Fosroc Colpor 200 PF Curing Agent SDS (NZ)

Fosroc Colpor 200 PF Curing Agent SDS (NZ)
Safety Data Sheet
Hazardous Substance, Dangerous Goods
1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION
Product name:
FOSROC COLPOR 200 PF CURING AGENT
Recommended use: Curing agent of a two part pitch-free polyurethane sealant. Applied by gun or poured.
Supplier:
Parchem Construction Suppliers Pty Ltd
ABN:
Street Address:
80 069 961 968
7 Lucca Road
Wyong NSW 2259
Australia
(02) 4350 5000
Telephone:
Emergency telephone number:
Distributed in New Zealand by:
Concrete Plus
23 Watts Road
Sockburn
New Zealand
(03) 343 0090
Australia – 1800 033 111
New Zealand – 0800 734 607
2. HAZARDS IDENTIFICATION
This material is hazardous according to criteria of EPA New Zealand.
EPA Group Standard: Construction Products (Subsidiary Hazard) Group Standard 2006; HSR002544
Signal Word
Danger
Hazard Classification
6.3A - Substances that are irritating to the skin
6.4A - Substances that are irritating to the eye
6.5A - Substances that are respiratory sensitisers
6.8C - Substances that produce toxic human reproductive or developmental effects on or via lactation
6.9 - Respiratory tract irritant
6.9B (Repeated exposure) - Substances that are harmful to human target organs or systems
9.1A - Substances that are very ecotoxic in the aquatic environment (H410)
Hazard Statement(s)
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335
May cause respiratory irritation.
H362
May cause harm to breast-fed children.
H373
May cause damage to organs through prolonged or repeated exposure.
H410
Very toxic to aquatic life with long lasting effects.
Prevention Precautionary Statement(s)
P102
Keep out of reach of children.
P103
Read label before use.
P201
Obtain special instructions before use.
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 1 of 8
Version: 1.0
Safety Data Sheet
P260
P263
P264
P270
P271
P273
P280
P285
Do not breathe mist, vapours or spray.
Avoid contact during pregnancy/while nursing.
Wash hands, face and all exposed skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective clothing, gloves, eye/face protection and suitable respirator.
In case of inadequate ventilation wear respiratory protection.
Response Precautionary Statement(s)
P101
If medical advice is needed, have product container or label at hand.
P302+P352
IF ON SKIN: Wash with plenty of soap and water.
P332+P313
If skin irritation occurs: Get medical advice/attention.
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P342+P311
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313
If eye irritation persists: Get medical advice/attention.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P312
Call a POISON CENTER or doctor/physician if you feel unwell.
P362
Take off contaminated clothing and wash before reuse.
Storage Precautionary Statement(s)
P405
Store locked up
P403+233
Store in a well ventilated place. Keep container tightly closed
Disposal Precautionary Statement(s)
P501
Dispose of contents/container in accordance with regional and national regulations
DANGEROUS GOODS CLASSIFICATION
Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous
Goods by Road & Rail” and the “New Zealand NZS5433: Transport of Dangerous Goods on Land”.
Class:
9
Miscellaneous Dangerous Goods
3. COMPOSITION INFORMATION
CHEMICAL ENTITY
Alkanes, C14-17, chloroDiphenylmethane diisocyanate
CAS NO.
PROPORTION
85535-85-9
9016-87-9
>60%
10 – 30%
________
100%
4. FIRST AID MEASURES
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand
0800 764 766).
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 2 of 8
Version: 1.0
Safety Data Sheet
Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing
and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at
rest until fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and
have a qualified person give oxygen through a facemask. If breathing has stopped apply artificial respiration
at once. In the event of cardiac arrest, apply external cardiac massage. Seek immediate medical advice.
Skin contact: If skin or hair contact occurs, immediately remove contaminated clothing and flush skin and
hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre
or a Doctor; or for 15 minutes and transport to Doctor or Hospital.
Eye contact: If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue
flushing until advised to stop by the Poisons Information Centre or a Doctor; or for at least 15 minutes and
transport to Doctor or Hospital.
Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink.
Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek
medical advice.
PPE for First Aiders: Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation.
If inhalation risk exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715
and AS/NZS 1716. Available information suggests that gloves made from nitrile rubber should be suitable
for intermittent contact. However, due to variations in glove construction and local conditions, the user
should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet.
Wash contaminated clothing and other protective equipment before storing or re-using.
Notes to physician: Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Hazchem Code: •3Z
Suitable extinguishing media: If material is involved in a fire use alcohol resistant foam, standard foam or
dry agent (carbon dioxide, dry chemical powder).
Specific hazards: Combustible liquid.
Fire fighting further advice: If safe to do so, remove containers from path of fire. Keep containers cool with
water spray. On burning may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and
suitable protective clothing if risk of exposure to vapour or products of combustion.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours. Wipe up with
absorbent (clean rag or paper towels). Allow absorbent to dry before disposing with normal household
garbage.
LARGE SPILLS
Clear area of all unprotected personnel. Prevent further leakage or spillage if safe to do so. Slippery when
spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye
contamination and the inhalation of vapours. Work up wind or increase ventilation. Contain - prevent run off
into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly
labelled containers or drums for disposal.
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
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Safety Data Sheet
If contamination of sewers or waterways has occurred advise local emergency services.
Dangerous Goods – Initial Emergency Response Guide No: 47
7. HANDLING AND STORAGE
Handling: Avoid skin and eye contact and inhalation of vapour, mist or aerosols.
Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs.
Store away from incompatible materials described in Section 10. Store away from sources of heat or
ignition. Keep containers closed when not in use - check regularly for leaks.
This material is classified as a Dangerous Good Class 9 Miscellaneous Dangerous Goods as per the criteria
of the Australian Dangerous Goods Code and must be stored in accordance with the relevant regulations.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
National occupational exposure limits: No value assigned for this specific material by the Department of
Labour New Zealand.
Biological Limit Values: As per the “National Model Regulations for the Control of Workplace Hazardous
Substances (Safe Work Australia)” the ingredients in this material do not have a Biological Limit Allocated.
Engineering measures: Use only in well ventilated areas. Use with local exhaust ventilation or while
wearing appropriate respirator. Keep containers closed when not in use.
Personal protection equipment: YELLOW: OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES,
RESPIRATOR.
Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation. If inhalation risk exists
wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Available information suggests that gloves made from butyl rubber/leather/natural rubber/neoprene/nitrile
rubber/polyethylene/polyvinyl alcohol (PVA)/polyvinyl chloride (PVC)/teflon should be suitable for intermittent
contact. However, due to variations in glove construction and local conditions, the user should make a final
assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated
clothing and other protective equipment before storing or re-using.
Hygiene measures:
Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or smoke. Wash hands
prior to eating, drinking or smoking. Avoid skin and eye contact and inhalation of vapour, mist or aerosols.
Ensure that eyewash stations and safety showers are close to the workstation location.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form / Colour / Odour: Brown viscous liquid with a musty odour.
Solubility:
Specific Gravity:
Relative Vapour Density (air=1):
Vapour Pressure (20 °C):
Flash Point (°C):
Insoluble in water.
1.25
N Av
N Av
>180
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 4 of 8
Version: 1.0
Safety Data Sheet
Flammability Limits (%):
Autoignition Temperature (°C):
Melting Point/Range (°C):
Boiling Point/Range (°C):
pH:
Viscosity:
N Av
N Av
N Av
N Av
N Av
N Av
(Typical values only - consult specification sheet)
N Av = Not available
N App = Not applicable
10. STABILITY AND REACTIVITY
Reactivity: Material may polymerise generating heat.
Chemical stability: This material is thermally stable when stored and used as directed.
Hazardous reactions: This material can undergo polymerisation. Reacts with acids, amines, alcohols and
glycols. Reacts strongly with alkaline metals and metal powder.
Conditions to avoid: Elevated temperatures and sources of ignition.
Incompatible materials: Oxidising agents, alkali metals and alkali earth metals.
Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and
the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs
are:
Acute Effects
Inhalation: Material may be an irritant to mucous membranes and respiratory tract. A respiratory sensitiser.
Can cause possible allergic reactions.
Skin contact: Contact with skin will result in irritation.
Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract.
Eye contact: An eye irritant.
Acute toxicity
Inhalation: This material has been classified as non-hazardous.
Acute toxicity estimate (based on ingredients): >20 mg/L
Skin contact: This material has been classified as non-hazardous.
Acute toxicity estimate (based on ingredients): >2,000 mg/Kg
Ingestion: This material has been classified as non-hazardous.
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 5 of 8
Version: 1.0
Safety Data Sheet
Corrosion/Irritancy: Eye: this material has been classified as a Category 6.4A Hazard (reversible effects to
Skin: this material has been classified as a Category 6.3A Hazard (irritant to skin).
Sensitisation: Inhalation: this material has been classified as a Category 6.5A Hazard (respiratory
sensitiser).
Skin: this material has been classified as not a skin sensitiser.
Aspiration hazard: This material has been classified as non-hazardous.
Specific target organ toxicity (single exposure): This material has been classified as a Category 6.9
Hazard. Exposure via inhalation may result in respiratory irritation.
Chronic Toxicity
Mutagenicity: This material has been classified as non-hazardous.
Carcinogenicity: This material has been classified as non-hazardous.
Reproductive toxicity (including via lactation): This material has been classified as a Category 6.8C
Hazard, toxic to reproduction, effects on or via lactation.
Specific target organ toxicity (repeat exposure): This material has been classified as a Category 6.9B
Hazard. Exposure via inhalation may result in respiratory irritation.
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways.
Acute aquatic hazard: This material has been classified as a Category 9.1A Hazard.
Acute toxicity estimate (based on ingredients): <1 mg/L
Long-term aquatic hazard: This material has been classified as a Category 9.1A Hazard.
Acute toxicity estimate (based on ingredients): <1 mg/L
Ecotoxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility: No information available.
13. DISPOSAL CONSIDERATIONS
Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal
protection equipment is used, see “Section 8. Exposure Controls and Personal Protection” of this SDS.
If possible material and its container should be recycled. If material or container cannot be recycled,
dispose in accordance with local, regional, national and international Regulations.
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 6 of 8
Version: 1.0
Safety Data Sheet
14. TRANSPORT INFORMATION
ROAD AND RAIL TRANSPORT
Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous
Goods by Road & Rail” and the “New Zealand NZS5433: Transport of Dangerous Goods on Land”.
Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to
this Code when transported by road or rail in packaging, IBC’s or any other receptacles not exceeding 500
Kg(L).
UN No:
Dangerous Goods Class:
Packing Group:
Hazchem Code:
Emergency Response Guide No:
3082
9 Miscellaneous Dangerous Goods
III
•3Z
47
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CONTAINS CHLORINATED PARAFFINS)
Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), oxidising agents (Class 5.1)
or organic peroxides (Class 5.2), however exemptions may apply.
MARINE TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG
Code) for transport by sea.
This material is classified as a Marine Pollutant (P) according to the International Maritime Dangerous
Goods Code.
UN No:
Dangerous Goods Class:
Packing Group:
3082
9 Miscellaneous Dangerous Goods
III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CONTAINS CHLORINATED PARAFFINS)
AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by air.
UN No:
Dangerous Goods Class:
Packing Group:
3082
9 Miscellaneous Dangerous Goods
III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CONTAINS CHLORINATED PARAFFINS)
15. REGULATORY INFORMATION
This material is not subject to the following international agreements:
Montreal Protocol (Ozone depleting substances)
The Stockholm Convention (Persistent Organic Pollutants)
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 7 of 8
Version: 1.0
Safety Data Sheet
The Rotterdam Convention (Prior Informed Consent)
This material is subject to the following international agreements:
Basel Convention (Hazardous Waste)
 Wastes from production, formulation and use of resins, latex, plasticizers, glues/adhesives
International Convention for the Prevention of Pollution from Ships (MARPOL)
 Annex III - Harmful Substances carried in Packaged Form
This material/constituent(s) is covered by the following requirements:

All the constituents of this material are listed on the Australian Inventory of Chemical Substances
(AICS).
16. OTHER INFORMATION
Literary reference
This Safety Data Sheet has been prepared by Chemical Data Services Pty Ltd (chemdata.com.au) on behalf
of its client.
Supersedes: January 2011
Reason(s) For Issue: Revised. Format change. Change in Hazardous Substance Classification
Technical Support: Australia - 1300 737 787, New Zealand – 0800 657 156
Safety Data Sheets are updated frequently. Please ensure that you have a current copy.
This SDS summarises at the date of issue our best knowledge of the health and safety hazard information of
the product, and in particular how to safely handle and use the product in the workplace. Since Parchem
Construction Supplies Pty Ltd and Concrete Plus cannot anticipate or control the conditions under which the
product may be used, each user must, prior to usage, review this SDS in the context of how the user intends
to handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the
user should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent
to our customers and is also available upon request.
Product name: FOSROC COLPOR 200 PF CURING AGENT
SDS No: PARNZLEN000109
Issued: 23 June 2015
Page: 8 of 8
Version: 1.0
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