485 - Reclaim W SDS English (Canada)

485 - Reclaim W SDS English (Canada)
Material Safety Data Sheet
Reclaim W White Linen
1. Product and company identification
Product name
: Reclaim W White Linen
Supplier
Synonym
: Betco Corporation
1001 Brown Avenue
Toledo, OH 43607
www.betco.com
888-462-3826
: Not available.
Trade name
: Not available.
Material uses
: Special: Laundry aids
Manufacturer
: Betco Corporation
1001 Brown Avenue
Toledo, Ohio 43607
www.betco.com
888-462-3826
Code
: 485
MSDS #
: 485
Validation date
: 4/2/2015.
Print date
: 4/2/2015.
In case of emergency
: Chemtrec (800) 424-9300
Product type
: Powder.
2. Hazards identification
Emergency overview
Physical state
: Solid. [Powder.]
Color
: White.
Odor
: Not available.
Signal word
: DANGER!
Hazard statements
: CORROSIVE. . CAUSES BURNS. . CAUSES EYE AND SKIN IRRITATION. MAY BE
HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET
ORGAN DAMAGE, BASED ON ANIMAL DATA.
: Do not breathe dust. Do not ingest. Do not eat, drink or smoke when using this product.
Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
: Dermal contact. Eye contact. Inhalation. Ingestion.
Precautionary measures
Routes of entry
Potential acute health effects
Inhalation
Ingestion
: Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs. Exposure to decomposition products
may cause a health hazard. Serious effects may be delayed following exposure.
: Harmful if swallowed.
Skin
: Severely irritating to the skin.
Eyes
: Severely irritating to eyes. Risk of serious damage to eyes.
Potential chronic health effects
Chronic effects
Carcinogenicity
: Contains material that may cause target organ damage, based on animal data.
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
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2. Hazards identification
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Target organs
: Contains material which may cause damage to the following organs: lungs, upper
respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, stomach.
Over-exposure signs/symptoms
Inhalation
Ingestion
Skin
Eyes
Medical conditions
aggravated by overexposure
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
: Not determined.
: Adverse symptoms may include the following:
irritation
redness
: Adverse symptoms may include the following:
pain or irritation
watering
redness
: Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
See toxicological information (Section 11)
3. Composition/information on ingredients
Name
CAS number
%
sodium hydroxide
sodium carbonate
troclosene sodium, dihydrate
1310-73-2
497-19-8
51580-86-0
20 - 40
20 - 40
10 - 20
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
Notes to physician
4/2/2015.
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
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5. Fire-fighting measures
Flammability of the product
: Fine dust clouds may form explosive mixtures with air.
Extinguishing media
Suitable
: Use dry chemical powder.
Not suitable
: Do not use water jet.
Special exposure hazards
Hazardous thermal
decomposition products
Special protective
equipment for fire-fighters
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
metal oxide/oxides
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on fire
hazards
: Not available.
Special remarks on
explosion hazards
: Not available.
6. Accidental release measures
Personal precautions
Environmental precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment (see Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill
Large spill
: Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid dust generation. Do not dry sweep. Place spilled material in a designated,
labeled waste container. Vacuum dust with equipment fitted with a HEPA filter and
place in a closed, labeled waste container. Dispose of via a licensed waste disposal
contractor.
: Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Avoid creating dusty conditions and prevent wind
dispersal. Prevent entry into sewers, water courses, basements or confined areas.
Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a
HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed
waste disposal contractor. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
7. Handling and storage
Handling
4/2/2015.
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Avoid
the creation of dust when handling and avoid all possible sources of ignition (spark or
flame). Prevent dust accumulation. Use only with adequate ventilation. Wear
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7. Handling and storage
appropriate respirator when ventilation is inadequate. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not
in use. Electrical equipment and lighting should be protected to appropriate standards
to prevent dust coming into contact with hot surfaces, sparks or other ignition sources.
Empty containers retain product residue and can be hazardous. Do not reuse container.
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Storage
8. Exposure controls/personal protection
Occupational exposure limits
TWA (8 hours)
STEL (15 mins)
Ceiling
Ingredient
List name
ppm
mg/m³ Other
ppm
ppm
mg/m³ Other
sodium hydroxide
US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
-
-
-
-
2
2
2
2
-
-
mg/m³ Other
2
-
-
Notations
[3]
[3]Skin sensitization
Consult local authorities for acceptable exposure limits.
Recommended monitoring
procedures
Engineering measures
Hygiene measures
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Respiratory
Hands
4/2/2015.
: Use a properly fitted, particulate filter respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough
time): butyl rubber
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8. Exposure controls/personal protection
Eyes
Skin
Environmental exposure
controls
Other protection
Personal protective
equipment (Pictograms)
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles. If
operating conditions cause high dust concentrations to be produced, use dust goggles.
Recommended: safety glasses
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
: Not available.
:
9. Physical and chemical properties
Physical state
: Solid. [Powder.]
Flash point
Burning time
Burning rate
: Closed cup: Not applicable. [Product does not sustain combustion.]
: Not available.
: Not available.
Auto-ignition temperature
: Not available.
Flammable limits
: Not available.
Color
: White.
Odor
: Not available.
Taste
: Not available.
Molecular weight
: Not applicable.
Molecular formula
: Not applicable.
pH
Boiling/condensation point
Melting/freezing point
: Not applicable.
: Not available.
: Not available.
Critical temperature
: Not available.
Relative density
: Not applicable.
Vapor pressure
: Not available.
Vapor density
: Not available.
Volatility
: Not available.
Odor threshold
: Not available.
Evaporation rate
: Not available.
SADT
Viscosity
Ionicity (in water)
: Not available.
: Not available.
: Not available.
Dispersibility properties
: Easily dispersible in the following materials: cold water and hot water.
Solubility
: Easily soluble in the following materials: cold water and hot water.
Physical/chemical
properties comments
: Not available.
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10. Stability and reactivity
Chemical stability
: The product is stable.
Conditions to avoid
: Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Take precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during transfer by grounding and
bonding containers and equipment before transferring material. Prevent dust
accumulation.
: Reactive or incompatible with the following materials:
oxidizing materials
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Incompatible materials
Hazardous decomposition
products
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
troclosene sodium, dihydrate
LD50 Dermal
LD50 Oral
LD50 Oral
Rat
Rat
Rat
>5000 mg/kg
1671 mg/kg
4090 mg/kg
-
sodium carbonate
Conclusion/Summary
: Not available.
Chronic toxicity
Not available.
Conclusion/Summary
: Not available.
Irritation/Corrosion
Product/ingredient name
Result
Species
Score Exposure
Observation
sodium hydroxide
Eyes - Severe irritant
Monkey
-
-
Eyes - Mild irritant
Rabbit
-
Eyes - Severe irritant
Rabbit
-
Eyes - Severe irritant
Eyes - Severe irritant
Rabbit
Rabbit
-
Skin - Mild irritant
Human
-
Skin - Severe irritant
Rabbit
-
Eyes - Severe irritant
Skin - Mild irritant
Eyes - Mild irritant
Rabbit
Rabbit
Rabbit
-
Eyes - Moderate irritant
Rabbit
-
Eyes - Severe irritant
Skin - Mild irritant
Rabbit
Rabbit
-
troclosene sodium, dihydrate
sodium carbonate
Conclusion/Summary
24 hours 1
Percent
400
Micrograms
24 hours 50
Micrograms
1 Percent
0.5 minutes 1
milligrams
24 hours 2
Percent
24 hours 500
milligrams
0.5 Grams
0.5 Grams
0.5 minutes
100
milligrams
24 hours 100
milligrams
50 milligrams
24 hours 500
milligrams
-
: Not available.
Sensitizer
Not available.
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11. Toxicological information
Conclusion/Summary
: Not available.
Carcinogenicity
Not available.
Conclusion/Summary
: Not available.
Classification
Not available.
Mutagenicity
Not available.
Conclusion/Summary
: Not available.
Teratogenicity
Not available.
Conclusion/Summary
: Not available.
Reproductive toxicity
Not available.
Conclusion/Summary
Synergistic products
: Not available.
: Not available.
12. Ecological information
Ecotoxicity
: No known significant effects or critical hazards.
Aquatic ecotoxicity
Product/ingredient name
Result
Species
Exposure
sodium hydroxide
Acute EC50 40.38 mg/l Fresh water
Crustaceans - Ceriodaphnia
dubia - Neonate
Fish - Gambusia affinis - Adult
Fish - Poecilia reticulata - Young
Daphnia - Daphnia magna
Fish - Oncorhynchus mykiss
Algae - Navicula seminulum
Crustaceans - Amphipoda
Daphnia - Daphnia magna
Fish - Lepomis macrochirus
48 hours
troclosene sodium, dihydrate
sodium carbonate
Conclusion/Summary
Acute LC50 125 ppm Fresh water
Chronic NOEC 56 mg/l Marine water
Acute EC50 0.28 ppm Fresh water
Acute LC50 0.24 ppm Fresh water
Acute EC50 242000 µg/l Fresh water
Acute LC50 176000 µg/l Fresh water
Acute LC50 265000 µg/l Fresh water
Acute LC50 300000 µg/l Fresh water
96 hours
96 hours
48 hours
96 hours
96 hours
48 hours
48 hours
96 hours
: Not available.
Persistence/degradability
Not available.
Conclusion/Summary
: Not available.
Partition coefficient: noctanol/water
: Not available.
Bioconcentration factor
: Not available.
Mobility
: Not available.
Toxicity of the products of
biodegradation
Other adverse effects
: Not available.
4/2/2015.
: No known significant effects or critical hazards.
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13. Disposal considerations
Waste disposal
Waste stream
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: Not available.
RCRA classification
: Not available.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
PG* Label
Additional
information
DOT Classification
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide)
RQ (sodium
hydroxide)
8
II
Reportable quantity
2915.5 lbs / 1323.6 kg
Package sizes
shipped in quantities
less than the product
reportable quantity are
not subject to the RQ
(reportable quantity)
transportation
requirements.
Limited quantity
Yes.
TDG Classification
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide)
8
II
Explosive Limit and
Limited Quantity
Index
1
Mexico
Classification
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide)
8
II
-
ADR/RID Class
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide)
8
II
The environmentally
hazardous substance
mark is not required
when transported in
sizes of ≤5 L or ≤5 kg.
Tunnel code
(E)
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14. Transport information
IMDG Class
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide).
Marine pollutant
(troclosene sodium,
dihydrate)
8
II
The marine pollutant
mark is not required
when transported in
sizes of ≤5 L or ≤5 kg.
IATA-DGR Class
1759
CORROSIVE
SOLIDS, N.O.S.
(sodium hydroxide)
8
II
The environmentally
hazardous substance
mark may appear if
required by other
transportation
regulations.
PG* : Packing group
15. Regulatory information
United States inventory
(TSCA 8b)
: All components are listed or exempted.
WHMIS (Canada)
: Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class E: Corrosive material
Canadian lists
Canadian NPRI
: None of the components are listed.
CEPA Toxic substances
: None of the components are listed.
Canada inventory
: All components are listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists
Chemical Weapons
Convention List Schedule
I Chemicals
: Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Taiwan inventory (CSNN): All components are listed or exempted.
: Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
III Chemicals
: Not listed
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16. Other information
Label requirements
Hazardous Material
Information System (U.S.A.)
: CORROSIVE. . CAUSES BURNS. . CAUSES EYE AND SKIN IRRITATION. MAY BE
HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET
ORGAN DAMAGE, BASED ON ANIMAL DATA.
:
*
Health
2
Flammability
0
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
References
: Not available.
Other special
considerations
: Not available.
Date of printing
: 4/2/2015.
Date of issue
Date of previous issue
: 4/2/2015.
Version
: 1
Prepared by
: Not available.
: 12/10/2014.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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