CLO 30024 01

CLO 30024 01
SAFETY DATA SHEET
Issuing Date January 5, 2015
Revision Date New
Revision Number 0
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name
Clorox Automatic Toilet Bowl Cleaner
Other means of identification
Synonyms
None.
Recommended use of the chemical and restrictions on use
Recommended Use
Toilet bowl cleaner
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Address
The Clorox Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
For Medical Emergencies, call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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Clorox® Automatic Toilet Bowl Cleaner
Revision Date New
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Acute toxicity - Oral
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Reproductive toxicity
Oxidizing solids
Category 4
Category 1B
Category 1
Category 1
Category 1B
Category 2
GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Danger
Hazard statements
Harmful if swallowed
Causes severe skin burns and eye damage
May cause an allergic skin reaction
May damage fertility or the unborn child
May intensify fire; oxidizer
Appearance White
Physical State Solid
Odor Slight chlorine
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Contaminated work clothing should not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Keep only in original container
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
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Clorox® Automatic Toilet Bowl Cleaner
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Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Immediately call a POISON CENTER or doctor/physician
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth. Do NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Spill
Absorb spillage to prevent material damage
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not Applicable
Unknown Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.
Interactions with Other Chemicals
Reacts with other household chemicals such as acid toilet bowl cleaners, rust removers, acids, vinegar, and ammonia-containing
products to produce hazardous gases, such as chlorine/bromine and other chlorinated/brominated compounds. Avoid contact with
strong alkalis.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No
Weight %
Trade Secret
2,4-Imidazolidinedione, 1-bromo-3-chloro-5,5-dimethyl16079-88-2
40 - 60
*
1,3-Dichloro-5,5-dimethyl hydantoin
118-52-5
20 - 30
*
Boric acid
10043-35-3
10 - 20
*
2,4-Imidazolidinedione, 1,3-dichloro-5-ethyl-5-methyl89415-87-2
7 - 15
*
* The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
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Clorox® Automatic Toilet Bowl Cleaner
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4. FIRST AID MEASURES
First aid measures
General Advice
Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Seek immediate medical
attention/advice. Remove contact lenses, if applicable, and continue flushing.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. IF ON
CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before
removing clothes If skin irritation persists, call a physician. For severe burns, immediate
medical attention is required.
Inhalation
Move to fresh air. If not breathing, give artificial respiration. Administer oxygen if breathing is
difficult and you are trained.
Ingestion
Do NOT induce vomiting. Rinse mouth. Clean mouth with water and afterwards drink plenty
of water. Never give anything by mouth to an unconscious person. Call a physician or
Poison Control Center immediately.
Protection of First-aiders
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms/Effects
Burning sensation. Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes.
Hives.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically. Product is a corrosive material. Use of gastric lavage or emesis is
contraindicated. Possible perforation of stomach or esophagus should be investigated. Do
not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in
blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. May
cause sensitization of susceptible persons.
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Clorox® Automatic Toilet Bowl Cleaner
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use water. Do not use dry chemicals or foams. CO2 or Halon may provide limited control. Flood fire area with water from a distance.
Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire.
May ignite combustibles (wood paper, oil, clothing, etc.). Runoff may create fire or explosion hazard.
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact
No
Sensitivity to Static Discharge
Yes
Protective Equipment and Precautions for Firefighters
Do not move cargo or vehicle if cargo has been exposed to heat. Fight fire from maximum distance or use unmanned hose holders or
monitor nozzles. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor; if this is
impossible, withdraw from area and let fire burn.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Attention! Corrosive material. Avoid contact with skin, eyes and clothing. Ensure adequate
ventilation. Use personal protective equipment. Evacuate personnel to safe areas. Keep
people away from and upwind of spill/leak. Avoid dust formation. Do not breathe dust
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Refer to Section 8 Stop leak if you can do it without risk.
Other Information
DO NOT GET WATER INSIDE CONTAINERS.
Environmental precautions
Environmental Precautions
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if
safe to do so. Should not be released into the environment. Do not allow material to
contaminate ground water system. Prevent product from entering drains. Do not flush into
surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so. Cover with DRY earth, DRY sand, or other
non-combustible material followed with plastic sheet to minimize spreading or contact with rain.
Methods for Cleaning Up
With clean shovel place material into clean, dry container and cover loosely; move containers
from spill area. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Dike far ahead of liquid spill for later
disposal. Following product recovery, flush area with water.
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Clorox® Automatic Toilet Bowl Cleaner
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. Handle product only in closed system or provide appropriate exhaust ventilation
at machinery. Do not eat, drink or smoke when using this product. Remove and wash
contaminated clothing before re-use. Avoid dust formation. Fine dust dispersed in air may
ignite. Wear personal protective equipment. Keep away from heat, sparks and open flame.
No smoking. Do not breathe dust
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture.
Store locked up. Keep out of the reach of children. Store away from other materials. Keep
away from heat and sources of ignition. Keep in properly labeled containers. Do not store
near combustible materials. Store in accordance with the particular national regulations.
Store in accordance with local regulations.
Incompatible Products
Acids. Bases. Organic material. Combustible materials. Hydrocarbons.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name
1,3-Dichloro-5,5-dimethyl
hydantoin
118-52-5
Boric acid (H3BO3)
10043-35-3
ACGIH TLV
OSHA PEL
STEL: 0.4 mg/m
TWA: 0.2 mg/m3
TWA: 0.2 mg/m3
NIOSH IDLH
IDLH: 5 mg/m3
TWA: 0.2 mg/m3
STEL: 0.4 mg/m3
TWA: 2 mg/m3 inhalable fraction
STEL: 6 mg/m3 inhalable fraction
-
-
3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Face-shield.
Skin and Body Protection
Wear protective gloves/clothing. Long sleeved clothing. Chemical resistant apron. Impervious
gloves. Wear fire/flame resistant/retardant clothing.
Respiratory Protection
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
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Clorox® Automatic Toilet Bowl Cleaner
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Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Remove and wash contaminated clothing before re-use.
Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection.
Contaminated work clothing should not be allowed out of the workplace. Provide regular
cleaning of equipment, work area and clothing. Wash hands before breaks and immediately
after handling the product. For environmental protection, remove and wash all contaminated
protective equipment before re-use. Do not breathe dust
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Appearance
Color
Property
pH
Melting/freezing point
Boiling Point/Range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive Properties
Oxidizing Properties
Other Information
Softening Point
VOC Content (%)
Solid
White
No information available
Odor
Odor Threshold
Values
No data available
No data available
No data available
No data available
No data available
No data available
Remarks/ Method
None known
None known
None known
None known
None known
None known
No data available
No data available
No data available
No data available
No data available
Liquid
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
No data available
No data available
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Slight chlorine
No information available
Clorox® Automatic Toilet Bowl Cleaner
Revision Date New
10. STABILITY AND REACTIVITY
Reactivity
Oxidizer.
Chemical stability
Stable under recommended storage conditions. Strong oxidizer. Contact with other material may cause fire.
Possibility of Hazardous Reactions
Reacts with other household chemicals such as acid toilet bowl cleaners, rust removers, acids, vinegar, and ammonia-containing
products to produce hazardous gases, such as chlorine/bromine and other chlorinated/brominated compounds.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Exposure to air or moisture over prolonged periods. Excessive heat. Heat, flames and sparks. Incompatible products. Heating in air.
Dust formation.
Incompatible materials
Acids. Bases. Organic material. Combustible materials. Hydrocarbons.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
There is no data available for this product. Corrosive by inhalation (based on components).
Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and
weakness for several hours. Pulmonary edema may occur with tightness in the chest,
shortness of breath, bluish skin, decreased blood pressure, and increased heart rate. Inhaled
corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal.
May cause irritation of respiratory tract. Harmful by inhalation.
Eye Contact
There is no data available for this product. Causes burns. (based on components). Corrosive
to the eyes and may cause severe damage including blindness. Causes serious eye damage.
May cause irreversible damage to eyes.
Skin Contact
There is no data available for this product. Corrosive. (based on components) Causes burns.
Ingestion
There is no data available for this product. Causes burns (based on components). Ingestion
causes burns of the upper digestive and respiratory tract. May cause severe burning pain in
the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may
decrease. Brownish or yellowish stains may be seen around the mouth. Swelling of the
throat may cause shortness of breath and choking May cause lung damage if swallowed. May
be fatal if swallowed and enters airways. Ingestion may cause irritation to mucous membranes.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May be harmful
if swallowed.
Chemical Name
Boric acid
10043-35-3
LD50 Oral
LD50 Dermal
LC50 Inhalation
= 2660 mg/kg ( Rat )
> 2000 mg/kg ( Rabbit )
> 0.16 mg/L ( Rat ) 4 h
Information on toxicological effects
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Clorox® Automatic Toilet Bowl Cleaner
Symptoms
Revision Date New
Redness of the skin. Burning. May cause blindness. Coughing and/ or wheezing. Itching.
Rashes. Hives.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
May cause sensitization of susceptible persons. May cause sensitization by skin contact.
May cause sensitization by inhalation.
Mutagenic Effects
No information available.
Carcinogenicity
No information available.
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Contains a known or suspected reproductive toxin.
No information available.
No information available.
No known effect based on information supplied. Chronic exposure to corrosive fumes/gases
may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic
cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may
also be seen. Effects from this product caused by acute exposure may cause permanent
damage to target organs and/or may cause chronic conditions. Contains a known or
suspected reproductive toxin. Possible risks of irreversible effects.
Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Reproductive system.
Digestive System. Kidney.
No information available.
Target Organ Effects
Aspiration Hazard
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
760.00 mg/kg
ATEmix (inhalation-gas)
7,000.00
ppm (4 hr)
ATEmix (inhalation-dust/mist)
5.01 mg/L
ATEmix (inhalation-vapor)
30.00ATEmix
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic organisms
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other Adverse Effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations. Do not contaminate food or feed by disposal of this
product.
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Clorox® Automatic Toilet Bowl Cleaner
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Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT
Limited Quantity.
TDG
UN-No
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1479
OXIDIZING SOLID, N.O.S.
5.1
II
UN1479, OXIDIZING SOLID, N.O.S.
(1-BROMO-3-CHLORO-5,5-DIMETHYL-2,4-IMIDAZOLIDINEDIONE ), 5.1, II
UN-No
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1479
OXIDIZING SOLID, N.O.S.
5.1
II
UN1479, OXIDIZING SOLID, N.O.S.
(1-BROMO-3-CHLORO-5,5-DIMETHYL-2,4-IMIDAZOLIDINEDIONE ), 5.1, II
UN-No
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1479
OXIDIZING SOLID, N.O.S.
5.1
II
UN1479, OXIDIZING SOLID, N.O.S.
(1-BROMO-3-CHLORO-5,5-DIMETHYL-2,4-IMIDAZOLIDINEDIONE ), 5.1, II
ICAO
IATA
IMDG/IMO
UN-No
Proper Shipping Name
Hazard Class
Packing Group
EmS No.
Description
UN1479
OXIDIZING SOLID, N.O.S.
5.1
II
F-A, S-Q
UN1479, OXIDIZING SOLID, N.O.S.
(1-BROMO-3-CHLORO-5,5-DIMETHYL-2,4-IMIDAZOLIDINEDIONE ), 5.1, II
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL
Complies
All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
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Clorox® Automatic Toilet Bowl Cleaner
Revision Date New
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Yes
Yes
Yes
Yes
Yes
Clean Water Act \
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization
Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of
this material.
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name
1,3-Dichloro-5,5-dimethyl hydantoin
118-52-5
New Jersey
X
Massachusetts
X
International Regulations
Canada
WHMIS Hazard Class
C - Oxidizing materials
D2A - Very toxic materials
E - Corrosive material
B - Flammable/Combustible Materials
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Pennsylvania
X
Rhode Island
Illinois
Clorox® Automatic Toilet Bowl Cleaner
Revision Date New
16. OTHER INFORMATION
NFPA
Health Hazard 3
Flammability 1
Instability 1
HMIS
Health Hazard 3*
Flammability 1
Physical Hazard 1
Chronic Hazard Star Legend
*Indicates a chronic health hazard.
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
New
Revision Note
New
Reference
CLX50567-001/50657.001
Physical and Chemical
Hazards OX
Personal Protection X
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process, unless specified in the text.
End of Safety Data Sheet
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