SAFETY DATA SHEET Sid Harvey item # 332 SDS # Z0206 1. Identification Product identifier UNI-WELD CLEAR OR PURPLE PRIMER Other means of identification SDS number 2402E Recommended use Part Numbers: Clear - 9324, 9336S, 9346S, 9356S, 9366S Purple - 8724, 8736S, 8746S, 8756S, 8766S, 90324, 90336S, 90346S, 90356S, 90366S Joining PVC Pipes Recommended restrictions None known. Synonyms Manufacturer/Importer/Supplier/Distributor information Company Name Address Telephone E-mail Transport Emergency Emergency First Aid Contact person United Elchem Industries c/o Oatey Co. 4700 West 160th Street Cleveland, OH 44135 216-267-7100 [email protected] Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator 2. Hazard(s) identification Physical hazards Flammable liquids Category 2 Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard OSHA defined hazards Category 1 Not classified. Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 1 / 10 Disposal Hazard(s) not otherwise classified (HNOC) Dispose of contents/container in accordance with local/regional/national/international regulations. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Acetone 67-64-1 30-60 Cyclohexanone 108-94-1 15-40 Furan, Tetrahydro- 109-99-9 10-30 Methyl ethyl ketone 78-93-3 10-30 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 2 / 10 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL Cyclohexanone (CAS 108-94-1) PEL 2400 mg/m3 1000 ppm 200 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) PEL 50 ppm 590 mg/m3 Methyl ethyl ketone (CAS 78-93-3) PEL 200 ppm 590 mg/m3 200 ppm US. ACGIH Threshold Limit Values Components Type Value Acetone (CAS 67-64-1) STEL TWA STEL 750 ppm 500 ppm 50 ppm TWA STEL 20 ppm 100 ppm Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 3 / 10 US. ACGIH Threshold Limit Values Components Methyl ethyl ketone (CAS 78-93-3) Type Value TWA STEL 50 ppm 300 ppm TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA Cyclohexanone (CAS 108-94-1) TWA 590 mg/m3 250 ppm 100 mg/m3 Furan, Tetrahydro- (CAS 109-99-9) STEL 25 ppm 735 mg/m3 250 ppm 590 mg/m3 200 ppm 885 mg/m3 TWA Methyl ethyl ketone (CAS 78-93-3) STEL 300 ppm 590 mg/m3 200 ppm TWA Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) 50 mg/l 80 mg/l Acetone 1,2-Cyclohexan ediol, with hydrolysis Cyclohexanol, with hydrolysis Tetrahydrofura n MEK 8 mg/l Furan, Tetrahydro- (CAS 2 mg/l 109-99-9) Methyl ethyl ketone (CAS 2 mg/l 78-93-3) * - For sampling details, please see the source document. Specimen Sampling Time Urine Urine * * Urine * Urine * Urine * Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air Appropriate engineering changes per hour) should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles). Eye/face protection UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 4 / 10 Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Translucent. Physical state Liquid. Form Liquid. Color Clear. or Purple Odor Solvent. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 °C) Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C) Evaporation rate 5.5 - 8 Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.82 - 0.86 Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity < 100 cP Other information Bulk density 7 lb/gal VOC (Weight %) 505 g/l SQACMD Method 304 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. Incompatible materials UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 5 / 10 Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation Inhalation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity Components May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Species Test Results Acute Dermal LD50 Rabbit 20 ml/kg Inhalation LC50 Rat 50 mg/l, 8 Hours Oral LD50 Rat 5800 mg/kg Acute Dermal LD50 Rabbit 948 mg/kg Inhalation LC50 Rat 8000 ppm, 4 hours Oral LD50 Rat 1540 mg/kg Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) * Estimates for product may be based on additional component data not shown. Causes skin irritation. Skin corrosion/irritation Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Not available. Respiratory sensitization Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 6 / 10 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects. Reproductive toxicity Specific target organ toxicity single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Acetone (CAS 67-64-1) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours Cyclohexanone (CAS 108-94-1) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) No data available. Mobility in soil Other adverse effects -0.24 0.81 0.46 0.29 No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group UN1993 Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 25063 LBS, Acetone RQ = 12522 LBS) 3 3 II UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 7 / 10 Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Read safety instructions, SDS and emergency procedures before handling. IB2, T7, TP1, TP8, TP28 150 202 242 UN1993 Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone) 3 II No. 3H Read safety instructions, SDS and emergency procedures before handling. UN1993 FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone) 3 II No. F-E, S-E Read safety instructions, SDS and emergency procedures before handling. Not available. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Furan, Tetrahydro- (CAS 109-99-9) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Hazard categories Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 8 / 10 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia Inventory name Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - On inventory (yes/no)* Yes Yes No No SDS US Issue date: 17-December-2014 9 / 10 Country(s) or region United States & Puerto Rico Inventory name Toxic Substances Control Act (TSCA) Inventory On inventory (yes/no)* Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 17-December-2014 Revision date - Version # 01 Health: 2 Flammability: 3 Physical hazard: 0 The information in the sheet was written based on the best knowledge and experience currently available. United Elchem Industries c/o Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. HMIS® ratings Disclaimer UNI-WELD CLEAR OR PURPLE PRIMER 924273 Version #: 01 Revision date: - SDS US Issue date: 17-December-2014 10 / 10 4700 W. 160TH Street P.O. Box 35906 Cleveland, Ohio 44135 Emergency Tel No. (303) 623-5716 Collect ATE RIAL SAFETY DATA SHEET OATEY PURPLE PRIMER/CLEANER Latest Revision Date .•. 05/28/97 Date of Issue ... • .... 08/13/97 ============================================================================ section 1 IDENTITY OF MATERIAL TRADE NAME •.••• •• •~TEY PURPLE PRIMER/CLEANER PROOUCT NUMBERS ••• 30768, 30780, 30783, 30796, 30806 FORMULA ••••••••••• CH(3)OOC(2)H(5)+CH(2)CH(2)CH(2)CH(2)0+CH (3)CO SyNONyMS •• ••• • .••• Methyl Ethyl Ketone, Tetrahydrofuran, Cyclohexanone, Acetone ============================================================================ SECTION 2 HAZARDOUS INGREDIENTS INGREDIENTS Methyl Ethyl Ketone Acetone Cycl ohexanone Tetrahydrofuran (See SECTION 6) Violet Dye Red Dye CAS NlJ4BER 78-93-3 67-64-1 108-94-1 109-99-9 81-48-1 4477-79-6 " 13-17" 7O-8OX S-1OX 1- 5" <1" <12: SEC 313 ---v-es No No No No No ============================================================================ SECTION 3 KNOWN HAZARDS UNDER 29 CFR 1910.1200 HAZARDS YES Combustible Liquid Flanmable Liquid x Pyrophor ic Material Explosive Material Unstable Material Water Reactive Material Oxidizer Organic Peroxide Corrosive Material Carpressed Gas Irritant x C rcinogen NTP/IARC/OSHA (see SECTION 6) NO x x x x x x x x x x HAZARDS Skin Hazard Eye Hazard Tox ic Agent Highly Toxic Agent Sensitizer Kidney Toxin Reproductive Toxin Blood Toxin Nervous System Toxin Lung Toxin Liver Tox in YES x x x x x x NO x x x x x ========~===============~============~==============~======================= SECTION 4 REGULATION CHEMICAL lLV (TWA) PEL (Transitional Limits) STEl Hazard Action L Methyl Ethyl Ketone 200 ppn, 590 mil/cu m 200 ppn, 590 mil/cu m 300 pp1l, 885 mg/cu m N/A Acetone 750 ppn,1800 ng/cu m 1000 ppn, 2400 ng/cu 1000 pp1l, 2400 ng/cu m N/A Cyclohexanone 25 ppn, 100 ITQ/cu m (skin) 50 ppn, ZOO mil/cu m 100 pp1l, 400 mg/cu m N/A Tetrahydrofuran 200 ppn, 590 lIg/cu m 200 ppn, 590 ng/cu m 250 pp1l 735 mg/cu m N/A SECTION=S===;;= = ===========REGULATED= IDENTIFlCATION=================TIf~~~1F == DOT PROPER SHIPPING NAME •••.•••. CONSUMER COMMODITY ORM-D (For gallons: Flammable Liquid N.O.S . , Methyl Ethyl Ketone, Acetone) 3, UN 1993 , PG II, Cleaner/Primer-ODS DOT HAZARD CLASS ••••••••••• • .••• Flammable Liquid SHIPPING 10 NUMBER .••• •.•....... 149980-2 (Gallons Only) EPA HAZARDOUS WASTE 10 NUMBER •.• U-213 & F-OOS EPA HAZARD WASTE CLASS •••••••••• Ignitable ~aste/Toxic Waste ============================================================================ SECTION 6 EFFECTS OF EXPOSURE ENTRY ROUTE ••••• INHALE - YES INGEST - YES SKIN - YES EYE - YES INHALATION .....• May cause irritation of mucous membranes, nose & throat, headache, dizziness , nausea, numbness of the extremities and narcosis in high concentrations. Has caused CNS depression & liver damage in animals, and concentrations of 1000-3000 pp1l caused retardat ion of fetal development in rats. TETRAHYDROFURAN The National Toxicology program has reported that exposure of mice and rats to Tetrahydrofuran (THF) vapor ~ARNING •..•• levels up to 1800 pp1l 6 hr/day, 5 days/week for their lifetime caused an increased incidence of kidney tum in male rats an dliver tumors in female mice. The significance of these find ings for human health are unclear at this time, and may be related to "species spec ific" effects. Elevated incidences of tumors in humans have not been reported for THF. THF is not l isted as a carcinogen by NTP, IARC, or OSHA. One THF vendor has recOIImeuded a re<iJction in the "acceptable exposure l imi til from 200 ppm to 25 ppn, 8 and 12 hour time weighted average. SKIN •••••••••••• Chronic contact or chronic exposure to vapors of high concentration may cause i rritation & dermatitis. May poss i bl Y be absorbed th rough the ski n. EyE •••••••• ••••• Vapors or direct contact may irritate. INGESTION •••••.• May be aspirated into the lungs or cause systemic effects as with inhalation. TARGET ORGANS ... Eye, Skin, Lung , Central Nervous System (Continued on next page) OATEY PURPLE PRIMER/CLEANER ==========================================================================~= SECTION 7 EMERGENCY AND FIRST AID PROCEDURES - 303/623-5716 COLLECT SKIN ••..••••. If irritation arises, wash thoroughly with soap and water. Seek medical attention if irritation persists. EyES •..•••.•• If fumes cause irritation, move to fresh air and irrigate eyes with water for 15 minutes. If irritation persists, seek medical attention. INHALATION .•• Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician immediately. INGESTION •••• Drink water and call a poison control center or physician immediately. Avoid alcoholic beverages. Never give anything by mouth to an unconscious person. ============================================================================ SECTION 8 PHYSICAL AND CHEMICAL PROPERTIES NFPA HAZARD SIGNAL .•••.••• BOILING POINT •..••.••••••• MELTING POINT •.••••••••••• VAPOR PRESSURE .••••••••••• VAPOR DENSITY (AIR = 1) ••• VOLATILE COMPONENTS ••••••• SOLUBILITY IN yATER ••••••• PH .••.•••••••••••..••••••• SPECIFIC GRAViTy •••••••••• EVAPORATION RATE •••••••••• APPEARANCE •...•••••••••••• ODOR •••••.•.•••••••••••••• YILL DISSOLVE IN ••.••••••• MATERIAL IS ••••••••••••••• HEALTH 2 STABILITY 133 Degrees F / 56 C N/A 70 mmHg @ 20 Degrees C 2.0 100% 28 parts N/A 0.79 (BUAC = 1) = 6.0 • 8.0 Purple Liquid Sharp, penetrating odor. Yater, organic solvents Liquid FLAMMABILITY 3 SPECIAL NONE ============================================================================ SECTION 9 FIRE AND EXPLOSION HAZARD DATA FLAMMABILITy •••••••••••••.•.•••••• LEL =2.0 X Volume UEL= 13.0 X volume FLASHPOINT AND METHOD USED .••••••• 0 . 5 Degrees F. / PMCC STABILITy .•.•.•••••••••••...•••••• Stable CONDITIONS TO AVOID: Heat, sparks and open flame. HAZARDOUS DECOMP. POTS.: Carbon monoxide/ carbon dioxide/hydrogen chloride/smoke. HAZARDOUS POLyMERIZATION •........• Yill Not Occur. CONDITIONS TO AVOID: none INCOMPATIBILITY/MAT. TO AVOID •.•.• Acids, oxidizing materials, alkalis, chlorinated inorganics (potassium, calcium and sodium hypochlorite), copper or copper alloys. SPECIAL FIRE FIGHTING PROCEDURE ••• FOR SMALL FIRES: Use dry chemical, C02, water or foam extinguisher. FOR LARGE FIRES: Evacuate area and call Fire Department immediately. ==========================================================================~= SECTION 10 SPILL AND DISPOSAL INFORMATION SPILL OR LEAK PROCEDURES ••• Ventilate area, stop leak if it can be done without risk. Take up with sand, earth, or other non·combustible absorbant. ~ASTE DiSPOSAL ••.•••••••••• Dispose of according to local, state, and Federal regulations. ==========================================================================~= SECTION 11 SAFE USAGE DATA PROTECTIVE EQUIPMENT TYPES ••• EYES: Safety Glasses with side shields. RESPIRATORY: NIOSH·Approved cannister respirator in Rubber Gloves OTHER: Eye wash and safety shower absence of adequate ventilation. GLOVES: should be available. VENTILATION •••••••••••••••••• GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below PEL. LOCAL EXHAUST: Open doors &windows. If ~ed in enclosed area, use exhaust fans. PRECAUTIONS ...••••••••••••••• HANDLING & STORAGE: Keep away from heat, sparks and flames; store in cool, dry place. OTHER: Containers, even empties will retain residue and vapors. ==========================================================================~= SECTION 12 MANUFACTURER OR SUPPLIER DATA FIRM NAME &MAILING ADDRESS .•• DATEY CO., 4700 Y. 160th Street, P.O. Box 35906 Cleveland, Ohio 44135 OATEY PHONE NUMBER ..•....••••. (216) 267-7100 EMERGENCY PHONE NUMBERI ••••••• For Emergency First Aid call (303) 623-5716 COLLECT For chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300 ==========================================================================~= SECTION 13 DISCLAIMER The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our knowledge. However, Ostey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use. OATEYCO. HEALTH, SAFETY, AND ENVIRONMENTAL BULLETIN May 22,1997 TETRAHYDROFURAN Tetrahydrofuran, also known as THF, is a major component of PVC and CPVC solvent cements and primers. It is used because it is one of the best solvents known for these polymers and generally has low toxicity properties. It has been used in these products since they were first developed over forty years ago. Recently the National Toxicology Program completed and published a draft of a technical report on a cancer study of THF using rats and mice. In this study tumors were found in female mice livers and male rat kidneys when the animals were exposed to very high levels of THF via inhalation throughout their lifetimes. Male mice and female rats did not show any tumors at the same levels. .:The exposures were up to 1800 ppm which is much higher than the current OSHA Permissible Exposure Limit ("PEL") of 200 ppm. There are currently valid scientific questions which cast some doubt on whether this result is predictive of human cancer. Oatey, other solvent cement producers, and a THF industry group are funding follow-up research to answer some of these questions and to determine whether the results of this study are relevant to human cancer. As of this date. none of the international agencies which maintain lists of cancer-causing agents, including NTP, have classified THF as a cancer-causing agent. Furthermore. there is no data which identifies THF as a human cancer-causing agent even though it has been used by large popUlations of workers for many years. The current OSHA Permissible Exposure Limit for THF is 200 ppm. This means that a person can be exposed to an average of200 ppm ofTHF over a normal work day without OSHA requiring any special protective actions. OSHA has not changed this standard as a result of the draft NTP study. Under most conditions, a plumber'S exposure to THF is well below this level. However, prolonged use of solvent cements in poorly ventilated, enclosed areas can result in higher exposures. Under those conditions we strongly recommend providing adequate ventilation or the use of respirators which are NIOSH approved for organic solvents. NSF International, which certifies solvent cement products for potable water applications under ANSIINSF Standard 61, is also currently evaluating the implications of the NTP study relative to the acceptable levels of THF extracted from plastic piping systems joined with solvent cements. Oatey, other solvent cement producers, and the THF industry task force are discussing the results of this evaluation with NSF. Please refer any questions to the Oatey Technical Service Department.
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