Crest URE-Seam Plus Urethane Seam Sealer

Crest URE-Seam Plus Urethane Seam Sealer
MATERIAL SAFETY DATA SHEET
URETHANE, SPRAY SEAM & URE-SEAM PLUS SEALANTS
6/23/05
PRODUCTS COVERED: CH-V, CS-F, CS-BL, CS-GR, CU-P, CU-PB, CU-PW, SU-P
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Hazardous Ingredi- HMIS RATING
Volatile
Stock
Number Product Name on Label
ents in Products*
H F R
Appearance and Odor
Volume%
CH-V
HY-VIS Urethane Windshield Adhesive
2,5,10,13,17
3 2 0
Black paste, mild solvent
5-10
CS-F
Fast Set Urethane
1,2,3,4,12,14,17,18
3 2 0
Black paste, mild solvent
5-10
CS-BL
Spray Seam Sprayable Seam Sealer
1,2,6,9,15,16
1 1 0
Black paste, mild solvent
5-10
CS-GR Spray Seam Sprayable Seam Sealer
1,2,6,9,15,16
1 1 0
Gray paste, mild solvent
5-10
CU-P
Ure-Seam Plus Urethane Seam Sealer
1,2,8,11,15,16,18,19
2 3 0
Gray paste, mild solvent
5-10
CU-PB
Ure-Seam Plus Urethane Seam Sealer
1,2,8,11,15,16,18,19
2 3 0
Black paste, mild solvent
5-10
CU-PW Ure-Seam Plus Urethane Seam Sealer
1,8,11,15,16,18,19
2 3 0
White paste, mild solvent
5-10
SU-P
Ure-Seam Plus Urethane Seam Sealer
1,2,8,11,15,16,18,19
2 3 0
Gray paste, mild solvent
5-10
*Chronic health effects may occur from the solvents and calcium carbonate contained in these products. See NOTEs in SECTION VI.
SECTION III HAZARDOUS INGREDIENTS
Flash Vapor Pres- Evap. Rate Boiling Flammable AutoigniExposure Limits*
CAS
in ppm (parts
Point sure (mm Hg (n-Butyl
Point
Limits in % tion Pt.
Ingredients
Number
Per million)
°F °C at 20°C)
Acetate=1) °F °C Lower Upper °F
°C
3
1. Calcium Carbonate**
1317-65-3 10 mg/m Dust A
-NANA
NA
-NA-NA-NA3
2. Carbon Black
1333-86-4 3.5mg/m Dust A
-NANA
NA
-NA-NA-NA3. DBU
6674-22-2 Not Established
233 112
<0.1
<0.1
-NAUnknown
500 260
3
4. Dibutyltin Diacetate
1067-33-0 0.1 mg/m A,O(Skin) -NA<0.1
<0.1
Unknown Unknown
Unknown
5. DUP (Diundecylphthalate)
3648-20-2 Not Established
-NA<0.1
<0.1
Unknown Unknown
Unknown
6. Di-Isononyl Phthalate
28553-12-0 Not Established
-NA<0.1
<0.1
Unknown Unknown
Unknown
7. Ethyl Benzene
100-41-4 100 A
59 15
7
0.5
277 136
1.0 6.7
810 432
8. Hydrophobic Amor3
phous Fumed Silica 68611-44-9 10 mg/m dust
-NANA
NA
-NA-NA-NA9. Isoparaffin Mixture
64742-48-9 300 E
104 40
<10
0.3
313 156
0.7 7.0
559 293
10. Polyurethane Polymer
Unknown Not Established
-NANA
NA
-NA-NA-NA11. Polyvinyl Chloride
9002-86-2 Not Established
-NANA
NA
-NA-NA-NA12. Silane
1760-24-3 Not Established
-NANA
NA
-NA-NA-NA13. Silane
13822-56-5 Not Established
-NANA
NA
-NA-NA-NA14. Silane
227095-51-0 Not Established
-NANA
NA
-NA-NA-NA3
15. Silica-Crystalline
14808-60-7 0.1 mg/m R.D.A, O -NANA
NA
-NA-NA-NA3
16. Titanium Dioxide
13463-67-7 10 mg/m Dust A
-NANA
NA
-NA-NA-NA17. Toluene
108-88-3 50 A (Skin), 200 O
45 7
38
1.5
230 110
1.2 7.0
900 482
18. Urethane Prepolymer
Proprietary Not Established
-NANA
NA
-NA-NA-NA19. Xylene
1330-20-7 100 A, O
80 27
10
0.8
281 138
1.0 7.0
810 432
3
*A means ACGIH TLV, O means OSHA, mg/m means milligrams per cubic meter, E means Suppliers Recommendation
>means greater than, < means less than, NA means Not Applicable, R.D. means Respirable Dust, Skin means vapor exposure to
the skin must also be considered. **See SECTION VI for health hazards.
SECTION IV PHYSICAL DATA
Evaporation Rate: See SECTIONS II, III. Vapor Density:
Unusual Fire and Explosion Hazards: Vapors are heavier than air
Heavier than air. Solubility in Water (Wt%): Less than 1.
and may travel along the ground or be moved by ventilation and
Volatile Volume %: See SECTION II. Approximate Boiling ignited by pilot lights, other flames, sparks, heaters, electric motors,
Point: See SECTIONS II, III. Product Density: Heavier than smoking or other ignition sources at locations far from material
handling point. At elevated temperatures [130°F (54°C) or over]
water. Appearance and Odor: See SECTION II.
containers may vent, rupture or burst (cartridges may extrude their
SECTION V FIRE AND EXPLOSION DATA
plungers).
Flash Point (Tag Closed Cup Method):
SECTION VI HEALTH HAZARD DATA
CH-V, CS-F: 52°F (11°C). CU-P, CU-PB, CU-PW, SU-P:
PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, Eye
Greater than 140°F (60°C). CS-BL, CS-GR: Greater than
contact, Ingestion (very unlikely).
200°F (93°C).
SIGNS AND SYMPTOMS OF EXPOSURE:
Flammable Limits: See SECTIONS II, III.
INHALATION:
Autoignition Temperature: See SECTIONS II, III.
Acute Exposure: Solvent vapors at concentrations above the
Extinguishing Media: Foam, carbon dioxide, dry chemical.
Fire Fighting Procedures: Full protective equipment, inTLV can irritate the respiratory tract (nose, throat, lungs) causing a
cluding self-contained breathing apparatus, is recommended burning sensation, runny nose, sore throat, coughing, chest discomfort (tightness). May cause central nervous system depression with
because highly toxic gasses may be generated by combustion or thermal decomposition. Water from fog nozzles may the following progressive symptoms: headache, dizziness, nausea,
staggering gait, confusion, unconsciousness, cessation of breathing
be used to cool closed containers to prevent pressure build
and death
up (containers may leak or burst).
Urethane, Spray Seam & Ure-Seam Plus Sealants MSDS 6/23/05 page 2
Chronic Exposure: Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Symptoms include:
loss of memory, loss of intellectual ability and loss of coordination. NOTE: INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING SOLVENT VAPORS MAY
BE HARMFUL OR FATAL!
SKIN CONTACT:
Acute Exposure: Repeated or prolonged skin contact with
sealants can result in dry, defatted and cracked skin causing
increased susceptibility to infection. Skin irritation may develop
into contact dermatitis.
Chronic Exposure: Exposure to small amounts of sealants
over long periods of time may cause some or all of the symptoms as in acute exposure to sealants.
EYE CONTACT:
Acute Exposure: Solvent vapors may irritate the eyes with
resulting itching, burning, redness. Permanent tissue damage
may occur if the sealants are applied directly to the eyes and not
flushed out immediately.
Chronic Exposure: Symptoms as in acute exposure but to a
lesser degree and eye damage not likely.
INGESTION:
Acute Exposure: (Not likely) Irritation to the mouth, and if
swallowed, to the esophagus, stomach tissue and digestive
tract.
Chronic Exposure: Unknown.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
None specifically known to Crest Industries, Inc. but it is possible
that eye, respiratory tract, skin, liver, kidney, blood cell formation, nervous system and brain diseases may be aggravated by
overexposure to the products on this MSDS.
CARCINOGENICITY: Products not listed by NTP, IARC or
OSHA. NOTE: 1. Calcium Carbonate contains small but detectable amounts of Crystalline Silica which if inhaled can
cause cancer of the lungs. Under normal use conditions the
Crystalline Silica is not free to be inhaled as dust. If the
dried sealants are sanded, inhalation of the sanding dust
must be avoided. WEAR A DUST MASK.
SECTION VII EMERGENCY AND FIRST
AID PROCEDURES
EYE CONTACT: Flush with clean, lukewarm water (low pressure) for at least 15 minutes while lifting eyelids. Refer person to
physician for immediate attention.
SKIN CONTACT: Remove contaminated clothing immediately.
Wipe off excess material with rags or paper towels. Clean with
waterless hand cleaner or wash affected areas thoroughly with
soap and water. Wash contaminated clothing thoroughly before
reuse. Apply skin cream if irritated. Seek medical attention if irritation persists.
INHALATION: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention.
INGESTION: Induce vomiting. Consult physician, hospital
emergency room or poison control center immediately. Have list
of ingredients available.
NOTES TO PHYSICIAN:
Eyes: Stain for evidence of corneal injury. If cornea burned,
instill antibiotic/steroid preparation frequently.
Skin: Treat symptomatically.
Inhalation: Treat as for solvent vapor inhalation.
Ingestion: Treat symptomatically.
SECTION VIII EMPLOYEE PROTECTION
RECOMMENDATIONS
EYE PROTECTION: Wearing of safety glasses is desirable
during use of sealants. Contact lenses should not be worn.
SKIN PROTECTION: Cover as much of the skin as possible
with appropriate clothing. Wear solvent resistant gloves.
VENTILATION AND RESPIRATORY PROTECTION: If exhaust ventilation sufficient to keep the air-borne concentration of
solvents below their respective TLVs is not possible, an
OSHA/MSHA approved TC23C Respirator or TC19C Air Supplied Respirator must be used. Observe OSHA regulations (29
CFR 1910.134) for respirator use. NOTE: THERE MUST
ALWAYS BE ENOUGH VENTILATION TO KEEP VAPOR
CONCENTRATION BELOW THE LOWER FLAMMABLE
LIMIT! If the dried sealants are sanded, WEAR A DUST
MASK to avoid inhalation of dust.
OTHER PROTECTIVE MEASURES: Eyewash stations should
be available. Educate and train employees in safe use of products. Follow all label instructions.
SECTION IX REACTIVITY DATA
STABILITY: Stable under normal room conditions.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (Materials to Avoid): Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS:
ALL will, by high heat and fire, give off carbon dioxide, carbon
monoxide, hydrocarbon vapors and smoke.
CH-V, CS-F, CU-P, CU-PB, CU-PW and SU-P may also give off
nitrogen oxides and isocyanates. CU-P, CU-PB, CU-PW, SU-P
may also give off hydrogen chloride, chlorine, phosgene and
chlorinated hydrocarbon vapors.
SECTION X SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED
OR SPILLED: Wear protective equipment including respiratory
protection. Prevent further spillage. Evacuate nonessential personnel. Remove all sources of ignition and ventilate the area.
Keep spill from reaching sewers and waterways. Collect material with non-sparking tools and put in a tightly sealed container.
Remove container to a safe place.
WASTE DISPOSAL METHOD: Follow all federal, state and
local environmental control regulations. Incineration of the material is the preferred method. Containers must be handled with
care due to flammable and toxic residue.
RCRA STATUS: Since these products are ignitable and contain toxic solvents, they are hazardous when discarded.
SECTION XI SPECIAL PRECAUTIONS &
STORAGE DATA
STORAGE TEMPERATURE
MINIMUM / MAXIMUM: 50°F (10°C) / 130°F (54°C)
RECOMMENDED SHELF LIFE: One year
PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE
AND USE: Keep away from heat, sparks and open flame. Do
not store in temperatures above 130°F (54°C) or in direct
sunlight. The sealants remain usable longest when kept as cool
and dry as possible.) Do not inhale vapors. Avoid contact with
skin and eyes. Wash hands after use and before eating, drinking, smoking or using the toilet. Educate and train employees in
the safe use and handling of these materials as required under
the OSHA Hazard Communication Standard (29 CFR
1910.1200)
KEEP OUT OF THE REACH OF CHILDREN
Urethane, Spray Seam & Ure-Seam Plus Sealants MSDS 6/23/05 page 3
SECTION XII FEDERAL EPA REGULATION COMPLIANCE INFORMATION
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT of 1986
1) Section 313 Supplier Notification:
Chemicals marked with an * in the following tables are subject to the Toxic Chemical Release
Inventory Reporting Requirements using EPA FORM R (40 CFR Part 372).
2) Section 312: All the chemicals listed are subject to Emergency and Hazardous Chemical Inventory Forms
and Community Right-to-Know Reporting Requirements: Tier I and Tier II Reports (40 CFR Part 370).
NOTE: This information MUST, according to law, be included in all MSDSs that are copied and distributed
for materials covered by this MSDS.
HAZARDOUS INGREDIENTS IN SEALANTS APPROXIMATE PERCENTAGES BY WEIGHT
Ingredients (Chemicals)
CAS Number CH-V CS-F CS-BL CS-GR CU-P CU-PB CU-PW SU-P
1. Calcium Carbonate
1317-65-3
30
P*
P*
P*
P*
P*
P*
2. Carbon Black
1333-86-4
P*
P*
P*
P*
P*
P*
P*
3. DBU
6674-22-2
P*
4. Dibutyltin Diacetate
1067-33-0
P*
5. DUP (Diundecylphthalate)
3648-20-2
10
6. Di-Isononyl Phthalate
28553-12-0
5-15
5-15
*7. Ethyl Benzene
100-41-4
01
01
01
01
8. Hydrophobic Amorphous
Fumed Silica
68611-44-9
P*
P*
P*
P*
9. Polyurethane Polymer
Unknown
P*
10. Isoparaffin Mixture
64742-48-9
10-15
10-15
11. Polyvinyl Chloride
9002-86-2
P*
P*
P*
P*
12. Silane
1760-24-3
P*
13. Silane
13822-56-5
05
14. Silane
227095-51-0
P*
15. Silica-Crystalline
14808-60-7
P*
P*
P*
P*
P*
P*
16. Titanium Dioxide
13463-67-7
P*
P*
P*
P*
P*
*17. Toluene
108-88-3
04
5-10
18. Urethane Prepolymer
Mixture
70
70
P*
P*
P*
P*
*19. Xylene
1330-20-7
06
06
06
06
Physical Hazard-Fire
04
5-10
06
06
06
06
Physical Hazard-Pressure Release
None of the Sealants have this hazard
Health Hazard-Acute
04
5-10
06
06
06
06
Health Hazard-Chronic
P*
P*
P*
P*
P*
P*
P*
P*
Physical Hazard-Reactivity
None of the Sealants have this hazard
*Present at an unknown percentage greater than 0.1.
SECTION XIII VOLATILE ORGANIC COMPOUND (V.O.C.) CONTENT OF SEALANTS
ACCORDING TO THE FEDERAL EPA
Stock Numbers
CH-V CS-F CS-BL CS-GR CU-P CU-PB CU-PW SU-P
Percent by Weight
6.5
6.5
10.7
10.7
6.0
6.0
6.0
6.0
Pounds per Gallon
0.53
0.62
1.32
1.32
0.61
0.61
0.61
0.61
Grams per Liter
63
74
158
158
73
73
73
73
Pounds per Container 0.043 0.051 0.108 0.108 0.050 0.050
0.050
0.050
SECTION XIV CALIFORNIA PROPOSITION 65 WARNINGS
According to the California Safe Drinking Water and Toxic Enforcement Act (PROPOSITION 65) "No person in the course of doing
business shall knowingly and intentionally expose any individual to a chemical known to the State of California to cause cancer,
birth defects or reproductive toxicity without first giving clear and reasonable warning to such individuals of such an exposure". The
following warnings apply:
1. Products Covered Containing Toluene: CH-V, CS-F
WARNING: These products contain a chemical known to the State of California to cause birth defects and
other reproductive harm.
2. Products Covered Containing Silica-Crystalline: CS-BL, CS-GR, CU-P, CU-PB, CU-PW, SU-P.
WARNING: These products contain chemicals known to the State of California to cause cancer.
SECTION XV OZONE DEPLETION IN THE UPPER ATMOSPHERE
None of the products on this MSDS contains upper atmosphere ozone-depleting substances.
DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated.
Crest Industries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed or
implied, as to the completeness or accuracy of the information. It is offered solely for your consideration, investigation and
verification. The user is ultimately responsible for the safe use of the material in accordance with applicable federal, state,
provincial and local laws and regulations.
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