MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 CHEMTREC: (800) 424-9300 REVISION DATE: November 11, 2004 DATE OF ISSUE: December 29, 2004 I - Product Identification Windshield Deicer Concentrate PRODUCT CODE: 0470 CHEMICAL FORMULATION: Alcohol based cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 1 HAZARD RATING: 4 - Extreme; 3 - High; FLAMMABILITY: 3 2 - Moderate; 1 - Slight; REACTIVITY: 0 0 - Insignificant II - Hazardous Ingredients SUBSTANCE Methanol Key: Values reported as TWA unless noted. APPROX OSHA ACGIH EPA 40 CFR: % PEL TLV 302 355 372 65.0-75.0 200 ppm 200 ppm Y N Y CAS # 67-56-1 PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exp osure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT (°F): N/D VAPOR PRESSURE (mm Hg): N/D VAPOR DENSITY (AIR = 1): N/D SOLUBILITY IN WATER: Soluble APPEARANCE AND ODOR: Clear, dark blue liquid; alcohol odor. SPECIFIC GRAVITY (WATER = 1): 0.875 VOC CONTENT (% by weight): 65.0-75.0 EVAPORATION RATE (WATER = 1): N/D pH: N/A IV - Fire and Explosion Hazard Data FLASH POINT (°F): < 70 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/D LOWER: N/D EXTINGUISHING MEDIA: Water, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Vapors may travel considerable distance to a source of ignition and flash back. PRODUCT NAME: Windshield Deicer Concentrate PRODUCT CODE: 0470 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers. CONDITIONS TO AVOID: Heat, sparks and open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None. EFFECTS OF OVEREXPOSURE IF IN EYES: Mild irritation and redness, tearing, blurred vision. May injure eye tissue if not removed promptly. IF ON SKIN: Redness, dryness, irritation, defatting with prolonged or repeated exposure. IF SWALLOWED: Gastrointestinal irritation, dizziness, drowsiness, drunkenness, weakness, CNS depression. May be harmful or fatal if swallowed. Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchiopneumonia or pulmonary edema. IF INHALED: Respiratory tract irritation, nausea, vomiting, headache and dizziness. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Wash with soap and water. Remove contaminated clothing and launder before reuse. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Give affected person one to two glasses of water. Do not induce vomiting unless told to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If breathing has stopped administer artificial respiration. If breathing is difficult, administer oxygen. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and remove all source of ignition. Soak up spilled material with inert absorbent material and place in a properly labeled container for proper disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses or chemical goggles OTHER PROTECTIVE EQUIPMENT: Eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat or open flame. Keep container tightly closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: Compounds, cleaning liquid (Methanol) DOT CLASS: 3 DOT ID NUMBER: NA1993 DOT PACKING GROUP: II The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportat ion is further intended, different shipping names and labeling may apply. REVISION DATE: November 11, 2004 Prepared by: PMR DATE OF ISSUE: December 29, 2004 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material.