1. Identification of the substance/mixture and of the company/undertaking

1. Identification of the substance/mixture and of the company/undertaking
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
1. Identification of the substance/mixture and of the company/undertaking
Product name
AR500 BAP WHITE
Product code
FFW607S7
Formula Date: 2015-02-20
Intended use
Coating powder for professional use
Powder application by electrostatic spraying
Axalta Powder Coating Systems USA, Inc.
9800 Genard Rd
US Houston, TX 77041
Telephone
Product information
Medical emergency
Transportation emergency
(800) 438-3876
(855) 274-5698
(800) 424-9300 (CHEMTREC)
2. Hazards identification
This preparation is hazardous per the following GHS criteria
GHS-Classification
Target Organ Systemic Toxicant - Repeated exposure
Category 1
Endpoints which are “”not classified“”, “”cannot classified“” and “”not applicable“” are not shown
GHS-Labelling
Hazard symbols
Signal word
Danger
Hazard statements
Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Do not eat, drink or smoke when using this product.
Get medical advice/ attention if you feel unwell.
Dispose of contents/container in accordance with local regulations.
Other hazards which do not result in classification
Contains isocyanates. See information supplied by the manufacturer.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
64.2 %
3. Composition/information on ingredients
Mixture of synthetic resins and pigments
Components
CAS-No.
63843-89-0
Chemical Name
Hindered amine light stabilizer
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
Concentration
1 - 4%
1-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
CAS-No.
Chemical Name
Concentration
137658-79-8
Uv absorber hydroxyphenyl triazine
1 - 4%
100-41-4
Ethylbenzene
0.2%
Non-regulated ingredients 90 - 100%
OSHA Hazardous: Yes
4. First aid measures
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical
advice.
Skin contact
Do NOT use solvents or thinners. Take off contaminated clothing and shoes immediately. Wash skin thoroughly with soap and water
or use recognized skin cleanser. If skin irritation persists, call a physician.
Inhalation
Avoid breathing dust. Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough. Move to
fresh air. If breathing is irregular or stopped, administer artificial respiration. If symptoms persist, call a physician.
Ingestion
If swallowed, seek medical advice immediately and show this container or label.
Most Important Symptoms/effects, acute and delayed
Inhalation
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
Dust generated from this product may cause irritation of the eyes. Repeated or prolonged contact may cause skin irritation with
discomfort and dermatitis.
Indication of Immediate medical attention and special treatment needed if necessary
No data available on the product. See section 3 and 11 for hazardous ingredients found in the product.
5. Firefighting measures
Suitable extinguishing media
Water sprayDry chemical
Extinguishing media which shall not be used for safety reasons
High volume water jet
Hazardous combustion products
CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section.
Fire and Explosion Hazards
The product is not flammable. The product itself does not burn.
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
2-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
Special Protective Equipment and Fire Fighting Procedures
Full protective flameproof clothing should be worn as appropriate. Wear self contained breathing apparatus for fire fighting if
necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or
public waterways.
6. Accidental release measures
Procedures for cleaning up spills or leaks
Sweep up material and dispose of properly. Avoid breathing any dust that might be generated. Spills of fine material should be
cleaned using gentle sweeping or vacuuming. Cleaning methods (e.g. compressed air) which can generate potentially combustible
dust clouds should not be used.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers,
lakes or waste water systems.
7. Handling and storage
Precautions for safe handling
Observe label precautions. Close container after each use. Do not transfer contents to unlabeled containers. Wash thoroughly after
handling and before eating or smoking. Precautions should be taken to prevent the formation of dusts in concentrations above
flammable, explosive or occupational exposure limits. Keep away from open flames, hot surfaces and sources of ignition. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or
other ignition sources.
If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations produce fine
material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds.
Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods
(e.g. compressed air) which can generate potentially combustible dust clouds should not be used.
Advice on protection against fire and explosion
Always keep in containers of same material as the original one. Airborne dusts are potentially explosive. Avoid formation of
significant deposits of material as they may become airborne and form combustible dust clouds. Handling and processing operations
should be conducted in accordance with best practices (e.g.NFPA-654). Never use pressure to empty container: container is not a
pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards
and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards.
Storage
Requirements for storage areas and containers
Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking.
Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Advice on common storage
Store separately from oxidizing agents and strongly alkaline and strongly acidic materials.
8. Exposure controls/personal protection
Engineering controls and work practices
Do not breathe dust. Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasibleby the use of a local exhaust ventilation. If these are not sufficient to maintain exposure to dusts below the OEL, suitable respiratory
protection must be worn.
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
3-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
CAS-No.
Chemical Name
Time
Type
Value
Note
Note
Source
National occupational exposure limits
CAS-No.
100-41-4
Chemical Name
Ethylbenzene
Time
Type
Value
Source
ACGIH
8 hr
TWA
20 ppm
OSHA
8 hr
TWA
100 ppm
Dupont
8 & 12
hour
TWA
25 ppm
** TWA = Time-weighted average.
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
Should any dust be generated, it should not be breathed. If a respirator is needed to meet applicable exposure limits, wear a properly
fitted air-purifying respirator approved by NIOSH. Follow respirator manufacturer s directions for respirator use.
Do not breathe
dust. If respirator is required to meet applicable exposure limits, use a NIOSH approved TC-84A respirator in accordance with
regulatory requirements (in the US follow OSHA standard 29CFR1910.134) and the respirator manufacturer’s directions.
Eye protection
Desirable in all industrial situations.
Skin and body protection
Gloves are recommended
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
Environmental exposure controls
Do not let product enter drains. For ecological information, refer to Ecological Information Section 12.
9. Physical and chemical properties
Appearance
Form: solid
Colour: white
Flash point
Lower Explosive Limit
Upper Explosive Limit
Evapouration rate
Vapor pressure of principal solvent
Water solubility
Vapor density of principal solvent (Air = 1)
Approx. Boiling Range
Approx. Freezing Range
Gallon Weight (lbs/gal)
Specific Gravity
Percent Volatile By Volume
Percent Volatile By Weight
Not applicable.
Not applicable.
Not applicable.
not applicable
0.1 hPa
nil
Not applicable.
Not applicable.
Not applicable.
13.51
1.62
1.28%
0.82%
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
4-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
Percent Solids By Volume
Percent Solids By Weight
pH (waterborne systems only)
Partition coefficient: n-octanol/water
Ignition temperature
Decomposition temperature
Viscosity (23 C)
VOC* less exempt (lbs/gal)
VOC* as packaged (lbs/gal)
98.72%
99.18%
not applicable
no data available
290 C
Not applicable.
Not applicable.
0.1
0.1
DIN 51794
ISO 2431-1993
Does not sustain combustion.
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of
manufacture.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage conditions.
Materials to avoid
None reasonably foreseeable.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke,
oxides of nitrogen.
Hazardous Polymerization
Will not occur.
Sensitivity to Static Discharge
no data available
Sensitivity to Mechanical Impact
None known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
Dust generated from this product may cause irritation of the eyes. Repeated or prolonged contact may cause skin irritation with
discomfort and dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
5-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
Acute oral toxicity
not hazardous
Acute dermal toxicity
Not classified according to GHS criteria
Acute inhalation toxicity
Not classified according to GHS criteria
% of unknown composition 64.2 %
Skin corrosion/irritation
Not classified according to GHS criteria
Serious eye damage/eye irritation
Not classified according to GHS criteria
Respiratory sensitisation
Not classified according to GHS criteria
Skin sensitisation
Not classified according to GHS criteria
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Not classified according to GHS criteria
Toxicity for reproduction
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Single exposure
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Repeated exposure
Skin Absorption
Spleen Hindered amine light stabilizer
thymus Hindered amine light stabilizer
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. )
No information available.
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
6-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
Symptoms related to the physical, chemical and toxicological characteristics
Based on the properties of the isocyanate components and considering toxicological data on similar products, the following applies:
This formulation may cause acute irritation and/or sensitization of the respiratory system leading to an asthmatic condition,
wheeziness and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to
atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Symptoms and
signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through
skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with the preparation may
cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid
splashed in the eyes may cause irritation and reversible damage.
Whether the hazardous chemical is listed by NTP, IARC or OSHA
Titanium dioxide
Ethylbenzene
IARC 2B
IARC 2B
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
13. Disposal considerations
Waste Disposal Method
Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with
Federal, State, Provincial, and local requirements. Do not incinerate in closed containers.
14. Transport information
Not classified as dangerous in the meaning of transport regulations.
Matters needing attention for transportation
Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by
loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with
the relevant statutes and rules.
15. Regulatory information
TSCA Status
In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status
Product is not DSL listed because one or more ingredients are not on the DSL inventory.
Photochemical Reactivity
Photochemically reactive
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
WARNING! This product contains a chemical known to the State of California to cause cancer.
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
7-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
CAS #
Ingredient
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
CERCLA
RQ(lbs)
CAA
HAP
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
N
NR
NR
C
N
CERCLA
RQ(lbs)
NR
CAA
HAP
N
Regulatory information
CAS #
63843-89-0
137658-79-8
100-41-4
Ingredient
Hindered amine light stabilizer
Uv absorber hydroxyphenyl
triazine
Ethylbenzene
N
NR
NR
NA
N
NA
N
N
NR
NR
A,C,F
Y
1,000
Y
Key:
EPCRA
Emergency Planning and Community Right-to-know Act (aka Title III, SARA)
302
Extremely hazardous substances
311/312 Categories
F = Fire Hazard
R = Reactivity Hazard
P = Pressure Related Hazard
313 Information
Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA
HAP
TPQ
RQ
NA
NR
Comprehensive Emergency Response, Compensation and Liability Act of 1980.
Listed as a Clean Air Act Hazardous Air Pollutant.
Threshold Planning Quantity.
Reportable Quantity
not available
not regulated
A = Acute Hazard
C = Chronic Hazard
16. Other information
HMIS rating
H: 2 F: 0 R: 1
Glossary of Terms:
ACGIH
IARC
NTP
OEL
OSHA
STEL
TWA
PNOR
PNOC
American Conference of Governmental Industrial Hygienists.
International Agency for Research on Cancer.
National Toxicology Program.
Occupational Exposure Limit
Occupational Safety and Health Administration.
Short term exposure limit.
Time-weighted average.
Particles not otherwise regulated.
Particles not otherwise classified.
NOTE: The list (above) of glossary terms may be modified.
Notice from Axalta Coating Systems
The document reflects information provided to Axalta Coating Systems by its suppliers. Information is accurate to the best of our
knowledge and is subject to change as new data is received by Axalta Coating Systems. Persons receiving this information should
make their own determination as to its suitability for their purposes prior to use. The information on this Safety Data Sheet relates
only to the specific material designated herein and does not relate to use in combination with any other material or in any process.
SDS prepared by:
Axalta Coating Systems Regulatory Affairs
Report version
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
8-9
2015-05-13
SAFETY DATA SHEET
FFW607S7 v2.0
en/US
Version
2.0
Revision Date:
Changes
2, 3, 4, 5, 6, 7, 8, 9, 11, 14, 15
2015-05-13
axalta.us
FFW607S7
c 2015 Axalta Coating Systems, LLC and all affiliates. All rights reserved.
Copies
may be made only for those using Axalta Coating Systems products.
9-9
2015-05-13
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