BG Air Intake System Cleaner

BG Air Intake System Cleaner
Material Safety Data Sheet
BG Air Intake System Cleaner
1.
Product and company identification
Material uses
Manufacturer
: Other non-specified industry: Cleaner.
: BG Products Inc.
701 S. Wichita Street
Wichita, KS, 67213, USA
www.bgprod.com
MSDS #
Validation date
Responsible name
: 206
: 6/3/2010.
: Kolin Anglin, Environmental Coordinator
316-265-2686
[email protected]
In case of emergency
: (800) 424-9300 (CHEMTREC)
2.
Hazards identification
Physical state
Odor
OSHA/HCS status
Emergency overview
: Liquid.
: Solvents
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY
CAUSE FLASH FIRE. MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON
ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY
CAUSE CANCER, BASED ON ANIMAL DATA.
Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions
before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin
and clothing. Contains material that may cause target organ damage, based on animal
data. Use only with adequate ventilation. Keep container tightly closed and sealed until
ready for use.
Potential acute health effects
Inhalation
: Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.
Skin
: Harmful in contact with skin. May cause skin irritation.
Eyes
: May cause eye irritation.
Potential chronic health effects
Chronic effects
: Contains material that may cause target organ damage, based on animal data.
Carcinogenicity
: Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Target organs
: Contains material which may cause damage to the following organs: blood, kidneys,
liver, gastrointestinal tract, upper respiratory tract, skin, eyes, central nervous system
(CNS).
Over-exposure signs/symptoms
No known significant effects or critical hazards.
Medical conditions
: Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by overexposure
See toxicological information (section 11)
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3.
Composition/information on ingredients
Name
CAS number
%
1-Methyl-2-Pyrrolidinone
Xylene
Distillates (petroleum), hydrotreated light
2-Propanol
Acetone
Ethylbenzene
872-50-4
1330-20-7
64742-47-8
67-63-0
67-64-1
100-41-4
15 - 40
10 - 30
5 - 10
5 - 10
5 - 10
1-5
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
4.
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
Notes to physician
5.
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention if symptoms occur.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention if symptoms occur.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms occur.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention if symptoms occur.
: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Fire-fighting measures
Flammability of the product
Extinguishing media
Suitable
Not suitable
Special exposure hazards
: Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier
than air and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. Runoff to
sewer may create fire or explosion hazard.
: Use dry chemical, CO2, water spray (fog) or foam.
: Do not use water jet.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
Special protective
equipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
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6.
Accidental release measures
Personal precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see section 8).
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose of via a licensed waste disposal contractor.
Large spill
: Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via
a licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
7.
Handling and storage
Handling
: Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use non-sparking tools. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Storage
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8.
Exposure controls/personal protection
Ingredient
6/3/2010.
Exposure limits
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8.
Exposure controls/personal protection
1-Methyl-2-Pyrrolidinone
Xylene
Distillates (petroleum), hydrotreated light
2-Propanol
Acetone
Ethylbenzene
AIHA WEEL (United States, 1/2008). Absorbed through skin.
TWA: 10 ppm 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 100 ppm 8 hour(s).
TWA: 434 mg/m³ 8 hour(s).
STEL: 150 ppm 15 minute(s).
STEL: 651 mg/m³ 15 minute(s).
OSHA PEL (United States, 11/2006).
TWA: 100 ppm 8 hour(s).
TWA: 435 mg/m³ 8 hour(s).
ACGIH TLV (United States, 1/2008). Absorbed through skin.
TWA: 200 mg/m³ 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 200 ppm 8 hour(s).
STEL: 400 ppm 15 minute(s).
NIOSH REL (United States, 6/2008).
TWA: 400 ppm 10 hour(s).
TWA: 980 mg/m³ 10 hour(s).
STEL: 500 ppm 15 minute(s).
STEL: 1225 mg/m³ 15 minute(s).
OSHA PEL (United States, 11/2006).
TWA: 400 ppm 8 hour(s).
TWA: 980 mg/m³ 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 500 ppm 8 hour(s).
TWA: 1188 mg/m³ 8 hour(s).
STEL: 750 ppm 15 minute(s).
STEL: 1782 mg/m³ 15 minute(s).
NIOSH REL (United States, 6/2008).
TWA: 250 ppm 10 hour(s).
TWA: 590 mg/m³ 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 1000 ppm 8 hour(s).
TWA: 2400 mg/m³ 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 100 ppm 8 hour(s).
STEL: 125 ppm 15 minute(s).
NIOSH REL (United States, 6/2008).
TWA: 100 ppm 10 hour(s).
TWA: 435 mg/m³ 10 hour(s).
STEL: 125 ppm 15 minute(s).
STEL: 545 mg/m³ 15 minute(s).
OSHA PEL (United States, 11/2006).
TWA: 100 ppm 8 hour(s).
TWA: 435 mg/m³ 8 hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring
: If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
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8.
Exposure controls/personal protection
Hygiene measures
Personal protection
Respiratory
Hands
Eyes
Skin
Environmental exposure
controls
9.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
: Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Physical and chemical properties
Physical state
Flash point
Auto-ignition temperature
Flammable limits
:
:
:
:
Color
Odor
pH
Boiling/condensation point
Melting/freezing point
Specific gravity
Vapor pressure
Vapor density
Odor threshold
Evaporation rate
Solubility
Pour point
Density
VOC content
:
:
:
:
:
:
:
:
:
:
:
:
:
:
6/3/2010.
Liquid.
Closed cup: -14°C (6.8°F)
270°C (518°F)
Lower: 2.6%
Upper: 12.8%
Yellow.
Solvents
Not available.
Not available.
-54°C (-65.2°F)
0.8534
<110 kPa (<825 mm Hg)
>1 [Air = 1]
Not available.
Not available.
Insoluble in the following materials: cold water and hot water.
-54°C (-65.2°F)
7.117 (lbs/gal)
45 % (w/w)
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10. Stability and reactivity
Chemical stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Possibility of hazardous
reactions
: The product is stable.
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
: Highly reactive or incompatible with the following materials:
oxidizing materials
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
: Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
1-Methyl-2-Pyrrolidinone
LD50 Dermal
LD50 Oral
LD50 Oral
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
Rabbit
Rat
Rat
Rabbit
Rat
Rat
Rabbit
Rat
Rabbit
Rat
8 g/kg
3914 mg/kg
5800 mg/kg
12800 mg/kg
5000 mg/kg
5000 ppm
>1700 mg/kg
4300 mg/kg
>5000 mg/kg
3500 mg/kg
4 hours
-
Acetone
2-Propanol
Xylene
Ethylbenzene
Carcinogenicity
Classification
Product/ingredient name
ACGIH
IARC
EPA
NIOSH
NTP
OSHA
Xylene
Distillates (petroleum),
hydrotreated light
2-Propanol
Acetone
Ethylbenzene
A4
A3
3
-
-
-
-
-
A4
A4
A3
3
2B
-
-
-
-
12. Ecological information
Product/ingredient name
Result
Species
Exposure
1-Methyl-2-Pyrrolidinone
Acute LC50 1.23 ppm Fresh water
48 hours
Acetone
Acute LC50 7550000 ug/L Fresh water
Acute LC50 10000 ug/L Fresh water
Acute LC50 >100000 ug/L Fresh water
2-Propanol
Acute LC50 1400000 ug/L Marine water
Acute LC50 >1400000 ug/L
Distillates (petroleum),
hydrotreated light
Xylene
Acute LC50 2200 ug/L Fresh water
Daphnia - Daphnia magna - <24
hours
Crustaceans - Asellus aquaticus
Daphnia - Daphnia magna
Fish - Pimephales promelas Juvenile (Fledgling, Hatchling,
Weanling) - 0.2 to 0.5 g
Crustaceans - Crangon crangon
Fish - Gambusia affinis - 20 to 30
mm
Fish - Lepomis macrochirus - 35
to 75 mm
Crustaceans - Palaemonetes
pugio
Fish - Oncorhynchus mykiss - 0.6
g
Daphnia - Daphnia magna -
Acute LC50 8500 ug/L Marine water
Acute LC50 3300 ug/L Fresh water
Ethylbenzene
6/3/2010.
Acute EC50 2930 ug/L Fresh water
206
48 hours
48 hours
96 hours
48 hours
96 hours
4 days
48 hours
96 hours
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12. Ecological information
Acute LC50 >5200 ug/L Marine water
Acute LC50 4200 ug/L Fresh water
Chronic NOEC 3300 ug/L Marine water
Octanol/water partition
coefficient
Neonate - <=24 hours
Crustaceans - Americamysis
bahia - <24 hours
Fish - Oncorhynchus mykiss
Fish - Menidia menidia
48 hours
96 hours
96 hours
: Not available.
13. Disposal considerations
Waste disposal
: The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
PG* Label
Additional
information
DOT Classification
UN1993
FLAMMABLE
LIQUIDS, N.O.S.
(Acetone, Xylene)
3
II
-
IMDG Class
UN1993
FLAMMABLE
LIQUIDS, N.O.S.
(Acetone, Xylene)
3
II
Emergency
schedules (EmS)
F-E, S-E
IATA-DGR Class
UN1993
FLAMMABLE
LIQUIDS, N.O.S.
(Acetone, Xylene)
3
II
-
PG* : Packing group
15. Regulatory information
United States
HCS Classification
U.S. Federal regulations
6/3/2010.
: Flammable liquid
Carcinogen
Target organ effects
: United States inventory (TSCA 8b): Not determined.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Ethylbenzene; Xylene; Distillates
(petroleum), hydrotreated light; 2-Propanol; Acetone; 1-Methyl-2-Pyrrolidinone
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard; Xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard; Distillates (petroleum), hydrotreated light: Delayed (chronic) health hazard; 2206
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15. Regulatory information
Propanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard; Acetone: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard; 1-Methyl-2-Pyrrolidinone: Fire hazard, Immediate (acute) health hazard, Delayed
(chronic) health hazard
Clean Air Act Section
112(b) Hazardous Air
Pollutants (HAPs)
DEA List II Chemicals
(Essential Chemicals)
Clean Water Act (CWA) 307: Ethylbenzene
Clean Water Act (CWA) 311: Ethylbenzene; Xylene
: Listed
: Listed
SARA 313
Product name
CAS number
Concentration
Form R - Reporting
requirements
1-Methyl-2-Pyrrolidinone
Xylene
2-Propanol
Ethylbenzene
872-50-4
1330-20-7
67-63-0
100-41-4
15 - 40
10 - 30
5 - 10
1-5
Supplier notification
1-Methyl-2-Pyrrolidinone
Xylene
2-Propanol
Ethylbenzene
872-50-4
1330-20-7
67-63-0
100-41-4
15 - 40
10 - 30
5 - 10
1-5
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations
Massachusetts
: The following components are listed: 1-METHYL-2-PYRROLIDONE; ACETONE;
ISOPROPYL ALCOHOL; XYLENE; ETHYL BENZENE
New York
: The following components are listed: Acetone; Xylene (mixed); Ethylbenzene
New Jersey
: The following components are listed: ACETONE; ISOPROPYL ALCOHOL; XYLENES;
ETHYL BENZENE
Pennsylvania
: The following components are listed: 2-PYRROLIDINONE, 1-METHYL-; 2PROPANONE; 2-PROPANOL; BENZENE, DIMETHYL-; BENZENE, ETHYLRhode Island
: None of the components are listed.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
1-Methyl-2-Pyrrolidinone
No.
Yes.
No.
Ethylbenzene
Yes.
No.
No.
3200 μg/day
(inhalation)
No.
United States inventory
(TSCA 8b)
Canada
WHMIS (Canada)
Canadian lists
Canadian NPRI
6/3/2010.
: Not determined.
: Class B-2: Flammable liquid
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
: The following components are listed: N-Methyl-2-pyrrolidone; Volatile organic
compounds; Isopropyl alcohol; Hydrotreated light distillate; Xylene; Ethylbenzene
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15. Regulatory information
CEPA Toxic substances
: The following components are listed: Volatile organic compounds
Canada inventory
: Not determined.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists
: Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
16. Other information
Hazardous Material
Information System (U.S.A.)
:
*
Health
1
Flammability
4
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented
HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection
:
Association (U.S.A.)
Flammability
4
Health
1
0
Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
: 6/3/2010.
Date of issue
Date of previous issue
: No previous validation.
Version
: 1
Indicates information that has changed from previously issued version.
Notice to reader
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16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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