199 - Clear Image Concentrate SDS English (Canada)

199 - Clear Image Concentrate SDS English (Canada)
Material Safety Data Sheet
Clear Image
1. Product and company identification
Product name
Clear Image
:
Supplier
Synonym
: Betco Corporation
1001 Brown Avenue
Toledo, OH 43607
www.betco.com
888-462-3826
: Not available.
Trade name
: Not available.
Material uses
: Special: Glass cleaners
Manufacturer
: Betco Corporation
1001 Brown Avenue
Toledo, Ohio 43607
www.betco.com
888-462-3826
Code
: 199
MSDS #
: 199
Validation date
: 4/29/2015.
Print date
: 4/30/2015.
In case of emergency
: Chemtrec (800) 424-9300
Product type
: Liquid.
2. Hazards identification
Emergency overview
Physical state
: Liquid.
Color
: Clear. Blue.
Odor
: Pleasant.
Signal word
: WARNING!
Hazard statements
: HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. CAUSES
EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
: Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Do
not eat, drink or smoke when using this product. Avoid contact with eyes, skin and
clothing. Keep container closed. Wash thoroughly after handling.
: Dermal contact. Eye contact. Inhalation. Ingestion.
Precautionary measures
Routes of entry
Potential acute health effects
Inhalation
Ingestion
: Toxic by inhalation. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
: Toxic if swallowed.
Skin
: Toxic in contact with skin. Moderately irritating to the skin.
Eyes
: Severely irritating to eyes. Risk of serious damage to eyes.
Potential chronic health effects
Chronic effects
: Contains material that may cause target organ damage, based on animal data.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
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2. Hazards identification
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Target organs
: Contains material which may cause damage to the following organs: blood, kidneys,
liver, spleen, lymphatic system, upper respiratory tract, skin, bone marrow, central
nervous system (CNS), eye, lens or cornea.
Over-exposure signs/symptoms
Inhalation
: Not determined.
Ingestion
: Not determined.
Skin
: Adverse symptoms may include the following:
irritation
redness
: Adverse symptoms may include the following:
pain or irritation
watering
redness
: Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
Eyes
Medical conditions
aggravated by overexposure
See toxicological information (Section 11)
3. Composition/information on ingredients
Name
CAS number
%
2-butoxyethanol
tetrasodium ethylene diamine tetraacetate
sodium dodecyl sulphate
111-76-2
64-02-8
151-21-3
5 - 10
1-5
1-5
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
Notes to physician
4/30/2015.
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately. In case of contact with eyes, rinse immediately with plenty of
water.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
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5. Fire-fighting measures
Flammability of the product
: In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable
: Use an extinguishing agent suitable for the surrounding fire.
Not suitable
: None known.
Special exposure hazards
Hazardous thermal
decomposition products
Special protective
equipment for fire-fighters
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on fire
hazards
: Not available.
Special remarks on
explosion hazards
: Not available.
6. Accidental release measures
Personal precautions
Environmental precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill
Large spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
: Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
7. Handling and storage
Handling
4/30/2015.
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
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7. Handling and storage
Storage
: Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
8. Exposure controls/personal protection
Occupational exposure limits
TWA (8 hours)
STEL (15 mins)
Ceiling
Ingredient
List name
ppm
mg/m³ Other
ppm
ppm
mg/m³ Other
2-butoxyethanol
US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
20
20
20
20
20
97
97
-
-
-
-
mg/m³ Other
-
-
-
Notations
[3]
[3]Skin sensitization
Consult local authorities for acceptable exposure limits.
Recommended monitoring
procedures
Engineering measures
Hygiene measures
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. Ensure that eyewash stations and safety showers are
close to the workstation location if mandated by workplace safety regulations or if the
risk of exposure coupled with the product hazard indicates significant risk exists.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
Personal protection
Respiratory
Hands
Eyes
Skin
4/30/2015.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. 1 - 4 hours (breakthrough
time): butyl rubber
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles.
Recommended: safety glasses with side-shields
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
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8. Exposure controls/personal protection
Environmental exposure
controls
Other protection
Personal protective
equipment (Pictograms)
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
: Not available.
: Not available.
9. Physical and chemical properties
Physical state
: Liquid.
Flash point
: Closed cup: >100°C (>212°F)
Burning time
: Not applicable.
Burning rate
: Not applicable.
Auto-ignition temperature
: Not available.
Flammable limits
Color
Odor
: Not available.
: Clear. Blue.
: Pleasant.
Taste
: Not available.
Molecular weight
: Not applicable.
Molecular formula
: Not applicable.
pH
: 7 to 10.5
Boiling/condensation point
: Not available.
Melting/freezing point
: Not available.
Critical temperature
: Not available.
Relative density
Vapor pressure
Vapor density
: 0.98
: Not available.
: Not available.
Volatility
: Not available.
Odor threshold
: Not available.
Evaporation rate
: Not available.
SADT
: Not available.
Viscosity
: Not available.
Ionicity (in water)
: Not available.
Dispersibility properties
: Easily dispersible in the following materials: cold water and hot water.
Solubility
Physical/chemical
properties comments
: Easily soluble in the following materials: cold water and hot water.
: Not available.
10. Stability and reactivity
Chemical stability
: The product is stable.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition
products
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
4/30/2015.
: Under normal conditions of storage and use, hazardous reactions will not occur.
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11. Toxicological information
Acute toxicity
Product/ingredient name
Result
2-butoxyethanol
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
sodium dodecyl sulphate
LD50 Oral
tetrasodium ethylene diamine LD50 Oral
tetraacetate
Conclusion/Summary
Species
Dose
Exposure
Rat
Rabbit
Rat
Rat
Rat
450 ppm
220 mg/kg
250 mg/kg
1288 mg/kg
10 g/kg
4 hours
-
: Not available.
Chronic toxicity
Not available.
Conclusion/Summary
: Not available.
Irritation/Corrosion
Product/ingredient name
Result
Species
Score Exposure
Observation
2-butoxyethanol
Eyes - Moderate irritant
Rabbit
-
-
Eyes - Severe irritant
Rabbit
-
Skin - Mild irritant
Rabbit
-
Eyes - Mild irritant
Rabbit
-
Eyes - Moderate irritant
Rabbit
-
Eyes - Moderate irritant
Skin - Mild irritant
Rabbit
Dog
-
Skin - Mild irritant
Guinea pig
-
Skin - Mild irritant
Human
-
Skin - Mild irritant
Human
-
Skin - Mild irritant
Human
-
Skin - Mild irritant
Human
-
Skin - Mild irritant
Human
-
Skin - Mild irritant
Human
-
Skin - Moderate irritant
Human
-
Skin - Moderate irritant
Human
-
Skin - Moderate irritant
Mouse
-
Skin - Mild irritant
Pig
-
Skin - Mild irritant
Rabbit
-
Skin - Moderate irritant
Rabbit
-
tetrasodium ethylene diamine Eyes - Moderate irritant
Rabbit
-
sodium dodecyl sulphate
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24 hours 100
milligrams
100
milligrams
500
milligrams
250
Micrograms
24 hours 100
milligrams
10 milligrams
24 hours 25
milligrams
24 hours 25
milligrams
2 hours 2
Percent
504 hours 0.3
Percent
24 hours 0.06
Percent
22 hours 10
Percent
47 hours 0.5
Percent
18 hours 2
Percent
48 hours 3
Percent
24 hours 0.1
Percent
24 hours 25
milligrams
24 hours 25
milligrams
24 hours 50
milligrams
24 hours 25
milligrams
24 hours 100
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11. Toxicological information
tetraacetate
Skin - Moderate irritant
Conclusion/Summary
Rabbit
-
milligrams
24 hours 500
milligrams
-
: Not available.
Sensitizer
Not available.
Conclusion/Summary
: Not available.
Carcinogenicity
Not available.
Conclusion/Summary
: Not available.
Classification
Product/ingredient name
ACGIH
IARC
EPA
NIOSH
NTP
OSHA
2-butoxyethanol
A3
3
-
-
-
-
Mutagenicity
Not available.
Conclusion/Summary
: Not available.
Teratogenicity
Not available.
Conclusion/Summary
: Not available.
Reproductive toxicity
Not available.
Conclusion/Summary
Synergistic products
: Not available.
: Not available.
12. Ecological information
Ecotoxicity
Aquatic ecotoxicity
: No known significant effects or critical hazards.
Product/ingredient name
Result
Species
Exposure
2-butoxyethanol
Acute EC50 >1000 mg/l Fresh water
Acute LC50 800000 µg/l Marine water
Acute LC50 1250000 µg/l Marine water
Acute EC50 1200 µg/l Marine water
Acute LC50 900 µg/l Marine water
Daphnia - Daphnia magna
Crustaceans - Crangon crangon
Fish - Menidia beryllina
Algae - Skeletonema costatum
Crustaceans - Artemia salina Adult
Daphnia - Daphnia pulex Neonate
Fish - Cirrhinus mrigala - Larvae
Algae - Ulva fasciata - Zoea
Crustaceans - Pseudosida
ramosa - Neonate
Daphnia - Daphnia magna Neonate
Fish - Pimephales promelas
Fish - Lepomis macrochirus
48 hours
48 hours
96 hours
96 hours
48 hours
sodium dodecyl sulphate
Acute LC50 1400 µg/l Fresh water
Acute LC50 590 µg/l Fresh water
Chronic NOEC 1.25 mg/l Marine water
Chronic NOEC 1 mg/l Fresh water
Chronic NOEC 3.2 mg/l Fresh water
Chronic NOEC >1357 µg/l Fresh water
tetrasodium ethylene diamine Acute LC50 486000 µg/l Fresh water
tetraacetate
Conclusion/Summary
Persistence/degradability
4/30/2015.
48 hours
96 hours
96 hours
21 days
21 days
42 days
96 hours
: Not available.
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12. Ecological information
Not available.
Conclusion/Summary
: Not available.
Partition coefficient: noctanol/water
Bioconcentration factor
: Not available.
Mobility
: Not available.
Toxicity of the products of
biodegradation
: Not available.
Other adverse effects
: No known significant effects or critical hazards.
: Not available.
13. Disposal considerations
Waste disposal
Waste stream
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: Not available.
RCRA classification
: Not available.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
PG* Label
Additional
information
DOT Classification
Not
regulated.
-
-
-
-
TDG Classification
Not
regulated.
-
-
-
-
Mexico
Classification
Not
regulated.
-
-
-
-
ADR/RID Class
Not
regulated.
-
-
-
-
IMDG Class
Not
regulated.
-
-
-
-
IATA-DGR Class
Not
regulated.
-
-
-
-
PG* : Packing group
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15. Regulatory information
United States inventory
(TSCA 8b)
: Not determined.
WHMIS (Canada)
: Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
Canadian NPRI
: The following components are listed: 2-Butoxyethanol
CEPA Toxic substances
: The following components are listed: 2-butoxyethanol
Canada inventory
: Not determined.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists
: Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
Chemical Weapons
Convention List Schedule
I Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
Chemical Weapons
Convention List Schedule
III Chemicals
: Not listed
: Not listed
16. Other information
Label requirements
Hazardous Material
Information System (U.S.A.)
: HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. CAUSES
EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
:
*
Health
2
Flammability
1
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
References
: Not available.
Other special
considerations
: Not available.
Date of printing
: 4/30/2015.
Date of issue
: 4/29/2015.
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16. Other information
Date of previous issue
: 3/31/2015.
Version
: 2.01
Prepared by
: Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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