tight chemical protective clothing and breathing apparatus. Appropriate measures : dilute.

E = There may be a public safety hazard outside the immediate area of the incident, and that the following actions should be considered :

1. People should be warned to stay indoors with all doors and windows closed, preferably in rooms upstairs and facing away from the incident. Ignition sources should be eliminated and any ventilation stopped.

2. Effects may spread beyond the immediate vicinity. all non-essential personnel should be instructed to move at least 250 metres away from the incident.

3. Police and fire brigade incident commanders should consult each other and with a product expert, or with a source of product expertise.

4. The possible need for subsequent evacuation should be considered, but it should be remembered that in most cases it will be safer to remain in a building than to evacuate.

Sea transport (IMDG)

Proper shipping name

Class

: ETHYLENE OXIDE

: 2.3

: F-D Emergency Schedule (EmS) - Fire

Emergency Schedule (EmS) - Spillage : S-U

Packing instruction : P200

Air transport (ICAO-TI / IATA-DGR)

Proper shipping name (IATA)

Class

Passenger and Cargo Aircraft

Cargo Aircraft only

Special precautions for user

: ETHYLENE OXIDE

: 2.3

: DO NOT LOAD IN PASSENGER AIRCRAFT.

: FORBIDDEN.

Labelling ADR

Other transport information

: Avoid transport on vehicles where the load space is not separated from the driver's compartment.

Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency.

Before transporting product containers :

- Ensure there is adequate ventilation.

- Ensure that containers are firmly secured.

- Ensure cylinder valve is closed and not leaking.

- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.

- Ensure valve protection device (where provided) is correctly fitted.

: 2.3 : Toxic gas.

2.1 : flammable gas.

: Avoid transport on vehicles where the load space is not separated from the driver's compartment.

Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency.

Before transporting product containers :

- Ensure that containers are firmly secured.

- Ensure cylinder valve is closed and not leaking.

- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.

- Ensure valve protection device (where provided) is correctly fitted.

- Ensure there is adequate ventilation.

- Compliance with applicable regulations.

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

MATERIAL SAFETY DATA SHEET

Ethylene oxide

Page : 10

Revised edition no : 5

Date : 8 / 11 / 2012

Supersedes : 24 / 10 / 2012

AL069

SECTION 15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU legislation

Restrictions on use

Seveso directive 96/82/EC

National legislation

: Restricted to professional users (Annex XVII REACH).

: Not covered.

: Ensure all national/local regulations are observed.

15.2. Chemical Safety Assessment

: A CSA does not need to be carried out for this product.

SECTION 16. Other information

Indication of changes

Training advice

List of full text of R-phrases in section : R6 : Explosive with or without contact with air.

3.

R12 : Extremely flammable.

R23 : Toxic by inhalation.

R36/37/38 : Irritating to eyes, respiratory system and skin.

R45 : May cause cancer.

R46 : May cause heritable genetic damage.

List of full text of H-statements in section 3.

: EUH006 - Explosive with or without contact with air.

H220 - Extremely flammable gas.

H280 - Contains gas under pressure; may explode if heated.

H315 - Causes skin irritation.

H319 - Causes serious eye irritation.

H331 - Toxic if inhaled.

H335 - May cause respiratory irritation.

H340 - May cause genetic defects.

H350 - May cause cancer.

Further information

: Revised safety data sheet in accordance with commisssion regulation (EU) No 453/2010

: Ensure all national/local regulations are observed.

Receptacle under pressure.

Ensure operators understand the toxicity hazard.

Ensure operators understand the flammability hazard.

Users of breathing apparatus must be trained.

The hazard of asphyxiation is often overlooked and must be stressed during operator training.

Note

DISCLAIMER OF LIABILITY

: Classification in accordance with calculation methods of regulation (EC) 1272/2008 CLP / (

EC) 1999/45 DPD.

This Safety Data Sheet has been established in accordance with the applicable European

Union legislation.

: This Safety Data Sheet has been established in accordance with the applicable European

Union legislation.

: Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out.

Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted.

The contents and format of this SDS are in accordance with EC Commission Directive 2001/58/EC.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

End of document

Air Liquide Australia Limited

Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia

Tel: + 61 3 9697 9888

Fax: + 61 3 9690 7107

[email protected]

In case of emergency : 1800 812 588

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