SAFETY DATA SHEET

SAFETY DATA SHEET
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
Print Date: 01/07/2016
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC Complete
Recommended use of the chemical and restrictions on use
Identified uses: A urethane adhesive -COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number:
800-258-2436
[email protected]
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Gases under pressure - Liquefied gas
Acute toxicity - Category 4 - Inhalation
Skin irritation - Category 2
Eye irritation - Category 2B
Respiratory sensitisation - Category 1
Skin sensitisation - Category 1
Effects on or via lactation
Specific target organ toxicity - single exposure - Category 3
Specific target organ toxicity - repeated exposure - Category 2 - Inhalation
Label elements
Hazard pictograms
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated
company of Dow
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
Signal word: DANGER!
Hazards
Contains gas under pressure; may explode if heated.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
May cause harm to breast-fed children.
May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Avoid contact during pregnancy/ while nursing.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves.
In case of inadequate ventilation wear respiratory protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor/ physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
Water Reactive
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Construction and composite applications
This product is a mixture.
Component
CASRN
Concentration
Polymethylenepolyphenylisocyanate,
propoxylated glycerin polymer
57029-46-6
>= 30.0 - <= 60.0 %
Polymethylenepolyphenyl polyisocyanate,
polypropyleneglycol copolymer
53862-89-8
>= 5.0 - <= 10.0 %
Diphenylmethane Diisocyanate, isomers and
homologues
9016-87-9
>= 15.0 - <= 40.0 %
4,4' -Methylenediphenyl diisocyanate
101-68-8
>= 10.0 - <= 30.0 %
1,1,1,2-Tetrafluoroethane
811-97-2
>= 10.0 - <= 30.0 %
Paraffin waxes and Hydrocarbon waxes,
chlorinated
63449-39-8
>= 5.0 - <= 10.0 %
Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.
Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Excessive exposure may aggravate preexisting asthma and other respiratory
disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). Maintain adequate
ventilation and oxygenation of the patient. May cause asthma-like (reactive airways) symptoms.
Bronchodilators, expectorants, antitussives and corticosteroids may be of help. May cause respiratory
sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of
help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen fluoride.
Hydrogen halides. Carbon dioxide.
Unusual Fire and Explosion Hazards: Some components of this product will burn in a fire situation.
Container may vent and/or rupture due to fire. Vaporizes quickly at room temperature. Dense smoke
is produced when product burns.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Do not use direct water stream.
May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned
hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising
sound from venting safety device or discoloration of the container. Move container from fire area if this
is possible without hazard. Use water spray to cool fire-exposed containers and fire-affected zone
until fire is out.
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas.
Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate area of leak or spill. If
available, use foam to smother or suppress. Confined space entry procedures must be followed
before entering the area. Refer to section 7, Handling, for additional precautionary measures. See
Section 10 for more specific information. Use appropriate safety equipment. For additional
information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Vermiculite. Sand. Clay. Do NOT use absorbent materials such
as: Cement powder (Note: may generate heat). Collect in suitable and properly labeled open
containers. Do not place in sealed containers. Suitable containers include: Metal drums. Plastic
drums. Polylined fiber pacs. Wash the spill site with large quantities of water. Attempt to neutralize
by adding suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%; liquid detergent
0.2 - 2%; water to make up to 100%, OR Formulation 2: concentrated ammonia solution 3 - 8%; liquid
detergent 0.2 - 2%; water to make up to 100%. If ammonia is used, use good ventilation to prevent
vapor exposure. Contact your supplier for clean-up assistance. See Section 13, Disposal
Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes, skin, and clothing. Avoid prolonged or
repeated contact with skin. Wash thoroughly after handling. Do not swallow. Avoid breathing vapor.
Use with adequate ventilation. Keep container tightly closed. Contents under pressure. Do not
puncture or incinerate container. Do not enter confined spaces unless adequately ventilated. See
Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Store in a dry place. Protect from atmospheric moisture. Maintain a
nitrogen atmosphere. Do not store product contaminated with water to prevent potential hazardous
reaction. Avoid temperatures above 50°C (122°F) See Section 10 for more specific information.
Additional storage and handling information on this product may be obtained by calling your sales or
customer service contact.
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Storage stability
Storage temperature:
20 - 30 °C (68 - 86 °F)
Issue Date: 01/04/2016
Storage Period:
12 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure limits are listed below, if they exist.
Component
4,4' -Methylenediphenyl
diisocyanate
1,1,1,2-Tetrafluoroethane
Regulation
ACGIH
OSHA Z-1
NIOSH REL
NIOSH REL
US WEEL
Type of listing
TWA
Value/Notation
0.005 ppm
C
0.2 mg/m3 0.02 ppm
TWA 0.05 mg/m3 0.005 ppm
C
0.2 mg/m3 0.02 ppm
TWA
1,000 ppm
Exposure controls
Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Chlorinated polyethylene. Neoprene.
Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl chloride ("PVC" or
"vinyl"). Viton. Examples of acceptable glove barrier materials include: Butyl rubber.
Nitrile/butadiene rubber ("nitrile" or "NBR"). NOTICE: The selection of a specific glove
for a particular application and duration of use in a workplace should also take into
account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure
guideline. When atmospheric levels may exceed the exposure guideline, use an approved airpurifying respirator equipped with an organic vapor sorbent and a particle filter. For situations
where the atmospheric levels may exceed the level for which an air-purifying respirator is
effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing
apparatus). For emergency response or for situations where the atmospheric level is
unknown, use an approved positive-pressure self-contained breathing apparatus or positivepressure air line with auxiliary self-contained air supply.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state
Color
Odor
Odor Threshold
pH
Melting point/range
Freezing point
Boiling point (760 mmHg)
Flash point
Evaporation Rate (Butyl Acetate
= 1)
Flammability (solid, gas)
Lower explosion limit
Upper explosion limit
Vapor Pressure
Relative Vapor Density (air = 1)
Relative Density (water = 1)
Water solubility
Partition coefficient: noctanol/water
Auto-ignition temperature
Decomposition temperature
Kinematic Viscosity
Explosive properties
Oxidizing properties
Molecular weight
Foam
Black
Very slight
No test data available
Not applicable
No test data available
No test data available
No test data available
closed cup Not applicable
No test data available
No data available
No test data available
No test data available
2,100 kPa at 55 °C (131 °F) Calculated.
No test data available
1.169 at 25 °C (77 °F) Calculated.
No test data available
No data available
No test data available
No test data available
Not applicable
Not explosive
No
No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Unstable at elevated temperatures.
Possibility of hazardous reactions: Can occur. Elevated temperatures can cause hazardous
polymerization.
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
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Conditions to avoid: Avoid temperatures above 50°C (122°F) Elevated temperatures can cause
container to vent and/or rupture. Exposure to elevated temperatures can cause product to
decompose.
Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal
compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many
materials to release heat. The reaction rate increases with temperature as well as with increased
contact; these reactions can become violent. Contact is increased by stirring or if the other material
acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and
will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a
layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Toxic gases are released during decomposition.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. Observations in animals include: Gastrointestinal irritation.
As product: Single dose oral LD50 has not been determined.
LD50, Rat, > 2,000 mg/kg Estimated.
Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
LD50, Rabbit, > 2,000 mg/kg Estimated.
Acute inhalation toxicity
In confined or poorly ventilated areas, vapor can easily accumulate and can cause
unconsciousness and death due to displacement of oxygen. Excessive exposure may cause
irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema
(fluid in the lungs.) Effects may be delayed. Symptoms of excessive exposure may be
anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive
exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular
heartbeats). Decreased lung function has been associated with overexposure to isocyanates.
As product: The LC50 has not been determined.
Skin corrosion/irritation
Prolonged contact may cause moderate skin irritation with local redness.
Material may stick to skin causing irritation upon removal.
May stain skin.
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Serious eye damage/eye irritation
May cause eye irritation.
May cause slight temporary corneal injury.
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.
Contains component(s) which have been reported to cause effects on the following organs in animals:
Kidney.
Liver.
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Teratogenicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother.
Contains component(s) which did not cause birth defects in animals; other fetal effects occurred only
at doses toxic to the mother.
Reproductive toxicity
Based on information for component(s): May cause harm to breastfed babies.
Mutagenicity
In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI
are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative.
Animal mutagenicity studies were predominantly negative. For the component(s) tested: 1,1,1,2tetrafluoroethane Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
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COMPONENTS INFLUENCING TOXICOLOGY:
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer
Acute inhalation toxicity
The LC50 has not been determined.
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
Acute inhalation toxicity
The LC50 has not been determined.
Diphenylmethane Diisocyanate, isomers and homologues
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l
For similar material(s): 2,4'-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4
Hour, Aerosol, 0.31 mg/l
For similar material(s): 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1
Hour, Aerosol, 2.24 mg/l
4,4' -Methylenediphenyl diisocyanate
Acute inhalation toxicity
LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l
1,1,1,2-Tetrafluoroethane
Acute inhalation toxicity
LC50, Rat, 4 Hour, vapour, > 1,500 mg/l
Paraffin waxes and Hydrocarbon waxes, chlorinated
Acute inhalation toxicity
The LC50 has not been determined.
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer
Acute toxicity to fish
For this family of materials:
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
Diphenylmethane Diisocyanate, isomers and homologues
Acute toxicity to fish
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
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Issue Date: 01/04/2016
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
4,4' -Methylenediphenyl diisocyanate
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
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Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
1,1,1,2-Tetrafluoroethane
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, 450 mg/l
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 980 mg/l
Toxicity to bacteria
EC50, Pseudomonas putida, static test, 6 Hour, Growth inhibition, > 730 mg/l
Paraffin waxes and Hydrocarbon waxes, chlorinated
Acute toxicity to fish
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 0.1 mg/l
Persistence and degradability
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer
Biodegradability: For this family of materials: Material is readily biodegradable. Passes
OECD test(s) for ready biodegradability.
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
Biodegradability: Expected to degrade slowly in the environment.
Diphenylmethane Diisocyanate, isomers and homologues
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
4,4' -Methylenediphenyl diisocyanate
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
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Issue Date: 01/04/2016
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
1,1,1,2-Tetrafluoroethane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 4 %
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Theoretical Oxygen Demand: 0.47 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 1,700 d
Method: Estimated.
Paraffin waxes and Hydrocarbon waxes, chlorinated
Biodegradability: Expected to degrade slowly in the environment.
Theoretical Oxygen Demand: 2.89 mg/mg
Bioaccumulative potential
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer
Bioaccumulation: No relevant data found.
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
Bioaccumulation: In the aquatic and terrestrial environment, movement is expected to be
limited by its reaction with water forming predominantly insoluble polyureas.
Diphenylmethane Diisocyanate, isomers and homologues
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
4,4' -Methylenediphenyl diisocyanate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
1,1,1,2-Tetrafluoroethane
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 1.68 Estimated.
Paraffin waxes and Hydrocarbon waxes, chlorinated
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater
than 7).
Partition coefficient: n-octanol/water(log Pow): 7.4 Estimated.
Mobility in soil
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer
No relevant data found.
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Diphenylmethane Diisocyanate, isomers and homologues
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
4,4' -Methylenediphenyl diisocyanate
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
1,1,1,2-Tetrafluoroethane
Potential for mobility in soil is high (Koc between 50 and 150).
Partition coefficient(Koc): 97 Estimated.
Paraffin waxes and Hydrocarbon waxes, chlorinated
Expected to be relatively immobile in soil (Koc > 5000).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient(Koc): > 5000 Estimated.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Proper shipping name
UN number
Class
Packing group
Reportable Quantity
Issue Date: 01/04/2016
Chemical under pressure, n.o.s.(1,1,1,2-Tetrafluoroethane,
Paraffin waxes and Hydrocarbon waxes, chlorinated)
UN 3500
2.2
MDI
Classification for SEA transport (IMO-IMDG):
Proper shipping name
CHEMICAL UNDER PRESSURE, N.O.S.(1,1,1,2Tetrafluoroethane, Paraffin waxes and Hydrocarbon waxes,
chlorinated)
UN number
UN 3500
Class
2.2
Packing group
Marine pollutant
Paraffin waxes and Hydrocarbon waxes, chlorinated
Transport in bulk
Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):
Proper shipping name
Chemical under pressure, n.o.s.(1,1,1,2-Tetrafluoroethane,
Paraffin waxes and Hydrocarbon waxes, chlorinated)
UN number
UN 3500
Class
2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard
Chronic Health Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard
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Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Components
CASRN
4,4' -Methylenediphenyl diisocyanate
101-68-8
Diphenylmethane Diisocyanate, isomers and homologues
9016-87-9
Pennsylvania Worker and Community Right-To-Know Act:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Revision
Identification Number: 101222699 / A001 / Issue Date: 01/04/2016 / Version: 5.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH
C
NIOSH REL
OSHA Z-1
TWA
US WEEL
USA. ACGIH Threshold Limit Values (TLV)
Ceiling
USA. NIOSH Recommended Exposure Limits
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
8-hour, time-weighted average
USA. Workplace Environmental Exposure Levels (WEEL)
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
Page 16 of 17
Product name: TILE BOND™ Roof Tile Adhesive 23lb HFC
Complete
Issue Date: 01/04/2016
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturerspecific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
Page 17 of 17
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