PPG VM4991 - Harlequin Magenta To Gold (English)

PPG VM4991 - Harlequin Magenta To Gold (English)
SAFETY DATA SHEET
Date of issue/Date of revision
25 August 2015
Version 4
Section 1. Identification
Product name
: MAGENTA TO GOLD
Product code
: VM4991
Other means of
identification
: Not available.
Product type
: Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Product use
: Industrial applications.
Use of the substance/
mixture
: Coating. Paints. Painting-related materials.
Uses advised against
: Not applicable.
Supplier
Emergency telephone
number
Technical Phone Number
: PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
: (412) 434-4515 (U.S.)
(514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)
: 1-800-647-6050
Section 2. Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 8.6%
GHS label elements
United States
Page: 1/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 2. Hazards identification
Hazard pictograms
:
Signal word
: Danger
Hazard statements
: Flammable liquid and vapor.
Causes serious eye damage.
Causes skin irritation.
Suspected of causing cancer.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention
Response
Storage
Disposal
Supplemental label
elements
Hazards not otherwise
classified
: Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling.
: Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or physician.
Apply generous quantities of fresh calcium gluconate gel to all areas. Get immediate
medical attention.
: Store locked up. Store in a well-ventilated place. Keep cool.
: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: Sanding and grinding dusts may be harmful if inhaled. Repeated exposure to high vapor
concentrations may cause irritation of the respiratory system and permanent brain and
nervous system damage. Inhalation of vapor/aerosol concentrations above the
recommended exposure limits causes headaches, drowsiness and nausea and may
lead to unconsciousness or death. Avoid contact with skin and clothing. Wash
thoroughly after handling. Emits toxic fumes when heated.
: Prolonged or repeated contact may dry skin and cause irritation.
United States
Page: 2/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Product name
: MAGENTA TO GOLD
Ingredient name
%
CAS number
n-butyl acetate
butan-1-ol
xylene
magnesium fluoride
2-ethoxy-1-methylethyl acetate
2-methoxy-1-methylethyl acetate
2-methylpropan-1-ol
Aluminium powder (stabilized)
ethylbenzene
chromium
≥25 - <50
≥5 - <10
≥5 - <10
≥3 - <5
≥1 - <3
≥1 - <3
≥1 - <1.9
≥1 - <3
≥0.3 - <1
≥0.3 - <1
123-86-4
71-36-3
1330-20-7
7783-40-6
54839-24-6
108-65-6
78-83-1
7429-90-5
100-41-4
7440-47-3
SUB codes represent substances without registered CAS Numbers.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Ingestion
: Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Apply generous quantities of fresh calcium gluconate gel to all areas. Get immediate
medical attention.
: If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: Causes serious eye damage.
Inhalation
Skin contact
: Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
: Causes skin irritation. Defatting to the skin.
Ingestion
: Can cause central nervous system (CNS) depression.
United States
Page: 3/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 4. First aid measures
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
: Adverse symptoms may include the following:
pain
watering
redness
: Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
: Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
: Adverse symptoms may include the following:
stomach pains
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
Specific treatments
Protection of first-aiders
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
: No specific treatment.
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
: Use dry chemical, CO₂, water spray (fog) or foam.
Unsuitable extinguishing
media
: Do not use water jet.
Specific hazards arising
from the chemical
: Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard.
United States
Page: 4/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
Special protective actions
for fire-fighters
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill
Large spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
United States
Page: 5/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 7. Handling and storage
Precautions for safe handling
Protective measures
Special precautions
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
: Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
: Ingestion of product or cured coating may be harmful. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Vapors are heavier than air and may spread along floors. If this material is part of a
multiple component system, read the Safety Data Sheet(s) for the other component or
components before blending as the resulting mixture may have the hazards of all of its
parts.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
: Do not store above the following temperature: 35°C (95°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
n-butyl acetate
ACGIH TLV (United States, 4/2014).
STEL: 200 ppm 15 minutes.
TWA: 150 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 300 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ACGIH TLV (United States, 4/2014).
butan-1-ol
xylene
United States
Page: 6/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 8. Exposure controls/personal protection
magnesium fluoride
2-ethoxy-1-methylethyl acetate
2-methoxy-1-methylethyl acetate
2-methylpropan-1-ol
aluminium powder (stabilised)
ethylbenzene
chromium
A
ACGIH
C
F
IPEL
OSHA
R
Z
=
=
=
=
=
=
=
=
Key to abbreviations
Acceptable Maximum Peak
American Conference of Governmental Industrial Hygienists.
Ceiling Limit
Fume
Internal Permissible Exposure Limit
Occupational Safety and Health Administration.
Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL Z2 (United States, 2/2013).
TWA: 2.5 mg/m³ 8 hours. Form: Dust
ACGIH TLV (United States, 4/2014).
TWA: 2.5 mg/m³, (as F) 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 2.5 mg/m³, (as F) 8 hours.
None.
IPEL (PPG, 4/2009).
TWA: 50 ppm
ACGIH TLV (United States, 4/2014).
TWA: 152 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 300 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ACGIH TLV (United States, 4/2014).
TWA: 1 mg/m³ 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³, (as Al) 8 hours. Form:
Respirable fraction
TWA: 15 mg/m³, (as Al) 8 hours. Form: Total
dust
ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ACGIH TLV (United States, 4/2014).
TWA: 0.5 mg/m³, (measured as Cr) 8 hours.
Form: Inorganic
OSHA PEL (United States, 2/2013).
TWA: 1 mg/m³, (as Cr) 8 hours.
S
SR
SS
STEL
TD
TLV
TWA
=
=
=
=
=
=
=
Potential skin absorption
Respiratory sensitization
Skin sensitization
Short term Exposure limit values
Total dust
Threshold Limit Value
Time Weighted Average
Consult local authorities for acceptable exposure limits.
United States
Page: 7/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 8. Exposure controls/personal protection
Recommended monitoring
procedures
Appropriate engineering
controls
Environmental exposure
controls
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Gloves
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: Chemical splash goggles and face shield.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
: For prolonged or repeated handling, use the following type of gloves:
Recommended: neoprene
May be used: polyvinyl alcohol (PVA), Viton®, butyl rubber, nitrile rubber
Body protection
Other skin protection
Respiratory protection
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
United States
Page: 8/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 9. Physical and chemical properties
Appearance
Physical state
: Liquid.
Color
: Not available.
Odor
Melting point
: Not available.
: Not available.
: Not available.
: Not available.
Boiling point
: >37.78°C (>100°F)
Flash point
: Closed cup: 25°C (77°F)
Material supports
combustion.
: Yes.
Auto-ignition temperature
: Not available.
Decomposition temperature
: Not available.
Flammability (solid, gas)
: Not available.
Lower and upper explosive
(flammable) limits
: Lower: 1.2%
Evaporation rate
: 0.83 (butyl acetate = 1)
Vapor pressure
: 1.2 kPa (8.9 mm Hg) [room temperature]
Vapor density
Relative density
: Not available.
: 0.97
Density ( lbs / gal )
: 8.1
Solubility
: Insoluble in the following materials: cold water.
Partition coefficient: noctanol/water
: Not available.
Viscosity
: Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
Volatility
: 80% (v/v), 71.81% (w/w)
% Solid. (w/w)
: 28.19
Odor threshold
pH
Section 10. Stability and reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.
Incompatible materials
: Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
United States
Page: 9/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 10. Stability and reactivity
Hazardous decomposition
products
: Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
n-butyl acetate
LC50 Inhalation Vapor
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LD50 Oral
LC50 Inhalation Vapor
Rat
Rat
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rat
Rat
>21.1 mg/l
2000 ppm
>17600 mg/kg
10.768 g/kg
24000 mg/m³
8000 ppm
3400 mg/kg
790 mg/kg
6670 ppm
5000 ppm
>1.7 g/kg
4.3 g/kg
2330 mg/kg
6990 mg/m³
4 hours
4 hours
4 hours
4 hours
4 hours
4 hours
4 hours
LD50 Oral
LD50 Dermal
Rat
Rabbit
4.705 g/kg
>5 g/kg
-
LD50 Oral
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
Rat
Rat
Rabbit
Rat
Rat
Rabbit
Rat
8532 mg/kg
6500 mg/m³
2 g/kg
2460 mg/kg
4000 ppm
17.8 g/kg
3.5 g/kg
4 hours
4 hours
-
butan-1-ol
xylene
magnesium fluoride
2-ethoxy-1-methylethyl
acetate
2-methoxy-1-methylethyl
acetate
2-methylpropan-1-ol
ethylbenzene
Conclusion/Summary
Dose
Exposure
: There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Respiratory
Sensitization
: There are no data available on the mixture itself.
: There are no data available on the mixture itself.
: There are no data available on the mixture itself.
Conclusion/Summary
Skin
Respiratory
: There are no data available on the mixture itself.
: There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary
: There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary
: There are no data available on the mixture itself.
United States
Page: 10/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 11. Toxicological information
Classification
Product/ingredient name
OSHA
IARC
NTP
xylene
magnesium fluoride
ethylbenzene
chromium
-
3
3
2B
3
-
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
Reproductive toxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary
: There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name
Category
n-butyl acetate
butan-1-ol
magnesium fluoride
2-ethoxy-1-methylethyl acetate
2-methylpropan-1-ol
Category 3
Category 3
Category 3
Category 3
Category 3
Specific target organ toxicity (repeated exposure)
Name
Category
magnesium fluoride
ethylbenzene
Category 2
Category 2
Target organs
: Contains material which causes damage to the following organs: brain, central nervous
system (CNS), eye, lens or cornea.
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the nervous system, liver, gastrointestinal tract, upper respiratory tract, skin,
bones, ears.
Aspiration hazard
Name
Result
2-ethoxy-1-methylethyl acetate
ethylbenzene
ASPIRATION HAZARD - Category 1
ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Potential acute health effects
Eye contact
Inhalation
Skin contact
Ingestion
: Causes serious eye damage.
: Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
: Causes skin irritation. Defatting to the skin.
: Can cause central nervous system (CNS) depression.
United States
Page: 11/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 11. Toxicological information
Over-exposure signs/symptoms
Eye contact
: Adverse symptoms may include the following:
pain
watering
redness
Inhalation
: Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact
: Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion
: Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary
: There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Short term exposure
Potential immediate
: There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate
: There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
: May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
: Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
United States
Page: 12/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 11. Toxicological information
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route
ATE value
Oral
Dermal
Inhalation (gases)
Inhalation (vapors)
Inhalation (dusts and mists)
6460 mg/kg
12845.2 mg/kg
132122.9 ppm
93.34 mg/l
29.71 mg/l
Section 12. Ecological information
Toxicity
Product/ingredient name
Result
Species
Exposure
2-methoxy-1-methylethyl
acetate
ethylbenzene
Acute LC50 161 mg/l Fresh water
Fish
96 hours
Acute LC50 150 to 200 mg/l Fresh water Fish - Lepomis macrochirus Young of the year
96 hours
Persistence and degradability
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
xylene
ethylbenzene
-
-
Readily
Readily
Product/ingredient name
LogPow
BCF
Potential
n-butyl acetate
butan-1-ol
xylene
2-ethoxy-1-methylethyl
acetate
2-methoxy-1-methylethyl
acetate
2-methylpropan-1-ol
ethylbenzene
1.78
0.88
3.16
0.76
7.4 to 18.5
-
low
low
low
low
0.56
-
low
0.76
3.15
79.43
low
low
Bioaccumulative potential
Mobility in soil
Soil/water partition
coefficient (KOC)
: Not available.
United States
Page: 13/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
DOT
IMDG
IATA
UN number
UN1263
UN1263
UN1263
UN proper shipping
name
PAINT
PAINT
PAINT
Transport hazard class 3
(es)
3
3
Packing group
III
III
Environmental hazards No.
No.
No.
Marine pollutant
substances
Product RQ (lbs)
Not applicable.
Not applicable.
Not applicable.
1980.9
(xylene, n-butyl acetate)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
RQ substances
III
Additional information
DOT
: Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
IMDG
: None identified.
IATA
: None identified.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
United States
Page: 14/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 15. Regulatory information
United States
United States inventory (TSCA 8b) : All components are listed or exempted.
U.S. Federal regulations
SARA 302/304
SARA 304 RQ
:
: Not applicable.
Composition/information on ingredients
No products were found.
SARA 311/312
Classification
: Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
n-butyl acetate
butan-1-ol
xylene
magnesium fluoride
2-ethoxy-1-methylethyl acetate
2-methoxy-1-methylethyl acetate
2-methylpropan-1-ol
aluminium powder (stabilised)
ethylbenzene
chromium
Yes.
Yes.
Yes.
No.
Yes.
Yes.
Yes.
Yes.
Yes.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
Yes.
Yes.
Yes.
Yes.
Yes.
No.
Yes.
No.
Yes.
Yes.
No.
No.
No.
Yes.
No.
No.
No.
No.
Yes.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
-
SARA 313
Supplier notification
Chemical name
: butan-1-ol
xylene
Aluminium powder (stabilized)
ethylbenzene
CAS number
71-36-3
1330-20-7
7429-90-5
100-41-4
Concentration
5 - 10
3-7
0.5 - 1.5
0.1 - 1
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
United States
Page: 15/16
Product code VM4991
Date of issue 25 August 2015
Version 4
Product name MAGENTA TO GOLD
Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health
:
3
*
Flammability :
3
Physical hazards :
0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are
to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Health
:
3
Flammability :
3
Date of previous issue
: 6/6/2015
Organization that prepared
the MSDS
: EHS
Instability
:
0
Key to abbreviations
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
United States
Page: 16/16
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertising