Chlorine Starter Kit MSDS
Page 1 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Spa Sanitizing Granules
GENERAL USE: Spa Sanitizer
PRODUCT DESCRIPTION: Sodium Dichloro-s-trazinetione Dihydrate
MOLECULAR FORMULA: C3CI2N3O3Na-2H2O
ACTIVE INGREDIENT(S): Sodium Dichloro-s-triazinetrione Dihydrate
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: White granular product
IMMEDIATE CONCERNS: Corrosive. Causes irreversible eye damage. May be fatal if inhaled. Harmful if swallowed
or absorbed through skin. Will burn with evolution of chlorine and equally toxic gases. Do not get in eye, on skin, or
on clothing. Avoid breathing dust and fumes.
POTENTIAL HEALTH EFFECTS
EYES: Dust and process vapors may irritate eyes.
SKIN: Initially non-irritating but prolonged contact will produce chemical burns. Burns are also induced when moisture
is added.
INGESTION: May cause Irritation or burns to the gastrointestinal tract.
INHALATION: Irritating to nose, mouth, throat and lungs. May cause burns to respiratory tract.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
ACUTE TOXICITY: Repeated exposure may cause eye, nose, throat and pharynx irritation.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
Chemical Name
Sodium Dichloro-s-triazinetrione Dihydrate
Wt.%
CAS
EINECS
100 051580-86-0
--
COMMENTS: 55.0 - 56.0% active chlorine
4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if
symptoms occur. Wash clothing before reuse.
INGESTION: Immediately drink large quantities of water. Do NOT induce vomiting. Call a physician at once. Do not give
anything by mouth to an unconscious person.
INHALATION: Remove victim to fresh air. If breathing is difficult, administer oxygen. Call a physician.
ADDITIONAL INFORMATION: Chronic Effect: Prolonged contact may result in irritation to eyes, skin and mucous
membranes.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Not Applicable
FLAMMABLE LIMITS: 0 to 0
Notes: Non-flammable.
EXTINGUISHING MEDIA: Use massive amounts of water.
EXPLOSION HAZARDS: Highly reactive oxidizing materials may result in fire.
FIRE FIGHTING PROCEDURES: Saturate with massive quantities of water to extinguish thermal decomposing
products. If possible, isolate them to an open area, wearing self-contained breathing apparatus with full facepiece and
protective clothing.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Sweep up spill with a dry broom and contain. Do not allow material to sit on ground and become moist.
Do not contaminate with water, organics or nitrogen compounds.
7. HANDLING AND STORAGE
Page 3 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
HANDLING: Keep away from moisture, sunlight and high temperatures. Keep away from flammable liquids,
combustibles and oxidizers. Avoid dust formation.
STORAGE: Store in a cool, dry, well-ventilated area. Do not store at temperatures above 60 deg C/140 deg F.
STORAGE TEMPERATURE: Less than 25 degrees Celsius.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL
Chemical Name
Sodium Dichloro-s-triazinetrione
Dihydrate
ppm
mg/m 3
ACGIH TLV
ppm
TWA
Not
Established
Not
Established
STEL
Not
Established
Not
Established
mg/m3
SupplierOEL
ppm
mg/m 3
[1]
[1]
Footnotes:
1. The TLV for Chlorine is 0.5 ppm (1.5 mg/m3) TWA and 1ppm STEL.
ENGINEERING CONTROLS: Local exhaust with circulation to the outside is needed in the event of decomposition
which produces fumes and chlorine gas.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear chemical safety glasses or goggles.
SKIN: Impervious gloves.
RESPIRATORY: If needed, use OSHA-NIOSH approved respirator for dusts, mists, and fumes with TLV not less
thatn 0.05 mg/m3.
PROTECTIVE CLOTHING: Neoprene apron and impervious clothing.
WORK HYGIENIC PRACTICES: Provide safety shower and eyewash station in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Solid
ODOR: Mild chlorine.
APPEARANCE: White granular.
pH: 6.5
Page 4 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
VAPOR PRESSURE: 100
VAPOR DENSITY: 100
BOILING POINT: Not Applicable
FREEZING POINT: Not Applicable
FLASHPOINT AND METHOD: Not Applicable
SOLUBILITY IN WATER: 26.2 g/100ml H2O at 25 degrees C
EVAPORATION RATE: Not Applicable
SPECIFIC GRAVITY: 1.95
VISCOSITY: Not Applicable
(VOC): 100.000
10. STABILITY AND REACTIVITY
STABILITY: Stable under dry and normal conditions.
POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen trichloride, chlorine, cyanic acid
INCOMPATIBLE MATERIALS: Avoid contact with organic matter. Avoid contact with easily chlorinated or oxidized
materials which may result in fire.
Avoid contact with ammonia, ammonium salts, urea or similar compounds which contain nitrogen. This may form
nitrogen trichloride, a highly explosive compound.
Avoid contamination with oils and greases which may cause decomposition with the formation of CO2 and CI2.
This product may form an explosive mixture with calcium hypochlorite.
In a formulation containing this material as the major component, alkaline materials such as soda ash (Na2CO3) in the
presence of moisture may cause violent decomposition and fire.
Avoid contact with alcohols, ethers, and solvents (toluene, xylene, turpentine, etc.)
Avoid contact with small amounts of water. (Do not add water to chemical, add chemical to water.)
11. TOXICOLOGICAL INFORMATION
COMMENTS: Acute Toxicity: Oral LD50 738 mg/kg (rat) 1355 (male) 1400 (female)
Page 5 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY (ACUTE)
48-HOUR EC50: 3.19 TLM ppm Oryzlas Latipes
GENERAL COMMENTS: This product is toxic to fish and aquatic life.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not restricted by DOT
SPECIAL SHIPPING NOTES: DOT Special Provision #28 states "The dihydrated sodium salt of dichlorisocyanuric acid
is not subject to the requirements of this subchapter."
15. REGULATORY INFORMATION
UNITED STATES
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All ingredients in this mixture are in compliance with TSCA.
REGULATIONS
STATE REGULATIONS Massachusetts Hazardous Substance - Yes
Pennsylvania Hazardous Substance - Yes
CALIFORNIA PROPOSITION 65: NA = Not Applicable
FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This is an EPA-registered product.
16. OTHER INFORMATION
REVISION SUMMARY: Revision #: 1 This MSDS replaces the June 11, 2008 MSDS. Any changes in information are as
follows: In Section 1 Date Prepared In Section 1 Date Prepared In Section 1 Date Prepared In Section 1 Date
Page 6 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Spa Sanitizing Granules
06/23/2008
1
Spa Choice Spa Sanitizing Granules
Prepared In Section 1 Date Prepared In Section 1 Date Prepared In Section 1 Date Prepared In Section 1 Date
Prepared
NFPA CODES
HMIS RATING
HEALTH:
3
FLAMMABILITY:
0
PHYSICAL HAZARD:
1
0
3
1
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/01/2008
MSDS No: Spa Choice Clear & Sparkle
Revision No: New MSDS
Spa Choice Clear & Sparkle
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Clear & Sparkle
GENERAL USE: Swimming pool clarifier.
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
EYES: Minor transient irritation.
SKIN: Substance does not generally irritate and is only mildly irritating to susceptible people.
INGESTION: Poses little or no immediate hazard.
INHALATION: Not expected to be toxic by inhalation.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Wt.%
Proprietary Blend
100
4. FIRST AID MEASURES
EYES: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
SKIN: Wash with soap and water. Get medical attention if irritation develops or persists.
INGESTION: Not considered toxic.
INHALATION: Remove to fresh air.
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/01/2008
MSDS No: Spa Choice Clear & Sparkle
Revision No: New MSDS
Spa Choice Clear & Sparkle
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: > 100°C (212°F) CC
EXTINGUISHING MEDIA: Carbon dioxide, water, water fog, dry chemical, chemical foam.
EXPLOSION HAZARDS: None.
FIRE FIGHTING PROCEDURES: Spills produce extremely slippery surfaces.
FIRE FIGHTING EQUIPMENT: No special equipment required.
6. ACCIDENTAL RELEASE MEASURES
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or waterways.
GENERAL PROCEDURES: Do not flush with water. Dam up. Soak up with inert absorbent material. If liquid has been
spilled in large quantities, clean up promptly by scoop or vacuum. Keep in suitable and closed containers for disposal.
After cleaning, flush away traces with water.
7. HANDLING AND STORAGE
HANDLING: Wash hands after handling.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL
Chemical Name
Proprietary Blend
TWA
ppm
mg/m 3
[1]
[1]
Footnotes:
1. Although a component of this product is considered an OSHA Hazardous material, this product does not contain any
reportable OSHA hazardous materials.
ENGINEERING CONTROLS: Natural ventilation is adequate. Use local exhaust if misting occurs.
PERSONAL PROTECTIVE EQUIPMENT
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/01/2008
MSDS No: Spa Choice Clear & Sparkle
Revision No: New MSDS
Spa Choice Clear & Sparkle
EYES AND FACE: Wear safety glasses with side shields. Do not wear contacts.
RESPIRATORY: In case of insufficient respiration, wear suitable respiratory equipment.
PROTECTIVE CLOTHING: Chemical resistant apron.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild.
APPEARANCE: Blue liquid.
pH: 5.8 to 7.1
VAPOR PRESSURE: N/A
VAPOR DENSITY: 1.04 g/cm3
FLASHPOINT AND METHOD: > 100°C (212°F) CC
SOLUBILITY IN WATER: Complete.
EVAPORATION RATE: Not Available
VISCOSITY #1: 1000 to 3000 CPS
10. STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: No decomposition if stored and applied as directed. Burning of the dried
material can produce hydrogen chloride gas, nitrogen oxides (NOx), carbon oxides.
INCOMPATIBLE MATERIALS: Oxidizing agent may cause exothermic reactions.
11. TOXICOLOGICAL INFORMATION
ACUTE
ORAL LD50: > 2000 mg/kg (rat)
Notes: Not expected to be toxic.
CHRONIC: NOEL/Oral (rat) 90 day = 5000 mg/kg.
IRRITATION: Testing on rabbits shows minor transient irritation which cleared in days. Skin exposure may cause skin
irritation with susceptible persons.
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/01/2008
MSDS No: Spa Choice Clear & Sparkle
Revision No: New MSDS
Spa Choice Clear & Sparkle
TERATOGENIC EFFECTS: Not teratogenic. Noel=175 mg/kg.
MUTAGENICITY: Not mutagenetic.
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY (ACUTE)
96-HOUR LC50: > 10 mg/l (Danio Rerio)
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Hazard Categories: Health: Immediate (Acute) Health Hazard
313 REPORTABLE INGREDIENTS: No ingredients listed at or above the de minimus level.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: No components of this product are present above the de minimus levels.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All ingredients in this mixture are in compliance with TSCA.
16. OTHER INFORMATION
REVISION SUMMARY: New MSDS
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/01/2008
MSDS No: Spa Choice Clear & Sparkle
Revision No: New MSDS
Spa Choice Clear & Sparkle
HMIS RATING
NFPA CODES
HEALTH:
1
FLAMMABILITY:
0
PHYSICAL HAZARD:
0
0
1
0
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Defense
Revision No: New MSDS
Spa Choice Defense
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Defense
GENERAL USE: Spa Descaler
MANUFACTURER
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: Irritating to eyes and skin.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: Ingestion is not expected to be a primary route of exposure.
INHALATION: May be harmful if inhaled. Do not breathe spray mists of the undiluted product. Effects will depend
upon strength and length of time of exposure.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
CARCINOGENICITY: Not listed by NTP, IARC or OSHA.
TARGET ORGAN STATEMENT: May cause damage to the eyes, skin and upper respiratory tract.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Proprietary Blend - No Reportable OSHA Hazardous Materials
4. FIRST AID MEASURES
Wt.%
0
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Defense
Revision No: New MSDS
Spa Choice Defense
EYES: Hold eyelids open and flush with a copious amounts of water for at least 15 minutes. Seek immediate medical
attention, preferably with an ophthalmologist.
SKIN: Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and wash thoroughly
before reuse. If irritation persists, consult a health care professional.
INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with plenty of water or milk. Irrigate the esophagus and dilute
the stomach by slowly giving1 to 2 glasses of water or milk. In cases where the individual is semi-comatose, comatose
or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In cases of intentional ingestion, seek immediate medical
assistance. Take individual to nearest medical facility.
INHALATION: Immediately move person to fresh air. If individual experiences nausea, headache, dizziness, has
difficulty in breathing or is cyanotic, seek immediate medical treatment.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Not Available
FLAMMABLE LIMITS: 0 to 0
EXTINGUISHING MEDIA: Water fog, carbon dioxide, foam, dry chemical.
FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective
gear.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide may be formed upon burning.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES: Initially minimize are affected by spill or leak. Block any potential routes to water systems.
Ensure that spilled or leaked product does not come into contact with material listed as incompaible. Clay, soil, or
commercially available absorbent may be used to recover any material that cannot readily be recovered as pure
product. Flushing residual material to an industrial sewer, may be acceptable if authorized approval is obtained.
7. HANDLING AND STORAGE
HANDLING: Do not get on skin or in eyes.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Local exhaust.
PERSONAL PROTECTIVE EQUIPMENT
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Defense
Revision No: New MSDS
Spa Choice Defense
EYES AND FACE: Safety glasses with side shields or goggles.
SKIN: Chemical-resistant gloves.
RESPIRATORY: None normally required.
PROTECTIVE CLOTHING: Body protective clothing and shoes.
WORK HYGIENIC PRACTICES: Provide safety shower and eyewash station in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild.
pH: 4.32
VAPOR PRESSURE: Not Available
VAPOR DENSITY: 1.21 g/cm3
BOILING POINT: 100°C (212°F)
FREEZING POINT: Not Available
FLASHPOINT AND METHOD: Not Available
SOLUBILITY IN WATER: Soluble in water.
SPECIFIC GRAVITY: 1.010
10. STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: None known, but carbon monoxide may be formed upon burning.
INCOMPATIBLE MATERIALS: None known.
11. TOXICOLOGICAL INFORMATION
ACUTE
DERMAL LD50: > 2000 mg/kg (rabbit)
ORAL LD50: > 5000 mg/kg (rat)
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Defense
Revision No: New MSDS
Spa Choice Defense
12. ECOLOGICAL INFORMATION
COMMENTS: None available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
RCRA/EPA WASTE INFORMATION: This product is not considered a hazardous waste as defined under the Resource
Conservation and Recovery Act (RCRA).
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Corrosive Liquid, N.O.S. (Acrylamide-Acrylic Acid Copolymer)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN 1760
PACKING GROUP: III
OTHER SHIPPING INFORMATION: DOT exception 173.154 - this product qualifies as a Consumer Commodity
(ORM-D) when inner packaging does not exceed 1 gallons.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No
313 REPORTABLE INGREDIENTS: No ingredients listed at or above the de minimus level.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: No components of this product are present above the de minimus levels.
16. OTHER INFORMATION
REVISION SUMMARY: New MSDS
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Defense
Revision No: New MSDS
Spa Choice Defense
HMIS RATING
NFPA CODES
HEALTH:
1
FLAMMABILITY:
1
PHYSICAL HAZARD:
0
1
1
0
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Foam Free
Revision No: New MSDS
Spa Choice Foam Free
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Foam Free
GENERAL USE: Spa and Swimming Pool Defoamer
PRODUCT DESCRIPTION: Silicone emulsion
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
EYES: May cause temporary redness and discomfort.
SKIN: No significant irritation expected from short-term exposure.
INGESTION: Low ingestion hazard in normal use.
INHALATION: May cause mild irritation if exposed to spray or mist.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
No hazardous materials as defined in OSHA Hazard Communication
Wt.%
100
4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if any adverse effect
occurs.
SKIN: No first aid needed.
INGESTION: Treat according to person's condition and specifics of exposure.
INHALATION: No first aid needed.
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Foam Free
Revision No: New MSDS
Spa Choice Foam Free
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: > 100°C (212°F) CC
FLAMMABLE LIMITS: 0 to 0
EXTINGUISHING MEDIA: On large fires, use dry chemical, foam or water spray. On small fires, use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
EXPLOSION HAZARDS: None known.
FIRE FIGHTING PROCEDURES: Use water to cool containers exposed to fire.
FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective
gear.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can produce carbon oxides and traces of
incompletely burned carbon compounds, silicon dioxide, and formaldehyde.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES: Determine whether to evacuate or isolate the area according to your local emergency plan.
Observe all personal protection equipment recommendations. For large spills, provide diking or other appropriate
containment to keep from spreading. If diked material can be pumped, store recovered material in appropriate
container. Clean up remaining materials from spill with suitable absorbent. Clean area as appropriate since spilled
materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or
detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur.
7. HANDLING AND STORAGE
HANDLING: Use with adequate ventilation. Avoid eye contact.
STORAGE: Use reasonable care and store away from oxidizing materials.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: General ventilation is adequate.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety glasses as a minimum.
SKIN: Wash thoroughly after handling.
RESPIRATORY: None normally required.
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Foam Free
Revision No: New MSDS
Spa Choice Foam Free
PROTECTIVE CLOTHING: No special protection needed.
OTHER USE PRECAUTIONS: Avoid eye contact. Use reasonable care.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Slight.
APPEARANCE: White liquid.
VAPOR PRESSURE: Not Determined
VAPOR DENSITY: Not Determined.
FREEZING POINT: N/A
FLASHPOINT AND METHOD: > 100°C (212°F) CC
EVAPORATION RATE: < 1
SPECIFIC GRAVITY: 1.000
VISCOSITY #1: < 5000 CST
10. STABILITY AND REACTIVITY
STABILITY: Stable.
POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: None known.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxidizing material can cause a reaction.
INCOMPATIBLE MATERIALS: None known.
11. TOXICOLOGICAL INFORMATION
COMMENTS: None available.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: Not available.
CHEMICAL FATE INFORMATION: Not available.
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Foam Free
Revision No: New MSDS
Spa Choice Foam Free
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
RCRA/EPA WASTE INFORMATION: This product is not considered a hazardous waste as defined under the Resource
Conservation and Recovery Act (RCRA).
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: No CHRONIC: No
313 REPORTABLE INGREDIENTS: None.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: Not considered hazardous.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All ingredients are listed or exempt.
REGULATIONS
STATE REGULATIONS
Massachusetts:
7664-93-9 <0.1% Sulfuric Acid
New Jersey:
7732-18-5 >60% Water
63148-62-9 15-40% Polydimethylsiloxane
67762-90-7 1-5% Methylated silica
9004-67-5 1-5% Methylcellulose
Pennsylvania:
7732-18-5 >60% Water
63148-62-9 15-40% Polydimethylsiloxane
CALIFORNIA PROPOSITION 65: There are no chemicals present known to the State of California to cause cancer.
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 07/17/2008
MSDS No: Spa Choice Foam Free
Revision No: New MSDS
Spa Choice Foam Free
RCRA STATUS: Not regulated.
16. OTHER INFORMATION
REVISION SUMMARY: New MSDS
NFPA CODES
1
0
0
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 12/17/2008
MSDS No: Spa Choice pH Decreaser
Spa Choice pH Decreaser
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice pH Decreaser
GENERAL USE: pH Decreaser
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: Causes eye irritation. May cause skin and respiratory tract irritation. Avoid contact with
eyes and skin. Avoid breathing dust. Wash exposed skin thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: May cause mild to severe irritation. May cause burn if not flushed with water.
SKIN: Prolonged exposure may cause moderate irritation. May cause burn if not flushed with water.
INGESTION: Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause
injury; swallowing amounts larger than that may cause injury.
INHALATION: May irritate or burn nose, throat and lungs.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
CARCINOGENICITY: Not listed by NTP, IARC or OSHA.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing respiratory conditions.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Vol. %
CAS
EINECS
Sulfuric Acid, Monosodium Salt
0
007681-38-1 231-665-7
Sulfuric Acid Disodium Salt
8
007757-82-6 231-820-9
COMMENTS: Common Name: Sodium Bisulfate
4. FIRST AID MEASURES
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 12/17/2008
MSDS No: Spa Choice pH Decreaser
Spa Choice pH Decreaser
EYES: Immediately flush eyes with water for al least 15 minutes, lifting eyelids to thoroughly flush. If redness persists,
get prompt medical attention.
SKIN: Immediately flush affected area with water for at least 15 minutes. If burn occurs, seek immediate medical
attention.
INGESTION: If large amounts are swallowed (greater than a tablespoonful), drink large quantities of water or milk.
Follow with Milk of Magnesia, beaten eggs or vegetable oil. Do not induce vomiting. Contact a physician immediately.
INHALATION: Remove to fresh air. If breathing has not returned to normal within a few minutes after exposure, get
medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Not combustible.
FLAMMABLE LIMITS: 0 to 0
GENERAL HAZARD: Because material will readily dissolve in water to form a weak acid solution, avoid water contact
with material, if possible.
EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire.
FIRE FIGHTING EQUIPMENT: Because product readily dissolves in water for form a weak acid solution, us acid
protective equipment. No gases or toxic fumes are emitted from this reaction, however if elevated temperatures are
reached (above 806 deg F), self contained breathing apparatus should be used.
HAZARDOUS DECOMPOSITION PRODUCTS: At temperatures above 806 deg F, hazardous fumes sulfur oxide and
sulfur trioxide are evolved.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES: Vacuum or shovel material and place in disposal container. Avoid excessive dust
generation. Dilute residual material with large amounts of water and direct to sanitary sewer if regulations permit.
COMMENTS: WATER SPILL: Readily dissolves in water to form a weak acid solution. If water is isolated or can be
contained, neutralize with weak alkaline solution. Notify appropriate authorities if require by regulations.
7. HANDLING AND STORAGE
HANDLING: Wear all recommended personal protective clothing when handling. Avoid contact with eyes. Wash
thoroughly after handling. Minimize dust generation. Avoid breathing dust.
STORAGE: Material is hygroscopic and will readily absorb moisture. Keep containers tightly closed. DO NOT store
where exposed to moist conditions. DO NOT store near strong alkalis.
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 12/17/2008
MSDS No: Spa Choice pH Decreaser
Spa Choice pH Decreaser
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL
ACGIH TLV
SupplierOEL
ppm
mg/m 3
ppm
mg/m3
ppm
mg/m 3
TWA
ppm [1]
mg/m3 [1]
ppm
mg/m3
NL ppm
NL
mg/m3
STEL
ppm
mg/m3
ppm
mg/m3
NL ppm
NL
mg/m3
Chemical Name
Sulfuric Acid, Monosodium Salt
Footnotes:
1. This material meets the definition as an Irritant as defined in OSHA's Hazard Communication Standard.
ENGINEERING CONTROLS: Local exhaust.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear chemical safety glasses or goggles.
SKIN: Rubber gloves and cotton-blend coveralls.
RESPIRATORY: In dusty atmospheres (greater than 10 mg/m3) use a NIOSH-approved dust respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Dry crystalline solid.
ODOR: Fresh to pungent.
APPEARANCE: Off-white granular powder.
pH: < 1.0 5% aqueous solution spherical shaped beads.
VAPOR PRESSURE: N/A
VAPOR DENSITY: N/A.
MELTING POINT: 350°C (177°F)
FLASHPOINT AND METHOD: Not combustible.
SOLUBILITY IN WATER: 1080 g/L
DENSITY: 80-85 lbs/ft3 (loose)
MOLECULAR WEIGHT: 120
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 12/17/2008
MSDS No: Spa Choice pH Decreaser
Spa Choice pH Decreaser
10. STABILITY AND REACTIVITY
STABILITY: Stable.
POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Sulfur dioxide and sulfur trioxide are formed when heated over 806 deg
F.
INCOMPATIBLE MATERIALS: Avoid contact with strong alkaline material such as caustic. Dissolves readily in water to
form a weak acid solution. DO NOT mix with liquid chlorine bleach, ammonia cleansers or similar products. Do not
store dry product where exposed to moist conditions.
11. TOXICOLOGICAL INFORMATION
ACUTE
ORAL LD50: 2800 mg/kg (rat)
SKIN EFFECTS: Neither corrosive nor destructive to skin of rabbits. Occasionally a very slight rash may appear.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: This material dissolves in water to form a weak acid solution. A 0.05% or
greater (by weight) solution of this product will likely be harmful to aquatic life.
CHEMICAL FATE INFORMATION: Material will decompose in soil. Studies show that there are no adverse effects of
applying the main ingredient in this product directly to crops. In fact, there are existing products on the market that use
sodum bisulfate as a soil additive to improve crop production. However, do not apply excessive quantities to soil.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated.
15. REGULATORY INFORMATION
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Date Issued: 12/17/2008
MSDS No: Spa Choice pH Decreaser
Spa Choice pH Decreaser
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
313 REPORTABLE INGREDIENTS: None.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA RQ: No.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
Chemical Name
CAS
Sulfuric Acid, Monosodium Salt
007681-38-1
Sulfuric Acid Disodium Salt
007757-82-6
TSCA REGULATORY: All components are listed on the TSCA Inventory.
CALIFORNIA PROPOSITION 65: There are no chemicals present known to the State of California to cause cancer.
16. OTHER INFORMATION
REVISION SUMMARY: New MSDS
HMIS RATING
NFPA CODES
HEALTH:
2
FLAMMABILITY:
0
PHYSICAL HAZARD:
0
0
2
1
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice pH Increaser
12/17/2008
1
Spa Choice pH Increaser
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice pH Increaser
GENERAL USE: pH Increaser
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: Irritating to the eyes. Continuous contact may irritate skin.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye irritation.
SKIN: Continuous contact causes skin irritation (red, dry, cracked skin).
INGESTION: May be harmful if swallowed.
INHALATION: Excessive levels of dust may irritate the mucous membranes and upper respiratory tract.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Carbonic Acid, Disodium Salt
Wt.%
CAS
EINECS
100 000497-19-8 207-838-8
4. FIRST AID MEASURES
EYES: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate
medical attention, preferably with an ophthalmologist.
SKIN: Wash with soap and water. Get medical attention if irritation develops or persists.
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice pH Increaser
12/17/2008
1
Spa Choice pH Increaser
INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with plenty of water. Slowly give 1 to 2 glasses of water. Never
give anything by mouth to an unconscious person. Get immediate medical attention.
INHALATION: Remove to fresh air. If breathing is difficult, get medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Not combustible.
FLAMMABLE LIMITS: 0 to 0
EXTINGUISHING MEDIA: Water, fog, carbon dioxide, dry chemical.
FIRE FIGHTING EQUIPMENT: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective
gear.
HAZARDOUS DECOMPOSITION PRODUCTS: Emits fumes of sodium oxide.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES: Sweep up and recycle into process, if possible. Use appropriate equipment if dust is
generated or contact with eyes is expected. Flush residues and liquid to holding area for neutralization before
discharge.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store
material in a cool and dry place.
HANDLING: Do not breathe dust. Avoid contact with skin and eyes.
STORAGE: Store in a cool dry place. Keep away from acids.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice pH Increaser
12/17/2008
1
Spa Choice pH Increaser
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL
Chemical Name
Carbonic Acid, Disodium Salt
TWA
SupplierOEL
ppm
mg/m3
ppm
mg/m 3
[1]
[1]
NL
NL
NL
NL
STEL
Footnotes:
1. NL = Not Listed
ENGINEERING CONTROLS: Local exhaust.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear splash goggles.
SKIN: Impervious gloves.
RESPIRATORY: In dusty atmospheres use a NIOSH-approved dust respirator.
PROTECTIVE CLOTHING: Chemical resistant apron and arm-protector. If clothing becomes contaminated, remove
and launder before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Solid
APPEARANCE: White granular.
pH: 11.4 1% solution.
VAPOR PRESSURE: N/A
VAPOR DENSITY: N/A.
BOILING POINT: Decomposes
FREEZING POINT: 851°C (1564°F)
FLASHPOINT AND METHOD: Not combustible.
SOLUBILITY IN WATER: 33.2% maximum
SPECIFIC GRAVITY: 2.509
10. STABILITY AND REACTIVITY
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice pH Increaser
12/17/2008
1
Spa Choice pH Increaser
STABILITY: Stable.
POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with acids except under controlled conditions.
INCOMPATIBLE MATERIALS: Aluminum powder, acids, fluorine, molten lithium.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Severely irritating (rabbit).
SKIN EFFECTS: Non-irritant to intact skin. Minor irritant may occur to abraded skin.
CHRONIC: May cause severe irritations of the eyes including the corneal opacities.
CARCINOGENICITY
Notes: None of the components in this product are listed by IARC, NTP, OSHA or ACGIH as carcinogen.
SENSITIZATION: Non-sensitizer.
TARGET ORGANS: Eyes.
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY (ACUTE)
96-HOUR LC50: > 300 mg/L (Bluegill Sunfish)
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated.
15. REGULATORY INFORMATION
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice pH Increaser
12/17/2008
1
Spa Choice pH Increaser
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR370): 10000 lbs.
313 REPORTABLE INGREDIENTS: None.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: Not listed.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
Chemical Name
CAS
Carbonic Acid, Disodium Salt
000497-19-8
TSCA STATUS: All ingredients in this mixture are in compliance with TSCA.
16. OTHER INFORMATION
REVISION SUMMARY: Revision #: 1. This MSDS replaces the July 01, 2008 MSDS. Any changes in information are as
follows: In Section 1: MSDS Number
HMIS RATING
NFPA CODES
HEALTH:
2
FLAMMABILITY:
0
PHYSICAL HAZARD:
0
0
2
0
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Re-Energize
GENERAL USE: Oxidizer
PRODUCT DESCRIPTION: Potassium Monopersulfate Compound (Peroxygen Salt)
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: White granular product
IMMEDIATE CONCERNS: This product is a skin and eye corrosive, and a nose and throat irritant. May cause allergic
skin reactions in sensitive individuals. Ingestion may cause inflammation and damage to the lining of the stomach,
resulting in bleeding.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye corrosion or ulceration. Severe eye damage may result if not immediately treated.
SKIN: Corrosive to skin. Skin contact with aqueous solutions or the dry powder upon contact with moisture or
perspiration may cause skin burns or ulceration. Temporary body hair loss may occur in contacted areas. Skin
contact with the product may cause allergic skin reactions in sensitive individuals.
INGESTION: May cause gastritis, possibly progressing to necrosis or hemorrhage.
INHALATION: May cause nose bleeds and irritation of the upper respiratory passages with coughing and discomfort.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
CARCINOGENICITY: None of the components present in this material at concentrations equal to or greater than
0.1% are listed by IARC, NTP, OSHA, or ACGIH as a carcinogen.
MEDICAL CONDITIONS AGGRAVATED: Individuals with pre-existing conditions of the skin or gastrointestingal tract
may have increased susceptibility to the toxicity of excessive exposures.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
Chemical Name
Wt.%
CAS
EINECS
Magnesium Carbonate
2
000546-93-0 208-915-9
Potassium Bisulfate
23
007646-93-7 231-594-1
Potassium Peroxydisulfate
3
007727-21-1 231-781-8
Potassium Peroxymonosulfate
43
010058-23-8 233-187-7
Potassium Sulfate
29
007778-80-5 231-915-5
4. FIRST AID MEASURES
EYES: Hold eyelids apart and immediately flush with plenty of water for at least 15 minutes. Call a physician
immediately.
SKIN: Immediately flush skin with plenty of water for at least 15 minutes, while removing contaminated clothing and
shoes. Call a physician. Wash contaminated clothing before reuse.
INGESTION: DO NOT INDUCE VOMITING. Immediately give 2 glasses of water. Never give anything by mouth to an
unconscious person. Call a physician.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Will not burn.
FLAMMABLE LIMITS: 0 to 0
EXTINGUISHING MEDIA: Water. Do not use carbon dioxide or other gas-filled fire extinguishers. They will have no
effect on decomosing persulfates.
EXPLOSION HAZARDS: Improper storage of large masses of this product can trap heat and lead to ignition of
combustibles. Grinding or intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of
oxidizing material, if present, may occur.
FIRE FIGHTING PROCEDURES: Will release oxygen when heated, intensifying a fire. Acidic mist may be present. Self
contained breathing apparatus should be used.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Sweep up thoroughly. Flush area with low pressure water.
Page 3 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
7. HANDLING AND STORAGE
HANDLING: Do not inhale. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Wash clothing after
use.
STORAGE: Store in a cool, dry, well-ventilated area away from heat sources.
LOADING TEMPERATURE: Replace the lid on plastic pails when they are not in use to prevent contamination and
extend shelf life.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL
Chemical Name
ppm
Magnesium Carbonate
TWA
Potassium Peroxydisulfate
TWA
ACGIH TLV
mg/m3
ppm
mg/m 3
15T, 5
NIC
(10)
0.1
ENGINEERING CONTROLS: Local exhaust.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear safety glasses with side shields.
SKIN: Where there is potential for skin contact, wear impervious gloves, apron, pants and jacket.
RESPIRATORY: A NIOSH-approved air purifying respirator with an appropriate particulate cartridge or canister may
be permissable under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air-supplied respirator if there is
any potential of an uncontrolled release, if exposure levels are not know, or any other circumstances where air
purifying respirators may not provide adequate protection.
COMMENTS: NOTE: EXPOSURE LIMIT OF MONPERSULFATE COMPOUND
PEL = Particulates (Not Otherwise Regulated) 15 mg/m3, 8 Hr. TWA, total dust
TLV = None established.
AEL (Manufacturer's recommended exposure limit) Oxone Monopersulfate Compound - 1 mg/m3; Total Dust, 8 & 12 hr
TWA. Potassium Sulfate - 10 mg/m3, 8 hr. TWA.
9. PHYSICAL AND CHEMICAL PROPERTIES
Page 4 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
PHYSICAL STATE: Solid
ODOR: Mild chlorine.
APPEARANCE: White granular.
pH: 2.3 (1% solution)
VAPOR PRESSURE: None
VAPOR DENSITY: Not volatile.
BOILING POINT: @ 760 mm Hg - decomposes
MELTING POINT: Decomposes
FLASHPOINT AND METHOD: Will not burn.
EVAPORATION RATE: Not volatile.
SPECIFIC GRAVITY: 1.000 to 1.400
(VOC): 100.000
10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: No
STABILITY: Stable when handled and stored as indicated.
CONDITIONS TO AVOID: May be unstable at temperatures above 170 deg C (338 deg F). Avoid storage at
temperatures above 52 deg C (125 deg F). Prevent ingress of humidity and moisture into container or package. Always
close the lid.
POSSIBILITY OF HAZARDOUS REACTIONS: Decomposes when heated or dampened, releasing oxygen and heat of
decomposition.
INCOMPATIBLE MATERIALS: The mixture of this product with compounds containing halides or active halogens
(bromine, chlorine, iodine) can cause the release of the respective halogen gas, if moisture is present. Avoid these
gases (bromine and chlorine) because they are very irritating to eyes and lungs even at low concentrations. Never mix
this product with dry or concentrate bromine-containing chemicals such as bromates, bromides, or any concentrated
bromine pool chemicals. Mixing this product with dry chlorine chemicals such as hypochlorites, sodium
dichloroisocyanurate (dichlor), sodium trichloroisocyanurate (trichlor) or with sodium chloride (salt), may cause the
release of chlorine gas.
Mixing with cyanides can cause release of hydrogen cyanide gas. Mixing with heavy metal salts such as those of
cobalt, nicket, copper, or manganese can cause decomposition with release of oxygen and heat.
11. TOXICOLOGICAL INFORMATION
Page 5 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
ACUTE
SKIN ABSORPTION: > 11000 mg/kg (rabbits)
ORAL LD50: 200-2000 mg/kg (rat)
INHALATION LC50: > 5 mg/L (4 hour)
Notes: In rats.
EYE EFFECTS: This product is a severe eye irritant in animals.
SKIN EFFECTS: This product is a severe skin irritant in animals, but not a skin sensitizer.
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY (ACUTE)
96-HOUR LC50: 53 mg/L (Rainbow Trout)
48-HOUR EC50: 3.5 mg/L (Daphnia Magna)
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Corrosive Solid, Acidic, Inorganic, N.O.S. (monopersulfate compound)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN 3260
PACKING GROUP: II
OTHER SHIPPING INFORMATION: DOT exception 173.154 - this product qualifies as a Consumer Commodity
(ORM-D) when inner packaging does not exceed 2.2 lbs and outer packaging does not exceed 66 lbs.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Not listed.
Page 6 of 6
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/01/2008
Spa Choice Re-Energize
10/14/2008
2
Spa Choice Re-Energize
FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: No
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: Not listed.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
Chemical Name
CAS
Magnesium Carbonate
000546-93-0
Potassium Bisulfate
007646-93-7
Potassium Peroxydisulfate
007727-21-1
Potassium Peroxymonosulfate
010058-23-8
Potassium Sulfate
007778-80-5
16. OTHER INFORMATION
REVISION SUMMARY: Revision #: 2. This MSDS replaces the June 13, 2008 MSDS.
NFPA CODES
HMIS RATING
HEALTH:
3
FLAMMABILITY:
0
PHYSICAL HAZARD:
1
0
3
1
PERSONAL PROTECTION:
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
Page 1 of 4
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/28/2008
Spa Choice Spa Fragrances
10/29/2008
1
Spa Choice Spa Fragrances
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spa Choice Spa Fragrances
GENERAL USE: Spa Fragrance
PRODUCT DESCRIPTION: Spa Fragrance
MANUFACTURER
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
DISTRIBUTOR
Suncoast Chemicals Company
14480 62nd Street North
Clearwater FL 33760
Product Stewardship: (727) 531-8913
24 HR. EMERGENCY TELEPHONE NUMBERS
Chem-Tel 24-Hour Emergency # (800) 255-3924
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
EYES: None reported.
SKIN: None reported.
INGESTION: None reported.
INHALATION: None reported.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS
EINECS
Water
007732-18-5 231-791-2
1,2,3- Propanetriol
000056-81-5 200-289-5
1,2-propanediol
000057-55-6 200-338-0
Fragrance
Siloxanes And Silicones, Di-me
May contain FD&C Red 40; FD&C Red 33; FD&C Blue 1; FD&C Yellow 5; and/or FD&C
Yellow 6.
063148-62-9 xxx-xxx-x
Page 2 of 4
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
Spa Choice Spa Fragrances
4. FIRST AID MEASURES
EYES: Immediately irrigate the eye for five minutes.
SKIN: Not applicable.
INGESTION: Not applicable.
INHALATION: Not applicable.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: No data.
FLAMMABLE LIMITS: 0 to 0
EXTINGUISHING MEDIA: Flood with water or use carbon dioxide, foam, or dry chemical.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES: Clean up with soap and water.
7. HANDLING AND STORAGE
HANDLING: Exercise reasonable care and caution.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: No special ventilation requirements.
9. PHYSICAL AND CHEMICAL PROPERTIES
VAPOR DENSITY: N/A.
BOILING POINT: N/A
FLASHPOINT AND METHOD: No data.
SOLUBILITY IN WATER: Complete.
07/28/2008
Spa Choice Spa Fragrances
10/29/2008
1
Page 3 of 4
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/28/2008
Spa Choice Spa Fragrances
10/29/2008
1
Spa Choice Spa Fragrances
EVAPORATION RATE: N/A.
SPECIFIC GRAVITY: 1.035 to 1.038 at 25°C
10. STABILITY AND REACTIVITY
STABILITY: Stable.
11. TOXICOLOGICAL INFORMATION
COMMENTS: None available.
12. ECOLOGICAL INFORMATION
COMMENTS: None available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated.
15. REGULATORY INFORMATION
COMMENTS None
16. OTHER INFORMATION
REVISION SUMMARY: Revision #: 1. This MSDS replaces the July 29, 2008 MSDS.
Page 4 of 4
MATERIAL SAFETY DATA SHEET
Date Issued:
MSDS No:
Date Revised:
Revision No:
07/28/2008
Spa Choice Spa Fragrances
10/29/2008
1
Spa Choice Spa Fragrances
MANUFACTURER DISCLAIMER: Although reasonable care has been taken in the preparation of this document, we
extend no warranties and make no representations as to the accuracy or completeness of the information contained
therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for
the consequences of its use. Each individual should make a detemination as to the suitability of the information for
their particular purpose(s).
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