1. Identification of the substance/mixture and of the company/undertaking

1. Identification of the substance/mixture and of the company/undertaking
SAFETY DATA SHEET
LE1175S v2.0
en/CA
1. Identification of the substance/mixture and of the company/undertaking
Product name
Activator 70-80◦ F
Product code
LE1175S
Intended use
Hardener for professional use
Supplier
Axalta Coating Systems Canada Company
408 Fairall Street
CA Ajax, ON L1S 1R6
Manufacturer
Axalta Coating Systems, LLC
Two Commerce Square, 2001 Market Street, Suite 3600
US Philadelphia PA, 19103
Telephone
Product information
Medical emergency
Transportation emergency
Chemical Family
Clearcoat-Solventborne
Formula Date: 2009-08-04
(800) 668-6945
(855) 274-5698
(613) 996-6666 (CANUTEC)
2. Hazards identification
This preparation is hazardous per the following GHS criteria
GHS-Classification
Flammable liquids
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitisation
Target Organ Systemic Toxicant - Single exposure
Category 2
Category 2
Category 2A
Category 1
May cause respiratory irritation.
Endpoints which are “not classified”, “cannot classified” and “not applicable” are not shown.
GHS-Labelling
B12766434
Hazard symbols
Signal word
Warning
Hazard statements
Flammable liquid and vapour.
May cause respiratory irritation.
May cause an allergic skin reaction.
Causes skin irritation.
Causes serious eye irritation.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/ vapours/ spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Contaminated work clothing should not be allowed out of the workplace.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower.
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF exposed or if you feel unwell: Call a POISON CENTER or doctor/ physician.
IF ON SKIN: Wash with plenty of soap and water.
Specific treatment (see supplemental first aid instructions on this label).
If skin irritation or rash occurs: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local regulations.
Other hazards which do not result in classification
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
0%
3. Composition/information on ingredients
Mixture of synthetic resins and solvents
Components
CAS-No.
98-56-6
Chemical Name
4-chlorobenzotrifluoride
Concentration
48 - 59%
28182-81-2
Aliphatic polyisocyanate resin
26 - 37%
53880-05-0
Isophorone diisocyanate homopolymer
4 - 15%
123-86-4
Butyl acetate
1 - 4%
110-12-3
Methyl isoamyl ketone
1 - 4%
1330-20-7
Xylene
1 - 4%
100-41-4
Ethylbenzene
0.5%
Any concentration shown as a range is due to batch variation.
Non-regulated ingredients 0.1 - 1.0%
4. First aid measures
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical
advice.
B12766434
Skin contact
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use
recognized skin cleanser. If skin irritation persists, call a physician.
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2016-02-17
SAFETY DATA SHEET
LE1175S v2.0
en/CA
Inhalation
Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped,
administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a
physician.
Ingestion
If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do NOT induce vomiting.
Keep at rest.
Most Important Symptoms/effects, acute and delayed
Inhalation
May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps:
headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage. Exposure to isocyanates may cause respiratory
sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or
permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates
may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to
isocyanates must not be exposed to vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis. Skin contact my cause skin sensitization.
Indication of Immediate medical attention and special treatment needed if necessary
No data available on the product. See section 3 and 11 for hazardous ingredients found in the product.
5. Firefighting measures
Suitable extinguishing media
Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical
Extinguishing media which shall not be used for safety reasons
High volume water jet
Hazardous combustion products
CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section.
Fire and Explosion Hazards
Flammable liquid. Vapor/air mixture will burn when an ignition source is present.
Special Protective Equipment and Fire Fighting Procedures
Full protective flameproof clothing should be worn as appropriate. Wear self contained breathing apparatus for fire fighting if
necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or
public waterways.
B12766434
6. Accidental release measures
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2016-02-17
SAFETY DATA SHEET
LE1175S v2.0
en/CA
Procedures for cleaning up spills or leaks
Ventilate area. Remove sources of ignition. Do not breathe vapors. Do not get in eyes or on skin. Wear a positive-pressure,
supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination
solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are:
20% Surfactant (Tergitol TM 10) and 80% Water OR 0-10% Ammonia, 2-5% Detergent and Water (balance) Confine and remove with
inert absorbent. Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material
may be sealed and disposed of properly.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers,
lakes or waste water systems.
7. Handling and storage
Precautions for safe handling
Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY
CAUSE FLASH FIRE. Close container after each use. Ground containers when pouring. Do not transfer contents to bottles or
unlabeled containers. Wash thoroughly after handling and before eating or smoking. Do not store above 49 ◦ C (120 ◦ F).
If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation , and gloves. Combustible dust clouds may be created where operations produce fine
material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds.
Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods
(e.g. compressed air) which can generate potentially combustible dust clouds should not be used.
During baking at temperatures above 400◦ C, small amounts of hydrogen fluoride can be evolved; these amounts increase as
temperatures increase. Hydrogen fluoride vapours are very toxic and cause skin and eye irritation. Above 430◦ C an explosive
reaction may occur if finely divided fluorocarbon comes into contact with metal powder (aluminium or magnesium). Operations such
as grinding, buffing or grit blasting may generate such mixtures. Avoid any dust buildup with fluorocarbons and metal mixtures.
Advice on protection against fire and explosion
Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an
ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container:
container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good
housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other
fire hazards.
Storage
Requirements for storage areas and containers
Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking.
Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Advice on common storage
Store separately from oxidizing agents, strongly alkaline and strongly acidic materials, amines, alcohols and water. Precautions
should be taken to avoid exposure to atmospheric humidity or water. Evolution of CO2 in closed containers causes overpressure and
produces a risk of bursting.
Additional information on storage conditions
Precautions should be taken to avoid exposure to atmospheric humidity or water. Humid air and/or water will produce carbon dioxide
which will pressurize the container. Open drum carefully as content may be under pressure.
OSHA/NFPA Storage Classification: IC
8. Exposure controls/personal protection
B12766434
Engineering controls and work practices
Provide adequate ventilation. Air-fed protective respiratory equipment must be worn by spray operator even when good ventilation is
provided.
c Copyright 2016 Axalta Coating Systems Canada Company. All rights reserved.
Copies may be made only for those using Axalta Coating Systems products.
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
National occupational exposure limits
CAS-No.
Chemical Name
Time
Type
Value
8 & 12
hour
TWA
20 ppm
15 min
STEL
200 ppm
8 hr
TWA
150 ppm
OSHA
8 hr
TWA
150 ppm
98-56-6
4-chlorobenzotrifluoride
Source
Dupont
123-86-4
Butyl acetate
ACGIH
110-12-3
Methyl isoamyl ketone
ACGIH
8 hr
TWA
20 ppm
1330-20-7
Xylene
ACGIH
15 min
STEL
150 ppm
8 hr
TWA
100 ppm
OSHA
8 hr
TWA
100 ppm
Dupont
8 & 12
hour
TWA
100 ppm
ACGIH
8 hr
TWA
20 ppm
OSHA
8 hr
TWA
100 ppm
Dupont
8 & 12
hour
TWA
25 ppm
100-41-4
Ethylbenzene
Note
** TWA = Time-weighted average.
STEL = Short term exposure limit.
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
Do not breathe vapors or mists. Wear a positive-pressure, supplied air respirator (NIOSH approved TC-19C), while mixing activator
with paint, during application and until all vapors and spray mists are exhausted. Follow respirator manufacturer s directions for
respirator use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label instructions for
further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates should not use or be
exposed to this product if mixed with isocyanate activators/hardeners.
Eye protection
Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash
guard or side shields.
Skin and body protection
Neoprene gloves and coveralls are recommended.
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
B12766434
Environmental exposure controls
Do not let product enter drains.
c Copyright 2016 Axalta Coating Systems Canada Company. All rights reserved.
Copies may be made only for those using Axalta Coating Systems products.
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
9. Physical and chemical properties
Appearance
Form: liquid
Colour: clear
Flash point
Lower Explosive Limit
Upper Explosive Limit
Evapouration rate
Vapor pressure of principal solvent
Solubility of Solvent In Water
Vapor density of principal solvent (Air = 1)
Approx. Boiling Range
Approx. Freezing Range
Gallon Weight (lbs/gal)
Specific Gravity
Percent Volatile By Volume
Percent Volatile By Weight
Percent Solids By Volume
Percent Solids By Weight
pH (waterborne systems only)
Partition coefficient: n-octanol/water
Ignition temperature
Decomposition temperature
Viscosity (23 ◦ C)
VOC less exempt (g/liter)
VOC as packaged (g/liter)
24 - 38 ◦ C
0.9 %
10.5 %
Slower than Ether
4.6 hPa
partly miscible
6.24
127 ◦ C
Not applicable.
10.04
1.20
58.42%
59.92%
41.58%
40.08%
not applicable
no data available
415 ◦ C
Not applicable.
Not applicable.
199.9
110.7
DIN 51794
ISO 2431-1993
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of
manufacture.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage conditions.
Materials to avoid
Keep away from oxidising agents and strongly acid or alkaline materials. Amines and alcohols cause exothermic reactions. Mixture
reacts slowly with water resulting in evolution of CO2. Evolution of CO2 in closed containers causes overpressure and produces a
risk of bursting.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke,
oxides of nitrogen as well as hydrogen cyanide, amines, alcohols and water. In the event of fire Carbon monoxide, fluorinated
hydrocarbons, hydrogen fluoride, nitrogen oxides may be formed.
Hazardous Polymerization
Will not occur.
B12766434
Sensitivity to Static Discharge
Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product.
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
Sensitivity to Mechanical Impact
None known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps:
headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage. The thermal decomposition vapours of fluorinated
polymers may cause polymer fume fever with flu-like symptoms in humans, especially when smoking contaminated tobacco.
Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like
reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours
after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals
with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
not hazardous
Acute dermal toxicity
not hazardous
Acute inhalation toxicity
not hazardous
% of unknown composition 0 %
Skin corrosion/irritation
4-chlorobenzotrifluoride
Butyl acetate
Methyl isoamyl ketone
Xylene
Category 2
Category 3
Category 3
Category 2
Serious eye damage/eye irritation
4-chlorobenzotrifluoride
Methyl isoamyl ketone
Xylene
Category 2A
Category 2A
Category 2A
B12766434
Respiratory sensitisation
Not classified according to GHS criteria
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
Skin sensitisation
Aliphatic polyisocyanate resin
Isophorone diisocyanate homopolymer
Category 1
Category 1
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Not classified according to GHS criteria
Toxicity for reproduction
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Single exposure
No data available.
Target Organ Systemic Toxicant - Repeated exposure
Not classified according to GHS criteria
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. )
No information available.
Symptoms related to the physical, chemical and toxicological characteristics
Based on the properties of the isocyanate components and considering toxicological data on similar products, the following applies:
This formulation may cause acute irritation and/or sensitization of the respiratory system leading to an asthmatic condition,
wheeziness and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to
atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Exposure to
component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effect
such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of
consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with
the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the
skin. The liquid splashed in the eyes may cause irritation and reversible damage. Components of the product may be absorbed into
the body through the skin.
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
13. Disposal considerations
Provincial Waste Classification
Check appropriate provincial and local waste disposal regulations for proper classifications.
Waste Disposal Method
Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with
Federal, State, Provincial, and local requirements. Do not incinerate in closed containers.
B12766434
14. Transport information
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
International transport regulations
IMDG (Sea transport)
UN number:
Proper shipping name:
1263
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
Marine Pollutant:
3
Not applicable.
III
yes [4-chloro-a,a,a-trifluorotoluene]
ICAO/IATA (Air transport)
UN number:
1263
Proper shipping name:
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
3
Not applicable.
III
TDG
UN number:
Proper shipping name:
1263
PAINT RELATED MATERIAL
Hazard Class:
Subsidiary Hazard Class:
Packing group:
3
Not applicable.
III
Matters needing attention for transportation
Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by
loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with
the relevant statutes and rules.
15. Regulatory information
TSCA Status
In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status
All components of the mixture are listed on the DSL.
OCI Status:
All components of the mixture are listed on the Ontario Inventory of Chemical Substances.
Photochemical Reactivity
Non-photochemically reactive
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
WARNING: This product contains a chemical known to the State of California to cause cancer.
Regulatory information
CAS #
98-56-6
28182-81-2
B12766434
53880-05-0
Ingredient
4-chlorobenzotrifluoride
Aliphatic
polyisocyanate
resin
Isophorone diisocyanate
homopolymer
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
N
NR
NR
C,F,P
N
N
NR
NR
A,C,R
N
N
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NR
NR
A,C,F,N,R
N
CERCLA
RQ(lbs)
NR
NR
NR
CAA
HAP
N
N
N
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SAFETY DATA SHEET
LE1175S v2.0
en/CA
CAS #
123-86-4
110-12-3
1330-20-7
100-41-4
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
N
NR
NR
A,C,F
N
N
NR
NR
C
N
N
NR
NR
A,C,F
Y
N
NR
NR
A,C,F
Y
Ingredient
Butyl acetate
Methyl isoamyl ketone
Xylene
Ethylbenzene
CERCLA
RQ(lbs)
NR
NR
100
1,000
CAA
HAP
N
N
Y
Y
Key:
EPCRA
Emergency Planning and Community Right-to-know Act (aka Title III, SARA)
302
Extremely hazardous substances
311/312 Categories
F = Fire Hazard
R = Reactivity Hazard
P = Pressure Related Hazard
313 Information
Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA
HAP
TPQ
RQ
NA
NR
Comprehensive Emergency Response, Compensation and Liability Act of 1980.
Listed as a Clean Air Act Hazardous Air Pollutant.
Threshold Planning Quantity.
Reportable Quantity
not available
not regulated
A = Acute Hazard
C = Chronic Hazard
16. Other information
HMIS rating
H: 3 F: 3 R: 1
Glossary of Terms:
ACGIH
IARC
NTP
OEL
OSHA
STEL
TWA
PNOR
PNOC
American Conference of Governmental Industrial Hygienists.
International Agency for Research on Cancer.
National Toxicology Program.
Occupational Exposure Limit
Occupational Safety and Health Administration.
Short term exposure limit.
Time-weighted average.
Particles not otherwise regulated.
Particles not otherwise classified.
NOTE: The list (above) of glossary terms may be modified.
Notice from Axalta Coating Systems
The document reflects information provided to Axalta Coating Systems by its suppliers. Information is accurate to the best of our
knowledge and is subject to change as new data is received by Axalta Coating Systems. Persons receiving this information should
make their own determination as to its suitability for their purposes prior to use. The information on this Safety Data Sheet relates
only to the specific material designated herein and does not relate to use in combination with any other material or in any process.
SDS prepared by:
Axalta Coating Systems Regulatory Affairs
Report version
Version
2.0
B12766434
Revision Date:
Changes
2, 3, 4, 8, 11, 14, 15
2016-02-17
c Copyright 2016 Axalta Coating Systems Canada Company. All rights reserved.
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2016-02-17
SAFETY DATA SHEET
LE1175S v2.0
en/CA
B12766434
(800) 668-6945
cromax.ca
c Copyright 2016 Axalta Coating Systems Canada Company. All rights reserved.
Copies may be made only for those using Axalta Coating Systems products.
axalta.ca
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