MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 CHEMTREC: (800) 424-9300 REVISION DATE: December 14, 2009 DATE OF ISSUE: December 15, 2009 I - Product Identification Ultra Orange Squirt Concentrate PRODUCT CODE: 0435 CHEMICAL FORMULATION: Citrus based concentrated cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 1 HAZARD RATING: 4 - Extreme; 3 - High; FLAMMABILITY: 2 2 - Moderate; 1 - Slight; REACTIVITY: 0 0 - Insignificant II - Hazardous Ingredients SUBSTANCE Values reported as TWA unless noted. APPROX EPA 40 CFR: OSHA ACGIH % PEL TLV 302 355 372 CAS # d-Limonene 5.00-15.0 N/E N/E N N N 5989-27-5 Triethanolamine < 3.00 N/E 5 mg/m3 N N N 102-71-6 Ethoxylated Alkyl Amine < 3.00 N/E N/E N N N 68478-95-5 Diethanolamine < 2.00 N/E 2.0 mg/m3 Y N Y 111-42-2 Sodium Metasilicate < 2.00 N/E N/E N N N 6834-92-0 Poly(oxyethylene) nonylphenol < 2.00 N/E N/E N N N 9016-45-9 Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data SPECIFIC GRAVITY (WATER = 1): 0.99 BOILING POINT (°F): N/D VAPOR PRESSURE (mm Hg): N/D VOC CONTENT (% by weight): 5.00 – 15.0 VAPOR DENSITY (AIR = 1): N/D EVAPORATION RATE (WATER = 1): N/D SOLUBILITY IN WATER: Soluble pH: 10.0-11.0 APPEARANCE AND ODOR: Clear, dark orange liquid; citrus odor. IV - Fire and Explosion Hazard Data FLASH POINT (°F): 133 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/D LOWER: N/D EXTINGUISHING MEDIA: Water spray, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Use water spray to cool fire-exposed containers. PRODUCT NAME: Ultra Orange Squirt Concentrate PRODUCT CODE: 0435 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers and acids. CONDITIONS TO AVOID: Heat, sparks and open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield oxides of carbon. HAZARDOUS POLYMERIZATION: Will not occur. VI - Health Hazard Data ROUTES OF ENTRY INHALATION: EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate to severe irritation, redness, tearing. IF ON SKIN: Irritation, chapping and possible dermatitis with repeated or prolonged contact. Contains a possible sensitizer. IF SWALLOWED: Gastrointestinal irritation, nausea, vomiting, diarrhea. IF INHALED: Irritation of respiratory tract. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Flush area with cool water while removing contaminated clothing. Launder clothing separately before re-use. If irritation persists, obtain medical attention. IF SWALLOWED: Call a physician or poison control center immediately. Give one to two glasses of water. Do not induce vomiting unless instructed by a physician or poison control center. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If breathing has stopped, administer artificial respiration. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and extinguish all sources of ignition. Soak up with inert absorbent and place in a properly labeled closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Chemical goggles or safety glasses. OTHER PROTECTIVE EQUIPMENT: Eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place, away from heat or open flame. Keep container tightly closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. Do not cut or weld on empty containers as they may contain combustible residue. IX - Transportation Information (ground transportation only) DOT ID NUMBER: None DOT CLASS: None DOT PROPER SHIPPING NAME: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: December 14, 2009 Prepared by: Technical Dept. DATE OF ISSUE: December 15, 2009 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material.
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