SAFETY DATA SHEET LOW PRESSURE POLYURETHANE FOAM B-SIDE COMPONENT (134a) SECTION 1- IDENTIFICATION

SAFETY DATA SHEET LOW PRESSURE POLYURETHANE FOAM B-SIDE COMPONENT (134a) SECTION 1- IDENTIFICATION
SAFETY DATA SHEET
LOW PRESSURE POLYURETHANE FOAM
B-SIDE COMPONENT (134a)
SECTION 1- IDENTIFICATION
1.1 Product Identifier
Product Name:
Handi-Foam® E84 Class 1, Handi-Foam® Quick Cure, Handi-Foam ® SPF Roof Patch, Handi-Foam ®
Air Seal, Hand-Flow® Slow Rise, and Silent Seal ® SA.
ID SDS:
REACH Registration:
A16178B
1.2 Relevant identified uses of the substance or mixture and uses advised against:
General Use
Uses advised against
Low pressure polyurethane foam, Side-B Component, for PROFESSIONAL USE ONLY
No further information available
1.3 Details of the supplier and of the safety data sheet:
Manufacturer
Fomo Products Inc.
2775 Barber Road
Norton, Ohio 44203
In Ohio: 330-753-4585; 1-800-321-5585 (Monday-Friday, 8:00 am – 5:00pm EST)
1.4 Emergency telephone numbers:
In the U.S.A
International
CHEMTREC (24 hours) 1-800-424-9300
CHEMTREC (24 hours) 1-703-527-3887
SECTION 2- HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Mixture
Product definition:
Gases Under Pressure- Compressed Gas
Classification:
Skin Irritation- Category 2
Eye Irritation- Category 2A
2.2 Label elements
Labeling (Regulation (EC) No 1272/2008)
Hazard Symbols:
Signal Word:
Hazard Statements:
WARNING
H280
H315
H319
Contains gas under pressure; may explode if heated
Causes skin irritation
Causes serious eye irritation
P102
P201
P202
P251
P264
P271
P280
Keep Out of Reach of Children
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Pressurized container: Do not pierce or burn, even after use.
Wash hands and other skin areas exposed to material thoroughly after handling
Use outdoors or in a well-ventilated area
Wear protective gloves, protective clothing and eye protection
Prevention:
Response:
P302+P352
P305+P351+P338
P321
P333+P313
P337+P313
P362
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Specific treatment: Seek immediate medical advice. Refer to product label and Section 4 of this SDS
If skin irritation or rash occurs: Get medical attention
If eye irritation persists: Get medical attention
Take off contaminated clothing and wash before reuse.
P405
P410+P403
Store locked up
Protect from sunlight. Store in a well-ventilated place.
Storage:
Disposal:
P501
Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
Low Pressure SPF Side B (134a)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 2 OF 7
SECTION 3-COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances
Not applicable
3.2 Mixtures
Chemical characterization (preparation):
% by Weight
Ingredient
30-60
15-45
10-30
1-5
0.5 – 1.5
Proprietary Polyol Blend
Tris (1-chloro-2-propyl) Phosphate
1,1,1,2- Tetrafluoroethane
Pentamethyldiethylenetriamine
Diethylene Glycol
CAS No.
EC Number
EC Classification
13674-84-5
811-97-2
3030-47-5
111-46-6
237-158-7
217-377-0
221-201-1
203-872-2
T, R24; Xn,R22; C,R34
Xn, R22
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to the health or the environment and hence require reporting in this section.
SECTION 4- FIRST AID MEASURES
4.1 Description of first aid measures
Inhalation:
Eye:
Skin:
Ingestion:
If product vapors causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
difficult or irregular, administer oxygen. If respiratory arrest occurs, start artificial respiration by a trained individual. Loosen
tight fitting clothing such as a jacket or tie. Seek medical attention immediately.
Immediately flush eyes with large amounts of water for at least 15 minutes, holding the eyes open with fingers and
occasionally lifting the upper and lower lids. Use lukewarm water if possible. If present and easy to do, remove contact lenses.
If irritation persists, get medical attention.
Flush skin with large amounts of water while removing contaminated clothing. Gently wipe product from skin with a damp cloth
and continue rinsing for 15 minutes. Wash clothing before reuse. Call a physician if irritation persists.
If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation:
Eye:
Skin:
Ingestion:
Chronic:
Mist or vapor may cause irritation of the nose, throat and respiratory tract. Symptoms may include sore throat, coughing,
headache, nausea and shortness of breath. Inhalation of propellant may cause lightheadedness, headache and lethargy.
May cause eye irritation. Symptoms may include redness, swelling, stinging, and tearing. May cause temporary corneal
injury. Product vapor may cause eye irritation with symptoms of burning and tearing.
May cause mild skin irritation. Symptoms may include localized redness and discomfort.
May cause gastrointestinal irritation: stomach distress, nausea, or vomiting. Repeated ingestion may be harmful.
Pre-existing disorders of the skin and respiratory system may be aggravated by exposure to this product. Diethylene glycol
has caused reproductive and developmental effects in some laboratory animal’s tests.
4.3 Notes to the physician
If case of an accident or if you feel unwell, seek medical advice immediately (show label or SDS if possible).
SECTION 5- FIRE FIGHTING MEASURES
5.1 Extinguishable media
Suitable methods of extinction: Use dry chemical, carbon dioxide, alcohol resistant foams and water spray
Unsuitable methods of extinction: None
5.2 Special hazards arising from the substance or mixture
Cans, cylinders, or refillable tanks may explode due to the buildup of pressure when exposed to extreme heat. Highly toxic gases may be
generated by thermal decomposition or combustion. Overexposure to decomposition products may cause a health hazard. Symptoms may
not be immediately apparent or may be delayed.
5.3 Advice for firefighters
Keep upwind of fire. Wear full fire-fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fireexposed containers cool.
SECTION 6- ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected
personnel. Eliminate sources of ignition. Ventilate the area.
6.2 Environmental precautions
Avoid dispersal of spilled material or run-off and prevent contact with soil and entry into drains, sewers or waterways.
Low Pressure SPF Side B (134a)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 3 OF 7
6.3 Methods and materials for containment and cleaning up
Cover drains and contain spill. Cover spilled material with a large quantity of inert absorbent. Collect material and place into an approved,
open-head metal container. Clean contaminated area with soap and water.
6.4 Reference to other sections
For indications about waste treatment, see Section 13
SECTION 7- HANDLING AND STORAGE
7.1 Precautions for safe handling
Observe label precautions. Wear all appropriate protective equipment specified in Section 8. Keep containers closed when not in use.
Advice on protection against fire and explosion
Contents under pressure. Exposure to high temperatures can cause containers to rupture or explode.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry, well-ventilated area and away from incompatible materials (see Section 10.5). Storage temperature is 60-90F (16-32C).
Products stored below 60F (16C) or above 90F (32C) must be given adequate time to warm up/cool down. Do not expose the tanks/kits
to open flame or temperatures above 122F (50C); storage at elevated temperatures can cause the container to rupture. Excessive heat
can cause premature aging of components resulting in a shorter shelf life. Protect unused product from freezing. Storage below 60F
(16C) may affect foam quality if chemicals are not warmed to room temperature before using. Protect containers from physical abuse.
Always store the containers in the upright position. KEEP OUT OF REACH OF CHILDREN.
SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control Parameters
Ingredient
CAS Number
OSHA-PEL
ACGIH-TLV
Other
Diethylene Glycol
111-46-6
WEEL 10 mg/kg
1,1,1,2 Tetrafluoroethane
811-97-2
WEEL 1,000 ppm
8.2 Exposure controls:
Engineering Controls: Use local and general exhaust ventilation to control levels of exposure.
Eye/face Protection: Wear protective goggles or safety glasses with side shields.
Hand Protection: Use chemically resistant gloves (i.e. Nitrile gloves). Nitrile/butadiene rubber, butyl rubber, polyethylene, PVC (vinyl), or
neoprene gloves are also effective. Glove selection should take into account potential body reactions to certain materials and
manufacturer’s instructions for use. Break through time of selected gloves must be greater than the intended use period.
Other Protective Equipment: Use clothing that protects against dermal exposure. Appropriate protective clothing varies depending on the
potential for exposure. To ensure proper skin protection, wear PPE in such a manner that no skin is exposed.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guidelines. Use products only in a well-ventilated
area. Engineering and administrative (work practices) controls should be implemented to protect the workers. If atmospheric levels are
expected to exceed the exposure levels, use a NIOSH approved air purifying respirator equipped with an organic vapor cartridge and a
particulate filter. If atmospheric levels exceed 10 times the TLV or PEL level for which an air-purifying respirator is effective, use a powered
air purifying respirator (PAPR). The type of respiratory protection selected must comply with the requirements set forth in OSHA’s
Respiratory Protection Standard (29 CFR 1910.134). The odor and irritancy of this material is inadequate to warn of excessive exposure.
Hygiene Measures: An eye wash station or portable eye wash station should be in the area. Wash hands thoroughly after use, before
eating, drinking or using the lavatory. Employees/Users should be educated and trained in the safe use and handling of this product.
SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
General Physical Form
Odor
Odor Threshold
pH
Melting Point/Freezing Point
Initial Boiling Point and Boiling Range
Flash Point
Evaporation Rate
Flammability
Lower Flammability/Explosive Limit
Amber to dark brown liquid. Forms an off-white to yellowish froth when released from the
container
Slight fluorocarbon and amine odor
No data available
No data available
No data available
Propellant -26C (-15F); >93C (200F), liquid phase
Estimated >392F (>200C).
No data available
No applicable
Not available
Low Pressure SPF Side B (134a)
Upper Flammability/Explosive Limit
Vapor Pressure in Container
Vapor Pressure of Liquid
Vapor Density
Relative Density/Specific Gravity
Solubility
Partition coefficient: n-octanol/water
Auto-ignition Temperature
Decomposition Temperature
Viscosity
Oxidizing Properties
VOC Content (calculated minus
exempt compounds)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 4 OF 7
Not available
Contents under pressure have a vapor pressure >50 psi (>345kPa)
Liquid phase vapor pressure: <1 mm Hg @ 40C
No data available
~ 1.2 @ 25C (Water = 1)
Water: partly soluble, does not react
No data available
No data available
No data available
No data available
Not available
Calculated at around 25 g/L
SECTION 10- STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions of use and recommended storage conditions. See Section 7 for storage recommendations.
10.3 Possibility of hazardous reactions
Exposure to elevated temperatures can cause containers to rupture or explode. Contents are under pressure.
10.4 Conditions to avoid
Temperatures below 60°F (16°C) or temperatures above 90°F (32°C). Avoid heat and flames.
10.5 Incompatible materials
Alcohols, strong bases, amines, metal compounds, ammonia, and strong oxidizers.
10.6 Hazardous decomposition products
May include, and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen fluoride and traces of hydrogen cyanide.
SECTION 11- TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute oral toxicity
Expected to have low acute oral toxicity
Acute inhalation toxicity
Expected to have low acute inhalation toxicity
Acute dermal toxicity
Expected to have a low acute dermal toxicity
Skin irritation
May cause mild skin irritation
Eye irritation
Causes eye irritation
Sensitization
No data available
Genotoxicity
No data available
Mutagenicity
No data available
Specific organ toxicity- single exposure
No data available
Specific organ toxicity- repeated exposure
No data available
Aspiration hazard
No data available
11.2 Further information
None of the components of this product are listed as carcinogens by IARC, ACGIH, NTP or OSHA. No data is available regarding the
mutagenicity or teratogenicity of this product, nor is there any available data that indicates that it causes adverse or fertility effects.
Chronic toxicity from prolonged and repeated exposure to Diethylene glycol (DEG) is associated with kidney, and to a lesser degree liver
effects. Available data indicates that DEG is negative in in-vitro genotoxicity tests. Some positive results were obtained in in-vivo
genotoxicity studies, however, only at high toxic doses of DEG. Overall, DEG is considered non-genotoxic. Several animal reproductive
toxicity studies indicate that human data or case reports on reproductive and developmental effects of DEG are available.
Handle in accordance with good industrial hygiene and safe practices.
Low Pressure SPF Side B (134a)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 5 OF 7
SECTION 12- ECOLOGICAL INFORMATION
12.1 Ecotoxicity
The ecotoxicity of this product has not been experimentally determined. However, it is expected to have low acute aquatic toxicity based on
the acute aquatic toxicity of the individual components and their concentrations in this composition.
12.2 Persistence and degradability
Product is readily biodegradable.
12.3 Bioaccumulation potential
Product is not expected to bioaccumulate
12.4 Mobility
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
Additional ecological information: Do not allow material to run into surface waters, wastewater, or soil. An environmental hazard cannot
be excluded in the event of unprofessional handling or disposal
SECTION 13- DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Always wear proper protective equipment as you would while spraying the two-component foam in a well-ventilated area.
Procedure for handling empty or partially used disposable cylinders:
1. DO NOT INCINERATE TANKS
2. Dispense the foam into a waste container like a cardboard box or plastic bag. Depressurize the used cylinders using the
dispensing unit with a new nozzle attached. Spray the foam until one of the components/cylinders no longer sprays chemical.
3. Remove the nozzle and then continue to depressurize by dispensing the chemicals into a waste container (a box lined with a
plastic bag) that has adequate industrial liquid absorbing medium in the bottom. Dispense the residual chemicals until the
pressure is down to a minimum or there are just large bubbles in the hose.
4. Close the cylinder valves completely, and then operate the dispensing unit again to empty and depressurize the hoses. Use a
9/16” wrench and remove the hoses from the cylinders. Use caution in case there is some residual chemical and/or pressure in
the hoses.
5. Invert the cylinder and point away from face. Slowly open the cylinder over the waste container to catch any residual spray.
6. Return the cylinder to an upright position. Shake the container; there should not be any sloshing of liquid. Make sure to leave
valves OPEN-do not close.
7. DISPOSE OF EMPTY CYLINDERS ACCORDING TO APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. CHECK
WITH YOUR LOCAL WASTE DISPOSAL SERVICE FOR GUIDANCE.
NOTE: After dispensing if one cylinder has chemical left in it; treat as hazardous material.
Procedure for handling empty refillable tanks:
THESE TANKS ARE RETURNABLE. These tanks are shipped back to Fomo Products, Inc. to be cleaned, refilled, and redistributed.
Return instructions are included in or on the A-tank collar.
SECTION 14- TRANSPORTATION
Note: Transportation information is for reference only. Customer is urged to consult 49 CFR 100-177, IMDG, IATA, EC, United Nations
TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging
materials and methods of shipping.
Containers Less Than 1000 cu. cm. (1 liter)
Containers Greater Than 1000 cu. cm. (1 liter)
Ground
Consumer Commodity ORM-D
UN1956 Compressed Gas n.o.s. (Fluorinated
hydrocarbon, nitrogen) 2.2 (Non-Flammable Gas
Label)
UN1950 Aerosols, Non-flammable 2.2
(Non-flammable Gas Label)
LIMITED QUANTITY
Packing Instructions (Cargo & Passenger) 203
UN1956 Compressed Gas n.o.s. (Fluorinated
hydrocarbon, nitrogen) 2.2 (Non-flammable Gas Label)
Packing Instruction (Cargo & Passenger) 200
UN1950 Aerosols, Non-flammable 2.2
(Non-flammable Gas Label)
LIMITED QUANTITY
UN1956 Compressed Gas n.o.s. (Fluorinated
hydrocarbon, nitrogen 2.2 (Non-flammable Gas Label)
Air
Water
Low Pressure SPF Side B (134a)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 6 OF 7
SECTION 15- REGULATORY
15.1 Safety, health, and environmental regulations/legislations specific for the substance or mixture
U.S. Federal Regulations:
OSHA Hazard Communication Standard: This material is classified as hazardous in accordance with OSHA 29 CFR 1910-1200
TSCA Status: All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory. This product is not
subject to TSCA 12(b) Export Notification.
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard
SARA 313 Information: No components of the product are subject to reporting levels established by Section 313 of the Emergency
Planning and Community Right-to-Know Act of 1986.
SARA 302/304 Extremely Hazardous Substance: No components of the product exceed the threshold (de minimis) reporting levels
established by these sections of the Title III of SARA.
SARA 302/304 Emergency Planning & Notification: No components of the product exceed the threshold (de minimis) report levels
established by these sections of the Title III of SARA.
Comprehensive Response Compensation and Liability Act (CERCLA): None of the substances in this product are contained in levels
that exceed the threshold (de minimis) reporting levels established by CERCLA
Clean Air Act (CAA) – This product does not have any components listed as a Hazardous Air Pollutant (HAP) designated in CAA
Section 112 (b). This product does not contain any Class 1 or Class 2 Ozone depletors.
Clean Water Act (CWA) – This products does not have any components listed as a Hazardous Substance under the CWA. None of the
chemicals in these products are listed as Priority Pollutants under the CWA. None of the chemicals listed in these products are listed as
Toxic Pollutants under the CWA.
U.S. State Regulations:
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains trace amount of substances
known to the State of California to cause cancer or other reproductive harm.
Other U.S. State Inventories:
Diethylene glycol (CAS#111-46-6) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air
Quality/air Pollutants lists: MN, PA
1,1,1,2- Tetrafluoroethane (CAS #811-97-2) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or
Air Quality/Air Pollutants lists: ME, WI
Canada
WHMIS Hazard Symbol and Classification:
A- Compressed Gas
Canada Controlled Product Regulations (CPR): This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulation, and the SDS contains all the information required by the Controlled Products Regulations.
Canadian Ingredient Disclosure List (IDL): None of the substances in this product are listed on the IDL.
Canadian National Pollutant Release Inventory (NPRI): None of the components of this product are listed on the NPRI
European Economic Community
Labeling (67/548/EEC or 1999/45/EC): None allocated
Risk Phrases: R22 Harmful if swallowed
R36 Irritating to eyes
R38 Irritating to skin
WGK, Germany (Water danger/protection): 1
Global Chemical Inventory Lists:
United States: Toxic Substance Control Act (TSCA)- Yes
Canada: Domestic Substances List (DSL)- Yes
Canada: Non-Domestic Substances List (NDSL)- No
Europe: Inventory of New and Existing Chemicals- (EINECS)- Yes
Australia: Australian Inventory of Chemical Substances (AICS)- Yes
New Zealand: New Zealand Inventory of Chemicals (NZLoC)- Yes
China: Inventory of Existing Chemical Substances in China (IECSC)- Yes
Japan: Inventory of Existing and New Chemical Substances (ENCS)- Yes
Korea: Existing Chemicals List (ECL)- Yes
Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS)- Yes
15.2 Chemical safety assessment: For this product a chemical safety assessment was not carried out
Low Pressure SPF Side B (134a)
ISSUE DATE: March 2005
LAST REV: March 2015
PAGE 7 OF 7
SECTION 16- OTHER
NFPA: Health Hazard 2; Flammability 1; Reactivity 1
HMIS: Health Hazard 2; Flammability 1; Physical Hazard 1
Hazard Rating: 0=minimal, 1= slight, 2=moderate, 3=severe, 4= extreme
The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof. The
manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the
persons receiving it will make their own determination as to its suitability for their purposes prior to use. In no event will the manufacturer
be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. No representations or
warranties, either expressed or implied, of merchantability or fitness for a particular use are made hereunder with respect to this information
or the product to which information refers.
Information contained herein is deemed to be reliable, conservative and accurate. Fomo Products, Inc. reserves the right to change the
design, specifications or any other features at any time and without notice, while otherwise maintaining regulatory compliance.
Revision-Updated to GHS Format, March 24, 2015 (Date of Preparation) Version 2.1
Replaces Version 2.0- November 18, 2014
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