Page 1 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Brominating Tabs GENERAL USE: Spa Sanitizer PRODUCT DESCRIPTION: Mini Slow Dissolving Tablets for Swimming Pool & Spa Disinfecting CHEMICAL FAMILY: Halogenated Hydantoin MANUFACTURER Clearon Corp. 95 MacCorkle Ave SW South Charleston WV 25303 Emergency Contact: Chemtrec (800) 424-9300 Product Stewardship: (304) 746-3000 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: White tablet IMMEDIATE CONCERNS: Corrosive. Causes irreversible eye damage and skin burns. Irritating to nose and throat. May be fatal if inhaled. Harmful if absorbed through skin or swallowed. Oxidizer. POTENTIAL HEALTH EFFECTS EYES: Corrosive. May cause temporary or permanent eye damage. SKIN: Exposure to wet skin may cause severe irritation. May cause skin sensitization. INHALATION: Irritant to upper respiratory tract. Shortness of breath, headache and nausea. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name 2,4-imidazolidinedione, Bromochloro-5,5-dimethyl 4. FIRST AID MEASURES Wt.% 98 CAS EINECS 032718-18-6 251-171-5 Page 2 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs EYES: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN: Remove contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for futher treatment advice. NOTES TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE FIGHTING MEASURES FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Dry powder, carbon dioxide or water spray. EXPLOSION HAZARDS: Oxidizing agent. Forms explosive mixtures with combustible, organic or other easily oxidizable materials. When heated to decomposition, may release poisonous and corrosive fumes. FIRE FIGHTING PROCEDURES: Cool containers with water spray. In closed stores, provide fire-fighters with selfcontained breathing apparatus in positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Evacuate area. RELEASE NOTES: Vacuum or sweep up material and place in a disposal container. Avoid dust formation. Collect solids for waste removal. Rinse contaminated area with plenty of water. Avoid access to streams, lakes or ponds. SPECIAL PROTECTIVE EQUIPMENT: Use dust respirator, rubber gloves and chemical safety goggles. 7. HANDLING AND STORAGE HANDLING: Keep containers tightly closed. STORAGE: Keep away from sources of ignition. Store in a cool, dry, well-ventilated area. Keep away from incompatible materials. STORAGE TEMPERATURE: Below 30 degrees C. LOADING TEMPERATURE: For transportation, it is possible to store at temperatures up to 50 degrees C. Page 3 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL Chemical Name 2,4-imidazolidinedione, Bromochloro-5,5-dimethyl ppm TWA N/E mg/m3 ACGIH TLV ppm mg/m 3 N/E ENGINEERING CONTROLS: Use local exhaust as necessary, especially under dusty conditions. Ventilation must be sufficient to maintain atmospheric concentration below recommended exposure limit. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear chemical safety glasses or goggles. SKIN: PVC gloves, body covering clothes and boots. RESPIRATORY: Approved respirator. WORK HYGIENIC PRACTICES: Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Safety shower and eye bath should be provided. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid ODOR: Faint halogenous odor APPEARANCE: White tablet. VAPOR PRESSURE: 9.35x10(-3) Pa (25 deg C) VAPOR DENSITY: 98 BOILING POINT: Not Applicable SOLUBILITY IN WATER: .22 g/100ml SPECIFIC GRAVITY: 1.800 to 2.0 (VOC): 98.000 10. STABILITY AND REACTIVITY Page 4 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs HAZARDOUS POLYMERIZATION: No STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Exposure to moisture. Heating above decomposition temperature. Contact with combustible materials may initiate decomposition of the material and emission of smoke. HAZARDOUS DECOMPOSITION PRODUCTS: CO, HBr, Cl2, NOx, HCl, CO2 INCOMPATIBLE MATERIALS: Oxidizing agents, bases, and combustible organic materials. 11. TOXICOLOGICAL INFORMATION ACUTE ORAL LD50: 929 mg/kg (rat) INHALATION LC50: 1.1 mg/l/4 hour (rat) CARCINOGENICITY IARC: Not classified as a carcinogen. IRRITATION: Dermal irritation (rabbit) - Corrosive SENSITIZATION: Sensitizer MUTAGENICITY: Mutagenic by the Ames Test. Mutagenic in the mouse lymphoma L5178Y test system. Non genotoxic in an in-vivo in micronucleous test in mice. Non genotoxic in an in-vivo liver unscheduled DNA synthesis (USD) assay. 12. ECOLOGICAL INFORMATION BIOACCUMULATION/ACCUMULATION: Based on low Kow values, i.e. less than one, this product would not be predicted to significantly accumulate in aquatic organisms, or sorb to organic material in soil or sediment. AQUATIC TOXICITY (ACUTE) 96-HOUR LC50: 1.2 mg/l (eastern oyster, Acute flow through) 1.9 mg/l (Mysid shrimp, Acute flow through) 0.4 mg/l (Rainbow trout, Static) 1.6 mg/l (Sheepshead minnow, Acute flow through) 48-HOUR EC50: 0.75 mg/l (Static) (Daphnia Magna) COMMENTS: Avian Toxicity: Oral LD50, Bobwhite Quail 1839 mg/kg Dietary LC50, Mallard Duck >5620 ppm Dietary LC50, Bobwhite quail >5620 ppm Page 5 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Oxidizing Solid, N.O.S. (Bromochloro-5, 5-Dimethylhydantoin) PRIMARY HAZARD CLASS/DIVISION: 5.1 UN/NA NUMBER: UN 1479 PACKING GROUP: II OTHER SHIPPING INFORMATION: DOT exception 173.154 - this product qualifies as a Consumer Commodity (ORM-D) when inner packaging does not exceed 2.2 lbs and outer packaging does not exceed 66 lbs. 15. REGULATORY INFORMATION UNITED STATES DOT LABEL SYMBOL AND HAZARD CLASSIFICATION Oxidizing SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: This product is a hazardous chemical under 29CFR 1910.1200 and is categorized as an IMMEDIATE, DELAYED HEALTH and REACTIVITY physical hazard. 313 REPORTABLE INGREDIENTS: No ingredients listed at or above the de minimus level. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: Not listed. FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This is an EPA-registered product. 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 1 This MSDS replaces the June 11, 2008 MSDS. Any changes in information are as follows: In Section 14 DOT UN/NA Number Page 6 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Brominating Tabs 06/13/2008 1 Spa Choice Brominating Tabs HMIS RATING NFPA CODES HEALTH: 3 FLAMMABILITY: 0 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: 0 3 1 OX MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Bromine Booster GENERAL USE: Bromine Enhancer. MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYES: May cause eye irritation. SKIN: Substance does not irritate intact skin. Slight irritant to abraded skin. INGESTION: Adbominal pain, nausea, vomiting. May cause drowsiness, muscular incoordination and respiratory depression. INHALATION: Irritant to upper respiratory tract. SIGNS AND SYMPTOMS OF OVEREXPOSURE CHRONIC EFFECTS: Repeated skin contact may cause dermatitis. Repeated oral intake of bromides (>9 mg/kg body weight/day) may affect the central nervous system. Warning symptoms include mental dullness, slurred speech, weakened memory, apathy, anorexia, constipation, drowsiness, and loss of sensitivity to touch and pain. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% Sodium Bromide 99 CAS EINECS 007647-15-6 231-599-9 4. FIRST AID MEASURES EYES: Hodling eyelids apart, flush with plenty of water for at least 20 minutes. Get medical attention immediately. Page 2 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster SKIN: Immediately wash skin with plenty of water for at least 15 minutes. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. INGESTION: If swallowed, wash mouth thoroughly with plenty of water and give water to drink. Get medical attention immediately. Never give an unconscious person anything to drink. INHALATION: In case of dust inhalation or the breathing of fumes of heated material, remove person to fresh air. Keep warm and quiet. Apply artificial respiration if necessary and get medical attention immediately. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not Flammable FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire. FIRE FIGHTING PROCEDURES: Cool containers with water spray. In closed stores, provide fire-fighters with selfcontained breathing apparatus in positive pressure mode. HAZARDOUS DECOMPOSITION PRODUCTS: Will decompose from 800 deg C releasing poisonous and corrosive fumes of hydrogen bromide and sodium oxide. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Sweep up and place in bag. Hold for waste disposal or possible re-use. Ventilate area and wash spill site after material pickup is complete. 7. HANDLING AND STORAGE HANDLING: Avoid bodily contact. Keep containers tightly closed. STORAGE: Store in a cool, dry, well-ventilated area away from incompatible materials. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 3 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL Chemical Name Sodium Bromide TWA ACGIH TLV ppm mg/m3 ppm mg/m 3 [1] [1] [1] [1] Footnotes: 1. Not established. ENGINEERING CONTROLS: Use with adequate ventilation. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety glasses recommended. SKIN: Protective gloves. RESPIRATORY: If needed, use OSHA-NIOSH approved respirator with cartridge for dusts/mists. PROTECTIVE CLOTHING: Body protective clothing and shoes. WORK HYGIENIC PRACTICES: Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Safety shower and eye bath should be provided. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid ODOR: None. APPEARANCE: White crystalline granules pH: Not Available VAPOR PRESSURE: 1 mm Hg @ 806 deg C VAPOR DENSITY: N/A. BOILING POINT: 1390°C FREEZING POINT: N/A MELTING POINT: 755°C FLASHPOINT AND METHOD: Not Flammable SOLUBILITY IN WATER: 94.6 g / 100 ml @ 25 deg C SPECIFIC GRAVITY: 3.203 Page 4 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Heating above decomp temperature of 800 deg C. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen bromide and sodium oxide. INCOMPATIBLE MATERIALS: Strong acids, strong oxidants, heavy metal salts. Reacts explosively with bromine trifluoride. 11. TOXICOLOGICAL INFORMATION ACUTE DERMAL LD50: > 2000 mg/kg (rabbit) ORAL LD50: 4200 mg/kg (rat) EYE EFFECTS: A slight irritant (rabbit) SKIN EFFECTS: Not a skin irritant (rabbit). Not a sensitizer (guinea pig). TERATOGENIC EFFECTS: Sodium bromide has been shown to cause embryo-fetal toxicity and malformations in rats at dose levels which also produce maternal toxicity. The No-Observed Effect Level (NOEL) is 100 mg/kg per day, and the acceptable daily intake (ADI) for sodium bromide from food and drinking water in humans is 1 mg/kg per day. Comparable high doses of sodium chloride (table salt) similarly cause malformation, embryo-fetal toxicity, and maternal toxicity in mice. MUTAGENICITY: Does not induce DNA repair in cultured human epitheliod cells. Not clastogenic in human lymphocytes metaphase analysis. Not mutagenic by the Ames test. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Sodium bromide is an organic salt, which fully dissociates in aquatic environment to bromide and sodium ions. It also undergoes degradation in soil to bromide ion (no further degradation or biodegradation will occur.) AQUATIC TOXICITY (ACUTE) 96-HOUR LC50: > 1000 mg/L (Rainbow Trout) 48-HOUR EC50: > 1000 mg/L (Daphnia Magna) GENERAL COMMENTS: Avian Toxicity: Oral LD50 >2250 mg/kg (Bobwhite Quail) Dietary LC50 >5633 ppm (Mallard Duck) Page 5 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION UNITED STATES TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS Sodium Bromide 007647-15-6 TSCA STATUS: All ingredients in this mixture are in compliance with TSCA. FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This is an EPA-registered product. 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 1 This MSDS replaces the July 14, 2008 MSDS. Any changes in information are as follows: In Section 2 Potential Heath Effects - Eyes In Section 16 HMIS Health NFPA Flammability NFPA Health NFPA Reactivity HMIS RATING NFPA CODES HEALTH: 2 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 0 2 0 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained Page 6 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/14/2008 Spa Choice Bromine Booster 07/14/2008 1 Spa Choice Bromine Booster therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/01/2008 MSDS No: Spa Choice Clear & Sparkle Revision No: New MSDS Spa Choice Clear & Sparkle 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Clear & Sparkle GENERAL USE: Swimming pool clarifier. MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYES: Minor transient irritation. SKIN: Substance does not generally irritate and is only mildly irritating to susceptible people. INGESTION: Poses little or no immediate hazard. INHALATION: Not expected to be toxic by inhalation. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% Proprietary Blend 100 4. FIRST AID MEASURES EYES: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. INGESTION: Not considered toxic. INHALATION: Remove to fresh air. Page 2 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/01/2008 MSDS No: Spa Choice Clear & Sparkle Revision No: New MSDS Spa Choice Clear & Sparkle 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: > 100°C (212°F) CC EXTINGUISHING MEDIA: Carbon dioxide, water, water fog, dry chemical, chemical foam. EXPLOSION HAZARDS: None. FIRE FIGHTING PROCEDURES: Spills produce extremely slippery surfaces. FIRE FIGHTING EQUIPMENT: No special equipment required. 6. ACCIDENTAL RELEASE MEASURES ENVIRONMENTAL PRECAUTIONS WATER SPILL: Do not discharge into drains or waterways. GENERAL PROCEDURES: Do not flush with water. Dam up. Soak up with inert absorbent material. If liquid has been spilled in large quantities, clean up promptly by scoop or vacuum. Keep in suitable and closed containers for disposal. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE HANDLING: Wash hands after handling. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL Chemical Name Proprietary Blend TWA ppm mg/m 3 [1] [1] Footnotes: 1. Although a component of this product is considered an OSHA Hazardous material, this product does not contain any reportable OSHA hazardous materials. ENGINEERING CONTROLS: Natural ventilation is adequate. Use local exhaust if misting occurs. PERSONAL PROTECTIVE EQUIPMENT Page 3 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/01/2008 MSDS No: Spa Choice Clear & Sparkle Revision No: New MSDS Spa Choice Clear & Sparkle EYES AND FACE: Wear safety glasses with side shields. Do not wear contacts. RESPIRATORY: In case of insufficient respiration, wear suitable respiratory equipment. PROTECTIVE CLOTHING: Chemical resistant apron. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Mild. APPEARANCE: Blue liquid. pH: 5.8 to 7.1 VAPOR PRESSURE: N/A VAPOR DENSITY: 1.04 g/cm3 FLASHPOINT AND METHOD: > 100°C (212°F) CC SOLUBILITY IN WATER: Complete. EVAPORATION RATE: Not Available VISCOSITY #1: 1000 to 3000 CPS 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: No decomposition if stored and applied as directed. Burning of the dried material can produce hydrogen chloride gas, nitrogen oxides (NOx), carbon oxides. INCOMPATIBLE MATERIALS: Oxidizing agent may cause exothermic reactions. 11. TOXICOLOGICAL INFORMATION ACUTE ORAL LD50: > 2000 mg/kg (rat) Notes: Not expected to be toxic. CHRONIC: NOEL/Oral (rat) 90 day = 5000 mg/kg. IRRITATION: Testing on rabbits shows minor transient irritation which cleared in days. Skin exposure may cause skin irritation with susceptible persons. Page 4 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/01/2008 MSDS No: Spa Choice Clear & Sparkle Revision No: New MSDS Spa Choice Clear & Sparkle TERATOGENIC EFFECTS: Not teratogenic. Noel=175 mg/kg. MUTAGENICITY: Not mutagenetic. 12. ECOLOGICAL INFORMATION AQUATIC TOXICITY (ACUTE) 96-HOUR LC50: > 10 mg/l (Danio Rerio) 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: Hazard Categories: Health: Immediate (Acute) Health Hazard 313 REPORTABLE INGREDIENTS: No ingredients listed at or above the de minimus level. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: No components of this product are present above the de minimus levels. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All ingredients in this mixture are in compliance with TSCA. 16. OTHER INFORMATION REVISION SUMMARY: New MSDS Page 5 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/01/2008 MSDS No: Spa Choice Clear & Sparkle Revision No: New MSDS Spa Choice Clear & Sparkle HMIS RATING NFPA CODES HEALTH: 1 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 0 1 0 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Defense Revision No: New MSDS Spa Choice Defense 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Defense GENERAL USE: Spa Descaler MANUFACTURER DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: Irritating to eyes and skin. POTENTIAL HEALTH EFFECTS EYES: May cause eye irritation. SKIN: May cause skin irritation. INGESTION: Ingestion is not expected to be a primary route of exposure. INHALATION: May be harmful if inhaled. Do not breathe spray mists of the undiluted product. Effects will depend upon strength and length of time of exposure. SIGNS AND SYMPTOMS OF OVEREXPOSURE CARCINOGENICITY: Not listed by NTP, IARC or OSHA. TARGET ORGAN STATEMENT: May cause damage to the eyes, skin and upper respiratory tract. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Proprietary Blend - No Reportable OSHA Hazardous Materials 4. FIRST AID MEASURES Wt.% 0 Page 2 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Defense Revision No: New MSDS Spa Choice Defense EYES: Hold eyelids open and flush with a copious amounts of water for at least 15 minutes. Seek immediate medical attention, preferably with an ophthalmologist. SKIN: Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and wash thoroughly before reuse. If irritation persists, consult a health care professional. INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with plenty of water or milk. Irrigate the esophagus and dilute the stomach by slowly giving1 to 2 glasses of water or milk. In cases where the individual is semi-comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In cases of intentional ingestion, seek immediate medical assistance. Take individual to nearest medical facility. INHALATION: Immediately move person to fresh air. If individual experiences nausea, headache, dizziness, has difficulty in breathing or is cyanotic, seek immediate medical treatment. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not Available FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Water fog, carbon dioxide, foam, dry chemical. FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide may be formed upon burning. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Initially minimize are affected by spill or leak. Block any potential routes to water systems. Ensure that spilled or leaked product does not come into contact with material listed as incompaible. Clay, soil, or commercially available absorbent may be used to recover any material that cannot readily be recovered as pure product. Flushing residual material to an industrial sewer, may be acceptable if authorized approval is obtained. 7. HANDLING AND STORAGE HANDLING: Do not get on skin or in eyes. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust. PERSONAL PROTECTIVE EQUIPMENT Page 3 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Defense Revision No: New MSDS Spa Choice Defense EYES AND FACE: Safety glasses with side shields or goggles. SKIN: Chemical-resistant gloves. RESPIRATORY: None normally required. PROTECTIVE CLOTHING: Body protective clothing and shoes. WORK HYGIENIC PRACTICES: Provide safety shower and eyewash station in the work area. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Mild. pH: 4.32 VAPOR PRESSURE: Not Available VAPOR DENSITY: 1.21 g/cm3 BOILING POINT: 100°C (212°F) FREEZING POINT: Not Available FLASHPOINT AND METHOD: Not Available SOLUBILITY IN WATER: Soluble in water. SPECIFIC GRAVITY: 1.010 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: None known, but carbon monoxide may be formed upon burning. INCOMPATIBLE MATERIALS: None known. 11. TOXICOLOGICAL INFORMATION ACUTE DERMAL LD50: > 2000 mg/kg (rabbit) ORAL LD50: > 5000 mg/kg (rat) Page 4 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Defense Revision No: New MSDS Spa Choice Defense 12. ECOLOGICAL INFORMATION COMMENTS: None available. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. RCRA/EPA WASTE INFORMATION: This product is not considered a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA). 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Corrosive Liquid, N.O.S. (Acrylamide-Acrylic Acid Copolymer) PRIMARY HAZARD CLASS/DIVISION: 8 UN/NA NUMBER: UN 1760 PACKING GROUP: III OTHER SHIPPING INFORMATION: DOT exception 173.154 - this product qualifies as a Consumer Commodity (ORM-D) when inner packaging does not exceed 1 gallons. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No 313 REPORTABLE INGREDIENTS: No ingredients listed at or above the de minimus level. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: No components of this product are present above the de minimus levels. 16. OTHER INFORMATION REVISION SUMMARY: New MSDS Page 5 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Defense Revision No: New MSDS Spa Choice Defense HMIS RATING NFPA CODES HEALTH: 1 FLAMMABILITY: 1 PHYSICAL HAZARD: 0 1 1 0 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Foam Free Revision No: New MSDS Spa Choice Foam Free 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Foam Free GENERAL USE: Spa and Swimming Pool Defoamer PRODUCT DESCRIPTION: Silicone emulsion MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYES: May cause temporary redness and discomfort. SKIN: No significant irritation expected from short-term exposure. INGESTION: Low ingestion hazard in normal use. INHALATION: May cause mild irritation if exposed to spray or mist. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name No hazardous materials as defined in OSHA Hazard Communication Wt.% 100 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if any adverse effect occurs. SKIN: No first aid needed. INGESTION: Treat according to person's condition and specifics of exposure. INHALATION: No first aid needed. Page 2 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Foam Free Revision No: New MSDS Spa Choice Foam Free 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: > 100°C (212°F) CC FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: On large fires, use dry chemical, foam or water spray. On small fires, use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. EXPLOSION HAZARDS: None known. FIRE FIGHTING PROCEDURES: Use water to cool containers exposed to fire. FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can produce carbon oxides and traces of incompletely burned carbon compounds, silicon dioxide, and formaldehyde. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Determine whether to evacuate or isolate the area according to your local emergency plan. Observe all personal protection equipment recommendations. For large spills, provide diking or other appropriate containment to keep from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. 7. HANDLING AND STORAGE HANDLING: Use with adequate ventilation. Avoid eye contact. STORAGE: Use reasonable care and store away from oxidizing materials. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: General ventilation is adequate. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety glasses as a minimum. SKIN: Wash thoroughly after handling. RESPIRATORY: None normally required. Page 3 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Foam Free Revision No: New MSDS Spa Choice Foam Free PROTECTIVE CLOTHING: No special protection needed. OTHER USE PRECAUTIONS: Avoid eye contact. Use reasonable care. 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Slight. APPEARANCE: White liquid. VAPOR PRESSURE: Not Determined VAPOR DENSITY: Not Determined. FREEZING POINT: N/A FLASHPOINT AND METHOD: > 100°C (212°F) CC EVAPORATION RATE: < 1 SPECIFIC GRAVITY: 1.000 VISCOSITY #1: < 5000 CST 10. STABILITY AND REACTIVITY STABILITY: Stable. POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Oxidizing material can cause a reaction. INCOMPATIBLE MATERIALS: None known. 11. TOXICOLOGICAL INFORMATION COMMENTS: None available. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Not available. CHEMICAL FATE INFORMATION: Not available. Page 4 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Foam Free Revision No: New MSDS Spa Choice Foam Free 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. RCRA/EPA WASTE INFORMATION: This product is not considered a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA). 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: No CHRONIC: No 313 REPORTABLE INGREDIENTS: None. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: Not considered hazardous. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All ingredients are listed or exempt. REGULATIONS STATE REGULATIONS Massachusetts: 7664-93-9 <0.1% Sulfuric Acid New Jersey: 7732-18-5 >60% Water 63148-62-9 15-40% Polydimethylsiloxane 67762-90-7 1-5% Methylated silica 9004-67-5 1-5% Methylcellulose Pennsylvania: 7732-18-5 >60% Water 63148-62-9 15-40% Polydimethylsiloxane CALIFORNIA PROPOSITION 65: There are no chemicals present known to the State of California to cause cancer. Page 5 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 07/17/2008 MSDS No: Spa Choice Foam Free Revision No: New MSDS Spa Choice Foam Free RCRA STATUS: Not regulated. 16. OTHER INFORMATION REVISION SUMMARY: New MSDS NFPA CODES 1 0 0 MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 12/17/2008 MSDS No: Spa Choice pH Decreaser Spa Choice pH Decreaser 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice pH Decreaser GENERAL USE: pH Decreaser MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: Causes eye irritation. May cause skin and respiratory tract irritation. Avoid contact with eyes and skin. Avoid breathing dust. Wash exposed skin thoroughly after handling. POTENTIAL HEALTH EFFECTS EYES: May cause mild to severe irritation. May cause burn if not flushed with water. SKIN: Prolonged exposure may cause moderate irritation. May cause burn if not flushed with water. INGESTION: Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury. INHALATION: May irritate or burn nose, throat and lungs. SIGNS AND SYMPTOMS OF OVEREXPOSURE CARCINOGENICITY: Not listed by NTP, IARC or OSHA. MEDICAL CONDITIONS AGGRAVATED: Pre-existing respiratory conditions. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Vol. % CAS EINECS Sulfuric Acid, Monosodium Salt 0 007681-38-1 231-665-7 Sulfuric Acid Disodium Salt 8 007757-82-6 231-820-9 COMMENTS: Common Name: Sodium Bisulfate 4. FIRST AID MEASURES Page 2 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 12/17/2008 MSDS No: Spa Choice pH Decreaser Spa Choice pH Decreaser EYES: Immediately flush eyes with water for al least 15 minutes, lifting eyelids to thoroughly flush. If redness persists, get prompt medical attention. SKIN: Immediately flush affected area with water for at least 15 minutes. If burn occurs, seek immediate medical attention. INGESTION: If large amounts are swallowed (greater than a tablespoonful), drink large quantities of water or milk. Follow with Milk of Magnesia, beaten eggs or vegetable oil. Do not induce vomiting. Contact a physician immediately. INHALATION: Remove to fresh air. If breathing has not returned to normal within a few minutes after exposure, get medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not combustible. FLAMMABLE LIMITS: 0 to 0 GENERAL HAZARD: Because material will readily dissolve in water to form a weak acid solution, avoid water contact with material, if possible. EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire. FIRE FIGHTING EQUIPMENT: Because product readily dissolves in water for form a weak acid solution, us acid protective equipment. No gases or toxic fumes are emitted from this reaction, however if elevated temperatures are reached (above 806 deg F), self contained breathing apparatus should be used. HAZARDOUS DECOMPOSITION PRODUCTS: At temperatures above 806 deg F, hazardous fumes sulfur oxide and sulfur trioxide are evolved. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Vacuum or shovel material and place in disposal container. Avoid excessive dust generation. Dilute residual material with large amounts of water and direct to sanitary sewer if regulations permit. COMMENTS: WATER SPILL: Readily dissolves in water to form a weak acid solution. If water is isolated or can be contained, neutralize with weak alkaline solution. Notify appropriate authorities if require by regulations. 7. HANDLING AND STORAGE HANDLING: Wear all recommended personal protective clothing when handling. Avoid contact with eyes. Wash thoroughly after handling. Minimize dust generation. Avoid breathing dust. STORAGE: Material is hygroscopic and will readily absorb moisture. Keep containers tightly closed. DO NOT store where exposed to moist conditions. DO NOT store near strong alkalis. Page 3 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 12/17/2008 MSDS No: Spa Choice pH Decreaser Spa Choice pH Decreaser 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV SupplierOEL ppm mg/m 3 ppm mg/m3 ppm mg/m 3 TWA ppm [1] mg/m3 [1] ppm mg/m3 NL ppm NL mg/m3 STEL ppm mg/m3 ppm mg/m3 NL ppm NL mg/m3 Chemical Name Sulfuric Acid, Monosodium Salt Footnotes: 1. This material meets the definition as an Irritant as defined in OSHA's Hazard Communication Standard. ENGINEERING CONTROLS: Local exhaust. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear chemical safety glasses or goggles. SKIN: Rubber gloves and cotton-blend coveralls. RESPIRATORY: In dusty atmospheres (greater than 10 mg/m3) use a NIOSH-approved dust respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Dry crystalline solid. ODOR: Fresh to pungent. APPEARANCE: Off-white granular powder. pH: < 1.0 5% aqueous solution spherical shaped beads. VAPOR PRESSURE: N/A VAPOR DENSITY: N/A. MELTING POINT: 350°C (177°F) FLASHPOINT AND METHOD: Not combustible. SOLUBILITY IN WATER: 1080 g/L DENSITY: 80-85 lbs/ft3 (loose) MOLECULAR WEIGHT: 120 Page 4 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 12/17/2008 MSDS No: Spa Choice pH Decreaser Spa Choice pH Decreaser 10. STABILITY AND REACTIVITY STABILITY: Stable. POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Sulfur dioxide and sulfur trioxide are formed when heated over 806 deg F. INCOMPATIBLE MATERIALS: Avoid contact with strong alkaline material such as caustic. Dissolves readily in water to form a weak acid solution. DO NOT mix with liquid chlorine bleach, ammonia cleansers or similar products. Do not store dry product where exposed to moist conditions. 11. TOXICOLOGICAL INFORMATION ACUTE ORAL LD50: 2800 mg/kg (rat) SKIN EFFECTS: Neither corrosive nor destructive to skin of rabbits. Occasionally a very slight rash may appear. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: This material dissolves in water to form a weak acid solution. A 0.05% or greater (by weight) solution of this product will likely be harmful to aquatic life. CHEMICAL FATE INFORMATION: Material will decompose in soil. Studies show that there are no adverse effects of applying the main ingredient in this product directly to crops. In fact, there are existing products on the market that use sodum bisulfate as a soil additive to improve crop production. However, do not apply excessive quantities to soil. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION Page 5 of 5 MATERIAL SAFETY DATA SHEET Date Issued: 12/17/2008 MSDS No: Spa Choice pH Decreaser Spa Choice pH Decreaser UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 313 REPORTABLE INGREDIENTS: None. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA RQ: No. TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS Sulfuric Acid, Monosodium Salt 007681-38-1 Sulfuric Acid Disodium Salt 007757-82-6 TSCA REGULATORY: All components are listed on the TSCA Inventory. CALIFORNIA PROPOSITION 65: There are no chemicals present known to the State of California to cause cancer. 16. OTHER INFORMATION REVISION SUMMARY: New MSDS HMIS RATING NFPA CODES HEALTH: 2 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 0 2 1 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 5 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice pH Increaser 12/17/2008 1 Spa Choice pH Increaser 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice pH Increaser GENERAL USE: pH Increaser MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: Irritating to the eyes. Continuous contact may irritate skin. POTENTIAL HEALTH EFFECTS EYES: Causes eye irritation. SKIN: Continuous contact causes skin irritation (red, dry, cracked skin). INGESTION: May be harmful if swallowed. INHALATION: Excessive levels of dust may irritate the mucous membranes and upper respiratory tract. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Carbonic Acid, Disodium Salt Wt.% CAS EINECS 100 000497-19-8 207-838-8 4. FIRST AID MEASURES EYES: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate medical attention, preferably with an ophthalmologist. SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. Page 2 of 5 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice pH Increaser 12/17/2008 1 Spa Choice pH Increaser INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with plenty of water. Slowly give 1 to 2 glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. INHALATION: Remove to fresh air. If breathing is difficult, get medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not combustible. FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Water, fog, carbon dioxide, dry chemical. FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Emits fumes of sodium oxide. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Sweep up and recycle into process, if possible. Use appropriate equipment if dust is generated or contact with eyes is expected. Flush residues and liquid to holding area for neutralization before discharge. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and dry place. HANDLING: Do not breathe dust. Avoid contact with skin and eyes. STORAGE: Store in a cool dry place. Keep away from acids. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 3 of 5 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice pH Increaser 12/17/2008 1 Spa Choice pH Increaser EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL Chemical Name Carbonic Acid, Disodium Salt TWA SupplierOEL ppm mg/m3 ppm mg/m 3 [1] [1] NL NL NL NL STEL Footnotes: 1. NL = Not Listed ENGINEERING CONTROLS: Local exhaust. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear splash goggles. SKIN: Impervious gloves. RESPIRATORY: In dusty atmospheres use a NIOSH-approved dust respirator. PROTECTIVE CLOTHING: Chemical resistant apron and arm-protector. If clothing becomes contaminated, remove and launder before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid APPEARANCE: White granular. pH: 11.4 1% solution. VAPOR PRESSURE: N/A VAPOR DENSITY: N/A. BOILING POINT: Decomposes FREEZING POINT: 851°C (1564°F) FLASHPOINT AND METHOD: Not combustible. SOLUBILITY IN WATER: 33.2% maximum SPECIFIC GRAVITY: 2.509 10. STABILITY AND REACTIVITY Page 4 of 5 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice pH Increaser 12/17/2008 1 Spa Choice pH Increaser STABILITY: Stable. POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Contact with acids except under controlled conditions. INCOMPATIBLE MATERIALS: Aluminum powder, acids, fluorine, molten lithium. 11. TOXICOLOGICAL INFORMATION EYE EFFECTS: Severely irritating (rabbit). SKIN EFFECTS: Non-irritant to intact skin. Minor irritant may occur to abraded skin. CHRONIC: May cause severe irritations of the eyes including the corneal opacities. CARCINOGENICITY Notes: None of the components in this product are listed by IARC, NTP, OSHA or ACGIH as carcinogen. SENSITIZATION: Non-sensitizer. TARGET ORGANS: Eyes. 12. ECOLOGICAL INFORMATION AQUATIC TOXICITY (ACUTE) 96-HOUR LC50: > 300 mg/L (Bluegill Sunfish) 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION Page 5 of 5 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice pH Increaser 12/17/2008 1 Spa Choice pH Increaser UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR370): 10000 lbs. 313 REPORTABLE INGREDIENTS: None. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: Not listed. TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS Carbonic Acid, Disodium Salt 000497-19-8 TSCA STATUS: All ingredients in this mixture are in compliance with TSCA. 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 1. This MSDS replaces the July 01, 2008 MSDS. Any changes in information are as follows: In Section 1: MSDS Number HMIS RATING NFPA CODES HEALTH: 2 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 0 2 0 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Re-Energize GENERAL USE: Oxidizer PRODUCT DESCRIPTION: Potassium Monopersulfate Compound (Peroxygen Salt) MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: White granular product IMMEDIATE CONCERNS: This product is a skin and eye corrosive, and a nose and throat irritant. May cause allergic skin reactions in sensitive individuals. Ingestion may cause inflammation and damage to the lining of the stomach, resulting in bleeding. POTENTIAL HEALTH EFFECTS EYES: May cause eye corrosion or ulceration. Severe eye damage may result if not immediately treated. SKIN: Corrosive to skin. Skin contact with aqueous solutions or the dry powder upon contact with moisture or perspiration may cause skin burns or ulceration. Temporary body hair loss may occur in contacted areas. Skin contact with the product may cause allergic skin reactions in sensitive individuals. INGESTION: May cause gastritis, possibly progressing to necrosis or hemorrhage. INHALATION: May cause nose bleeds and irritation of the upper respiratory passages with coughing and discomfort. SIGNS AND SYMPTOMS OF OVEREXPOSURE CARCINOGENICITY: None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. MEDICAL CONDITIONS AGGRAVATED: Individuals with pre-existing conditions of the skin or gastrointestingal tract may have increased susceptibility to the toxicity of excessive exposures. 3. COMPOSITION / INFORMATION ON INGREDIENTS Page 2 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize Chemical Name Wt.% CAS EINECS Magnesium Carbonate 2 000546-93-0 208-915-9 Potassium Bisulfate 23 007646-93-7 231-594-1 Potassium Peroxydisulfate 3 007727-21-1 231-781-8 Potassium Peroxymonosulfate 43 010058-23-8 233-187-7 Potassium Sulfate 29 007778-80-5 231-915-5 4. FIRST AID MEASURES EYES: Hold eyelids apart and immediately flush with plenty of water for at least 15 minutes. Call a physician immediately. SKIN: Immediately flush skin with plenty of water for at least 15 minutes, while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before reuse. INGESTION: DO NOT INDUCE VOMITING. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Will not burn. FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Water. Do not use carbon dioxide or other gas-filled fire extinguishers. They will have no effect on decomosing persulfates. EXPLOSION HAZARDS: Improper storage of large masses of this product can trap heat and lead to ignition of combustibles. Grinding or intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of oxidizing material, if present, may occur. FIRE FIGHTING PROCEDURES: Will release oxygen when heated, intensifying a fire. Acidic mist may be present. Self contained breathing apparatus should be used. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Sweep up thoroughly. Flush area with low pressure water. Page 3 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize 7. HANDLING AND STORAGE HANDLING: Do not inhale. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Wash clothing after use. STORAGE: Store in a cool, dry, well-ventilated area away from heat sources. LOADING TEMPERATURE: Replace the lid on plastic pails when they are not in use to prevent contamination and extend shelf life. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL Chemical Name ppm Magnesium Carbonate TWA Potassium Peroxydisulfate TWA ACGIH TLV mg/m3 ppm mg/m 3 15T, 5 NIC (10) 0.1 ENGINEERING CONTROLS: Local exhaust. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear safety glasses with side shields. SKIN: Where there is potential for skin contact, wear impervious gloves, apron, pants and jacket. RESPIRATORY: A NIOSH-approved air purifying respirator with an appropriate particulate cartridge or canister may be permissable under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air-supplied respirator if there is any potential of an uncontrolled release, if exposure levels are not know, or any other circumstances where air purifying respirators may not provide adequate protection. COMMENTS: NOTE: EXPOSURE LIMIT OF MONPERSULFATE COMPOUND PEL = Particulates (Not Otherwise Regulated) 15 mg/m3, 8 Hr. TWA, total dust TLV = None established. AEL (Manufacturer's recommended exposure limit) Oxone Monopersulfate Compound - 1 mg/m3; Total Dust, 8 & 12 hr TWA. Potassium Sulfate - 10 mg/m3, 8 hr. TWA. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 4 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize PHYSICAL STATE: Solid ODOR: Mild chlorine. APPEARANCE: White granular. pH: 2.3 (1% solution) VAPOR PRESSURE: None VAPOR DENSITY: Not volatile. BOILING POINT: @ 760 mm Hg - decomposes MELTING POINT: Decomposes FLASHPOINT AND METHOD: Will not burn. EVAPORATION RATE: Not volatile. SPECIFIC GRAVITY: 1.000 to 1.400 (VOC): 100.000 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION: No STABILITY: Stable when handled and stored as indicated. CONDITIONS TO AVOID: May be unstable at temperatures above 170 deg C (338 deg F). Avoid storage at temperatures above 52 deg C (125 deg F). Prevent ingress of humidity and moisture into container or package. Always close the lid. POSSIBILITY OF HAZARDOUS REACTIONS: Decomposes when heated or dampened, releasing oxygen and heat of decomposition. INCOMPATIBLE MATERIALS: The mixture of this product with compounds containing halides or active halogens (bromine, chlorine, iodine) can cause the release of the respective halogen gas, if moisture is present. Avoid these gases (bromine and chlorine) because they are very irritating to eyes and lungs even at low concentrations. Never mix this product with dry or concentrate bromine-containing chemicals such as bromates, bromides, or any concentrated bromine pool chemicals. Mixing this product with dry chlorine chemicals such as hypochlorites, sodium dichloroisocyanurate (dichlor), sodium trichloroisocyanurate (trichlor) or with sodium chloride (salt), may cause the release of chlorine gas. Mixing with cyanides can cause release of hydrogen cyanide gas. Mixing with heavy metal salts such as those of cobalt, nicket, copper, or manganese can cause decomposition with release of oxygen and heat. 11. TOXICOLOGICAL INFORMATION Page 5 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize ACUTE SKIN ABSORPTION: > 11000 mg/kg (rabbits) ORAL LD50: 200-2000 mg/kg (rat) INHALATION LC50: > 5 mg/L (4 hour) Notes: In rats. EYE EFFECTS: This product is a severe eye irritant in animals. SKIN EFFECTS: This product is a severe skin irritant in animals, but not a skin sensitizer. 12. ECOLOGICAL INFORMATION AQUATIC TOXICITY (ACUTE) 96-HOUR LC50: 53 mg/L (Rainbow Trout) 48-HOUR EC50: 3.5 mg/L (Daphnia Magna) 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Corrosive Solid, Acidic, Inorganic, N.O.S. (monopersulfate compound) PRIMARY HAZARD CLASS/DIVISION: 8 UN/NA NUMBER: UN 3260 PACKING GROUP: II OTHER SHIPPING INFORMATION: DOT exception 173.154 - this product qualifies as a Consumer Commodity (ORM-D) when inner packaging does not exceed 2.2 lbs and outer packaging does not exceed 66 lbs. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: Not listed. Page 6 of 6 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/01/2008 Spa Choice Re-Energize 10/14/2008 2 Spa Choice Re-Energize FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: Not listed. TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS Magnesium Carbonate 000546-93-0 Potassium Bisulfate 007646-93-7 Potassium Peroxydisulfate 007727-21-1 Potassium Peroxymonosulfate 010058-23-8 Potassium Sulfate 007778-80-5 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 2. This MSDS replaces the June 13, 2008 MSDS. NFPA CODES HMIS RATING HEALTH: 3 FLAMMABILITY: 0 PHYSICAL HAZARD: 1 0 3 1 PERSONAL PROTECTION: MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s). Page 1 of 4 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/28/2008 Spa Choice Spa Fragrances 10/29/2008 1 Spa Choice Spa Fragrances 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spa Choice Spa Fragrances GENERAL USE: Spa Fragrance PRODUCT DESCRIPTION: Spa Fragrance MANUFACTURER Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 DISTRIBUTOR Suncoast Chemicals Company 14480 62nd Street North Clearwater FL 33760 Product Stewardship: (727) 531-8913 24 HR. EMERGENCY TELEPHONE NUMBERS Chem-Tel 24-Hour Emergency # (800) 255-3924 2. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYES: None reported. SKIN: None reported. INGESTION: None reported. INHALATION: None reported. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS EINECS Water 007732-18-5 231-791-2 1,2,3- Propanetriol 000056-81-5 200-289-5 1,2-propanediol 000057-55-6 200-338-0 Fragrance Siloxanes And Silicones, Di-me May contain FD&C Red 40; FD&C Red 33; FD&C Blue 1; FD&C Yellow 5; and/or FD&C Yellow 6. 063148-62-9 xxx-xxx-x Page 2 of 4 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: Spa Choice Spa Fragrances 4. FIRST AID MEASURES EYES: Immediately irrigate the eye for five minutes. SKIN: Not applicable. INGESTION: Not applicable. INHALATION: Not applicable. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: No data. FLAMMABLE LIMITS: 0 to 0 EXTINGUISHING MEDIA: Flood with water or use carbon dioxide, foam, or dry chemical. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Clean up with soap and water. 7. HANDLING AND STORAGE HANDLING: Exercise reasonable care and caution. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: No special ventilation requirements. 9. PHYSICAL AND CHEMICAL PROPERTIES VAPOR DENSITY: N/A. BOILING POINT: N/A FLASHPOINT AND METHOD: No data. SOLUBILITY IN WATER: Complete. 07/28/2008 Spa Choice Spa Fragrances 10/29/2008 1 Page 3 of 4 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/28/2008 Spa Choice Spa Fragrances 10/29/2008 1 Spa Choice Spa Fragrances EVAPORATION RATE: N/A. SPECIFIC GRAVITY: 1.035 to 1.038 at 25°C 10. STABILITY AND REACTIVITY STABILITY: Stable. 11. TOXICOLOGICAL INFORMATION COMMENTS: None available. 12. ECOLOGICAL INFORMATION COMMENTS: None available. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated. 15. REGULATORY INFORMATION COMMENTS None 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 1. This MSDS replaces the July 29, 2008 MSDS. Page 4 of 4 MATERIAL SAFETY DATA SHEET Date Issued: MSDS No: Date Revised: Revision No: 07/28/2008 Spa Choice Spa Fragrances 10/29/2008 1 Spa Choice Spa Fragrances MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a detemination as to the suitability of the information for their particular purpose(s).
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