Screecher Aerosol Horn

Screecher Aerosol Horn
SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Date of issue: 02/24/2010
Revision date: 04/28/2015
Supersedes: 02/24/2015
Version: 2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
.1.
Product identifier
Chemical name
: 1,1,1,2-Tetrafluoroethane
Chemical formula
: F3CCH2F
Product name
: SCREECHER AEROSOL HORN
Synonyms
: R-134A
Product code
: 80144, 80145
SDS ID
: 2015031
1.2.
Relevant identified uses of the substance or mixture and uses advised against
Self defense device / warning device
1.3.
Details of the supplier of the safety data sheet
Mace Personal Defense & Security, Inc.
4400 Carnegie Avenue
Cleveland, OH, 44103
Tel: 440-424-5321
1.4.
Emergency telephone number
Emergency number
: CHEMTREC (800) 424-9300
Outside USA: +1 703-527-3888
24 hours
Customer ID: CCN13561
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
GHS-US classification
Liquefied gas H280
Full text of H-phrases: see section 16
2.2.
Label elements
GHS-US labelling
Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
: Warning
Hazard statements (GHS-US)
: H280 - Contains gas under pressure; may explode if heated
Precautionary statements (GHS-US)
: P410+P403 - Protect from sunlight. Store in a well-ventilated place
GHS04
2.3.
Other hazards
In high concentrations may cause asphyxiation.
2.4.
Unknown acute toxicity (GHS-US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1.
Substances
Name
: SCREECHER AEROSOL HORN
Name
Product identifier
%
GHS-US classification
1,1,1,2-Tetrafluoroethane
(CAS No) 811-97-2
100
Liquified gas; H280
Full text of H-phrases: see section 16
3.2.
Mixture
Not applicable
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SDS ID: 2015031
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SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
4.1.
Description of first aid measures
First-aid measures after inhalation
: In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/consciousness. Victim may not be aware of asphyxiation. Remove victim to
uncontaminated area wearing self contained breathing apparatus. Keep victim warm and
rested. Call a doctor. Apply artificial respiration if breathing stopped.
First-aid measures after skin contact
: Wash skin with plenty of water. If there is evidence of frostbite, bathe with lukewarm water. Do
not rub the affected area. If water is not available, cover with a clean, soft or similar covering.
Seek medical advise.
First-aid measures after eye contact
: Immediately flush with water for at least 15 minutes Obtain medical assistance. In case of
frostbite, water should be lukewarm, lifting eyelids occasionally to facilitate irrigation. Seek
medical attention if symptoms persist.
: Ingestion is not considered a potential route of exposure. DO Not induce vomiting unless
instructed by a physician. Call a poison center or a doctor if you feel unwell.
First-aid measures after ingestion
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: Symptoms may include loss of mobility/consciousness. Victim may not be aware of
asphyxiation.
Symptoms/injuries after skin contact
: May cause frostbite.
Symptoms/injuries after eye contact
: May cause frostbite.
4.3.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: Use extinguisher suitable for surronding area. Foam. Dry powder. Carbon dioxide. Water spray.
Sand.
Unsuitable extinguishing media
: Non known.
5.2.
Special hazards arising from the substance or mixture
Fire hazard
: Not combustible.
Explosion hazard
: Compressed gas. Heat may build pressure, rupturing closed containers, spreading fire and
increasing risk of burns and injuries.
5.3.
Advice for firefighters
Firefighting instructions
: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire
reaches explosives. Evacuate area.
Protective equipment for firefighters
: Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
General measures
6.1.1.
For non-emergency personnel
Emergency procedures
6.1.2.
: No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove
ignition sources. Use special care to avoid static electric charges.
: Evacuate unnecessary personnel. For further information refer to section 8 : Exposurecontrols/personal protection.
For emergency responders
Protective equipment
: Equip cleanup crew with proper protection. Wear self-contained breathing apparatus when
entering area unless atmosphere is proved to be safe. Ensure adequate air ventilation.
Emergency procedures
: Ventilate area.
6.2.
Environmental precautions
Prevent entry to sewers and public waters.
6.3.
Methods and material for containment and cleaning up
Methods for cleaning up
6.4.
: Try to stop release if safe to do. Prevent from entering sewers, basements and workpits, or any
place where its accumulation can be dangerous.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
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SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Additional hazards when processed
: Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or
burn, even after use.
Precautions for safe handling
: Provide good ventilation in process area to prevent formation of vapor. Do not spray on an
open flame or other ignition source. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only
outdoors or in a well-ventilated area. Avoid contacting with skin and eye. Suck back of water
into the container must be prevented. Do not allow back-feed into the container. Use only
properly specified equipment, which is suitable for this product, its supply pressure and
temperature. Do not puncher or drop cylinders, expose to open flame or excessive heat.
Hygiene measures
: Wash hands thoroughly after handling. Wash hands and other exposed areas with mild soap
and water before eating, drinking or smoking and when leaving work place.
7.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Keep only in the original container in a cool, well-ventilated place. Do not expose to
temperatures exceeding 50 °C/ 122 °F. Keep in fireproof place. Keep container tightly closed.
Incompatible products
: No additional information available.
Incompatible condition
: Sources of ignition. Direct sunlight. Heat sources.
7.3.
Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
No additional information available
8.2.
Exposure controls
Appropriate engineering controls
: Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Provide adequate ventilation.
Personal protective equipment
: Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory
protection.
Hand protection
: Wear insulating protective gloves.
Eye protection
: Chemical goggles or safety glasses.
Respiratory protection
: In case of insufficient ventilation wear appropriate respiratory protection.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Gas
Appearance
: Liquefied gas
Color
: Colorless
Odor
: Faint ethereal odor
Odor threshold
: No data available
pH
: Neutral
Relative evaporation rate (butyl acetate=1)
: >1
Melting point
: No data available
Freezing point
: -100.6 °C (-141.9 °F)
Boiling point
: -26.2 °C (-15.1 °F)
Flash point
: Not applicable
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapor pressure
: 80 psi at 21 °C (70 °F)
Relative vapor density at 20 °C
: 3.5 (Air=1)
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SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Relative density
: <1.22 (water=1)
Solubility
: 0.15% (w/w)
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: No data available
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: No data available
9.2.
Other information
Percent Volatility
: 100%
SECTION 10: Stability and reactivity
10.1.
Reactivity
May react violently with alkaline-earth and alkali metals.
10.2.
Chemical stability
Stable at ambient temperature and under normal conditions of use.
Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition.
10.3.
Possibility of hazardous reactions
Hazardous polymerization may occur if exposure to fire conditions
10.4.
Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating.
10.5.
Incompatible materials
Alkaline-earth and alkali metals.
10.6.
Hazardous decomposition products
No additional information available.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
1,1,1,2-Tetrafluoroethane (811-97-2)
LC50 inhalation rat (mg/l)
: Not classified
1500 g/m³ (Exposure time: 4 h)
Skin corrosion/irritation
: Not classified
Serious eye damage/irritation
: Not classified
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
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SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
SECTION 12: Ecological information
12.1.
Toxicity
Ecology - general
12.2.
: The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Persistence and degradability
No additional information available
12.3.
Bioaccumulative potential
No additional information available
12.4.
Mobility in soil
No additional information available
12.5.
Other adverse effects
Effect on ozone layer
: No additional information available
Effect on the global warming
: No additional information available
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Container under
pressure. Do not drill or burn even after use.
Additional information
: Flammable vapors may accumulate in the container.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
Transport document description (ADR)
: ID8000 Consumer commodity, 9
UN-No.(DOT)
: ID8000
Proper Shipping Name (DOT)
: Consumer commodity
Hazard Classes (DOT)
: 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140
Hazard labels (DOT)
: 9 - Class 9 (Miscellaneous dangerous materials)
DOT Packaging Exceptions (49 CFR 173.xxx)
: 167
DOT Packaging Non Bulk (49 CFR 173.xxx)
: 167
DOT Packaging Bulk (49 CFR 173.xxx)
: None
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 30 kg
DOT Quantity Limitations Cargo aircraft only (49 : 30 kg gross
CFR 175.75)
Additional information
Other information
: No supplementary information available.
ADR
No additional information available
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SCREECHER AEROSOL HORN
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Transport by sea
No additional information available
Air transport
UN-No.(IATA)
: 8000
Proper Shipping Name (IATA)
: Consumer commodity
Class (IATA)
: 9 - Miscellaneous Dangerous Goods
SECTION 15: Regulatory information
15.1. US Federal regulations
1,1,1,2-Tetrafluoroethane (811-97-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
1,1,1,2-Tetrafluoroethane (811-97-2)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification
Class A - Compressed Gas
EU-Regulations
1,1,1,2-Tetrafluoroethane (811-97-2)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
No information available
Classification according to Directive 67/548/EEC or 1999/45/EC
No information available
15.2.2.
National regulations
1,1,1,2-Tetrafluoroethane (811-97-2)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
\
15.3. US State regulations
SECTION 16: Other information
Revision date
: 04/28/2015
Full text of H-phrases:
-----Liquefied gas
-----H280
Gases under pressure : Liquefied gas
Contains gas under pressure; may explode if heated
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product
04/29/2015
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SDS ID: 2015031
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