Manual 12652443

Manual 12652443
Spies Hecker Material Safety Data Sheet
1. Identification of the substance/mixture and of the company/undertaking
Product name
R Supercryl Reducer 3054 Medium
Permacron
Product code
3054
Intended use
Thinner for professionnal use
Formula Date: 2013-05-13
Spies-Hecker
50 Applied Card Way, Suite 300
US Glen Mills, PA 19342
Telephone
Product information
Medical emergency
Transportation emergency
(888) 371-3313
(855) 274-5698
(800) 424-9300
2. Hazards identification
This preparation is hazardous per the following GHS criteria
GHS-Classification
Flammable liquids
Serious eye damage/eye irritation
Toxicity for reproduction
Target Organ Systemic Toxicant - Single exposure
Target Organ Systemic Toxicant - Repeated exposure
Category 3
Category 1
Category 2
Category 3
Category 2
Endpoints which are “not classified”, “cannot classified” and “not applicable” are not shown.
GHS-Labelling
Hazard symbols
Signal word
Danger
Hazard statements
Suspected of damaging fertility or the unborn child.
Flammable liquid and vapour.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Causes serious eye damage.
Precautionary statements
Obtain special instructions before use.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear protective gloves/ eye protection/ face protection.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Use only outdoors or in a well-ventilated area.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wear eye protection/ face protection.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor/ physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
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Spies Hecker Material Safety Data Sheet
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Dispose of contents/container in accordance with local regulations.
Other hazards which do not result in classification
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
0%
3. Composition/information on ingredients
mixture of solvents
Components
CAS-No.
123-86-4
Chemical Name
Butyl acetate
Concentration
48 - 59%
64742-48-9
Hydrotreated heavy naphtha (petroleum)
26 - 37%
1330-20-7
Xylene
8%
7397-62-8
Esters high boiling point
4 - 15%
100-41-4
Ethylbenzene
2.0%
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Non-regulated ingredients 5 - 10%
OSHA Hazardous: Yes
4. First aid measures
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical
advice.
Skin contact
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use
recognized skin cleanser. If skin irritation persists, call a physician.
Inhalation
Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped,
administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a
physician.
Ingestion
If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. Keep at rest.
Most Important Symptoms/effects, acute and delayed
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
2 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
Inhalation
May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps:
headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage. If this product mixed with an isocyanate
activator/hardener (see MSDS for the activator), the following health effects may apply: Exposure to isocyanates may cause
respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath,
wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated
overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing
problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis.
If this product is mixed with an isocyanate, skin contact may cause sensitization.
Indication of Immediate medical attention and special treatment needed if necessary
No data available on the product. See section 3 and 11 for hazardous ingredients found in the product.
5. Firefighting measures
Suitable extinguishing media
Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical
Extinguishing media which shall not be used for safety reasons
High volume water jet
Hazardous combustion products
CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section.
Fire and Explosion Hazards
Flammable liquid. Vapor/air mixture will burn when an ignition source is present.
Special Protective Equipment and Fire Fighting Procedures
Full protective flameproof clothing should be worn as appropriate. Wear self contained breathing apparatus for fire fighting if
necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or
public waterways.
6. Accidental release measures
Procedures for cleaning up spills or leaks
Ventilate area. Remove sources of ignition. Prevent skin and eye contact and breathing of vapor. If the material contains, or is mixed
with an isocyanate activator/hardener: Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection,
gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical
decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and 80% Water OR 0 -10%
Ammonia, 2-5% Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for 48 hours to allow C02
to vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not mixed with an
isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH approved
TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers,
lakes or waste water systems.
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
3 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
7. Handling and storage
Precautions for safe handling
Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY
CAUSE FLASH FIRE. Close container after each use. Ground containers when pouring. Do not transfer contents to bottles or
unlabeled containers. Wash thoroughly after handling and before eating or smoking. Do not store above 49 ◦ C (120 ◦ F).
If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations produce fine
material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds.
Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods
(e.g. compressed air) which can generate potentially combustible dust clouds should not be used.
Advice on protection against fire and explosion
Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an
ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container:
container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good
housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other
fire hazards.
Storage
Requirements for storage areas and containers
Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking.
Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Advice on common storage
Store separately from oxidizing agents and strongly alkaline and strongly acidic materials.
OSHA/NFPA Storage Classification: IC
8. Exposure controls/personal protection
Engineering controls and work practices
Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasible- by the use of a local
exhaust ventilation. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable
respiratory protection must be worn.
National occupational exposure limits
CAS-No.
123-86-4
1330-20-7
100-41-4
Chemical Name
Butyl acetate
Xylene
Ethylbenzene
Time
Type
Value
15 min
STEL
200 ppm
8 hr
TWA
150 ppm
OSHA
8 hr
TWA
150 ppm
ACGIH
15 min
STEL
150 ppm
8 hr
TWA
100 ppm
OSHA
8 hr
TWA
100 ppm
Dupont
8 & 12
hour
TWA
100 ppm
ACGIH
8 hr
TWA
20 ppm
OSHA
8 hr
TWA
100 ppm
Dupont
8 & 12
hour
TWA
25 ppm
Source
ACGIH
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
Note
4 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
** STEL = Short term exposure limit.
TWA = Time-weighted average.
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
Do not breathe vapors or mists. When this product is used with an isocyanate activator/hardener, wear a positive-pressure,
supplied-air respirator (NIOSH approved TC-19C) while mixing activator/hardener with paint, during application and until all vapors
and spray mist are exhausted. If product is used without isocyanate activator/hardener, a properly fitted air-purifying respirator with
organic vapor cartridges (NIOSH TC-23C) and particulate filter (NIOSH TC-84A) may be used. Follow respirator manufacturer’s
directions for respirator use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label
instructions and MSDS for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates
should not use or be exposed to this product if mixed with isocyanate activators/hardeners.
Eye protection
Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash
guard or side shields.
Skin and body protection
Neoprene gloves and coveralls are recommended.
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
Environmental exposure controls
Do not let product enter drains. For ecological information, refer to Ecological Information Section 12.
9. Physical and chemical properties
Appearance
Form: liquid
Colour: clear
Flash point
Lower Explosive Limit
Upper Explosive Limit
Evapouration rate
Vapor pressure of principal solvent
Water solubility
Vapor density of principal solvent (Air = 1)
Approx. Boiling Range
Approx. Freezing Range
Gallon Weight (lbs/gal)
Specific Gravity
Percent Volatile By Volume
Percent Volatile By Weight
Percent Solids By Volume
Percent Solids By Weight
pH (waterborne systems only)
Partition coefficient: n-octanol/water
Ignition temperature
Decomposition temperature
Viscosity (23 ◦ C)
VOC* less exempt (lbs/gal)
VOC* as packaged (lbs/gal)
75 ◦ F
0.6 %
7.5 %
Slower than Ether
10.6 hPa
moderate
4
125 ◦ C
Not applicable.
7.09
0.85
100.00%
100.00%
0.00%
0.00%
not applicable
no data available
245 ◦ C
Not applicable.
Not applicable.
7.1
7.1
DIN 51794
ISO 2431-1993
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
5 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of
manufacture.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage conditions.
Materials to avoid
None reasonably foreseeable.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke,
oxides of nitrogen.
Hazardous Polymerization
Will not occur.
Sensitivity to Static Discharge
Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product.
Sensitivity to Mechanical Impact
None known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps:
headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage. If this product mixed with an isocyanate
activator/hardener (see MSDS for the activator), the following health effects may apply: Exposure to isocyanates may cause
respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath,
wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated
overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing
problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
not hazardous
Acute dermal toxicity
not hazardous
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
6 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
Acute inhalation toxicity
not hazardous
% of unknown composition 0 %
Skin corrosion/irritation
Not classified according to GHS criteria
Serious eye damage/eye irritation
Xylene
Esters high boiling point
Category 2A
Category 1
Respiratory sensitisation
Not classified according to GHS criteria
Skin sensitisation
Not classified according to GHS criteria
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Not classified according to GHS criteria
Toxicity for reproduction
Esters high boiling point
Category 2
Target Organ Systemic Toxicant - Single exposure
• Inhalation
Respiratory system Esters high boiling point
Target Organ Systemic Toxicant - Repeated exposure
No data available.
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. )
No information available.
Symptoms related to the physical, chemical and toxicological characteristics
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse
health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous
system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of
consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with
the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the
skin. The liquid splashed in the eyes may cause irritation and reversible damage.
Whether the hazardous chemical is listed by NTP, IARC or OSHA
Ethylbenzene
IARC 2B
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
7 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
13. Disposal considerations
Waste Disposal Method
Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with
Federal, State, Provincial, and local requirements. Do not incinerate in closed containers.
14. Transport information
International transport regulations
IMDG (Sea transport)
UN number:
Proper shipping name:
1263
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
Marine Pollutant:
3
Not applicable.
III
no
ICAO/IATA (Air transport)
UN number:
1263
Proper shipping name:
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
3
Not applicable.
III
DOT
UN number:
Proper shipping name:
1263
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
Marine Pollutant:
EmS:
3
Not applicable.
III
no
F-E,S-E
Matters needing attention for transportation
Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by
loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with
the relevant statutes and rules.
15. Regulatory information
TSCA Status
In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status
All components of the mixture are listed on the DSL.
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
8 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
Photochemical Reactivity
Non-photochemically reactive
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
WARNING: This product contains a chemical known to the State of California to cause cancer.
Regulatory information
CAS #
123-86-4
64742-48-9
1330-20-7
7397-62-8
100-41-4
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
N
NR
NR
A,C,F
N
N
NR
NR
C
N
Ingredient
Butyl acetate
Hydrotreated heavy naphtha (petroleum)
Xylene
Esters high boiling point
Ethylbenzene
N
N
N
NR
NR
NR
NR
NR
NR
A,C,F
NA
A,C,F
CERCLA
RQ(lbs)
NR
NR
Y
N
Y
100
NR
1,000
CAA
HAP
N
N
Y
N
Y
Key:
EPCRA
Emergency Planning and Community Right-to-know Act (aka Title III, SARA)
302
Extremely hazardous substances
311/312 Categories
F = Fire Hazard
R = Reactivity Hazard
P = Pressure Related Hazard
313 Information
Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA
HAP
TPQ
RQ
NA
NR
Comprehensive Emergency Response, Compensation and Liability Act of 1980.
Listed as a Clean Air Act Hazardous Air Pollutant.
Threshold Planning Quantity.
Reportable Quantity
not available
not regulated
A = Acute Hazard
C = Chronic Hazard
16. Other information
HMIS rating
H: 2 F: 3 R: 0
Glossary of Terms:
ACGIH
IARC
NTP
OEL
OSHA
STEL
TWA
PNOR
PNOC
American Conference of Governmental Industrial Hygienists.
International Agency for Research on Cancer.
National Toxicology Program.
Occupational Exposure Limit
Occupational Safety and Health Administration.
Short term exposure limit.
Time-weighted average.
Particles not otherwise regulated.
Particles not otherwise classified.
NOTE: The list (above) of glossary terms may be modified.
Notice from
The document reflects information provided to Spies Hecker by its suppliers. Information is accurate to the best of our knowledge and
is subject to change as new data is received by Spies Hecker. Persons receiving this information should make their own
determination as to its suitability for their purposes prior to use. The information on this Safety Data Sheet relates only to the specific
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
9 - 10
2016-01-27
Spies Hecker Material Safety Data Sheet
material designated herein and does not relate to use in combination with any other material or in any process.
SDS prepared by:
Spies Hecker Regulatory Affairs Consultant
(888) 371-3313
spieshecker.us
axalta.us
T-37525
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
10 - 10
2016-01-27
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