SAFETY DATA SHEET Section 1. Chemical product and company identification

SAFETY DATA SHEET Section 1. Chemical product and company identification
SAFETY DATA SHEET
QC 91 HD ACID BATHROOM CLEANER
Section 1. Chemical product and company identification
Product name
Recommended use and
restrictions
: QC 91 HD ACID BATHROOM CLEANER
: Cleaning product
Use only for the purpose on the product label.
Product dilution information : Up to 16 oz/gal or 125 mL/L in water
Supplier's information
Code
Date of issue
: Ecolab Inc. Institutional Division
370 N. Wabasha Street
St. Paul, MN 55102
1-800-352-5326
: 903544-04
: 15 Oct 2013
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Hazards identification
GHS Classification
Product AS SOLD
: SKIN CORROSION/IRRITATION - Category 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 1
Product AT USE DILUTION
SKIN CORROSION/IRRITATION - Category
1
SERIOUS EYE DAMAGE/ EYE IRRITATION
- Category 1
: Danger
:
Danger
GHS label elements
Signal word
Symbol
Hazard statements
: Causes severe skin burns and eye damage.
Precautionary statements
Prevention
Response
: Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Do not mix
with bleach or other chlorinated products - will
cause chlorine gas. Wash hands thoroughly
after handling.
: IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for
breathing. Immediately call a POISON
CENTER or physician. IF SWALLOWED:
Immediately call a POISON CENTER or
physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse
skin with water or shower. Wash contaminated
clothing before reuse. Immediately call a
POISON CENTER or physician. IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to
Causes severe skin burns and eye damage.
Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Wash
hands thoroughly after handling.
IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for
breathing. Immediately call a POISON
CENTER or physician. IF SWALLOWED:
Immediately call a POISON CENTER or
physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse
skin with water or shower. Wash
contaminated clothing before reuse.
Immediately call a POISON CENTER or
physician. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 2. Hazards identification
do. Continue rinsing. Immediately call a
POISON CENTER or physician.
Storage
Disposal
: No other specific measures identified.
: See section 13 for waste disposal information.
Other hazards
: None known.
lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER
or physician.
No other specific measures identified.
See section 13 for waste disposal
information.
None known.
Section 3. Composition/information on ingredients
Substance/mixture
Product AS SOLD
: Mixture
Hazardous ingredients
Concentration Range (%)
CAS number
BUTOXYDIGLYCOL
19
112-34-5
CITRIC ACID
alcohols, c9-11, ethoxylated
methanesulphonic acid
COCAMINE OXIDE
5 - 20
5 - 20
5 - 20
1-5
77-92-9
68439-46-3
75-75-2
61788-90-7
Product AT USE DILUTION
Hazardous ingredients
Concentration Range (%)
CAS number
BUTOXYDIGLYCOL
2
112-34-5
CITRIC ACID
alcohols, c9-11, ethoxylated
1-5
1-5
77-92-9
68439-46-3
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Product AS SOLD
: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention
immediately.
: Take off immediately all contaminated clothing.
Rinse skin with water or shower. Get medical
attention immediately. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical
attention immediately.
: Get medical attention immediately. Rinse mouth.
Do not induce vomiting.
Product AT USE DILUTION
Rinse cautiously with water for several
minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get
medical attention immediately.
Take off immediately all contaminated
clothing. Rinse skin with water or shower.
Get medical attention immediately. Wash
clothing before reuse. Clean shoes
thoroughly before reuse.
Remove victim to fresh air and keep at rest
in a position comfortable for breathing. Get
medical attention immediately.
Get medical attention immediately. Rinse
mouth. Do not induce vomiting.
Protection of firstaiders
: No action shall be taken involving any personal risk or without suitable training. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have
been ingested or inhaled.
See toxicological information (section 11)
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 5. Fire-fighting measures
Product AS SOLD
Suitable fire extinguishing
media
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Specific fire-fighting
methods
Special protective
equipment for fire-fighters
: Use water spray, fog or foam.
: In a fire or if heated, a pressure increase will occur and the container may burst.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
sulfur oxides
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal
precautions
Environmental
precautions
Methods for
cleaning up
Product AS SOLD
: Initiate company's spill response procedures
immediately. Keep people out of area. Put on
appropriate personal protective equipment (see
section 8). Do not touch or walk through spilled
material.
: Avoid contact of spilled material and runoff with
soil and surface waterways.
: Follow company's spill procedures. Keep people
away from spill. Put on appropriate personal
protective equipment (see section 8). Absorb/
neutralize liquid material. Use a tool to scoop up
solid or absorbed material and put into
appropriate labeled container. Use a tool to
scoop up solid or absorbed material and place
into appropriate labeled waste container. Use a
water rinse for final clean-up.
Product AT USE DILUTION
Initiate company's spill response procedures
immediately. Keep people out of area. Put on
appropriate personal protective equipment
(see section 8). Do not touch or walk
through spilled material.
Avoid contact of spilled material and runoff
with soil and surface waterways.
Follow company's spill procedures. Keep
people away from spill. Put on appropriate
personal protective equipment (see section
8). Absorb/neutralize liquid material. Use a
tool to scoop up solid or absorbed material
and put into appropriate labeled container.
Use a tool to scoop up solid or absorbed
material and place into appropriate labeled
waste container. Use a water rinse for final
clean-up.
Section 7. Handling and storage
Handling
Storage
Product AS SOLD
: Do not get in eyes or on skin or clothing. Do not
breathe vapor or mist. Use only with adequate
ventilation. Do not mix with bleach or other
chlorinated products - will cause chlorine gas.
Wash thoroughly after handling.
: Keep out of reach of children. Keep container
tightly closed.
Product AT USE DILUTION
Do not get in eyes or on skin or clothing. Do
not breathe vapor or mist. Use only with
adequate ventilation. Wash thoroughly after
handling.
Keep out of reach of children. Keep
container tightly closed.
Store between the following temperatures: 10
and 50°C
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 8. Exposure controls/personal protection
Control parameters
Ingredient name
Exposure limits
BUTOXYDIGLYCOL
ACGIH TLV (United States, 3/2012).
TWA: 10 ppm 8 hours. Form: Inhalable
fraction and vapor
Product AS SOLD
Appropriate
: Use only with adequate ventilation. If user
operations generate dust, fumes, gas, vapor or
engineering controls
mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep
worker exposure to airborne contaminants below
any recommended or statutory limits. Provide
suitable facilities for quick drenching or flushing
of the eyes and body in case of contact or splash
hazard.
Personal protection
Eye protection
: Use chemical splash goggles. For continued or
severe exposure wear a face shield over the
goggles.
Hand protection
: Use chemical-resistant, impervious gloves.
Skin protection
: Use synthetic apron, other protective equipment
as necessary to prevent skin contact.
Product AT USE DILUTION
Use only with adequate ventilation. If user
operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local
exhaust ventilation or other engineering
controls to keep worker exposure to airborne
contaminants below any recommended or
statutory limits. Provide suitable facilities for
quick drenching or flushing of the eyes and
body in case of contact or splash hazard.
Use chemical splash goggles. For continued
or severe exposure wear a face shield over
the goggles.
Use chemical-resistant, impervious gloves.
Use synthetic apron, other protective
equipment as necessary to prevent skin
contact.
A respirator is not needed under normal and
intended conditions of product use.
Respiratory
protection
: A respirator is not needed under normal and
intended conditions of product use.
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing.
Section 9. Physical and chemical properties
Physical state
Product AS SOLD
: Liquid.
Product AT USE DILUTION
Liquid.
Color
: Green [Dark]
Green [Light]
Odor
pH
Flash point
: Fragrance-like
: 1.7 to 2.4 (100%)
: >93.3 °C (Closed cup)
Fragrance-like
0.38 to 1.38
> 100°C
Explosion limits
Flammability (solid,
gas)
Melting point
Boiling point
Evaporation rate
(butyl acetate = 1)
Vapor pressure
: Not available.
: Not available.
Vapor density
: Not available.
: 1.07 to 1.13 (Water = 1)
Relative density
Solubility
: Not available.
: Not available.
: Not available.
: Not available.
: Easily soluble in the following materials: cold
water and hot water.
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 9. Physical and chemical properties
Partition coefficient: : Not available.
n-octanol/water
Auto-ignition
temperature
Decomposition
temperature
Odor threshold
Viscosity
: Not available.
: Not available.
: Not available.
: Not available.
Section 10. Stability and reactivity
Product AS SOLD
Stability
Possibility of hazardous
reactions
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
: No specific data.
: Reactive or incompatible with the following materials: alkalis.
Incompatible with chlorinated solvents.
Do not mix with bleach or other chlorinated products - will cause chlorine gas.
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological information
Route of exposure
: Skin contact, Eye contact, Inhalation, Ingestion
Product AS SOLD
Symptoms
Eye contact
Skin contact
Inhalation
Ingestion
Acute toxicity
Eye contact
Skin contact
Inhalation
Ingestion
Product AT USE DILUTION
: Adverse symptoms may include the following:
pain
watering
redness
: Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: Adverse symptoms may include the following:
coughing
Respiratory tract irritation
: Adverse symptoms may include the following:
stomach pains
Adverse symptoms may include the following:
pain
watering
redness
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Adverse symptoms may include the following:
coughing
Respiratory tract irritation
Adverse symptoms may include the following:
stomach pains
:
:
:
:
Causes serious eye damage.
Causes severe burns.
May cause respiratory irritation.
May cause burns to mouth, throat and
stomach.
Causes serious eye damage.
Causes severe burns.
May cause respiratory irritation.
May cause burns to mouth, throat and stomach.
Toxicity data
Product/ingredient name
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 11. Toxicological information
2-(2-butoxyethoxy)ethanol
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
citric acid
alcohols, c9-11, ethoxylated
methanesulphonic acid
amines, coco alkyldimethyl, n-oxides
Rabbit
Rat
Rat
Rat
Rat
Rat
Rabbit
Rat
Rat
Rat
2764 mg/kg
3306 mg/kg
>2000 mg/kg
11700 mg/kg
>5000 mg/kg
1400 mg/kg
>1000 mg/kg
649 mg/kg
>2174 mg/kg
846 mg/kg
Chronic toxicity
Carcinogenicity
Mutagenicity
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
Fertility effects
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Section 12. Ecological information
Product AS SOLD
Ecotoxicity
: This material is harmful to aquatic life.
Aquatic and terrestrial toxicity
Product/ingredient name
Result
2-(2-butoxyethoxy)ethanol
Acute LC50 1300 mg/l
citric acid
Acute LC50 >100 mg/l
alcohols, c9-11, ethoxylated
Acute LC50 8.5 mg/l
methanesulphonic acid
Acute EC50 70 mg/l
amines, coco alkyldimethyl, n-oxides
Acute LC50 <1 mg/l
Other adverse effects
: No known significant effects or critical hazards.
Species
Fish
Fish
Fish
Daphnia
Fish
Exposure
96 hours
96 hours
96 hours
48 hours
96 hours
Section 13. Disposal considerations
Disposal methods
RCRA classification
Product AS SOLD
: Avoid disposal. Attempt to use product
completely in accordance with intended use.
Disposal should be in accordance with applicable
regional, national and local laws and regulations.
Product AT USE DILUTION
Avoid disposal. Attempt to use product
completely in accordance with intended use.
Disposal should be in accordance with
applicable regional, national and local laws
and regulations.
: Unused product is D002 (Corrosive)
Section 14. Transport information
Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification
provided may not reflect those exceptions and may not apply to all shipping modes or package sizes.
DOT
DOT Classification
UN3265
DOT Proper shipping name
Corrosive liquid, acidic, organic, n.o.s. (methane sulfonic acid)
Class
8
Packing group
III
IMO/IMDG
IMO/IMDG Classification
UN3265
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QC 91 HD ACID BATHROOM CLEANER
15 Oct 2013
Section 14. Transport information
IMO/IMDG Proper shipping name
Class
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHANE SULFONIC
ACID)
8
Packing group
III
For transport in bulk, see shipping documents for specific transportation information.
Product AT USE DILUTION
Not intended for transport.
Section 15. Regulatory information
Product AS SOLD
U.S. Federal regulations
TSCA 8(b) inventory
: All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No listed substance
SARA 302/304 emergency planning and notification: No listed substance
Product name
SARA 313
Form R - Reporting
requirements
CAS number
: 2-(2-butoxyethoxy)ethanol
112-34-5
Concentration
18.909
: No listed substance
California Prop. 65
Section 16. Other information
Product AS SOLD
Hazardous Material
Information System (U.S.A.)
Product AT USE DILUTION
:
Health
3
Health
3
Flammability
0
Flammability
0
Physical hazards
0
Physical hazards
0
:
National Fire Protection
Association (U.S.A.)
Flammability
0
Health
3
0
Instability/Reactivity
Special
Date of issue
Prepared by
Flammability
0
Health
3
0
Instability/Reactivity
Special
: 15 Oct 2013
: Regulatory Affairs
1-800-352-5326
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product in
the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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