0030132 01

0030132 01
Safety Data Sheet
Issue Date: 07/31/15
Revision Date: 07/31/15
Version 1.0
1. IDENTIFICATION
Product Identifier
Product Name:
SSS Mint Bowl Cleaner
Other means of identification
Product Code:
13003
Recommended use of the chemical and restrictions on use
Recommended Use:
Acid Toilet Bowl Cleaner Disinfectant
Details of the supplier of the safety data sheet
Manufactured for
Triple S
2 Executive Park Drive
Billerica, MA 01862
www.triple-s.com
Telephone Number
Company Phone Number 1-978-667-7900
Emergency Telephone (24 hr) 1-888-779-1339
2. HAZARDS IDENTIFICATION
GHS Classification
Corrosive to metals
:
Category 1
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Specific target organ toxicity single exposure
:
Category 3 (Respiratory system)
GHS Label element
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
:
Prevention:
P234 Keep only in original container.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray
P264 W ash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 W ear eye protection/ face protection.
P280 W ear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
Page 1 (9)
Safety Data Sheet
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER or
doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P390 Absorb spillage to prevent material damage.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P406 Store in corrosive resistant stainless steel container with a
resistant inner liner.
Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Ha z a rd o u s c o mp o n e n ts
Chemical Name
Quaternary ammonium compounds, di-C8-10alkyldimethyl, chlorides
Quaternary ammonium compounds, benzyl-C1216-alkyldimethyl, chlorides
W ater
Hydrogen chloride
Nonyl phenol ethoxylate
CAS-No.
68424-95-3
Concentration (%)
0.50
68424-85-1
0.30
7732-18-5
7647-01-0
9016-45-9
90.00 - 100.00
10.00
1.00 - 5.00
SECTION 4. FIRST AID MEASURES
If inhaled
:
Move to fresh air.
If breathing is irregular or stopped, administer artificial respiration.
Give oxygen.
First aider needs to protect himself.
Call a physician immediately.
In case of skin contact
:
Take off all contaminated clothing immediately.
After contact with skin, wash immediately with plenty of soap and
water.
Call a physician immediately.
:
W ater spray
Dry powder
Foam
SECTION 5. FIREFIGHTING
MEASURES
Suitable extinguishing media
Page 2 (9)
Safety Data Sheet
Specific hazards during
firefighting
Further information
:
Heating or fire can release toxic gas.
:
Use water spray to cool unopened
containers.
Special protective
equipment for firefighters
:
In the event of fire, wear selfcontained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MESAURES
Personal precautions,
protective equipment and
emergency proce- dures
:
Use respirator when
performing operations
involving potential exposure
to vapour of the product.
General advice
:
Do not flush into surface
water or sanitary sewer
system.
Methods and
materials for
containment and
cleaning up
:
Contain spillage, and then
collect with non-combustible
absorbent material, (e.g.
sand, earth, diatomaceous
earth, vermiculite) and place
in container for disposal
according to local / national
regulations (see section 13).
Environmental precautions
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
:
Avoid contact with skin and eyes.
Provide sufficient air exchange and/or exhaust in work rooms.
Conditions for safe storage
:
Keep container tightly closed and dry.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components
CAS-No.
Hydrogen chloride
7647-01-0
Value type
(Form of
exposure)
Ceil_Time
Control parameters / Permissible concentration
2 ppm
5 ppm
7 mg/m3
5 ppm
7 mg/m3
Basis
ACGIH
NIOSH/GUIDE
OSHA_TRANS
Page 5 (9)
Safety Data Sheet
TLV-C
5 ppm
7 mg/m3
2 ppm
Z1A
CAD ON OEL
Appropriate engineering controls
Personal protective equipment
Respiratory protection
:
In the case of vapour formation use a respirator with an approved
filter.
Remarks
:
W ear suitable gloves. Take note of the information given by the
producer concerning permeability and break through times, and of
special workplace conditions (mechanical strain, duration of contact).
Eye protection
:
Tightly fitting safety goggles
Face-shield
Skin and body protection
:
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Rubber or plastic apron
Rubber or plastic boots
Hygiene measures
:
W ash hands before breaks and immediately after handling the
product.
Avoid contact with skin, eyes and clothing.
Remove and wash contaminated clothing and gloves, including
the inside, before re-use.
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
:
liquid
Colour
:
green
Odour
:
mint
Odour Threshold
:
no data available
pH
:
<1
Melting point/freezing point
:
no data available
Boiling point/boiling range
:
no data available
Flash point
:
no data available
Evaporation rate
:
no data available
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Vapour pressure
:
no data available
Relative vapour density
:
no data available
Relative density
:
no data available
Page 6 (9)
Safety Data Sheet
Density
:
1.04 g/cm3 (25 °C)
Solubility(ies)
Water solubility
:
soluble
:
no data available
Partition coefficient: noctanol/water
Auto-ignition temperature
:
no data available
Decomposition temperature
:
no data available
Viscosity, dynamic
:
no data available
Viscosity, kinematic
:
no data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
:
Stable under recommended storage conditions.
Possibility of hazardous reactions
:
None known.Stable
Conditions to avoid
:
None known.
Incompatible materials
:
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure: Eyes Skin Ingestion Inhalation
Skin corrosion/irritation
Skin irritation
:
Remarks: Causes skin burns. Information given is based on data
obtained from similar substances.
:
Remarks: Severe eye irritation
Information given is based on data obtained from similar substances.
Serious eye damage/eye irritation
Eye irritation
Page 7 (9)
Safety Data Sheet
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Components:
Hydrogen chloride
Partition coefficient: n- octanol/water: log Pow: .025
Mobility in soil
no data available
Other adverse effects
Additional ecological information
:
There is no data available for this product.
SECTION 13. DISPOSAL CONSIDER ATIONS
Disposal methods
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
IATA
UN number
Proper shipping name
Transport hazard class
Packing group
Labels
Environmental hazards
1903
Liquid, corrosive, n.o.s.
(Hydrogen chloride solution)
8
III
8
: no
IMDG
UN number
Proper shipping name
Transport hazard class
Packing group
Labels
EmS Number 1
EmS Number 2
Environmental hazards
ADR
1903
Liquid, corrosive, n.o.s.
(Hydrogen chloride solution)
: 8
III
8
F-A
S-B
: Marine pollutant: no
Safety Data Sheet
UN number
Proper shipping name
1903
LIQUID, CORROSIVE, N.O.S.
Transport hazard class
Packing group
Hazard Identification Number
Labels
(Hydrogen chloride solution)
8
III Classification Code C9
80
8
Page 8 (9)
RID
UN number
Proper shipping name
1903
LIQUID, CORROSIVE, N.O.S.
(Hydrogen chloride solution)
8
III
C9
80
: 1903
8
noquid, corrosive n.o.s. (Hydrogen
: L
chloride solution)
8
III
8
: 153
Transport hazard class
Packing group
Classification Code
Hazard Identification Number
UN number
Labels
En
rdes
P
rovpireornsm
he
ipnptianlghanzaam
DOT
Transport hazard class
Packing group
Labels
Emergency Response Guidebook
Number
Environmental hazards
: no
TDG
UN number
Proper shipping name
1903
DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(Hydrogen chloride solution)
8
III
8
no
Transport hazard class
Packing group
Labels
Environmental hazards
Special precautions for user
: none
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC
Code
: Not applicable
SECTION 15. REGULATORY INFORMATION
Signal word
Hazard statements
:
:
DANGER!
Causes substantial but temporary eye injury.
Harmful if absorbed through skin.
Corrosive. Causes skin burns.
Corrosive. Causes irreversible eye damage.
EPCRA - Emergency Planning and Community Right-to-Know Act
Page 9 (9)
Safety Data Sheet
CERCL A Reportable Quantity
Components
CAS-No.
Hydrogen chloride
7647-01-0
SARA 311/312 Hazards
:
Component RQ
(lbs)
5000
Calculated
product RQ
(lbs)
50000
Acute Health Hazard
Page 9 (9)
Safety Data Sheet
SARA 302
Hydrogen chloride
Hydrogen chloride
7647-01-0
10 %
7647-01-0
10 %
US State Regulations
Massachusetts Right To Know
Pennsylvania Right To Know
New Jersey Right To Know
Hydrogen chloride
7647-01-0
Hydrogen chloride
7647-01-0
Hydrogen chloride
7647-01-0
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or
any other reproductive harm
SECTION 16. OTHER INFORMATION
HMIS
Revision Date:
Revision Note:
Health Hazards
3
Flammability
0
Physical Hazards
0
Personal Protection
B = Goggles, gloves
31-July-2015
New format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Page 10
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