10 ppm NITRIC OXIDE / N2

10 ppm NITRIC OXIDE / N2
B
C
Page : 1
MATERIAL SAFETY DATA SHEET
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
Warning
Revised edition no : 3
50026A
«
M
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name
SDS Nr
: 0-199ppm NITRIC OXIDE in NITROGEN
: 50026A
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
: Industrial and professional. Perform risk assessment prior to use.
Test gas / Calibration gas. Laboratory use Contact supplier for more uses information
1.3. Details of the supplier of the safety data sheet
Company identification
: Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road
Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
1.4. Emergency telephone number
Emergency telephone number
: 1800 812 588
SECTION 2. Hazards identification
2.1. Classification of the substance or mixture
Hazard Class and Category Code Regulation EC 1272/2008 (CLP)
• Physical hazards
: Gases under pressure - Compressed gas - Warning - (CLP : Press. Gas) - H280
Classification EC 67/548 or EC 1999/45
: Not classified as dangerous substance/mixture.
2.2. Label elements
Labelling Regulation EC 1272/2008 (CLP)
• Hazard pictograms
• Hazard pictograms code
• Signal word
• Hazard statements
• Precautionary statements
- Storage
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M
: GHS04
: Warning
: H280 - Contains gas under pressure; may explode if heated.
: P403 - Store in a well-ventilated place.
2.3. Other hazards
: Asphyxiant in high concentrations.
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
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Page : 2
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 3. Composition/information on ingredients
3.1. Substance / 3.2. Mixture
Mixture.
Substance name
Nitrogen
:
Contents
balance
CAS No
7727-37-9
EC No
231-783-9
Annex No
-----
*1
Not classified (DSD/DPD)
---------------------------------Press. Gas (H280)
Classification
Nitric oxide
:
< 0.02 %
10102-43-9
233-271-0
-----
*2
O; R8
T+; R26
C; R34
---------------------------------Acute Tox. 1 (H330)
Ox. Gas 1 (H270)
Skin Corr. 1B (H314)
EUH071
Press. Gas (H280)
Contains no other components or impurities which will influence the classification of the product.
* 1: Listed in Annex IV / V REACH, exempted from registration.
* 2: Registration deadline not expired.
* 3: Registration not required: Substance manufactured or imported < 1t/y
Full text of R-phrases see chapter 16. Full text of H-statements see chapter 16
SECTION 4. First aid measures
4.1. Description of first aid measures
- Inhalation
- Skin contact
- Eye contact
- Ingestion
: Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
: Adverse effects not expected from this product.
: Adverse effects not expected from this product.
: Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
: In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/
consciousness. Victim may not be aware of asphyxiation.
Refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
: None.
SECTION 5. Fire-fighting measures
5.1. Extinguishing media
- Suitable extinguishing media
: All known extinguishants can be used.
5.2. Special hazards arising from the substance or mixture
Specific hazards
Hazardous combustion products
: Exposure to fire may cause containers to rupture/explode.
: None.
5.3. Advice for fire-fighters
Specific methods
Special protective equipment for fire
fighters
: Coordinate fire measure to the surrounding fire. Cool endangered containers with water spray
jet from a protected position. Do not empty contaminated fire water into drains.
If possible, stop flow of product.
: In confined space use self-contained breathing apparatus.
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
C
Page : 3
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
: Evacuate area.
Try to stop release.
Ensure adequate air ventilation.
Wear self-contained breathing apparatus when entering area unless atmosphere is proved to
be safe.
Monitor concentration of released product.
6.2. Environmental precautions
: Try to stop release.
6.3. Methods and material for containment and cleaning up
: Ventilate area.
6.4. Reference to other sections
: See also sections 8 and 13.
SECTION 7. Handling and storage
7.1. Precautions for safe handling
Safe use of the product
Safe handling of the gas receptacle
: Use only properly specified equipment which is suitable for this product, its supply pressure
and temperature. Contact your gas supplier if in doubt.
Only experienced and properly instructed persons should handle gases under pressure.
The product must be handled in accordance with good industrial hygiene and safety
procedures.
Do not smoke while handling product.
Ensure the complete gas system was (or is regularily) checked for leaks before use.
: Refer to supplier's container handling instructions.
Do not allow backfeed into the container.
Protect cylinders from physical damage; do not drag, roll, slide or drop.
When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.)
designed to transport cylinders.
Leave valve protection caps in place until the container has been secured against either a wall
or bench or placed in a container stand and is ready for use.
If user experiences any difficulty operating cylinder valve discontinue use and contact
supplier.
Never attempt to repair or modify container valves or safety relief devices.
Damaged valves should be reported immediately to the supplier.
Keep container valve outlets clean and free from contaminates particularly oil and water.
Replace valve outlet caps or plugs and container caps where supplied as soon as container is
disconnected from equipment.
Close container valve after each use and when empty, even if still connected to equipment.
Never attempt to transfer gases from one cylinder/container to another.
Never use direct flame or electrical heating devices to raise the pressure of a container.
Do not remove or deface labels provided by the supplier for the identification of the cylinder
contents.
7.2. Conditions for safe storage, including any incompatibilities
: Keep away from combustible materials.
Keep container below 50°C in a well ventilated plac e.
Observe all regulations and local requirements regarding storage of containers.
Containers should not be stored in conditions likely to encourage corrosion.
Containers should be stored in the vertical position and properly secured to prevent toppling.
Stored containers should be periodically checked for general condition and leakage.
Container valve guards or caps should be in place.
Store containers in location free from fire risk and away from sources of heat and ignition.
7.3. Specific end use(s)
: None.
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
C
Page : 4
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 8. Exposure controls/personal protection
8.1. Control parameters
Occupational Exposure Limits
Nitric oxide
DNEL: Derived no effect level
PNEC: Predicted no effect
concentration
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
TLV© -TWA [ppm] : 25
LTEL - UK [ppm] : 25
STEL - UK [ppm] : 35
VME - France [mg/m³] : 30
VME - France [ppm] : 25
MAK (AU) Tagesmittelwert (ml/m³) : 25
MAK (AU) Tagesmittelwert (mg/m³) : 30
VLA-ED - Spain [ppm] : 25
VLA-ED - Spain [mg/m3] : 31
NGV - [ppm] : 25
NGV - [mg/m³] : 30
KTV - [ppm] : 50
KTV - [mg/m³] : 50
Grænserværdier (DK) (ppm) : 0.25
Grænserværdier (DK) (ppm) : 25
HTP-värden (FI) - 8 H - [ppm] : 3
HTP-värden (FI) - 8 H - [mg/m³] : 5.7
HTP-värden - 15min - [ppm] : 6
Grænserværdier (DK) : 30
HTP-värden - 15min - [mg/m³] : 11
GV Value Limit (Norway) [ppm] : 25
GV Value Limit (Norway) [mg/m³] : 30
8-Hour TWA (PL) (NDS) (mg/m³) : 3.5
15-Minute STEL (PL)(NDSCh) (mg/m³) : 7
TLV-TWA (Belgium) (ppm) : 25
None available.
None available.
8.2. Exposure controls
: Oxygen detectors should be used when asphixiating gases may be released.
Provide adequate general and local exhaust ventilation.
Ensure exposure is below occupational exposure limits (where available).
Systems under pressure shoud be regularily checked for leakages.
Consider work permit system e.g. for maintenance activities.
8.2.2. Individual protection measures, : A risk assessment should be conducted and documented in each work area to assess the
risks related to the use of the product and to select the PPE that matches the relevant risk.
e.g. personal protective equipment
The following recommendations should be considered.
Wear safety glasses with side shields
Wear leather safety gloves and safety shoes when handling cylinders.
: Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
8.2.3. Environmental exposure
specific methods for waste gas treatment.
controls
8.2.1. Appropriate engineering
controls
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
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Page : 5
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
- Physical state at 20°C / 101.3kPa
- Colour
Odour
Odour threshold
pH value
Molar mass [g/mol]
Melting point [°C]
Boiling point [°C]
Flash point [°C]
Evaporation rate (ether=1)
Flammability range [vol% in air]
Vapour pressure [20°C]
Relative density, gas (air=1)
Solubility in water [mg/l]
Partition coefficient n-octanol/water
Viscosity at 20°C [mPa.s]
Explosive Properties
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Gas.
Colourless gas.
Barely perceptible.
Odour threshold is subjective and inadequate to warn for overexposure.
Not applicable for gases and gas-mixtures.
Not applicable for gas-mixtures.
Not applicable for gas-mixtures.
Not applicable for gases and gas-mixtures.
Not flammable.
Not applicable for gas-mixtures.
Non flammable.
Not applicable.
Lighter or similar to air.
Not known, but considered to have low solubility.
Not applicable for gas-mixtures.
Not applicable.
Not applicable.
9.2. Other information
Other data
: None.
SECTION 10. Stability and reactivity
10.1. Reactivity
: No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
: Stable under normal conditions.
10.3. Possibility of hazardous reactions
: None.
10.4. Conditions to avoid
: None.
10.5. Incompatible materials
: None.
10.6. Hazardous decomposition products
: Under normal conditions of storage and use, hazardous decomposition products should not
be produced.
SECTION 11. Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Rat inhalation LC50 [ppm/4h]
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitisation
:
:
:
:
:
No known toxicological effects from this product.
• Nitric oxide : 57.5
No known effects from this product.
No known effects from this product.
No known effects from this product.
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
C
Page : 6
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 11. Toxicological information (continued)
Carcinogenicity
Germ cell mutagenicity
Toxic for reproduction : Fertility
Toxic for reproduction : unborn child
STOT-single exposure
STOT-repeated exposure
Aspiration hazard
:
:
:
:
:
:
:
No known effects from this product.
No known effects from this product.
No known effects from this product.
No known effects from this product.
No known effects from this product.
No known effects from this product.
Not applicable for gases and gas-mixtures.
SECTION 12. Ecological information
12.1. Toxicity
: No data available.
12.2. Persistence - degradability
: No data available.
12.3. Bioaccumulative potential
: No data available.
12.4. Mobility in soil
: No data available.
12.5. Results of PBT and vPvB assessment
: No data available.
12.6. Other adverse effects
Effect on ozone layer
Effect on the global warming
: None.
: No known ecological damage caused by this product.
SECTION 13. Disposal considerations
13.1. Waste treatment methods
: Ensure that the emission levels from local regulations or operating permits are not exceeded.
Do not discharge into any place where its accumulation could be dangerous.
Refer to the code of practice of EIGA (Doc. 30/10 “Disposal of Gases, downloadable at http://
www.eiga.org) for more guidance on suitable disposal methods
Contact supplier if guidance is required.
13.2. Additional information
: None.
SECTION 14. Transport information
UN number
Labelling ADR, IMDG, IATA
: 1956
n
ó
: 2.2 : Non flammable, non toxic gas.
Land transport (ADR/RID)
H.I. nr
UN proper shipping name
: 20
: COMPRESSED GAS, N.O.S. (Nitrogen)
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
C
Page : 7
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 14. Transport information (continued)
Transport hazard class(es)
Classification code
Packing Instruction(s)
Tunnel Restriction
HAZCHEM - Emergency Action Code
:
:
:
:
:
2
1A
P200
E : Passage forbidden through tunnels of category E.
2TE
2 = Fine water spray.
T = Recommended personal protective equipment : Full fire kit and breathing apparatus.
Appropriate measures : dilute.
E = There may be a public safety hazard outside the immediate area of the incident, and that
the following actions should be considered :
1. People should be warned to stay indoors with all doors and windows closed, preferably in
rooms upstairs and facing away from the incident. Ignition sources should be eliminated and
any ventilation stopped.
2. Effects may spread beyond the immediate vicinity. all non-essential personnel should be
instructed to move at least 250 metres away from the incident.
3. Police and fire brigade incident commanders should consult each other and with a product
expert, or with a source of product expertise.
4. The possible need for subsequent evacuation should be considered, but it should be
remembered that in most cases it will be safer to remain in a building than to evacuate.
:
:
:
:
:
COMPRESSED GAS, N.O.S. (Nitrogen)
2.2
F-C
S-V
P200
:
:
:
:
COMPRESSED GAS, N.O.S. (Nitrogen)
2.2
Allowed.
200
Sea transport (IMDG)
Proper shipping name
Class
Emergency Schedule (EmS) - Fire
Emergency Schedule (EmS) - Spillage
Packing instruction
Air transport (ICAO-TI / IATA-DGR)
Proper shipping name (IATA)
Class
Passenger and Cargo Aircraft
Packing instruction - Passenger and
Cargo Aircraft
Cargo Aircraft only
Packing instruction - Cargo Aircraft
only
: Allowed.
: 200
Special precautions for user
: Avoid transport on vehicles where the load space is not separated from the driver's
compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the
event of an accident or an emergency.
Before transporting product containers :
- Ensure there is adequate ventilation.
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
B
C
Page : 8
MATERIAL SAFETY DATA SHEET
Revised edition no : 3
Date : 26 / 11 / 2012
Supersedes : 26 / 9 / 2012
0-199ppm NITRIC OXIDE in NITROGEN
50026A
SECTION 15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Seveso directive 96/82/EC
: Not covered.
National legislation
: Ensure all national/local regulations are observed.
15.2. Chemical Safety Assessment
: A CSA does not need to be carried out for this product.
SECTION 16. Other information
: Revised safety data sheet in accordance with commisssion regulation (EU) No 453/2010
Indication of changes
: Receptacle under pressure.
Training advice
List of full text of R-phrases in section : R8 : Contact with combustible material may cause fire.
R26 : Very toxic by inhalation.
3.
R34 : Causes burns.
: EUH071 - Corrosive to respiratory tract.
List of full text of H-statements in
H270 - May cause or intensify fire; oxidizer.
section 3.
H280 - Contains gas under pressure; may explode if heated.
H314 - Causes severe skin burns and eye damage.
H330 - Fatal if inhaled.
: Classification in accordance with calculation methods of regulation (EC) 1272/2008 CLP / (
Further information
EC) 1999/45 DPD.
This Safety Data Sheet has been established in accordance with the applicable European
Union legislation.
: Before using this product in any new process or experiment, a thorough material compatibility
DISCLAIMER OF LIABILITY
and safety study should be carried out.
Details given in this document are believed to be correct at the time of going to press. Whilst
proper care has been taken in the preparation of this document, no liability for injury or
damage resulting from its use can be accepted.
The contents and format of this SDS are in accordance with EC Commission Directive 2001/58/EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Air Liquide Australia Limited
Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia
Tel: + 61 3 9697 9888
Fax: + 61 3 9690 7107
[email protected]
In case of emergency : 1800 812 588
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