MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 CHEMTREC: (800) 424-9300 REVISION DATE: April 15, 2009 DATE OF ISSUE: April 21, 2009 I - Product Identification Machine Dish Detergent PRODUCT CODE: 0664 CHEMICAL FORMULATION: Powder detergent. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 HAZARD RATING: 4 - Extreme; 3 - High; FLAMMABILITY: 0 2 - Moderate; 1 - Slight; REACTIVITY: 1 0 - Insignificant II - Hazardous Ingredients SUBSTANCE Sodium carbonate Sodium metasilicate Sodium dichloroisocyanurate APPROX % 40.0-50.0 10.0-20.0 1.0-2.0 Values reported as TWA unless noted. EPA 40 CFR: OSHA ACGIH PEL TLV 302 355 372 5 mg/m3 * 3 mg/ m3 * N N N 3 3 5 mg/m * 3 mg/ m * N N N 5 mg/m3 * 3 mg/ m3 * N N N CAS # 497-19-8 6834-92-0 51580-86-0 * respirable dust - 8-hr TWA Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data SPECIFIC GRAVITY (WATER = 1): N/A BOILING POINT (°F): N/A VAPOR PRESSURE (mm Hg): N/A VOC CONTENT (% by weight): <2.0 VAPOR DENSITY (AIR = 1): N/A EVAPORATION RATE (WATER = 1): N/A SOLUBILITY IN WATER: Soluble pH: N/A APPEARANCE AND ODOR: Fine, white powder; slight chlorine odor. IV - Fire and Explosion Hazard Data FLASH POINT (°F): N/A (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Water, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. Fire may produce hazardous fumes. UNUSUAL FIRE AND EXPLOSION HAZARD: Powder may produce chlorine gas when wet. PRODUCT NAME: Machine Dish Detergent PRODUCT CODE: 0664 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Acidic and reducing material. CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon and chlorine gas. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Mild to moderate irritation, redness tearing. IF ON SKIN: Irritation, with prolonged or repeated exposure. May aggravate existing skin conditions. IF SWALLOWED: Nausea, cramps, and diarrhea. IF INHALED: Irritation to upper respiratory tract. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water, for at least 15 minutes and obtain medical attention. IF ON SKIN: Flush with water for at least 15 minutes. Remove contaminated clothing and launder before re-use. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Rinse mouth with water. Give affected person 1 to 2 glasses of water. Do not induce vomiting unless instructed by a physician or poison control center. Never give anything to an unconscious person. IF INHALED: Remove person to fresh air. Call physician immediately. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area. Contain spill. Scoop up material for reuse or place in a labeled vented container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breathe dusts. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Chemical goggles or safety glasses. OTHER PROTECTIVE EQUIPMENT: Emergency eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place, away from acids. Keep container tightly closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT ID NUMBER: UN 3262 DOT CLASS: 8 DOT PROPER SHIPPING NAME: Corrosive solid, basic, inorganic, n.o.s. (sodium metasilicate, anhydrous) DOT PACKING GROUP: III The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: April 15, 2009 Prepared by: Technical Dept. DATE OF ISSUE: April 21, 2009 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material.
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