Toro 10w30 Engine Oil

Toro 10w30 Engine Oil
SECTION 1 - IDENTIFICATION
NFPA
Product Name:
MSDS Manufacturer
Number:
Product Use/Restriction:
Manufacturer Name:
Address:
General Phone Number:
MSDS Creation Date:
MSDS Revision Date:
GHS Class:
TORO PREMIUM 10W30 ENGINE OIL
1665
Engine lubricant
The Toro Company
8111 Lyndale Ave S
Bloomington,, Minnesota 55420
U.S.A.
1-952-888-8801
September 24, 2012
September 24, 2012
Skin Irritant, Category 2
Eye Irritant, Category 2
Specific Target Organ Toxicity, Category 3
1
1
0
HMIS
Health Hazard 2
Fire Hazard
1
Reactivity
0
Personal
Protection
X
SECTION 2 - HAZARD(S) IDENTIFICATION
GHS Pictograms:
Signal Word:
DANGER!
GHS Class:
Skin Irritant, Category 2
Eye Irritant, Category 2
Specific Target Organ Toxicity, Category 3
Hazard Statements:
May be fatal if swallowed and enters airways
Causes damage to organs through prolonged or repeated exposure
Causes eye irritation
Suspected of damaging fertility or the unborn child
May cause cancer
May cause long lasting harmful effects to aquatic life
Precautionary Statements:
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands thoroughly after handling.
Keep only in original container
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
1 of 7
©Toro 2012-2012
Emergency Overview:
WARNING! Irritant. Inhalation of vapors or mists from this product may
cause headache, nausea and irritation to the eyes, skin and respiratory
system.
Route of Exposure:
Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye:
May cause irritation. Overexposure may cause eye watering or discomfort,
redness and swelling.
Skin:
May cause skin irritation. May be harmful if absorbed through skin.
Prolonged or repeated contact can result in defatting and drying of the
skin, which may result in skin irritation and dermatitis (rash).
Inhalation:
Inhalation of vapors, mists or aerosols of the solution can cause respiratory
irritation.
Inhalation of high concentrations may cause central nervous system effects
characterized by nausea, headache, dizziness, unconsciousness and coma.
Caution should be taken to prevent aerosolization or misting of this product
without proper respiratory protection.
Ingestion:
May be harmful if swallowed. May cause vomiting. Do not ingest.
Product is expected to be relatively non-toxic unless lung aspiration occurs.
Aspiration is not expected with this material due to viscosity (thickness).
Should aspiration occur, may lead to chemical pneumonitis which is
characterized by pulmonary edema and hemorrhage and may be fatal.
Signs of lung involvement include increased respiratory rate, increased
heart rate, and a bluish discoloration of the skin. Coughing, choking and
gagging are often noted at the time of aspiration. This product has laxative
properties and may esult in abdominal cramps and diarrhea.
Signs/Symptoms:
Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs:
Eyes. Skin. Respiratory system. Digestive system.
Aggravation of Pre-Existing
Conditions:
None generally recognized.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS#
Severely hydrotreated paraffinic base oils
Mixture
Ingredient Percent
EC Num.
No data %
Zinc salt of dialkyl dithiophosphoric acid
Note:
Mixture
<1.5 %
All base oils, including additive carriers, contain
SECTION 4 - FIRST AID MEASURES
Eye Contact:
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.
Skin Contact:
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash
occurs: Get medical advice/attention. Wash contaminated clothing before
reuse.
Inhalation:
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at
rest in a position comfortable for breathing.
IF exposed or concerned: Call a POISON CENTER or doctor/physician.
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
2 of 7
©Toro 2012-2012
Ingestion:
IF SWALLOWED: Rinse mouth. Do not induce vomiting. Call a POISON
CENTER or doctor/physician if you feel unwell. If spontaneous vomiting
occurs keep head below hips to prevent aspiration and monitor for
breathing difficulty. Gastric lavage should be performed only by qualified
medical personnel. Keep affected person warm and at rest. Seek
immediate medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point:
>200°C (392°F)
Flash Point Method:
[ASTM D-92]
Auto Ignition Temperature:
Data not available.
Lower Flammable/Explosive
Limit:
Data not available.
Upper Flammable/Explosive
Limit:
Data not available.
Extinguishing Media:
Use alcohol resistant foam, carbon dioxide, dry chemical, or water fog or
spray when fighting fires involving this material.
Protective Equipment:
As in any fire, wear Self-Contained Breathing Apparatus (SCBA),
MSHA/NIOSH (approved or equivalent) and full protective gear.
Unusual Fire Hazards:
Dense smoke may be generated while burning. Toxic fumes, gases or
vapors may evolve on burning. Heavy flammable vapors may settle along
ground level. And low spots to create an invisible fire hazard. Vapors can
flow along surfaces to distant ignition sources and flash back.
Hazardous Combustion
Byproducts:
Fires involving this product may release oxides of carbon, phosphorus,
nitrogen and sulfur; reactive hydrocarbons and irritating vapors.
NFPA Ratings:
NFPA Health:
1
NFPA Flammability:
1
NFPA Reactivity:
0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personnel Precautions:
Use proper personal protective equipment as listed in section 8. Evacuate
area and keep unnecessary and unprotected personnel from entering the
spill area.
Environmental Precautions:
Keep spills and cleaning runoff out of municipal sewers, storm sewers,
ditches, waterways, and open bodies of water.
Methods for containment:
Contain spills with an inert absorbent material such as soil, sand or oil dry.
Dikes should be placed to contain spill in a manner that will prevent
material from entering sewers and waterways.
Methods for cleanup:
Eliminate all ignition sources including those beyond the immediate spill
area. Floor may be slippery; use care to avoid falling.
Transfer liquids and solid diking material to separate suitable containers
for recovery or disposal.
Clean up spills immediately observing precautions in the protective
equipment section.
Avoid breathing vapor, aerosol or mist.
Large spill, once contained, may be picked up using explosion proof,
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
3 of 7
©Toro 2012-2012
Large spill, once contained, may be picked up using explosion proof,
non-sparking vacuum pumps, shovels, or buckets, and disposed of in
suitable containers for disposal. If a large spill occurs notify appropriate
authorities.
Water Spill: Remove from surface by skimming or with suitable
adsorbents. If a large spill occurs notify appropriate authorities (normally
the National Response Center or Coast Guard).
Other Precautions:
CAUTION - If spilled material is cleaned up using a regulated solvent, the
resulting waste mixture will be regulated.
SECTION 7 - HANDLING and STORAGE
Handling:
Use with adequate ventilation. Avoid breathing vapor and contact with
eyes, skin and clothing.
Vapors can be evolved when material is heated during processing
operations.
To reduce potential for static discharge, bond and ground containers when
transferring material. Do not transfer to unmarked containers.
Fire extinguishers should be kept readily available. See NFPA 30 and OSHA
1910.106 -- Flammable and Combustible Liquids.
Empty containers retain product residue which may exhibit hazards of
material. Do not reuse, heat, burn, pressurize, cut, weld, braze, solder,
drill, grind, expose to sparks, flame, or ignition sources of empty containers
without proper commercial cleaning or reconditioning.
For handling hot/heated material, wear proper insulated protective
equipment to prevent risk of oil burns.
Storage:
Store in a cool, dry, well ventilated area away from sources of heat and
incompatible materials. Keep container tightly closed when not in use.
Ground all metal containers during storage and handling.
Keep away from direct sunlight.
Do not store product in excess of 49°C (120°F).
Do not store containers outside due to temperature fluctuations - risk of
drawing water into product through container seals due to cap and fluid
expansion and contractions.
Work Practices:
Handle in accordance with good industrial hygiene and safety practices.
Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Hygiene Practices:
Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid
inhaling vapor or mist.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls:
Use appropriate engineering control such as process enclosures,
explosion-proof local exhaust ventilation, or other engineering controls to
control airborne levels below recommended exposure limits. Good general
ventilation should be sufficient to control airborne levels. Where such
systems are not effective wear suitable personal protective equipment,
which performs satisfactorily and meets OSHA or other recognized
standards. Consult with local procedures for selection, training, inspection
and maintenance of the personal protective equipment.
Eye/Face Protection:
Wear appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the European
standard EN 166.
Skin Protection Description:
Wear appropriate protective gloves and other protective apparel to prevent
skin contact. Consult manufacturer's data for permeability data. Neoprene
or nitrile rubber gloves or protective clothing is recommended
If handling hot material use insulated protective equipment.
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
4 of 7
©Toro 2012-2012
Hand Protection Description:
Chemical-resistant gloves should be worn whenever this material is
handled. Neoprene or nitrile rubber gloves or protective clothing is
recommended
Gloves should be removed and replaced immediately if there is any
indication of degradation or chemical breakthrough. Rinse and remove
gloves immediately after use. Wash hands with soap and water.
For handling hot material, wear impervious insulated gloves and keep all
skin areas covered.
Respiratory Protection:
A NIOSH approved air-purifying respirator with an organic vapor cartridge
or canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided
by air purifying respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying
respirators may not provide adequate protection.
Other Protective:
Follow good industrial hygiene practices when handling this material.
Consumption of food and drink should be avoided in work areas where
product is present.
PPE Pictograms:
EXPOSURE GUIDELINES
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State:
Liquid.
Color:
Amber to dark brown color.
Odor:
Mild oily odor.
Boiling Point:
Data not available.
Melting Point:
Data not available.
Specific Gravity:
0.8623 at 15.6°C (60.0°F).
Solubility:
Negligible solubility in water.
Vapor Density:
>1 (Air = 1)
Vapor Pressure:
Percent Volatile:
negligible
Evaporation Rate:
Data not available.
Evaporation Point:
Data not available.
pH:
Data not available.
Viscosity:
Approximately 11.7 cSt at 100°C (212°F).
Flash Point:
>200°C (392°F)
Flash Point Method:
[ASTM D-92]
Auto Ignition Temperature:
Data not available.
SECTION 10 - STABILITY and REACTIVITY
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
5 of 7
©Toro 2012-2012
Chemical Stability:
Stable under normal conditions.
Hazardous Polymerization:
Will not occur.
Conditions to Avoid:
Extreme heat, sparks, and open flame. Incompatible materials, oxidizers
and oxidizing conditions.
Incompatible Materials:
Oxidising materials, strong acids, chlorine
Special Decomposition
Products:
Smoke, carbon monoxide and dioxide, and other aldehydes of incomplete
combustion. Oxides of carbon, phosphorus, nitrogen and sulfur; reactive
hydrocarbons and irritating vapors.
SECTION 11 - TOXICOLOGICAL INFORMATION
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
This material may be toxic to aquatic organisms and should be kept out of
sewage and drainage systems and all bodies of water.
Environmental Fate:
No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal:
This product unadulterated by other materials may be classified as a
nonregulated waste in some areas - but still needs to be disposed of at
approved facilities. Waste management should be in full compliance with
federal, state, and local laws.
Dispose of in accordance with Local, State, Federal and Provincial
regulations. Under RCRA it is the responsibility of the user of the product to
determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste.
Most used and non-use oils are incinerated by licensed burner facilities for
heat value, or reclaimed by oil recycling services. Look in a local telephone
directory or internet for headings under, 'Waste', 'Waste Services', 'Waste
Disposal' for companies licensed to handle such material. Additional
information can be obtained from local EPA, DNR, Sewer and Land-Fill
sites. Unused, packaged fluids may be donated to other companies or
charities (fluids MUST be unused).
The transportation, storage, treatment and disposal of RCRA waste
material must be conducted in compliance with 40 CFR 262, 263, 264, 268
and 270. Disposal can only occur in properly permitted facilities. Check
state and local regulations for any additional requirements as these may be
more restrictive than federal laws and regulations. Chemical additions,
processing or otherwise altering this material may make the waste
management information presented in this MSDS incomplete, inaccurate or
otherwise inappropriate. Disposal of this material must be conducted in
compliance with all federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
6 of 7
©Toro 2012-2012
DOT Shipping Name:
Not Regulated.
DOT UN Number:
Not Regulated.
SECTION 15 - REGULATORY INFORMATION
Risk Phrases:
R36/37/38 Irritating to eyes, respiratory system and skin.
R22 Harmful if swallowed.
Safety Phrase:
S20 When using do not eat or drink.
S24/25 Avoid contact with skin and eyes.
S36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
S26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
Severely hydrotreated paraffinic base oils :
TSCA Inventory Status:
Listed
Canada DSL:
Listed
SECTION 16 - ADDITIONAL INFORMATION
Label Hazard Warning:
May be fatal if swallowed and enters airways
Causes damage to organs through prolonged or repeated exposure
Causes eye irritation
Suspected of damaging fertility or the unborn child
May cause cancer
May cause long lasting harmful effects to aquatic life
Label Precautions:
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands thoroughly after handling.
Keep only in original container
HMIS Health Hazard:
2
HMIS Fire Hazard:
1
HMIS Reactivity:
0
HMIS Personal Protection:
X
MSDS Creation Date:
September 24, 2012
MSDS Revision Date:
September 24, 2012
Copyright© 1996-2011 Actio Corporation. All Rights Reserved.
TORO PREMIUM 10W30 ENGINE OIL
Revison Date: 9/24/2012
Product Code: 1665
RELEASED Version
7 of 7
©Toro 2012-2012
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