MSDS Sheets

MSDS Sheets
Material Safety Data Sheet
The Dow Chemical Company
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Print Date: 18 Jun 2010
The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1.
Product and Company Identification
Product Name
FROTH-PAK(TM) 620 AF HFC ISO Spray Foam Sealant
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
Customer Information Number:
800-258-2436
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact:
Local Emergency Contact:
2.
989-636-4400
989-636-4400
Hazards Identification
Emergency Overview
Color: Brown
Physical State: Liquid.
Odor: Musty
Hazards of product:
WARNING! May cause eye irritation. May cause skin irritation. May cause allergic
skin reaction. May cause allergic respiratory reaction. Vapor reduces oxygen
available for breathing. May cause central nervous system effects. Keep upwind of
spill. May cause anesthetic effects. May cause respiratory tract irritation. May cause
lung injury. May react with water. Stay out of low areas. Material reacts slowly with
water, releasing carbon dioxide which can cause pressure buildup and rupture of
closed containers. Elevated temperatures accelerate this reaction. Toxic fumes may
be released in fire situations. Contents under pressure.
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow
Page 1 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Potential Health Effects
Eye Contact: May cause moderate eye irritation. May cause slight temporary corneal injury.
Skin Contact: Prolonged contact may cause skin irritation with local redness. May stain skin.
Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that
skin contact with isocyanates may play a role in respiratory sensitization.
Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause
unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation
to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the
lungs.) Effects may be delayed. Decreased lung function has been associated with overexposure to
isocyanates. Excessive exposure may increase sensitivity to epinephrine and increase myocardial
irritability (irregular heartbeats). May cause central nervous system effects. Symptoms of excessive
exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed.
Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the
exposure guidelines may cause allergic respiratory reactions in individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may cause
injury. Observations in animals include: Gastrointestinal irritation.
Aspiration hazard: Based on available information, aspiration hazard could not be determined.
Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been
observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols.
Cancer Information: Lung tumors have been observed in laboratory animals exposed to respirable
aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with
respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these
effects reported for MDI.
Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth
defects; other fetal effects occurred only at high doses which were toxic to the mother. Based on
information for component(s): 1,1,1,2-Tetrafluoroethane. Has been toxic to the fetus in laboratory
animals at doses toxic to the mother.
3.
Composition Information
Component
CAS #
Diphenylmethane Diisocyanate, isomers and homologues
9016-87-9
4,4' -Methylenediphenyl diisocyanate
101-68-8
1,1,1,2-Tetrafluoroethane
811-97-2
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
4.
Amount
>= 60.0 - <= 100.0 %
>= 30.0 - <= 60.0 %
>= 5.0 - <= 10.0 %
First-aid measures
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Eye wash fountain should be located in immediate work area.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Page 2 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives
may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
Emergency Personnel Protection: First Aid responders should pay attention to self-protection and
use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
5.
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC
type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,
but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance.
Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel
from the area in case of rising sound from venting safety device or discoloration of the container.
Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed
containers and fire-affected zone until fire is out. Contain fire water run-off if possible. Fire water runoff, if not contained, may cause environmental damage. Review the "Accidental Release Measures"
and the "Ecological Information" sections of this (M)SDS.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire
from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to
the relevant sections.
Unusual Fire and Explosion Hazards: Some components of this product will burn in a fire situation.
Product reacts with water. Reaction may produce heat and/or gases. This reaction may be violent.
Container may rupture from gas generation in a fire situation. Blowing agent vaporizes quickly at room
temperature. Violent steam generation or eruption may occur upon application of direct water stream
to hot liquids. Dense smoke is produced when product burns.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide.
Carbon monoxide. Carbon dioxide. Hydrogen halides. Halogenated hydrocarbons.
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb
with materials such as: Vermiculite. Dirt. Sand. Clay. Do NOT use absorbent materials such as:
Cement powder (Note: may generate heat). Collect in suitable and properly labeled open containers.
Do not place in sealed containers. Suitable containers include: Metal drums. Plastic drums.
Page 3 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Polylined fiber pacs. Wash the spill site with large quantities of water. Attempt to neutralize by adding
suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%; liquid detergent 0.2 - 2%;
water to make up to 100%, OR Formulation 2: concentrated ammonia solution 3 - 8%; liquid detergent
0.2 - 2%; water to make up to 100%. If ammonia is used, use good ventilation to prevent vapor
exposure. Contact Dow for clean-up assistance. See Section 13, Disposal Considerations, for
additional information.
Personal Precautions: Isolate area. Ventilate area of leak or spill. Keep personnel out of low areas.
Keep upwind of spill. Keep unnecessary and unprotected personnel from entering the area. If
available, use foam to smother or suppress. Refer to Section 7, Handling, for additional precautionary
measures. See Section 10 for more specific information. Use appropriate safety equipment. For
additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
7.
Handling and Storage
Handling
General Handling: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid
prolonged or repeated contact with skin. Use with adequate ventilation. Wash thoroughly after
handling. Keep container tightly closed. Contents under pressure. Do not puncture or incinerate
container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind,
weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless
adequately ventilated. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Storage
Store under cover in a dry, clean, cool, well ventilated place away from sunlight. Do not store product
contaminated with water to prevent potential hazardous reaction.
Storage Period:
Storage temperature:
15 Months
24 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
Component
List
Type
Value
ACGIH
TWA
0.005 ppm
OSHA Table
Z-1
Ceiling
0.2 mg/m3 0.02 ppm
AIHA WEEL
TWA
4,240 mg/m3 1,000 ppm
|
4,4' -Methylenediphenyl
diisocyanate
||
1,1,1,2-Tetrafluoroethane
Personal Protection
Eye/Face Protection: Use chemical goggles. Eye wash fountain should be located in immediate work
area.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task. Remove
contaminated clothing immediately, wash skin area with soap and water, and launder clothing before
reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use gloves chemically resistant to this material. Examples of preferred
glove barrier materials include: Butyl rubber. Polyethylene. Chlorinated polyethylene. Ethyl
vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include:
Viton. Neoprene. Polyvinyl chloride ("PVC" or "vinyl"). Nitrile/butadiene rubber ("nitrile" or
"NBR"). NOTICE: The selection of a specific glove for a particular application and duration of
use in a workplace should also take into account all relevant workplace factors such as, but
Page 4 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
not limited to: Other chemicals which may be handled, physical requirements (cut/puncture
protection, dexterity, thermal protection), potential body reactions to glove materials, as well as
the instructions/specifications provided by the glove supplier.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator
equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric
levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure
air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or
for situations where the atmospheric level is unknown, use an approved positive-pressure selfcontained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. In
confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive
pressure air line with auxiliary self-contained air supply. The following should be effective types of airpurifying respirators: Organic vapor cartridge with a particulate pre-filter.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some
operations. Provide general and/or local exhaust ventilation to control airborne levels below the
exposure guidelines. Exhaust systems should be designed to move the air away from the source of
vapor/aerosol generation and people working at this point. The odor and irritancy of this material are
inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor
ventilation.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Odor Threshold
Flash Point - Closed Cup
Flammability (solid, gas)
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in water (by
weight)
pH
Decomposition
Temperature
Partition coefficient, noctanol/water (log Pow)
Evaporation Rate (Butyl
Acetate = 1)
Kinematic Viscosity
10.
Liquid.
Brown
Musty
No test data available
Not applicable
Not applicable to liquids
Lower: No test data available
Upper: No test data available
No test data available
240 psi @ 23 °C Estimated. Container is under pressure.
No test data available.
No test data available
1.24 Estimated.
No test data available
No test data available
insoluble, reacts, evolution of CO2
Not applicable
No test data available
No data available for this product. See Section 12 for individual
component data.
No test data available
No test data available
Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Page 5 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Elevated
temperatures can cause pressure buildup in closed containers due to the release of blowing agents.
Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up
can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can
cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this
reaction.
Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases.
Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate
of reaction increases with temperature as well as increased contact; these reactions can become
violent. Contact is increased by stirring or if the other material mixes with the diisocyanate.
Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The
reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate
carbon dioxide and heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper.
Galvanized metals. Avoid contact with absorbent materials such as: Moist organic absorbents. Avoid
unintended contact with polyols. The reaction of polyols and isocyanates generate heat.
Hazardous Polymerization
Can occur. Elevated temperatures can cause hazardous polymerization. Polymerization can be
catalyzed by: Strong bases. Water.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Gases are released during decomposition.
11.
Toxicological Information
Acute Toxicity
Ingestion
Single dose oral LD50 has not been determined. Estimated. LD50, Rat > 10,000 mg/kg
Dermal
The dermal LD50 has not been determined. Estimated. LD50, Rabbit > 2,000 mg/kg
Inhalation
The LC50 has not been determined. Estimated. LC50, Aerosol, Rat > 490 mg/m3
Serious eye damage/eye irritation
May cause moderate eye irritation. May cause slight temporary corneal injury.
Skin corrosion/irritation
Prolonged contact may cause skin irritation with local redness. May stain skin.
Sensitization
Skin
Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with
isocyanates may play a role in respiratory sensitization.
Respiratory
May cause allergic respiratory response. MDI concentrations below the exposure guidelines may
cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may
include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing
difficulties may be life threatening.
Repeated Dose Toxicity
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.
Chronic Toxicity and Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Developmental Toxicity
Page 6 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother. Based on information for component(s): 1,1,1,2Tetrafluoroethane. Has been toxic to the fetus in laboratory animals at doses toxic to the mother. Did
not cause birth defects in laboratory animals.
Reproductive Toxicity
No relevant information found.
Genetic Toxicology
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other
in vitro studies were negative. Animal mutagenicity studies were predominantly negative.
12.
Ecological Information
ENVIRONMENTAL FATE
Data for Component: Diphenylmethane Diisocyanate, isomers and homologues
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: 4,4' -Methylenediphenyl diisocyanate
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: 1,1,1,2-Tetrafluoroethane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is high (Koc between 50 and 150).
Henry's Law Constant (H): 5.00E-02 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 1.68 Estimated.
Partition coefficient, soil organic carbon/water (Koc): 97 Estimated.
Persistence and Degradability
1,1,1,2-Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential (ODP) of
zero, relative to CFC 12 (ODP=1). Material is expected to biodegrade only very slowly (in the
environment). Fails to pass OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
6.20E-15 cm3/s
1,700 d
Estimated.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
4%
28 d
OECD 301D Test
Theoretical Oxygen Demand: 0.47 mg/mg
Page 7 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
ECOTOXICITY
Data for Component: Diphenylmethane Diisocyanate, isomers and homologues
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species
tested).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: 4,4' -Methylenediphenyl diisocyanate
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species
tested).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: 1,1,1,2-Tetrafluoroethane
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 450 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 980 mg/l
13.
Disposal Considerations
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF
PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS
DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED
PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other
thermal destruction device.
14.
Transport Information
DOT Non-Bulk
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
DOT Bulk
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
IMDG
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
EMS Number: F-C,S-V
Page 8 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
Marine pollutant.: No
ICAO/IATA
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956Cargo Packing Instruction: 200
Passenger Packing Instruction: 200
Additional Information
Reportable quantity: 8,333 lb – MDI
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information can be
obtained through an authorized sales or customer service representative. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material.
15.
Regulatory Information
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning
and Community Right-to-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
Fire Hazard
Reactive Hazard
Sudden Release of Pressure Hazard
Yes
Yes
No
Yes
Yes
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Amount
Component
CAS #
4,4' -Methylenediphenyl diisocyanate
101-68-8
>= 30.0 - <= 60.0 %
Diphenylmethane Diisocyanate, isomers and
9016-87-9
>= 60.0 - <= 100.0 %
homologues
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous
Substances List and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or the
Pennsylvania Environmental Substance List, and are present at levels which require reporting.
Amount
Component
CAS #
4,4' -Methylenediphenyl diisocyanate
101-68-8
>= 30.0 - <= 60.0 %
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous
Substances List:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
US. Toxic Substances Control Act
Page 9 of 10
Product Name: FROTH-PAK(TM) 620 AF HFC ISO Spray Foam
Sealant
Issue Date: 02/25/2010
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or
are not required to be listed.
16.
Other Information
Recommended Uses and Restrictions
Component(s) for the manufacture of urethane polymers.
Revision
Identification Number: 1041164 / 0000 / Issue Date 02/25/2010 / Version: 2.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A
W/W
OEL
STEL
TWA
ACGIH
DOW IHG
WEEL
HAZ_DES
Action Level
Not available
Weight/Weight
Occupational Exposure Limit
Short Term Exposure Limit
Time Weighted Average
American Conference of Governmental Industrial Hygienists, Inc.
Dow Industrial Hygiene Guideline
Workplace Environmental Exposure Level
Hazard Designation
A value set by OSHA that is lower than the PEL which will trigger the need for
activities such as exposure monitoring and medical surveillance if exceeded.
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
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