MBC03CF - Metajuls Basecoats (MBC Series)

MBC03CF - Metajuls Basecoats (MBC Series)
The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID:
MBC03CF
Product Name:
Product Use:
Print date
Revision Date
COARSE BLACK DIAMOND SHIMRIN METALLIC
Paint product.
29/Sep/2005
27/Sep/2005
Company Identification
The Valspar Corporation
210 CROSBY
PICAYUNE, MS 39466
Manufacturer's Phone:
1-601-798-4731
24-Hour Medical Emergency
Phone:
1-888-345-5732
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
BUTYL ACETATE
123-86-4
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
Approx. Chemical name
Weight %
40 - 45
ACETIC ACID, BUTYL ESTER
30 - 35
Xylenes (o-, m-, p- isomers)
5 - 10
Ethyl benzene
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache,
nausea or respiratory irritation.
Eye Contact:
May cause moderate eye irritation.
Skin Contact:
May cause moderate skin irritation.
Product ID: MBC03CF
Page 1 of 7
Acute Ingestion:
None known
Other Effects:
May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be
harmful or fatal. May cause redness and blistering of skin.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never
give anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical
attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
Hazardous combustion products:
45º F ( 7º C) TCC/PM
1%
8%
Not available. º F ( º C)
No.
Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
See Section 10.
Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.
6. ACCIDENTAL RELEASE MEASURES
Product ID: MBC03CF
Page 2 of 7
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5,
"Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition.
Remove with inert absorbent and non sparking tools. Avoid all personal contact.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees
F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with
OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue,
including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must
be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above
the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing
or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected
equipment are properly bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Gloves: Neoprene or other nonporous. To prevent skin contact wear protective clothing covering all exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an
air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature
to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's
instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
BUTYL ACETATE
123-86-4
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
Approx. TWA (final)
Weight %
40 - 45
710 mg/m3 150 ppm
30 - 35
435 mg/m3 100 ppm
5 - 10
435 mg/m3 100 ppm
ACGIH Threshold Limit Value (TLV's)
Product ID: MBC03CF
Page 3 of 7
Ceilings limits (final)
Skin designations
Common Name
CAS-No.
BUTYL ACETATE
123-86-4
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
Approx. TWA
Weight %
40 - 45
150 ppm
STEL
30 - 35
100 ppm
150 ppm
5 - 10
100 ppm
125 ppm
Ceiling limits
Skin
designations
200 ppm
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):
Specific Gravity
Evaporation rate (butyl acetate = 1.0):
Normal for this product type.
Liquid
Not determined.
10 mmHG @ 68º F ( 20º C)
4
259º F ( 126º C)
Insoluble.
Not determined.
7.8
.93
1.1
10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:
Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.
Sensitivity to static discharge:
Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Mutagens:
Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient
evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
CAS-No.
ETHYLBENZENE
100-41-4
Approx. IARC Group 1 - Human IARC Group 2A - limited IARC Group 2b Weight % Evidence
human data
sufficient animal data
5 - 10
Monograph 77, 2000
Product ID: MBC03CF
Page 4 of 7
Common Name
CAS-No.
ETHYLBENZENE
100-41-4
Approx. NTP Known
Weight % carcinogens
5 - 10
NTP Suspect
carcinogens
NTP Evidence of
carcinogenicity
male rat-clear evidence;
female rat-some
evidence; male micesome evidence; female
mice-some evidence
Common Name
CAS-No.
ETHYLBENZENE
100-41-4
Approx. OSHA Select
Weight % carcinogens
5 - 10
OSHA Possible select
carcinogens
ACGIH Carcinogens
Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.
If this section is blank, no information is available.
12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
II
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
II
International Maritime Organization:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
II
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Product ID: MBC03CF
Page 5 of 7
Common Name
CAS-No.
XYLENE
1330-20-7
Approx. SARA 302
Weight %
30 - 35
ETHYLBENZENE
100-41-4
5 - 10
SARA 311/312 Hazard Class:
Acute:
Chronic:
Flammability:
Reactivity:
Sudden Pressure:
SARA 313
CERCLA RQ IN LBS.
form R reporting required 100
for 1.0% de minimis
concentration
form R reporting required 1000
for 1.0% de minimis
concentration
Yes
Yes
Yes
No
No
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
BUTYL ACETATE
XYLENE
ETHYLBENZENE
123-86-4
1330-20-7
100-41-4
Additional Non-Hazardous Materials
PROPRIETARY INERT
PROPRIETARY RESIN
PROPRIETARY RESIN
Trade Secret
Trade Secret
Trade Secret
California Proposition 65:
WARNING: This product contains a chemical known to the State of California to cause cancer.
Rule 66 status of product
Photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:
All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.
Canada Domestic Substances List:
All components of this product are listed on the Domestic
Substances List.
16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:
2
3
1
X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer,
NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management
District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International
Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established,
N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams
per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per
thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time
Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit.
Product ID: MBC03CF
Page 6 of 7
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance,
this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this
information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES,
EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT.
VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only
remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at
our option. This MSDS contains additional information required by the state of Pennsylvania.
Product ID: MBC03CF
Page 7 of 7
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertising