Terminix-tri-die bulk dust

Terminix-tri-die bulk dust
M AT E R I A L
S A F E T Y
D ATA
S H E E T
PRESCRIPTION TREATMENT® brand TRI-DIE® Silica & Pyrethrum Dust
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (PROSAR)
TRANSPORTATION: 800-424-9300 (CHEMTREC)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product Name:
EPA Reg. No.:
Product Code:
EPA Signal Word:
Distributed by:
SECTION 5. FIRE FIGHTING MEASURES
Prescription Treatment® brand Tri-Die®
Silica & Pyrethrum Dust
499-429
02-0232 (4 x 5 lb.)
CAUTION
Whitmire Micro-Gen Research Laboratories, Inc.
3568 Tree Court Industrial Blvd.
St. Louis MO 63122-6682
FIRE AND EXPLOSION
Flash Point (TCC): 177° F
Explodibility Limits of propellant in Air (% by volume):
Lower (LEL) = NE
Upper (UEL) = NE
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
None known.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPOSITION INFORMATION
ACTIVE INGREDIENTS (51.0%)
%
CAS NO.
Pyrethrins
1.0%
8003-34-7
Piperonyl Butoxide, Technical
10.0%
51-03-6
Amorphous Silica Dioxide
40.0%
112826-00-8
OTHER INGREDIENTS* (49.0%)
%
CAS NO.
Petroleum Distillate
> 10.0%
64742-47-8
* All ingredients may not be listed. Ingredients not listed do not meet the reporting
requirements of the OSHA Hazard Communication Standard (HCS) as specified in
29 CFR 1910.1200.
EXPOSURE INFORMATION
OSHA PEL ACGIH TLV
Material
STEL
TWA
STEL
TWA
Pyrethrins
NE
NE
10 mg/m3
5 mg/m3
Piperonyl Butoxide, Technical NE
NE
NE
NE
Amorphous Silica Dioxide
NE
NE
NE
NE
Petroleum Distillate
NE
NE
NE
NE
* TWA recommended by ingredient supplier = 300 ppm
SECTION 3. HAZARDS IDENTIFICATION
NOTES TO PHYSICIAN
Contains petroleum distillate – vomiting may cause aspiration pneumonia.
SIGNS/SYMPTOMS OF EXPOSURE
May cause eye irritation. Prolonged exposure may cause drying of nose and
throat.
ROUTES OF ENTRY
Primary: Skin
Secondary: Inhalation
Tertiary: Ingestion
HAZARDOUS DECOMPOSITION PRODUCTS
Can include carbon dioxide and carbon monoxide.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
None known.
SECTION 4. FIRST AID MEASURES
Have the product container or label with you when calling a poison control center or
doctor or going for treatment. Describe any symptoms and follow the advice given.
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give ANY liquid
to the person. Do not give anything by mouth to an unconscious person.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an
ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty
of water for 15-20 minutes. Call a poison control center or doctor for treatment
advice.
Eye Contact: Hold eyes open and rinse slowly and gently for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eyes. Call a poison control center or doctor for treatment advice.
Note to Physician: Contains petroleum distillate – vomiting may cause aspiration
pneumonia.
Medical Conditions Generally Aggravated by Exposure: None known.
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies.)
IN CASE OF FIRE
Extinguisher Media: CO2, Dry Chemical, Foam
Special Fire Fighting Procedures: None required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
IN CASE OF SPILL OR LEAK
Spilled material should be carefully collected and containerized in a manner that
produces the least amount of airborne dust. Residual surface material may be
removed with towels moistened with water.
This product contains the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) listed chemical Pyrethrins which has a reportable
quantity (RQ) of 1 lb. A release of more than 20 lbs. of this product (approx. 100
pails) is reportable to the National Response Center (800-424-8802).
Emergency Telephone Number of Chemtrec: (800) 424-9300 (for transportation spills)
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Eyes: Use proper protection – goggles or face shield recommended. Avoid contact with eyes.
Skin: Wear chemical resistant gloves. (Good practice requires that gross amounts
of any chemical be removed from the skin as soon as practical, especially before
eating or smoking.)
Inhalation: Use of a respirator may be appropriate when working with spills in
enclosed or confined spaces. When using a respirator, wear a NIOSH approved
respirator with an organic vapor (OV) cartridge or canister with any R, P, or HE
prefilter.
WASTE DISPOSAL METHOD
Do not contaminate water, food or feed by storage or disposal of wastes. Take full
or leaking containers to a local disposal company for biological treatment or
incineration. Review all Local, State, and Federal regulations concerning health
and pollution to determine approved disposal procedures. NEVER PLACE WASTES
DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
SECTION 7. HANDLING AND STORAGE
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Keep out of reach of children. CAUTION – Harmful if inhaled or absorbed through
skin. Causes moderate eye irritation. Avoid breathing dust. Avoid contact with
skin, eyes or clothing. Wash thoroughly with soap and water after handling. Special precautions should be taken so that all residue will be out of reach of children
or domestic animals. Avoid contamination of food and foodstuffs.
STORAGE
Do not contaminate water, food or feed. Keep container tightly closed. Store in a
cool, dry area inaccessible to children.
Page 1 of 2
M AT E R I A L
S A F E T Y
D ATA
S H E E T
PRESCRIPTION TREATMENT® brand TRI-DIE® Silica & Pyrethrum Dust
SECTION 12. ECOLOGICAL INFORMATION
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Respiratory Protection: None required when used according to label directions. For prolonged exposure or if used in enclosed or confined areas, a NIOSH
approved respirator with an organic vapor (OV) cartridge or canister with any R, P,
or HE prefilter may be used.
Protective Gloves: Chemical resistant gloves are recommended if prolonged or
repeated skin contact is likely. Good practice requires that gross amount of any
chemical be removed from the skin as soon as practical, especially before eating
or smoking.)
Eye Protection: Use proper protection – safety glasses are recommended.
Other Protective Equipment: None required.
VENTILATION
Local Exhaust: None required.
Mechanical: None required.
Special: None required.
Other: Provide adequate ventilation of treatment area.
SECTION 13. DISPOSAL CONSIDERATION
Do not contaminate water, food or feed by disposal of container or wastes. Dispose
of container and wastes in accordance with all Federal, state and local regulations.
Container Disposal: Empty container by using the product according to the label
directions. Do not reuse this container! Place empty container in trash or offer for
recycling if available. If container is partly filled, call your local solid waste agency
or call 1-800-CLEANUP for disposal instructions. NEVER PLACE UNUSED PRODUCT DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
Waste Disposal: Wastes resulting from the use of this product may be disposed
of on site or at an approved waste disposal facility. NEVER PLACE WASTES DOWN
ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
SECTION 14. TRANSPORT INFORMATION
SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Proper Shipping Description: Insecticide (Not Regulated)
Package Marking: None required.
Package Labeling: None required.
Certified Packaging: Not required.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Dry white powder.
Solubility in Water: Negligible
Viscosity: NE
Boiling Point: NE
pH: NE
This product is toxic to fish. Do not apply directly to water. Do not contaminate
water when disposing of equipment washwater or rinsate.
Odor: Characteristic Pyrethrum odor.
Vapor Pressure: NA
Vapor Density: NE
Freezing/Melting Point: NE
Density: 0.278 g/ml @ 20° C
SHIPMENT BY WATER OR AIR (IMDG / IATA CLASSIFICATION)
No information available.
SECTION 10. STABILITY AND REACTIVITY
SECTION 15. REGULATORY INFORMATION
REACTIVITY
Stability: Indefinite when used according to label directions.
Conditions to Avoid: None known.
Incompatibility (Material to Avoid): Strong oxidizing agents.
Hazardous Polymerization: Will not occur.
CERCLA
This product contains the CERCLA listed chemical Pyrethrins which has a
reportable quantity (RQ) of 1 lb.
HAZARDOUS DECOMPOSITION PRODUCTS
Can include carbon dioxide and carbon monoxide.
SECTION 11. TOXICOLOGICAL INFORMATION
ROUTES OF ENTRY
Primary: Skin
Secondary: Inhalation
Tertiary: Ingestion
ACUTE
Eyes: May cause eye irritation. Product produced conjunctival irritation in albino
rabbit eyes reversible within 72 hours. No corneal opacity or iritis was observed.
Skin: No known adverse effects to humans with intact skin. May be absorbed
through damaged skin. Acute dermal LD50 > 2000 mg/kg (rabbits). Primary skin
irritation index = 0.
Ingestion: Acute oral toxicity LD50 > 5000 mg/kg (rats).
Inhalation: A few cases of extrinsic asthma from pyrethrin mixtures have been
reported. Prolonged exposure may cause drying of nose and throat. Acute inhalation toxicity LC50 = 4.3 mg/L (rats).
CHRONIC / CARCINOGENICITY
Neither this product nor any of its ingredients are classified as carcinogens by the
National Toxicity Program (NTP), the International Agency for Research on Cancer
(IARC) or the Occupational Safety and Health Administration (OSHA).
SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA “Hazard Categories” promulgated under Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard
SARA TITLE III SECTION 313 CHEMICALS
This product contains the following substances subject to the reporting requirements of Title III of the Superfund Amendments and Reauthorization Act of 1986
(SARA Title III) and/or 40 CFR Part 372:
Piperonyl Butoxide, Technical (CAS #51-03-6)
10.0% by weight
TSCA
All components of this product are listed or excluded from listing on the US Toxic
Substance Control Act (TSCA) Chemical Substance Inventory.
SECTION 16. OTHER INFORMATION
NFPA HEALTH RATING INFORMATION
HEALTH - 1
FLAMMABILITY - 2
HMIS HAZARD RATING INFORMATION
HEALTH - 1
FLAMMABILITY - 2
REACTIVITY - 0
REACTIVITY - 0
KEY: 4 = Severe
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable
NE - Not Established
PEL - Permissible Exposure Limit
TLV - Threshold Limit Value
STEL - Short Term Exposure Limit (15 min.)
TWA - Time Weighted Average (8 hrs)
WHITMIRE MICRO-GEN
RESEARCH LABORATORIES, INC.
Page 2 of 2
Effective Date: 06/02/04
Review Date: NA
Supersedes: 07/27/00
Code #: 171-095 & 203-032
Text ID: 040601-2
Part Number: 19-0099-1
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