Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION

Safety Data Sheet Spartan Chemical Company, Inc. 1. PRODUCT AND COMPANY IDENTIFICATION
Safety Data Sheet
Spartan Chemical Company, Inc.
Revision Date: 11-May-2015
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name:
F-6 FLYING INSECT KILLER
Product Number:
Recommended Use:
Uses Advised Against:
6919
Insecticide
For Industrial and Institutional Use Only
Manufacturer/Supplier:
Spartan Chemical Company, Inc.
1110 Spartan Drive
Maumee, Ohio 43537 USA
800-537-8990 (Business hours)
www.spartanchemical.com
24 Hour Emergency Phone Numbers:
Medical Emergency/Information: 888-314-6171
CHEMTREC 800-424-9300
Transportation/Spill/Leak:
2. HAZARDS IDENTIFICATION
GHS Classification
GHS Label Elements
Signal Word:
Hazard Statements:
No signal word
No hazard statements
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated
Precautionary Statements:
Prevention:
Do not spray on an open flame or other ignition source
Pressurized container: Do not pierce or burn, even after use
Intentional misuse by deliberately concentrating and inhaling contents may be harmful or
fatal.
Response:
-Specific Treatment:
See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Storage:
Protect from sunlight. Do not expose to temperatures exceedin
Revision Date: 11-May-2015
6919 - F-6 FLYING INSECT KILLER
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Other Information:
2.04975% of the mixture consists of ingredient(s) of unknown toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
water
propane
N-butane
petroleum distillates
tetramethrin
sumithrin
CAS No
7732-18-5
74-98-6
106-97-8
64742-47-8
7696-12-0
26002-80-2
Weight-%
40-70
7-13
7-13
3-7
0.1-1
0.1-1
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact:
-Skin Contact:
-Inhalation:
-Ingestion:
Note to Physicians:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Wash with soap and water. If skin irritation occurs: Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
poison control center or physician if you feel unwell.
Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Get medical attention if you feel unwell.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Specific Hazards Arising from the
Chemical:
Hazardous Combustion Products:
Water spray (fog), Foam
Extremely flammable aerosol. Exposure to high temperature may cause containers to burst.
Bursting aerosol containers may be propelled from fire at high speed.
May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment and
Precautions for Firefighters:
Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full
protective gear. Water may be used to cool closed containers to prevent pressure build-up
and possible auto ignition or explosion when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Environmental Precautions:
Methods for Clean-Up:
Avoid contact with eyes and skin. Use personal protective equipment as required. Remove
all sources of ignition.
Do not rinse spill onto the ground, into storm sewers or bodies of water.
Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local / national regulations (see Section 13).
7. HANDLING AND STORAGE
Advice on Safe Handling:
Handle in accordance with good industrial hygiene and safety practice. Intentional misuse
by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away
handling.
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NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 C°.
Exposure to high temperature may cause containers to burst. Keep out of the reach of
children.
Storage Conditions:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
.
Occupational Exposure Limits:
Chemical Name
propane
74-98-6
ACGIH TLV
TWA: 1000 ppm
N-butane
106-97-8
TWA: 1000 ppm
OSHA PEL
TWA: 1000 ppm
TWA: 1800 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1800 mg/m3
(vacated) TWA: 800 ppm
(vacated) TWA: 1900 mg/m3
NIOSH
IDLH: 2100 ppm
TWA: 1000 ppm
TWA: 1800 mg/m3
TWA: 800 ppm
TWA: 1900 mg/m3
Provide good general ventilation.
If work practices generate dust, fumes, gas, vapors or mists which expose workers to
chemicals above the occupational exposure limits, local exhaust ventilation or other
engineering controls should be considered.
Engineering Controls:
Personal Protective Equipment
Eye/Face Protection:
Skin and Body Protection:
Respiratory Protection:
Wear splash goggles.
Wear rubber or other chemical-resistant gloves.
Not required with expected use.
If occupational exposure limits are exceeded or respiratory irritation occurs, use of a
NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section
3 should be considered.
Wash hands and any exposed skin thoroughly after handling.
See 29 CFR 1910.132-138 for further guidance.
General Hygiene Considerations:
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State:
Color:
Odor:
pH:
Melting Point / Freezing Point:
Boiling Point / Boiling Range:
Flash Point:
Evaporation Rate:
Flammability (solid, gas)
Upper Flammability Limit:
Lower Flammability Limit:
Vapor Pressure:
Vapor Density:
Specific Gravity:
Solubility(ies):
Partition Coefficient:
Autoignition Temperature:
Decomposition Temperature:
Viscosity:
Aerosol
White emulsion
Mild solvent
6.0-8.0
No information available.
99 °C / 210 °F (Product without propellant)
< -18 °C / < 0 °F (Propellant-estimated)
< 1 (Butyl acetate = 1)
No information available.
No information available.
No information available.
No information available.
No information available.
0.8189
Miscible in water
No information available.
No information available.
No information available.
No information available.
10. STABILITY AND REACTIVITY
Reactivity:
Chemical Stability:
Possibility of Hazardous Reactions:
Conditions to Avoid:
Incompatible Materials:
This material is considered to be non-reactive under normal conditions of use.
Stable under normal conditions.
Not expected to occur with normal handling and storage.
Extremes of temperature and direct sunlight.
Strong oxidizing agents. Strong acids.
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May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.
Hazardous Decomposition
Products:
11. TOXICOLOGICAL INFORMATION
Eyes, Skin, Ingestion, Inhalation.
Likely Routes of Exposure:
Symptoms of Exposure:
-Eye Contact:
-Skin Contact:
-Inhalation:
Pain and redness.
Drying of the skin.
Nasal discomfort and coughing. Intentional misuse by deliberately concentrating and
inhaling contents may be harmful or fatal.
Pain, nausea, vomiting and diarrhea.
-Ingestion:
Immediate, Delayed, Chronic Effects
Product Information:
Data not available or insufficient for classification.
Numerical Measures of Toxicity
The following acute toxicity estimates (ATE) are calculated based on the GHS document.
.
ATEmix (oral):
95238 mg/kg
ATEmix (dermal):
38095 mg/kg
ATEmix (inhalation-gas):
1287108 mg/l
Component Acute Toxicity Information
Chemical Name
water
7732-18-5
propane
74-98-6
N-butane
106-97-8
petroleum distillates
64742-47-8
Oral LD50
> 90 mL/kg ( Rat )
Dermal LD50
Not Available
Inhalation LC50
Not Available
Not Available
Not Available
= 658 mg/L ( Rat ) 4 h
Not Available
Not Available
= 658 mg/L ( Rat ) 4 h
> 5000 mg/kg ( Rat )
> 2000 mg/kg ( Rabbit )
> 5.2 mg/L ( Rat ) 4 h
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name
Algae/Aquatic Plants
Fish
petroleum distillates
64742-47-8
Not Available
45: 96 h Pimephales
promelas mg/L LC50
flow-through 2.2: 96 h
Lepomis macrochirus mg/L
LC50 static 2.4: 96 h
Oncorhynchus mykiss mg/L
LC50 static
Persistence and Degradability:
Bioaccumulation:
No information available.
No information available.
Other Adverse Effects:
No information available.
Toxicity to
Microorganisms
Not Available
Crustacea
4720: 96 h Den-dronereides
heteropoda mg/L LC50
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes:
Contaminated Packaging:
Dispose of in accordance with federal, state and local regulations.
Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with
federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT:
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Revision Date: 11-May-2015
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UN/ID No:
Proper Shipping Name:
Hazard Class:
Special Provisions:
UN1950
Aerosols
2.1
This product meets the exception requirements of section 49 CFR 173.306 as a limited
quantity and may be shipped as a limited quantity.
Shipping descriptions may vary based on mode of transport, quantities, package size,
and/or origin and destination. Check with a trained hazardous materials transportation
expert for information specific to your situation.
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)
All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313
This product does not contain listed substances above the "de minimus" level
SARA 311/312 Hazard Categories
Acute Health Hazard:
Chronic Health Hazard:
Fire Hazard:
Sudden release of pressure hazard:
Reactive Hazard:
Yes
No
No
No
No
California Proposition 65
This product does not contain any Proposition 65 chemicals
EPA Pesticide Registration Number: 706-83-5741
EPA Statement:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the
pesticide label:
EPA Pesticide Label:
Caution. Harmful if swallowed or absorbed through the skin. Avoid contact with skin, eyes or clothing. Thoroughly wash hands with soap and water
after handling and before eating, drinking, chewing gum using tobacco or using the toilet.
16. OTHER INFORMATION
Revision Date:
Reasons for Revision:
11-May-2015
No information available.
Disclaimer:
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
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