SDS Sanitizer

SDS Sanitizer
SAFETY DATA SHEET
ICE MACHINE SANITIZER
Product ID: MI089600
Revised: 02-11-2014
Replaces: 01-04-2012
1. IDENTIFICATION
Product Name:
Synonyms:
CAS Number:
Recommended Use:
Restrictions on Use:
ICE MACHINE SANITIZER
N.A.
MIXTURE
No data available.
No data available.
Manitowoc Ice
2110 South 26th Street
Manitowoc, WI 54220
(920) 682-0161
www.manitowocice.com
EMERGENCY RESPONSE NUMBER:
CHEMTREC Emergency # (US + Canada):
(800) 424-9300
CHEMTREC Emergency # (INTERNATIONAL):
+01-703-527-3887
2. HAZARD(S) IDENTIFICATION
Signal Word:
Danger
GHS Classification:
Serious Eye Damage/Eye Irritation Category 1
Skin Corrosion/Irritation Category 2
Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 3
Hazard Statements:
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation.
Precautionary Statements:
Prevention:
Avoid breathing dust, gas, mist, vapors or spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear gloves, eye and face protection and protective clothing.
Response:
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Specific treatment (see First Aid on SDS or on this label).
If skin irritation occurs: Get medical advice or attention.
Take off contaminated clothing and wash before reuse.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a secure manner.
Disposal:
Dispose of in accordance with local, regional and international regulations.
Page 1 of 6
ICE MACHINE SANITIZER
Product ID: MI089600
Hazards Not Otherwise Classified:
May cause damage to the kidneys, liver, blood, and may cause
birth defects and other reproductive harm.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component
Alkyl(50%C14,40%C12,10%C16) dimethyl benzyl ammonium chloride
Octyl decyl dimethyl ammonium chloride
Ethyl Alcohol
Didecyl dimethyl ammonium chloride
Dioctyl dimethyl ammonium chloride
CAS Number
68424-85-1
32426-11-2
64-17-5
7173-51-5
5538-94-3
% by Wt.
3.0 %
2.25 %
0-2%
1.125 %
1.125 %
4. FIRST-AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Tilt
head to avoid contaminating unaffected eye. Get immediate medical attention. Remove contact lenses after the
first 5 minutes and continue flushing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention immediately. Do not reuse clothing and shoes until cleaned. Wash with
soap and water.
Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial
respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY. Keep warm and quiet.
Ingestion: If swallowed, call a physician immediately. DO NOT induce vomiting unless directed to do so by a
physician. Never give anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head
below hips to prevent aspiration of liquid into the lungs. Have person sip a glass of water if able to swallow.
Note to Physicians:
Probable mucosal damage may contraindicate the use of gastric lavage.
Most Important Symptoms/Effects:
Eye Contact: CORROSIVE-Causes severe irritation and burns. May cause: permanent eye damage. blindness.
Skin Contact: CORROSIVE-Causes severe irritation and burns. Brief contact may cause: irritation. defatting.
Exposures not promptly washed off may lead to toxic effects similar to ingestion.
Skin Absorption: No data available.
Inhalation: May be corrosive to the respiratory tract. Severe irritation and burns may result. Vapors or mists may
irritate: throat. respiratory tract. High vapor concentrations may cause: central nervous system effects.
Symptoms may include: headache. dizziness. drowsiness. May be fatal if inhaled.
Ingestion: May be corrosive to the gastrointestinal tract. Severe irritation and burns may result. May cause:
gastrointestinal irritation. nausea. vomiting. diarrhea. death.
5. FIRE-FIGHTING MEASURES
Extinguishing Media: Dry chemical. Foam. Carbon dioxide. Water fog. DO NOT USE: Direct water stream.
Fire Fighting Methods: Evacuate area of unprotected personnel. Wear protective clothing including NIOSHapproved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and
decomposition products. Use water spray to cool fire-exposed containers. Do not use direct water stream. May
spread fire.
Fire and Explosion Hazards: Material will burn in fire, releasing toxic vapors. Contact with strong oxidizing
agents may cause fire.
Hazardous Combustion Products: Irritating and/or toxic gases.
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ICE MACHINE SANITIZER
Product ID: MI089600
6. ACCIDENTAL RELEASE MEASURES
Spill Clean-Up Procedures: CORROSIVE MATERIAL. Evacuate unprotected personnel from area. Maintain
adequate ventilation. Follow personal protective equipment recommendations found in Section 8. Never exceed
any occupational exposure limit. Keep out of low areas. Shut off source of leak if safe to do so. Contain spill,
place into drums for proper disposal. Soak up residue with non-flammable absorbent material. Place in nonleaking containers for immediate disposal. Flush remaining area with water to remove trace residue and dispose
of properly. Avoid direct discharge to sewers and surface waters. Notify authorities if entry occurs. Prevent entry
into basements, low areas, or confined areas. A vapor suppressing foam may be used to reduce vapors. Water
spray may reduce vapor, but may not prevent ignition in closed spaces. Use non-sparking tools and equipment.
CAUTION: Spilled material may be slippery. Do not touch or walk through spilled material.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Do not swallow. Avoid
breathing vapors, mists, or dust. Do not eat, drink, or smoke in work area. Wash thoroughly after handling.
Empty containers retain product residue (vapor, dust, or liquid) and can be dangerous. DO NOT pressurize, cut,
weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other
source of ignition. They may explode and cause injury or death. Avoid dust or mist formation. Ground all
equipment and containers before opening to prevent accumulation of static charge. Ground lines and equipment
used during transfer to reduce the possibility of static spark-initiated fire or explosion. Use non-sparking tools.
Storage: CORROSIVE MATERIAL. Store in a cool, well ventilated area, out of direct sunlight. Store in a dry
location away from heat. Keep away from incompatible materials. Keep containers tightly closed. Do not store in
unlabeled or mislabeled containers. Do not freeze. Do not store near heat or open flames. Static electricity may
accumulate and create a fire hazard. Ground fixed equipment. Bond and ground transfer containers and
equipment. See Section 10 for incompatible materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA Exposure Guidelines:
Component
Ethyl Alcohol
Limits
1000 ppm TWA; 1900 mg/m3 TWA
ACGIH Exposure Guidelines:
Component
Ethyl Alcohol
Limits
1000 ppm STEL
Engineering Controls: General room ventilation and local exhaust are required. Use explosion-proof ventilation
equipment. Maintain adequate ventilation. Do not use in closed or confined spaces. Avoid creating dust or mist.
Keep levels below exposure limits. To determine exposure levels, monitoring should be performed regularly.
Eye/Face Protection: Wear chemical safety goggles while handling this product. Wear additional eye protection
such as a face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne
material.
Skin Protection: Prevent contact with this product. Wear gloves and protective clothing depending on condition
of use. Protective gloves: Impervious. Rubber. Neoprene.
Respiratory Protection: Respiratory protection may be required to avoid overexposure when handling this
product. If exposure limits are exceeded, wear: NIOSH-Approved air-purifying respirator with: Organic vapor
cartridge. NIOSH-Approved self-contained breathing apparatus. DO NOT exceed limits established by the
respirator manufacturer. All respiratory protection programs must comply with OSHA 29 CFR 1910.134 and
ANSI Z88.2 requirements and must be followed whenever workplace conditions require a respirator's use.
Other Protective Equipment: Eye-wash station. Safety shower. Rubber apron. Chemical safety shoes. Rubber
boots. Impervious clothing. Protective clothing.
Page: 3 of 6
ICE MACHINE SANITIZER
Product ID: MI089600
General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work shift.
Good manufacturing practices require gross amounts of any chemical be removed from skin as soon as
practical, especially before eating or smoking.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid.
Color: Clear. Colorless.
Odor: No odor.
Odor Threshold: N.D.
pH: 8.00 (as is)
Freezing Point (deg. F): N.D.
Melting Point (deg. F): N.D.
Initial Boiling Point or Boiling Range: N.D.
Flash Point: None when heated to 100 Deg. C
Flash Point Method: COC.
Evaporation Rate (nBuAc = 1): N.D.
Flammability (solid, gas): N.D.
Lower Explosion Limit: N.A.
Upper Explosion Limit: N.A.
Vapor Pressure (mm Hg): N.D.
Vapor Density (air=1): N.D.
Specific Gravity or Relative Density: 0.990 @ 25 Deg. C
Solubility in Water: Complete
Partition Coefficient (n-octanol/water): N.D.
Autoignition Temperature: No Data
Decomposition Temperature: N.D.
Viscosity: N.D.
% Volatile (wt%): ~ 93
VOC (wt%): 0.75-1.5
VOC (lbs/gal): 0.06-0.12
Fire Point: N.D.
10. STABILITY AND REACTIVITY
Reactivity: No data available.
Chemical Stability: Stable under normal conditions.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur under normal conditions.
Contact with strong oxidizing agents may cause fire.
Conditions to Avoid: Avoid contact with heat, sparks, electric arcs, other hot surfaces, and open flames. Avoid
other ignition sources. Keep away from strong oxidizing agents.
Incompatible Materials: Strong oxidizing agents. Reducing agents.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Hydrogen chloride.
11. TOXICOLOGICAL INFORMATION
Component
Ethyl Alcohol
Oral LD50
No Data
Dermal LD50
No Data
Inhalation LC50
4H Rat: 124.7 mg/L
Routes of Exposure: Eyes. Skin. Inhalation. Ingestion. Absorption.
Eye Contact: CORROSIVE-Causes severe irritation and burns. May cause: permanent eye damage. blindness.
Skin Contact: CORROSIVE-Causes severe irritation and burns. Brief contact may cause: irritation. defatting.
Exposures not promptly washed off may lead to toxic effects similar to ingestion.
Page: 4 of 6
ICE MACHINE SANITIZER
Product ID: MI089600
Skin Absorption: No data available.
Inhalation: May be corrosive to the respiratory tract. Severe irritation and burns may result. Vapors or mists may
irritate: throat. respiratory tract. High vapor concentrations may cause: central nervous system effects.
Symptoms may include: headache. dizziness. drowsiness. May be fatal if inhaled.
Ingestion: May be corrosive to the gastrointestinal tract. Severe irritation and burns may result. May cause:
gastrointestinal irritation. nausea. vomiting. diarrhea. death.
Medical Conditions Aggravated by Exposure to Product: No data available.
Other: None known.
Cancer Information:
This product does not contain 0.1% or more of the known or potential carcinogens listed in NTP, IARC, or
OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicological Information: No data available.
Chemical Fate Information: No data available.
13. DISPOSAL CONSIDERATIONS
Hazardous Waste Number: N.A.
Disposal Method: Dispose of in a permitted hazardous waste management facility following all local, state and
federal regulations. Chemical additions to, processing of, or otherwise altering this material may make this waste
management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste
disposal requirements may be more restrictive or otherwise different from federal laws and regulations. Since
emptied containers retain product residue, follow label warnings even after container is emptied. DO NOT
pressurize, cut, weld, solder, drill, grind or expose empty containers to heat, flame, sparks or other sources of
ignition.
14. TRANSPORT INFORMATION
DOT (Department of Transportation):
Identification Number:
Proper Shipping Name:
Hazard Class:
Packing Group:
Label Required:
UN1903
Disinfectants, Liquid, Corrosive N.O.S. (Quaternary Ammonium Compound)
8
III
CORROSIVE
Note: The listed Transportation Classification does not address regulatory variations due to changes in
package size, mode of shipment or other regulatory descriptors. In the United States, it may be possible
to reclassify this material as a Consumer Commodity ORM-D based on 49 CFR 173.154 (b)(c).
15. REGULATORY INFORMATION
TSCA Inventory Status: This product or all components of this product are listed on the EPA/TSCA Inventory of
Chemical Substances.
SARA Title III Section 311/312 Category Hazards:
Immediate (Acute)
Delayed (Chronic)
Fire Hazard
Yes
No
No
Regulated Components:
Component
Ethyl Alcohol
CAS
Number
64-17-5
CERCLA
RQ
No
Note: *Ethyl alcohol in alcoholic beverages is listed.
Page: 5 of 6
Pressure Release
No
SARA
EHS
No
SARA
313
No
U.S.
HAP
No
Reactive
No
WI
HAP
No
Prop
65
Yes*
ICE MACHINE SANITIZER
Product ID: MI089600
FIFRA Information:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain
labeling requirements under federal pesticide law. These requirements differ from the classification criteria and
hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals.
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed, inhaled or absorbed through
the skin. Avoid breathing spray mist. Do not get in eyes, on skin or on clothing. Wear goggles or face shield and
rubber gloves and protective clothing when handling. Wash thoroughly with soap and water after handling and
before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and
wash clothing before reuse.
ENVIRONMENTAL HAZARDS
This pesticide is toxic to fish and aquatic invertebrates. Do not discharge effluent containing this product into
lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a
National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified
in writing prior to discharge. Do not discharge effluent containing this product into sewer systems without
previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or
Regional Office of the EPA.
PHYSICAL OR CHEMICAL HAZARDS
Do not use or store near heat or open flame. Do not mix with oxidizers, anionic soaps and detergents.
16. OTHER INFORMATION
Hazard Rating System
Health:
3
Flammability:
0
Reactivity:
0
* = Chronic Health Hazard
NFPA Rating System
Health:
3
Flammability:
0
Reactivity:
0
Special Hazard: None
MSDS Abbreviations
N.A. = Not Applicable
N.D. = Not Determined
HAP = Hazardous Air Pollutant
VOC = Volatile Organic Compound
C = Ceiling Limit
N.E./Not Estab. = Not Established
MSDS Prepared by: CSH
Reason for Revision: New format. Changes made throughout the MSDS.
Revised: 02-11-2014
Replaces: 01-04-2012
The data in this Material Safety Data Sheet relates to the specific material designated and does not relate
to its use in combination with any other material or process. The data contained is believed to be correct.
However, since conditions of use are outside our control it should not be taken as warranty or
representation for which MANITOWOC ICE assumes legal responsibility. This information is provided
solely for your consideration, investigation, and verification.
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