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37.0.1
Page 1/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Revision: 21.08.2014
1 Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Trade name: EpoFix Resin 1 Litre
· Article number: AGB8790R
· Relevant identified uses of the substance or mixture and uses advised against
For embedding and impregnation of materialographic specimens.
· Application of the substance / the preparation: No further information available.
· Details of the supplier of the safety data sheet
· Supplier.
Agar Scientific
Elektron Technology UK Ltd
Parsonage Lane
Stansted CM24 8GF
United Kingdom [email protected]
Tel: +44 (0) 1279 813 519
· Further information obtainable from: Technical Support
· Emergency telephone number: 24 hours: +44 (0)1856 407333
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2
Eye Irrit. 2
Skin Sens. 1
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS07 GHS09
· Signal word Warning
· Hazard-determining components of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
700) oxirane, mono[(C12-14-alkyloxy)methyl] derivs
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
(Contd. on page 2)
GB
37.0.1
Page 2/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
(Contd. of page 1)
· Precautionary statements
P101
P102
P103
P261
P280
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321
P362
P501
Specific treatment (see on this label).
Take off contaminated clothing and wash before reuse.
Dispose of contents/container in accordance with local/regional/national/ international regulations.
· Hazard description:
Human health: Irritating and may cause redness, itching and small vesicles. Risk of sensitisation to epoxy compounds. Irritating to eyes.
Environment: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures The product contains: epoxy resin.
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
CAS: 68609-97-2
EINECS: 271-846-8 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight 700)
Aquatic Chronic 2, H411;
H319; Skin Sens. 1, H317
Skin Irrit. 2, H315; Eye Irrit. 2, oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Skin Irrit. 2, H315; Skin Sens. 1, H317
60-90%
10-40%
4 First aid measures
· Description of first aid measures
· After inhalation:
Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and bring these instructions.
· After skin contact:
Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and bring these instructions.
· After eye contact:
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Continue flushing during transport to hospital. Bring these instructions.
· After swallowing:
Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. Do not induce vomiting.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
See section 11 for more detailed information on health effects and symptoms.
(Contd. on page 3)
GB
37.0.1
Page 3/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
(Contd. of page 2)
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: Extinguish with foam, carbon dioxide, dry powder or water fog.
· Special hazards arising from the substance or mixture
When heated and in case of fire, irritating vapours/gases may be formed.
· Advice for firefighters
· Protective equipment:
Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
· Environmental precautions: Avoid discharge into drains, water courses or onto the ground.
· Methods and material for containment and cleaning up:
Absorb spillage with suitable absorbent material.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Safe handling advice: Observe good chemical hygiene practices. Avoid contact with skin and eyes.
Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site.
Technical measures: Work practice should minimise contact. Technical aids: Use disposable equipment (rags, brushes, spatulas, putty knives, etc.), if possible.
Technical precautions: First-aid equipment, including eye wash bottle, must be available at the work site.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in closed original container in a dry place.
· Information about storage in one common storage facility: Avoid contact with oxidising agents.
· Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
(Contd. on page 4)
GB
37.0.1
Page 4/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
(Contd. of page 3)
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
Mix and prepare in a place with efficient exhaust ventilation. An eye wash bottle must be available at the work site.
· Personal protective equipment:
· General protective and hygienic measures:
Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment.
Remove contaminated clothing and wash the skin thoroughly with soap and water after work. When using do not eat, drink or smoke.
· Respiratory protection:
In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment. Use respiratory equipment with gas filter, type K.
· Protection of hands:
Protective gloves
Use disposable gloves protecting against epoxy along with cotton gloves closest to the skin.
Laminate (PE/EVOH) gloves are recommended. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
Face shield.
· Body protection: Risk of contact: Wear apron or protective clothing in case of splashes.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Colour:
· Odour:
· Odour threshold:
Liquid
Clear yellowish
Odourless
Not determined.
· pH-value: Not determined.
(Contd. on page 5)
GB
37.0.1
Page 5/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
(Contd. of page 4)
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
· Flash point:
· Flammability (solid, gaseous):
· Ignition temperature:
Undetermined.
> 34 °C
177 °C
Not applicable.
Decomposition temperature:
· Self-igniting:
· Danger of explosion:
· Explosion limits:
Lower:
Upper:
· Vapour pressure:
Not determined.
Product is not selfigniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
· Density:
· Relative density
· Vapour density
· Evaporation rate
Not determined.
1.1
Not determined.
Not determined.
· Solubility in / Miscibility with water: <1 %
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Kinematic:
· Solvent content:
Organic solvents:
· Other information
Not determined.
Not determined.
Not determined.
0.0 %
No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
Stable under normal temperature conditions.
Curing time: 12 hours
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No data
· Conditions to avoid Heating, moisture.
· Incompatible materials:
Water, Amines. Strong oxidising substances, strong acids and strong bases.
· Hazardous decomposition products:
When heated and in case of fire, irritating vapours/gases may be formed.
11 Toxicological information
· Information on toxicological effects
Inhalation: Not relevant at normal room temperatures. When heated, irritating vapours may be formed.
Ingestion: Irritating. May cause nausea, stomach pain and vomiting.
(Contd. on page 6)
GB
37.0.1
Page 6/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
(Contd. of page 5)
· Acute toxicity:
· Primary irritant effect:
· on the skin:
Irritating and may cause redness, itching and small vesicles. Risk of sensitisation to epoxy compounds.
· on the eye: Irritating and may cause redness and pain.
· Sensitization: Risk of sensitisation to epoxy compounds.
12 Ecological information
· Toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability This product is expected to be not readily biodegradable.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Dispose of waste and residues in accordance with local authority requirements. Waste is classified as hazardous waste.
Note that fully cured material is not considered as hazardous waste.
Waste from residues: EWC-code: 16 05 08
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA
· UN proper shipping name
· ADR
UN3082
3 0 8 2 E N V I R O N M E N T A L L Y H A Z A R D O U S
SUBSTANCE, LIQUID, N.O.S.
(Contd. on page 7)
GB
37.0.1
Page 7/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
· IMDG
· IATA
· Transport hazard class(es)
· ADR, IMDG, IATA
Revision: 21.08.2014
(Contd. of page 6)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S., MARINE POLLUTANT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
· Class 9 Miscellaneous dangerous substances and articles.
· Packing group
· ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant:
· Special marking (ADR):
· Special marking (IATA):
Yes
Symbol (fish and tree)
Symbol (fish and tree)
Symbol (fish and tree)
· Special precautions for user
· Danger code (Kemler):
· EMS Number:
Warning: Miscellaneous dangerous substances and articles.
90
F-A,S-F
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ)
· UN "Model Regulation":
5L
U N3 08 2, ENVIR ON M EN T ALL Y HAZARD OU S
SUBSTANCE, LIQUID, N.O.S., 9, III
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December
2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council
Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council
Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006 with amendments.
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No.
716).
The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.
The Management of Health and Safety at Work Regulations 1999 (SI 1999 No. 3242), with amendments. The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No. 895).
(Contd. on page 8)
GB
37.0.1
Page 8/8
Safety data sheet according to 1907/2006/EC, Article 31
Printing date 21.08.2014
Trade name: EpoFix Resin 1 Litre
Revision: 21.08.2014
(Contd. of page 7)
· National regulations:
· Other regulations, limitations and prohibitive regulations
As a general rule, persons under 18 years of age are not allowed to work with this product. Users must be carefully instructed in the proper work procedure, the dangerous properties of the product and the necessary safety instructions.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge and should assist the user with the safe handling of this material when properly applied. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing MSDS: Sales department
· Contact: [email protected]
Tel: +44 (0) 1279 813 519
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
GB
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