MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 CHEMTREC: (800) 424-9300 REVISION DATE: November 9, 2004 DATE OF ISSUE: November 9, 2004 I - Product Identification MR 2 PRODUCT CODE: 0210 CHEMICAL FORMULATION: Powdered glass cleaner. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 HAZARD RATING: 4 - Extreme; 3 - High; FLAMMABILITY: 0 2 - Moderate; 1 - Slight; REACTIVITY: 0 0 - Insignificant II - Hazardous Ingredients SUBSTANCE Values reported as TWA unless noted. APPROX OSHA ACGIH EPA 40 CFR: % PEL TLV 302 355 372 Sodium Sulfate 30.0-40.0 N/E Sulfamic acid 15.0-25.0 N/E Crystalline silica N/E N/E 3 3 CAS # N N N 7757-82-6 N N N 5329-14-6 15.0-25.0 (0.1 mg/m ) (0.1 mg/m ) N N N 14808-60-7 10.0-20.0 1 mg/m3 1 mg/m3 N N N 144-62-7 1.00-10.0 3 N N N 68855-54-9 (respirable fraction) Oxalic acid Diatomaceous Earth Key: 6 mg/m 3 10 mg/m PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT (°F): N/A SPECIFIC GRAVITY (WATER = 1): N/A VAPOR PRESSURE (mm Hg): N/A VOC CONTENT (% by weight): N/A VAPOR DENSITY (AIR = 1): N/A EVAPORATION RATE (WATER = 1): N/A SOLUBILITY IN WATER: Complete pH: N/D APPEARANCE AND ODOR: Free flowing off white powder, no odor. IV - Fire and Explosion Hazard Data FLASH POINT (°F): N/A (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Water, foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: Foam or water may cause frothing. Emits highly toxic and irritating fumes in a fire. Closed containers exposed to heat may explode. PRODUCT NAME: MR2 PRODUCT CODE: 0210 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers and alkali, nitrates, nitrites, carbonates, sulfides, cyanides, sodium oxide, sulfur oxides. CONDITIONS TO AVOID: Extreme heat & aluminum. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of sulfur, nitrogen, ammonia & formic acid. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: Crystalline silica (CAS #14808-60-7) EFFECTS OF OVEREXPOSURE IF IN EYES: Severe irritation & burns. Permanent damage may result. IF ON SKIN: Moderate to severe irritation. Prolonged skin contact may cause burns. IF SWALLOWED: Nausea, vomiting. May be harmful if swallowed. IF INHALED: Extremely harmful to mucous membranes and upper respiratory tract. Respirable crystalline silica can cause silicosis. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Flush with water for 15 minutes while removing contaminated clothing. Launder clothing separately before reuse. If irritation persists, obtain medical attention. IF SWALLOWED: Contact physician or poison control center immediately. Give affected person 1 to 2 glasses of water. Do not induce vomiting unless instructed by a physician or poison control center. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If breathing has stopped, administer artificial respiration. If breathing is difficult administer oxygen. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and remove all sources of ignition. Scoop up spilled material, avoiding generation of dust, and place in a properly marked closed container for proper disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breathe dust. If recommended Exposure Limits are exceeded wear a NIOSH approved respirator, following manufacturer’s recommendations. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses or goggles. OTHER PROTECTIVE EQUIPMENT: Eye wash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat or open flame. Keep container tightly closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: Consumer Commodity DOT CLASS: ORM-D DOT ID NUMBER: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. REVISION DATE: November 9, 2004 Prepared by: PMR DATE OF ISSUE: November 9, 2004 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material.