SAFETY DATA SHEET 1. Identification

SAFETY DATA SHEET 1. Identification
SAFETY DATA SHEET
Sid Harvey item # 332
SDS # Z0206
1. Identification
Product identifier
UNI-WELD CLEAR OR PURPLE PRIMER
Other means of identification
SDS number
2402E
Recommended use
Part Numbers: Clear - 9324, 9336S, 9346S, 9356S, 9366S Purple - 8724, 8736S, 8746S, 8756S,
8766S, 90324, 90336S, 90346S, 90356S, 90366S
Joining PVC Pipes
Recommended restrictions
None known.
Synonyms
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
United Elchem Industries c/o Oatey Co.
4700 West 160th Street
Cleveland, OH 44135
216-267-7100
[email protected]
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
2. Hazard(s) identification
Physical hazards
Flammable liquids
Category 2
Health hazards
Acute toxicity, oral
Category 4
Skin corrosion/irritation
Category 2
Serious eye damage/eye irritation
Category 2A
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Aspiration hazard
OSHA defined hazards
Category 1
Not classified.
Label elements
Signal word
Danger
Hazard statement
Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Storage
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
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Disposal
Hazard(s) not otherwise
classified (HNOC)
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
Supplemental information
Not applicable.
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number
%
Acetone
67-64-1
30-60
Cyclohexanone
108-94-1
15-40
Furan, Tetrahydro-
109-99-9
10-30
Methyl ethyl ketone
78-93-3
10-30
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
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6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Environmental precautions
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Acetone (CAS 67-64-1)
PEL
Cyclohexanone (CAS
108-94-1)
PEL
2400 mg/m3
1000 ppm
200 mg/m3
Furan, Tetrahydro- (CAS
109-99-9)
PEL
50 ppm
590 mg/m3
Methyl ethyl ketone (CAS
78-93-3)
PEL
200 ppm
590 mg/m3
200 ppm
US. ACGIH Threshold Limit Values
Components
Type
Value
Acetone (CAS 67-64-1)
STEL
TWA
STEL
750 ppm
500 ppm
50 ppm
TWA
STEL
20 ppm
100 ppm
Cyclohexanone (CAS
108-94-1)
Furan, Tetrahydro- (CAS
109-99-9)
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US. ACGIH Threshold Limit Values
Components
Methyl ethyl ketone (CAS
78-93-3)
Type
Value
TWA
STEL
50 ppm
300 ppm
TWA
200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Acetone (CAS 67-64-1)
TWA
Cyclohexanone (CAS
108-94-1)
TWA
590 mg/m3
250 ppm
100 mg/m3
Furan, Tetrahydro- (CAS
109-99-9)
STEL
25 ppm
735 mg/m3
250 ppm
590 mg/m3
200 ppm
885 mg/m3
TWA
Methyl ethyl ketone (CAS
78-93-3)
STEL
300 ppm
590 mg/m3
200 ppm
TWA
Biological limit values
ACGIH Biological Exposure Indices
Components
Value
Determinant
Acetone (CAS 67-64-1)
Cyclohexanone (CAS
108-94-1)
50 mg/l
80 mg/l
Acetone
1,2-Cyclohexan
ediol, with
hydrolysis
Cyclohexanol,
with hydrolysis
Tetrahydrofura
n
MEK
8 mg/l
Furan, Tetrahydro- (CAS
2 mg/l
109-99-9)
Methyl ethyl ketone (CAS 2 mg/l
78-93-3)
* - For sampling details, please see the source document.
Specimen
Sampling Time
Urine
Urine
*
*
Urine
*
Urine
*
Urine
*
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1)
Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)
Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)
Can be absorbed through the skin.
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
Appropriate engineering
changes per hour) should be used. Ventilation rates should be matched to conditions. If
controls
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Eye/face protection
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Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Translucent.
Physical state
Liquid.
Form
Liquid.
Color
Clear. or Purple
Odor
Solvent.
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
151 °F (66.11 °C)
Flash point
14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate
5.5 - 8
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Not available.
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
145 mm Hg @ 20 C
Vapor density
2.5
Relative density
0.82 - 0.86
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
< 100 cP
Other information
Bulk density
7 lb/gal
VOC (Weight %)
505 g/l SQACMD Method 304
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
Incompatible materials
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Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
Inhalation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact
Causes skin irritation.
Eye contact
Causes serious eye irritation.
Ingestion
May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity
Components
May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Species
Test Results
Acute
Dermal
LD50
Rabbit
20 ml/kg
Inhalation
LC50
Rat
50 mg/l, 8 Hours
Oral
LD50
Rat
5800 mg/kg
Acute
Dermal
LD50
Rabbit
948 mg/kg
Inhalation
LC50
Rat
8000 ppm, 4 hours
Oral
LD50
Rat
1540 mg/kg
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
* Estimates for product may be based on additional component data not shown.
Causes skin irritation.
Skin corrosion/irritation
Serious eye damage/eye
irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Not available.
Respiratory sensitization
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation
lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female
mice developed liver tumors while neither the female rats nor the male mice showed similar
results. Because the carcinogenic mechanisms could not be identified clearly in either species for
either tumor, the EPA determined that the male rat and female mouse findings are relevant to the
assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these
data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following
exposure to THF by all routes of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1)
3 Not classifiable as to carcinogenicity to humans.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is not expected to cause reproductive or developmental effects.
Reproductive toxicity
Specific target organ toxicity single exposure
Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
Specific target organ toxicity repeated exposure
Not classified.
Aspiration hazard
May be fatal if swallowed and enters airways.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components
Species
Test Results
Acetone (CAS 67-64-1)
Aquatic
Fish
LC50
Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
Cyclohexanone (CAS 108-94-1)
Aquatic
Fish
LC50
Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
No data is available on the degradability of this product.
Persistence and degradability
Bioaccumulative potential
No data available.
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
No data available.
Mobility in soil
Other adverse effects
-0.24
0.81
0.46
0.29
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
UN1993
Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 25063 LBS, Acetone RQ = 12522 LBS)
3
3
II
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Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Read safety instructions, SDS and emergency procedures before handling.
IB2, T7, TP1, TP8, TP28
150
202
242
UN1993
Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)
3
II
No.
3H
Read safety instructions, SDS and emergency procedures before handling.
UN1993
FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)
3
II
No.
F-E, S-E
Read safety instructions, SDS and emergency procedures before handling.
Not available.
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1)
LISTED
Cyclohexanone (CAS 108-94-1)
LISTED
Furan, Tetrahydro- (CAS 109-99-9)
LISTED
Methyl ethyl ketone (CAS 78-93-3)
LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
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Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.
Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1)
6532
Methyl ethyl ketone (CAS 78-93-3)
6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)
35 %WV
Methyl ethyl ketone (CAS 78-93-3)
35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)
6532
Methyl ethyl ketone (CAS 78-93-3)
6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
Canada
Domestic Substances List (DSL)
Canada
Non-Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
Yes
Europe
European List of Notified Chemical Substances (ELINCS)
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Yes
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Yes
UNI-WELD CLEAR OR PURPLE PRIMER
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On inventory (yes/no)*
Yes
Yes
No
No
SDS US
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Country(s) or region
United States & Puerto Rico
Inventory name
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
17-December-2014
Revision date
-
Version #
01
Health: 2
Flammability: 3
Physical hazard: 0
The information in the sheet was written based on the best knowledge and experience currently
available. United Elchem Industries c/o Oatey Co. cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its product,
may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and
disposal of the product, and to assume liability for loss, injury, damage or expense due to improper
use.
HMIS® ratings
Disclaimer
UNI-WELD CLEAR OR PURPLE PRIMER
924273 Version #: 01 Revision date: -
SDS US
Issue date: 17-December-2014
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4700 W. 160TH Street
P.O. Box 35906
Cleveland, Ohio 44135
Emergency Tel No.
(303) 623-5716 Collect
ATE RIAL SAFETY DATA SHEET
OATEY PURPLE PRIMER/CLEANER
Latest Revision Date .•. 05/28/97
Date of Issue ... • .... 08/13/97
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section 1
IDENTITY OF MATERIAL
TRADE NAME •.••• •• •~TEY PURPLE PRIMER/CLEANER
PROOUCT NUMBERS ••• 30768, 30780, 30783, 30796, 30806
FORMULA ••••••••••• CH(3)OOC(2)H(5)+CH(2)CH(2)CH(2)CH(2)0+CH (3)CO
SyNONyMS •• ••• • .••• Methyl Ethyl Ketone, Tetrahydrofuran, Cyclohexanone, Acetone
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SECTION 2
HAZARDOUS INGREDIENTS
INGREDIENTS
Methyl Ethyl Ketone
Acetone
Cycl ohexanone
Tetrahydrofuran (See SECTION 6)
Violet Dye
Red Dye
CAS NlJ4BER
78-93-3
67-64-1
108-94-1
109-99-9
81-48-1
4477-79-6
"
13-17"
7O-8OX
S-1OX
1- 5"
<1"
<12:
SEC 313
---v-es
No
No
No
No
No
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SECTION 3
KNOWN HAZARDS UNDER 29 CFR 1910.1200
HAZARDS
YES
Combustible Liquid
Flanmable Liquid
x
Pyrophor ic Material
Explosive Material
Unstable Material
Water Reactive Material
Oxidizer
Organic Peroxide
Corrosive Material
Carpressed Gas
Irritant
x
C rcinogen NTP/IARC/OSHA (see SECTION 6)
NO
x
x
x
x
x
x
x
x
x
x
HAZARDS
Skin Hazard
Eye Hazard
Tox ic Agent
Highly Toxic Agent
Sensitizer
Kidney Toxin
Reproductive Toxin
Blood Toxin
Nervous System Toxin
Lung Toxin
Liver Tox in
YES
x
x
x
x
x
x
NO
x
x
x
x
x
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SECTION 4
REGULATION
CHEMICAL
lLV (TWA)
PEL (Transitional Limits)
STEl
Hazard Action L
Methyl Ethyl Ketone 200 ppn, 590 mil/cu m
200 ppn, 590 mil/cu m
300 pp1l, 885 mg/cu m
N/A
Acetone
750 ppn,1800 ng/cu m
1000 ppn, 2400 ng/cu
1000 pp1l, 2400 ng/cu m
N/A
Cyclohexanone
25 ppn, 100 ITQ/cu m (skin)
50 ppn, ZOO mil/cu m
100 pp1l, 400 mg/cu m
N/A
Tetrahydrofuran
200 ppn, 590 lIg/cu m
200 ppn, 590 ng/cu m
250 pp1l 735 mg/cu m
N/A
SECTION=S===;;= = ===========REGULATED= IDENTIFlCATION=================TIf~~~1F ==
DOT PROPER SHIPPING NAME •••.•••. CONSUMER COMMODITY ORM-D (For gallons: Flammable Liquid N.O.S . ,
Methyl Ethyl Ketone, Acetone) 3, UN 1993 , PG II, Cleaner/Primer-ODS
DOT HAZARD CLASS ••••••••••• • .••• Flammable Liquid
SHIPPING 10 NUMBER .••• •.•....... 149980-2 (Gallons Only)
EPA HAZARDOUS WASTE 10 NUMBER •.• U-213 & F-OOS
EPA HAZARD WASTE CLASS •••••••••• Ignitable ~aste/Toxic Waste
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SECTION 6
EFFECTS OF EXPOSURE
ENTRY ROUTE ••••• INHALE - YES
INGEST - YES SKIN
- YES
EYE
- YES
INHALATION .....• May cause irritation of mucous membranes, nose & throat, headache, dizziness , nausea, numbness of the
extremities and narcosis in high concentrations. Has caused CNS depression & liver damage in animals, and
concentrations of 1000-3000 pp1l caused retardat ion of fetal development in rats.
TETRAHYDROFURAN The National Toxicology program has reported that exposure of mice and rats to Tetrahydrofuran (THF) vapor
~ARNING •..•• levels up to 1800 pp1l 6 hr/day, 5 days/week for their lifetime caused an increased incidence of kidney tum
in male rats an dliver tumors in female mice. The significance of these find ings for human health are
unclear at this time, and may be related to "species spec ific" effects. Elevated incidences of tumors
in humans have not been reported for THF. THF is not l isted as a carcinogen by NTP, IARC, or OSHA.
One THF vendor has recOIImeuded a re<iJction in the "acceptable exposure l imi til from 200 ppm to 25 ppn,
8 and 12 hour time weighted average.
SKIN •••••••••••• Chronic contact or chronic exposure to vapors of high concentration may cause i rritation & dermatitis. May
poss i bl Y be absorbed th rough the ski n.
EyE •••••••• ••••• Vapors or direct contact may irritate.
INGESTION •••••.• May be aspirated into the lungs or cause systemic effects as with inhalation.
TARGET ORGANS ... Eye, Skin, Lung , Central Nervous System
(Continued on next page)
OATEY PURPLE PRIMER/CLEANER
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SECTION 7
EMERGENCY AND FIRST AID PROCEDURES - 303/623-5716 COLLECT
SKIN ••..••••. If irritation arises, wash thoroughly with soap and water. Seek medical attention if irritation persists.
EyES •..•••.•• If fumes cause irritation, move to fresh air and irrigate eyes with water for 15 minutes. If irritation
persists, seek medical attention.
INHALATION .•• Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Keep victim quiet and warm. Call a poison control center or physician immediately.
INGESTION •••• Drink water and call a poison control center or physician immediately. Avoid alcoholic beverages. Never give
anything by mouth to an unconscious person.
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SECTION 8
PHYSICAL AND CHEMICAL PROPERTIES
NFPA HAZARD SIGNAL .•••.•••
BOILING POINT •..••.•••••••
MELTING POINT •.•••••••••••
VAPOR PRESSURE .•••••••••••
VAPOR DENSITY (AIR = 1) •••
VOLATILE COMPONENTS •••••••
SOLUBILITY IN yATER •••••••
PH .••.•••••••••••..•••••••
SPECIFIC GRAViTy ••••••••••
EVAPORATION RATE ••••••••••
APPEARANCE •...••••••••••••
ODOR •••••.•.••••••••••••••
YILL DISSOLVE IN ••.•••••••
MATERIAL IS •••••••••••••••
HEALTH
2
STABILITY
133 Degrees F
/ 56 C
N/A
70 mmHg @ 20 Degrees C
2.0
100%
28 parts
N/A
0.79
(BUAC = 1) = 6.0 • 8.0
Purple Liquid
Sharp, penetrating odor.
Yater, organic solvents
Liquid
FLAMMABILITY
3
SPECIAL
NONE
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SECTION 9
FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITy •••••••••••••.•.•••••• LEL =2.0
X Volume UEL= 13.0
X volume
FLASHPOINT AND METHOD USED .••••••• 0 . 5 Degrees F. / PMCC
STABILITy .•.•.•••••••••••...•••••• Stable CONDITIONS TO AVOID: Heat, sparks and open flame. HAZARDOUS DECOMP. POTS.:
Carbon monoxide/ carbon dioxide/hydrogen chloride/smoke.
HAZARDOUS POLyMERIZATION •........• Yill Not Occur. CONDITIONS TO AVOID: none
INCOMPATIBILITY/MAT. TO AVOID •.•.• Acids, oxidizing materials, alkalis, chlorinated inorganics (potassium, calcium and
sodium hypochlorite), copper or copper alloys.
SPECIAL FIRE FIGHTING PROCEDURE ••• FOR SMALL FIRES: Use dry chemical, C02, water or foam extinguisher. FOR LARGE FIRES:
Evacuate area and call Fire Department immediately.
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SECTION 10
SPILL AND DISPOSAL INFORMATION
SPILL OR LEAK PROCEDURES ••• Ventilate area, stop leak if it can be done without risk. Take up with sand, earth, or other
non·combustible absorbant.
~ASTE DiSPOSAL ••.•••••••••• Dispose of according to local, state, and Federal regulations.
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SECTION 11
SAFE USAGE DATA
PROTECTIVE EQUIPMENT TYPES ••• EYES: Safety Glasses with side shields. RESPIRATORY: NIOSH·Approved cannister respirator in
Rubber Gloves OTHER: Eye wash and safety shower
absence of adequate ventilation. GLOVES:
should be available.
VENTILATION •••••••••••••••••• GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use
below PEL. LOCAL EXHAUST: Open doors &windows. If ~ed in enclosed area, use exhaust fans.
PRECAUTIONS ...••••••••••••••• HANDLING & STORAGE: Keep away from heat, sparks and flames; store in cool, dry place. OTHER:
Containers, even empties will retain residue and vapors.
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SECTION 12
MANUFACTURER OR SUPPLIER DATA
FIRM NAME &MAILING ADDRESS .•• DATEY CO., 4700 Y. 160th Street, P.O. Box 35906 Cleveland, Ohio 44135
OATEY PHONE NUMBER ..•....••••. (216) 267-7100
EMERGENCY PHONE NUMBERI ••••••• For Emergency First Aid call (303) 623-5716 COLLECT For chemical transportation emergencies
ONLY, call Chemtrec at 1-800-424-9300
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SECTION 13
DISCLAIMER
The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of
our knowledge. However, Ostey cannot give any guarantees regarding information from other sources, and expressly does not
make warranties, nor assumes any liability for its use.
OATEYCO.
HEALTH, SAFETY, AND ENVIRONMENTAL BULLETIN
May 22,1997
TETRAHYDROFURAN
Tetrahydrofuran, also known as THF, is a major component of PVC and CPVC solvent
cements and primers. It is used because it is one of the best solvents known for these
polymers and generally has low toxicity properties. It has been used in these products
since they were first developed over forty years ago.
Recently the National Toxicology Program completed and published a draft of a
technical report on a cancer study of THF using rats and mice. In this study tumors were
found in female mice livers and male rat kidneys when the animals were exposed to very
high levels of THF via inhalation throughout their lifetimes. Male mice and female rats
did not show any tumors at the same levels. .:The exposures were up to 1800 ppm which
is much higher than the current OSHA Permissible Exposure Limit ("PEL") of 200 ppm.
There are currently valid scientific questions which cast some doubt on whether this
result is predictive of human cancer. Oatey, other solvent cement producers, and a THF
industry group are funding follow-up research to answer some of these questions and to
determine whether the results of this study are relevant to human cancer. As of this date.
none of the international agencies which maintain lists of cancer-causing agents,
including NTP, have classified THF as a cancer-causing agent. Furthermore. there is no
data which identifies THF as a human cancer-causing agent even though it has been used
by large popUlations of workers for many years.
The current OSHA Permissible Exposure Limit for THF is 200 ppm. This means that a
person can be exposed to an average of200 ppm ofTHF over a normal work day without
OSHA requiring any special protective actions. OSHA has not changed this standard as a
result of the draft NTP study. Under most conditions, a plumber'S exposure to THF is
well below this level. However, prolonged use of solvent cements in poorly ventilated,
enclosed areas can result in higher exposures. Under those conditions we strongly
recommend providing adequate ventilation or the use of respirators which are NIOSH
approved for organic solvents.
NSF International, which certifies solvent cement products for potable water applications
under ANSIINSF Standard 61, is also currently evaluating the implications of the NTP
study relative to the acceptable levels of THF extracted from plastic piping systems
joined with solvent cements. Oatey, other solvent cement producers, and the THF
industry task force are discussing the results of this evaluation with NSF.
Please refer any questions to the Oatey Technical Service Department.
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