lc104002

lc104002
Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 12/11/2013
Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product form
: Mixture
Product name
: Acetic Acid, 6.0N (6.0M)
Product code
: LC10400
1.2.
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
1.3.
: For laboratory and manufacturing use only.
Details of the supplier of the safety data sheet
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com
1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
GHS-US classification
Skin Corr. 1C H314
Eye Dam. 1 H318
2.2.
Label elements
GHS-US labelling
Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
: Danger
GHS05
Hazard statements (GHS-US)
: H314 - Causes severe skin burns and eye damage
Precautionary statements (GHS-US)
: P260 - Do not breathe mist, vapours, spray
P264 - Wash exposed skin thoroughly after handling
P280 - Wear protective gloves, eye protection
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable
for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P363 - Wash contaminated clothing before reuse
P405 - Store locked up
P501 - Dispose of contents/container to comply with local, state and federal regulations
2.3.
Other hazards
Other hazards not contributing to the
classification
2.4.
: None.
Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1.
Substance
Not applicable
12/11/2013
EN (English)
Page 1
Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Full text of H-phrases: see section 16
3.2.
Mixture
Name
Product identifier
%
GHS-US classification
Water
Acetic Acid
(CAS No) 7732-18-5
65.42
34.58
Not classified
Flam. Liq. 3, H226
Skin Corr. 1B, H314
Eye Dam. 1, H318
(CAS No) 64-19-7
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation
: Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a
position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact
: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact
: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion
: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or
doctor/physician.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries
: Causes severe skin burns and eye damage.
Symptoms/injuries after eye contact
: Causes serious eye damage.
4.3.
Indication of any immediate medical attention and special treatment needed
Obtain medical assistance.
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media
: Do not use a heavy water stream.
5.2.
Special hazards arising from the substance or mixture
Reactivity
5.3.
: Thermal decomposition generates : Corrosive vapours.
Advice for firefighters
Firefighting instructions
: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
Protective equipment
: Safety glasses. Gloves. Protective clothing.
Emergency procedures
: Evacuate unnecessary personnel.
6.1.2.
For emergency responders
Protective equipment
: Equip cleanup crew with proper protection.
Emergency procedures
: Ventilate area.
6.2.
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3.
Methods and material for containment and cleaning up
Methods for cleaning up
6.4.
: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
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EN (English)
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Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Precautions for safe handling
: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour. Do not breathe mist, vapours, spray.
Hygiene measures
: Wash exposed skin thoroughly after handling. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Comply with applicable regulations.
Storage conditions
: Keep container closed when not in use.
Incompatible products
: Strong oxidizers. metals. Strong bases.
Incompatible products
: Sources of ignition. Direct sunlight.
7.3.
Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
Acetic Acid (64-19-7)
USA ACGIH
ACGIH TWA (ppm)
10 ppm
USA ACGIH
ACGIH STEL (ppm)
10 ppm
USA OSHA
OSHA PEL (TWA) (mg/m³)
25 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
10 ppm
8.2.
Exposure controls
Appropriate engineering controls
: Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure.
Personal protective equipment
: Avoid all unnecessary exposure.
Hand protection
: Wear protective gloves.
Eye protection
: Chemical goggles or face shield.
Skin and body protection
: Wear suitable protective clothing.
Respiratory protection
: Wear appropriate mask.
Other information
: Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Colour
: Colourless.
Odour
: Vinegar odour.
Odour threshold
: No data available
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Self ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: No data available
Density
: 1.04 g/ml
Solubility
: Soluble in water.
Log Pow
: No data available
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EN (English)
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Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Log Kow
: No data available
Viscosity, kinematic
: 1.7 cSt
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: No data available
9.2.
Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.
Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2.
Chemical stability
Stable under normal conditions.
10.3.
Possibility of hazardous reactions
Reacts violently with (some) bases: release of heat.
10.4.
Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5.
Incompatible materials
Strong oxidizers. metals. Strong bases.
10.6.
Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
Water (7732-18-5)
LD50 oral rat
: Not classified
≥ 90000 mg/kg
Skin corrosion/irritation
: Causes severe skin burns and eye damage.
Serious eye damage/irritation
: Causes serious eye damage.
Respiratory or skin sensitisation
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
Potential Adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met.
Symptoms/injuries after eye contact
: Causes serious eye damage.
SECTION 12: Ecological information
12.1.
Toxicity
Acetic Acid (64-19-7)
LC50 fishes 1
EC50 Daphnia 1
EC50 other aquatic organisms 1
LC50 fish 2
EC50 Daphnia 2
12/11/2013
75 mg/l (96 h; Lepomis macrochirus)
47 mg/l (24 h; Daphnia magna; Not neutralized)
> 5000 mg/l (5 h; Activated sludge)
94 mg/l (96 h; Oryzias latipes)
95 mg/l (24 h; Daphnia magna; Static system)
EN (English)
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Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Acetic Acid (64-19-7)
TLM fish 1
Threshold limit algae 1
Threshold limit algae 2
12.2.
100 ppm (96 h; Carassius auratus)
90 mg/l (192 h; Microcystis aeruginosa; Neutralized)
4000 mg/l (192 h; Scenedesmus quadricauda; Neutralized)
Persistence and degradability
Acetic Acid, 6.0N (6.0M)
Persistence and degradability
Not established.
Acetic Acid (64-19-7)
Persistence and degradability
Biochemical oxygen demand (BOD)
Chemical oxygen demand (COD)
ThOD
BOD (% of ThOD)
Readily biodegradable in water. Inherently biodegradable. Biodegradable in the soil.
0.6 - 0.74 g O²/g substance
1.03 g O²/g substance
1.07 g O²/g substance
0.56 - 0.69 % ThOD
Water (7732-18-5)
Persistence and degradability
Not established.
12.3.
Bioaccumulative potential
Acetic Acid, 6.0N (6.0M)
Bioaccumulative potential
Not established.
Acetic Acid (64-19-7)
Log Pow
Bioaccumulative potential
-0.31 (Experimental value)
Bioaccumulation: not applicable.
Water (7732-18-5)
Bioaccumulative potential
Not established.
12.4.
Mobility in soil
Acetic Acid (64-19-7)
Surface tension
12.5.
0.028 N/m (20 °C)
Other adverse effects
Other information
: Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
Transport document description
: UN2790 Acetic acid solution (with more than 10 percent and less than 50 percent acid, by mass),
8, III
UN-No.(DOT)
: 2790
DOT NA no.
: UN2790
DOT Proper Shipping Name
: Acetic acid solution
Department of Transportation (DOT) Hazard
Classes
: 8 - Class 8 - Corrosive material 49 CFR 173.136
Hazard labels (DOT)
: 8 - Corrosive substances
Packing group (DOT)
: III - Minor Danger
with more than 10 percent and less than 50 percent acid, by mass
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EN (English)
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Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
DOT Special Provisions (49 CFR 172.102)
: IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx)
: 154
DOT Packaging Non Bulk (49 CFR 173.xxx)
: 203
DOT Packaging Bulk (49 CFR 173.xxx)
: 242
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5L
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
DOT Vessel Stowage Location
: A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
Additional information
Other information
: No supplementary information available.
ADR
Transport document description
:
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15: Regulatory information
15.1. US Federal regulations
Acetic Acid, 6.0N (6.0M)
SARA Section 311/312 Hazard Classes
Immediate (acute) health hazard
Acetic Acid (64-19-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
RQ (Reportable quantity, section 304 of EPA's
5000 lb
List of Lists) :
Water (7732-18-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Acetic Acid, 6.0N (6.0M)
WHMIS Classification
Acetic Acid (64-19-7)
WHMIS Classification
Water (7732-18-5)
WHMIS Classification
Class E - Corrosive Material
Class B Division 3 - Combustible Liquid
Class E - Corrosive Material
Uncontrolled product according to WHMIS classification criteria
EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
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EN (English)
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Acetic Acid, 6.0N (6.0M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Classification according to Directive 67/548/EEC or 1999/45/EC
Not classified
15.2.2.
National regulations
No additional information available
15.3. US State regulations
No additional information available
SECTION 16: Other information
Other information
: None.
Full text of H-phrases: see section 16:
-----Eye Dam. 1
-----Flam. Liq. 3
-----Skin Corr. 1B
-----Skin Corr. 1C
-----H226
-----H314
-----H318
Serious eye damage/eye irritation, Category 1
Flammable liquids, Category 3
Skin corrosion/irritation, Category 1B
Skin corrosion/irritation, Category 1C
Flammable liquid and vapour
Causes severe skin burns and eye damage
Causes serious eye damage
NFPA health hazard
: 3 - Short exposure could cause serious temporary or
residual injury even though prompt medical attention was
given.
NFPA fire hazard
: 0 - Materials that will not burn.
NFPA reactivity
: 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS III Rating
Health
: 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability
: 0 Minimal Hazard
Physical
: 0 Minimal Hazard
Personal Protection
: H
SDS US (GHS HazCom 2012)
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
12/11/2013
EN (English)
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