MATERIAL SAFETY DATA SHEET Material Identity

MATERIAL SAFETY DATA SHEET  Material Identity
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Page: 1 of 7
Feather Fill Black
MSDS Number: 121019
SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name:
Product Numbers:
Product Use:
Feather Fill G2 Black
100714 and 100715
19783ZP
Polyester Primer Surfacer
Distributed
Company By
Emergency Telephone Numbers:
FibreEasthill
Glass-Evercoat
CHEMTREC: 1-800-424-9300
The
Group
The Eastwood
Company
adba/
Division
of Illinois Tool
Works Inc.
CANUTEC: 1-613-996-6666
263
Shoemaker
Road
6600 Cornell Road
Pottstown,
19464
Cincinnati, PA
Ohio
USA
USA & Canada: 800-345-1178
Phone:
513-489-7600
Prepared By: Safety Department
Outside USA: 610-323-2200
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient(s)
Styrene
Polyester Resin
(Non-Hazardous)
Talc
Acetone
Barium Sulfate
Magnesite
Quartz (Crystalline Silica)
Carbon Black
CAS Number
100-42-5
Proprietary
EINECS Number
202-851-5
Proprietary
% (by weight)
25 – 30
20 – 25
14807-96-6
67-64-1
7727-43-7
546-93-0
14808-60-7
1333-86-4
238-877-9
200-662-2
231-784-4
208-915-9
238-878-4
215-609-9
20 – 25
10 – 15
5 – 10
1–5
0–2
0–2
OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations.
SECTION 3. HAZARDS IDENTIFICATION
***EMERGENCY OVERVIEW***
WARNING! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY
CAUSE FLASH FIRE. CAUSES EYE, SKIN, NOSE AND THROAT IRRITATION.
Potential Health Effects
Acute Effects (Short Term):
Eye:
Contact with liquid or vapor may result in irritation, redness, tearing,
and blurred vision.
Skin:
May cause mild skin irritation. Prolonged or repeated contact may
dry the skin. Symptoms may include redness, burning, drying and
cracking of skin, and skin burns.
Swallowing: Ingestion of this material may cause gastrointestinal irritation,
nausea, diarrhea, and vomiting. Aspiration of this material into the
lungs due to vomiting may produce chemical pneumonitis which
can be fatal.
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Page: 2 of 7
Feather Fill Black
MSDS Number: 121019
Inhalation: Excessive inhalation of vapors may cause nasal and respiratory
irritation, acute nervous system depression, fatigue, weakness,
nausea, headache, and dizziness. Symptoms usually occur at air
concentrations higher than the recommended exposure limits (See
Section 8).
Chronic Effects of Overexposure (Long Term):
Styrene:
Excessive overexposure to styrene has been found to cause the
following effects in humans and may aggravate pre-existing
disorders of these organs; central nervous system effects, effects
on hearing, mild effects on color vision and respiratory tract
damage.
Crystalline Silica: Crystalline silica is considered to be hazardous by inhalation,
and is a potential human carcinogen (IARC Group 1). The risk
depends on the duration and level of exposure to dust from sanding
surfaces or mist from spray applications. Crystalline silica may also
produce silicosis, which is a non-cancerous lung disease.
Acetone:
Overexposure to this material may have effects on the blood and
bone marrow.
Cancer Information: The International Agency for Research on Cancer (IARC) has
classified styrene as a group 2B carcinogen (possibly carcinogenic to humans).
This classification is not based on evidence that styrene may be carcinogenic,
but rather on a revised definition for Group 2B, and consideration of new data on
styrene oxide(Group 2A). The IARC has classified crystalline silica as a group 1
carcinogen (sufficient evidence of carcinogenicity in humans). The IARC has
classified carbon black as a group 2B carcinogen (possibly carcinogenic to
humans). This material may contain trace amounts of chemicals considered to be
carcinogenic by OSHA, (Benzene, IARC-Group 1, Ethylene Oxide, IARC-Group
1 and N-Nitrosodimethylamine, IARC Group-2A).
Other Health Effects:
NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system
damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal.
Primary Route(s) of Entry: Inhalation, Skin contact, Eye contact, Ingestion,
Skin absorption.
SECTION 4. FIRST AID MEASURES
Eyes:
Skin:
Flush eyes gently with water for at least 15 minutes. Seek
immediate medical attention.
Remove contaminated clothing. Wash exposed area with soap and
water. If symptoms persist, seek medical attention. Launder
clothing before reuse.
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Page: 3 of 7
Feather Fill Black
MSDS Number: 121019
Swallowing:
Consult a physician or poison control center immediately. DO NOT
INDUCE VOMITING. If individual is drowsy or unconscious, do not
give anything by mouth; place individual on the left side with the
head down. If possible, do not leave individual unattended. If
vomiting occurs spontaneously, keep head below hips to prevent
aspiration of liquid into lungs.
Inhalation:
If symptoms develop, immediately move individual away from
exposure and into fresh air. Seek immediate medical attention;
keep person warm and quiet. If person is not breathing, begin
artificial respiration. If breathing is difficult, oxygen may be benificial
if administered by trained personnel.
SECTION 5. FIRE FIGHTING MEASURES
Flash Point: 1.4 ºF (-17 ºC)
Explosive Limit: Lower: 1.0%
Upper: 12.8%
Autoignition Temperature: 788.0 ºF (420.0 ºC)
OSHA Flammability Class: Flammable Liquid – Class IB
Hazardous Products of Combustion: May form toxic and corrosive gases:
carbon dioxide, carbon monoxide, styrene oxide, nitrogen oxides, and
various hydrocarbons.
Fire and Explosion Hazards: Vapors are heavier than air and may travel along
the ground or may be moved by ventilation and ignited by pilot lights, other
flames, sparks, heaters, smoking, electric motors, static discharge, or
other ignition sources at locations distant from material handling point.
Extinguishing Media: Regular foam, carbon dioxide, dry chemical.
Fire Fighting Instructions: Water may be used to keep fire-exposed containers
cool until fire is out. Wear a self-contained breathing apparatus NIOSH
approved with a full facepiece operated in the positive pressure demand
mode with appropriate turn-out gear and chemical resistant personal
protective equipment.
NFPA Rating:
Health - 2,
Flammability - 3,
Reactivity - 2
SECTION 6. ACCIDENTAL RELEASE MEASURES
In Case of Spill: Eliminate all sources of ignition such as flares, flames (including
pilot lights), and electrical sparks. Ventilate the area. Wear proper protective
equipment (Section 8). Avoid breathing vapors. Collect with an inert absorbant
and dispose of properly.
SECTION 7. HANDLING AND STORAGE
Handling: All hazard precautions given in the data sheet must be observed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling. Use only
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Page: 4 of 7
Feather Fill Black
MSDS Number: 121019
with adequate ventilation. Do not breathe sanding dust, vapors or spray mist. Do
not take internally. Close container after each use. Keep out of reach of
children.
Storage: Store material in a cool, well-ventilated area. For maximum product quality,
avoid prolonged storage at temperatures above 75°F (25°C). Do not use or store
near heat, sparks, or open flame. Keep container tightly closed. Avoid contact
with incompatible materials.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection:
Chemical splash goggles in compliance with OSHA regulations are
recommended.
Skin Protection: Protective gloves and proper clothing should be worn to prevent
skin contact. Gloves should be made of neoprene or natural rubber.
To prevent repeated or prolonged skin contact, wear impervious
clothing and boots.
Respiratory Protection: Use a NIOSH approved respirator designed to remove
particulate matter and organic solvent vapors.
Engineering Controls: Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below acceptable limits.
Explosion-proof ventilation system is acceptable.
Exposure Guidelines:
Hazardous Ingredients
Acetone
Barium Sulfate
Carbon Black
Crystalline Silica
Magnesite
Styrene
Talc
CAS Number
67-64-1
7727-43-7
1333-86-4
14808-60-7
546-93-0
100-42-5
14807-96-6
Mppcf- millions of particles per cubic foot of air
OSHA PEL/TWA ACGIH TLV
1000 ppm
500 ppm
3
15 mg/m
10 mg/m3
3
3.5 mg/m
3.5 mg/m3
N/E
0.05 mg/m3
3
15 mg/m
10 mg/m3
100 ppm
20 ppm
20 mppcf
2 mg/m3
N/E-Not Established
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
133 - 293 °F/ 56 145 °C
Specific Gravity / 1.36/ 11.3 lbs/gal
Density:
Slower than ethyl
Evaporation
ether.
Rate:
Melting Point:
-13 °F / -25 °C
Boiling Point:
Vapor Density:
Heavier than air.
Percent Volatiles by
weight:
Physical State:
30 – 35 %
pH:
Neutral
Liquid
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Page: 5 of 7
Feather Fill Black
MSDS Number: 121019
Sharp, aromatic
Insoluble in
Odor:
Solubility:
odor.
water.
Black Liquid
Vapor Pressure: 180 mmHg @ 68
Appearance:
°F/20 °C (Acetone)
Unknown
Octanol/Water
Partition
Coefficient:
3.04 lbs/gal or
VOC (as
VOC (as applied*- 2%by 1.61 lbs/gal or
365 g/L
193 g/L
packaged-less
wt hardener- less
exempts and
exempts and water):
76.8 %
66.8 %
Percent Solids by
Percent Solids
weight – as applied* - 2
by weight – as
% by wt hardener
packaged:
13.6 %
25.6 %
VHAP Content by
VHAP Content
weight – as applied* - 2
by weight – as
% by weight hardener
packaged:
*NOTE: The applied VOC and VHAP Content is lower than the packaged VOC and
VHAP Content due to a reactive diluent (styrene) that reacts and becomes non-volatile
(bonded in the solid material) when the hardener is added.
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization: Product may undergo hazardous polymerization
if exposed to extreme heat.
Hazardous Decomposition: May form toxic and corrosive gases: carbon
dioxide, carbon monoxide,styrene oxide, nitogen oxides and various
hydrocarbons.
Chemical Stability: Stable under normal handling conditions.
Incompatibility: Avoid contact in uncontrolled conditions with: peroxides,
strong acids, strong oxidizing agents, halogens, reducing agents and
strong bases.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity Data:
Ingredient
CAS #
LD50 Oral-Rat
Styrene
100-42-5
5,000 mg/kg
Acetone
67-64-1
5,800 mg/kg
LC50 Inhalation-Rat
24 g/m3/4H
50,100 mg/m3/8H
N/E-Not Established
Carcinogenicity: See Cancer Information, Section 3.
Mutagenicity: No significant evidence found.
Teratogenicity: No significant risk of birth defects or reproductive toxicity of
styrene to humans.
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Feather Fill Black
SECTION 12. ECOLOGICAL INFORMATION
Page: 6 of 7
MSDS Number: 121019
Ecotoxicity: Styrene is toxic to aquatic organisms and should not be released
to sewage, draining systems or any body of water exceeding
concentrations of approved limits under applicable regulations and
permits.
SECTION 13. DISPOSAL CONSIDERATION
RCRA Hazardous Waste: This material as supplied, if discarded,
would be regulated as a hazardous waste under RCRA (40 CFR 261).
Dispose of in accordance with applicable federal, state, and local
regulations.
RCRA Hazard Class: This material would be regulated as EPA Hazardous
Waste Number D001 based on the characteristic of ignitablity.
SECTION 14. TRANSPORT INFORMATION
DOT Description: The DOT Classification for shipping is dependant on
quantity, type of packaging (a kit may include other components), or
method of shipment.
SECTION 15. REGULATORY INFORMATION
US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (USA) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4(a)
Component
RQ (lbs.)
Styrene
1000
Acetone
5000
SARA Title III: Section 302- Extremely Hazardous Substances
None
SARA Title III: Section 313- Toxic Chemical List
Component
CAS Number
Percentage
Styrene
100-42-5
25.6 %
EPA Hazardous Air Pollutants (HAPS) 40 CFR 63
Component
CAS Number
Percentage
Styrene
100-42-5
25.6 %
International Regulations
EINECS (Europe) The intentional ingredients of this product are listed.
DSL (Canada) The intentional ingredients of this product are listed.
WHMIS Classification
EW #19783ZP - Featherfill G2 Black Gallon
MATERIAL SAFETY DATA SHEET
Date Revised: 10/4/07
Feather Fill Black
Page: 7 of 7
MSDS Number: 121019
Health Hazard: D2A, D2B (Other Toxic Effects)
Physical Hazard: B2 (Flammable)
State and Local Regulations
California Proposition 65:
This product contains the following chemical(s) known to the state of
California to cause cancer. STYRENE OXIDE, CARBON BLACK, CRYSTALLINE
SILICA, ETHYLENE OXIDE, N-NITROSODIMETHYLAMINE, EPICHLOROHYDRIN
Styrene, in the presence of air and high temperature or prolonged
exposure of styrene/air mixture to sunlight, can react to form styrene
oxide.
This product contains the following chemical(s) known to the state of
California to cause birth defects or reproductive harm. TOLUENE, ETHYLENE
OXIDE, EPICHLOROHYDRIN
SECTION 16. OTHER INFORMATION
HMIS Rating:
Health – 2*, Flammability - 3,
Reactivity - 2
Key- 0=Least, 1=Slight, 2=Moderate, 3=Serious, 4=Extreme, *=Chronic Effects
Other Precautions for Use: This product must be mixed with Liquid Activator
(MEKP) prior to use. Please refer to the Material Safety Data Sheet (#100636)
for catalyst before using. If product is to be sanded, the OSHA PEL/TLV of 10
mg/m3 for nuisance dust should be observed.
Additional Information may be obtained by calling the Evercoat MSDS Hotline at
1-800-729-7600.
NOTICE: The information accumulated herein is believed to be correct as of the date issued from
sources, which are believed to be accurate and reliable. Since it is not possible to anticipate all
circumstances of use, recipients are advised to confirm, in advance of need, that the information
is current, applicable and suitable to their circumstances.
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