StarTron Diesel MSDS Sheet

StarTron Diesel MSDS Sheet

MATERIAL SAFETY DATA SHEET

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European Union Directives

PART I

What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION

PRODUCT NUMBER:

MANUFACTURER'S NAME:

U.S. ADDRESS:

93108, 93116, 93132, 93100, 93105, 93155

STAR BRITE

4041 S.W. 47 Avenue

INTERNATIONAL ADDRESS:

INTERNATIONAL EMERGENCY PHONE:

INTERNATIONAL BUSINESS PHONE:

DATE: September 9, 2009 dco Replaces: October 7, 2006

2. COMPOSITION and INFORMATION ON INGREDIENTS

EU LABELING AND CLASSIFICATION: This product meets the definition of the hazard class of Harmful, as defined by the

European Economic Community Guidelines.

EU CLASSIFICATION: [Xn] Harmful.

EU RISK PHRASES: [R: 65]: Harmful, may cause lung damage if swallowed.

EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when the substance

or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label.

CHEMICAL NAME CAS # EINECS # % w/v EU CLASSIFICATION FOR COMPONENTS

Proprietary Organic Compounds

Solvent Naphtha (Petroleum), Heavy Aliphatic 64742-96-7 265-200-4

< 0.5

> 95

HAZARD CLASSIFICATION: Not applicable.

RISK PHRASES: Not applicable.

HAZARD CLASSIFICATION: Xn [Harmful]

RISK PHRASES: R: 65

See Section 15 for full EU classification information of product and components.

NOTE: ALL Canadian WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. The MSDS is also prepared to include all European Union required information under EU Directives.

3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: This product is a clear, colorless liquid with a mild, paraffin-like odor. Health Hazards:

Inhalation overexposures to mists or sprays of this product can cause central nervous system effects. Severe inhalation exposures may be fatal. Skin contact may cause allergic reaction. Flammability Hazards: This product is combustible and may ignite if heated at or above its flash point of 65.5-73.8

°C (150-165°F). If involved in a fire, this product will produce irritating and toxic materials such as various carbon oxides, hydrocarbons and aldehydes. Reactivity Hazards: This product is not reactive. Environmental Hazards: This material may be harmful or fatal to contaminated plant, animal, and aquatic life. Emergency Recommendations: Emergency responders must wear the personal protective equipment suitable for the situation to which they are responding.

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3. HAZARD IDENTIFICATION (Continued)

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational overexposure are inhalation and contact with skin and eyes. The symptoms of overexposure to this product are described on the following page.

INHALATION: Due to the high vapor pressure of the main component, formation of mists or sprays of this product are unlikely, unless the product is heated or used in a manner to produce sprays. If this product inhaled, fume, mists or sprays can mildly irritate the respiratory system and cause coughing, sneezing, and difficulty breathing.

Depending on the concentration and duration of exposure, inhalation overexposure can cause central nervous system depression, including dizziness, headache, nausea, fatigue, vomiting and incoordination.

Severe inhalation overexposure (as may occur in a confined space with inadequate ventilation) may cause unconsciousness and death.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM

HEALTH HAZARD

FLAMMABILITY HAZARD

(BLUE)

(RED)

2

2

PHYSICAL HAZARD

(ORANGE)

PROTECTIVE EQUIPMENT

0

CONTACT WITH SKIN or EYES: Skin contact can cause mild to moderate irritation, depending on the duration and concentration of exposure. Symptoms of such overexposure may cause redness and irritation. Prolonged or repeated skin contact with this product may cause dermatitis (dry, red, scaly skin). Eye contact with this product may cause irritation, redness, and watering.

SKIN ABSORPTION: The components of this product are not known to

EYES

RESPIRATORY

HANDS BODY be absorbed through intact skin.

INGESTION: Ingestion is not anticipated to be a significant route of exposure for any component of this product. If this product is swallowed, it may cause nausea, vomiting, and diarrhea. A significant

SEE SECTION 8

SEE SECTION 8 hazard associated with ingestion of this product is aspiration; breathing this material into the lungs can cause severe lung irritation and tissue damage, which can cause chemical pneumonia or pulmonary edema

For Routine Industrial Use and Handling Applications

See Section 16 for Definition of Ratings

(life-threatening lung conditions).

INJECTION: Injection of this product (as may occur if skin is punctured by a contaminated object) can cause pain, redness, and local swelling.

HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of overexposure, the following symptoms may be observed:

ACUTE: Inhalation of fumes, mists or sprays can cause adverse effects on the central nervous system. Severe inhalation

overexposure may cause unconsciousness and death. A significant hazard associated with ingestion of this product is aspiration; breathing this material into the lungs can cause severe lung irritation and tissue damage, which can cause chemical pneumonia or pulmonary edema (life-threatening lung conditions).

CHRONIC: Repeated skin contact with this product may cause dermatitis (dry, red, scaly skin). See Section 11 (Toxicology

Information) for additional data.

TARGET ORGANS: ACUTE: Skin, eyes, central nervous system. CHRONIC: Skin.

PART II

What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES

Contaminated individuals must be taken for medical attention. Rescuers should be taken for medical attention, if necessary.

Take a copy of label and MSDS to health professional with the contaminated individual.

SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water and soap.

Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual must seek immediate medical attention if any adverse health effect occurs.

EYE EXPOSURE: If this product's liquid or vapors enter the eyes, open the contaminated individual's eyes while under gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 15 minutes.

INHALATION: If vapors, mists, or sprays of this product are inhaled, remove the contaminated individual to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. The contaminated individual should seek immediate medical attention.

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4. FIRST-AID MEASURES (Continued)

INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT

INFORMATION. If professional advice is not available, do not induce vomiting. Have victim rinse mouth with water or drink several cupfuls of water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, other skin disorders, and central nervous disorders may be aggravated by exposure to this product.

RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Provide oxygen, if necessary.

Pulmonary function tests, chest X-rays, and nervous system evaluations may prove useful.

5. FIRE-FIGHTING MEASURES

FLASH POINT: 65.5-73.8

°C (150-165°F)

AUTOIGNITION TEMPERATURE: >600 F

° >315 C°

FLAMMABLE LIMITS (in air by volume, %):

NFPA RATING

FLAMMABILITY

FIRE EXTINGUISHING MATERIALS:

Water

Foam: YES

Carbon Dioxide: YES

Dry Chemical: YES

Halon: YES Other: Any "ABC" Class.

HEALTH

2

2

0

INSTABILITY

UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is Class IIIA combustible liquid, which can ignite if heated at or above its flash point of

65.5-73.8

°C (150-165°F). If involved in a fire, this product will produce irritating and toxic materials such as various carbon oxides, aldehydes and hydrocarbons. This product can float on water and may travel to distant locations and spread fire. Containers may rupture violently when exposed to fire or excessive heat for sufficient time.

OTHER

See Section 16 for

Definition of Ratings

Explosion Sensitivity to Mechanical Impact: Not sensitive.

Explosion Sensitivity to Static Discharge: In general, materials similar to this product have low electrical conductivities and therefore the liquid can accumulate static charge by flow, agitation or pouring. The warmed vapour can be ignited by an electrostatic discharge of sufficient energy.

SPECIAL FIRE-FIGHTING PROCEDURES: Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Chemical resistant clothing may be necessary. Move containers from fire area if it can be done without risk to personnel. Water spray can be used to cool fire-exposed containers. Avoid getting water into containers because of the danger of boiling over. Stop leak before attempting to stop the fire. If the leak cannot be stopped, and if there is no risk to the surrounding area, let the fire burn itself out. Water fog or spray can also be used by trained firefighters to disperse this product’s vapors and to protect personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. Rinse contaminated equipment thoroughly with soapy water before returning such equipment to service.

6. ACCIDENTAL RELEASE MEASURES

RELEASE RESPONSE: In case of a release, clear the affected area and protect people. Spills will be slippery. Eliminate all sources of ignition before cleanup begins. Use non-sparking tools. Appropriately trained personnel in proper personal protective equipment, using pre-planned procedures should respond to uncontrolled releases. The proper personal protective equipment for incidental releases (e.g., 32-ounce container) should be rubber gloves and goggles. In the event that cleanup will generate excessive splashes, a face-shield, boots, and chemical resistant body protection should also be worn. In the event of a non-incidental release (e.g., several 1-gallon containers released in a poorly ventilated area), minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. A fire-retardant suit must be worn over the chemical resistant suit. Short-term colorimetric detector tubes for the determination of hydrocarbons and petroleum hydrocarbons are commercially available. Monitor area for combustible vapor levels. Monitoring must indicate less than

10% LEL (refer to Section 5, Fire-fighting Measures) before emergency response personnel are permitted in the area.

Monitoring must indicate that oxygen levels are above 19.5% before anyone is permitted in the area without Self-Contained

Breathing Apparatus. Absorb spilled liquid with activated carbon, polypads, or other suitable absorbent materials.

Decontaminate the area thoroughly. Place all spill residue in an appropriate container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures, or appropriate standards of Canada or EU Member States (see

Section 13, Disposal Considerations).

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PART III

How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE

WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.

Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing vapors, mists, or sprays of this product. Use in a well-ventilated location. Remove contaminated clothing immediately.

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.

Keep away from heat, sparks, and other sources of ignition. Keep container tightly closed when not in use. Open containers slowly on a stable surface. Use non-sparking tools. Bond and ground containers during transfers of material. If this product is transferred into another container, only use portable containers and dispensing equipment (faucet, pump, drip can) approved for flammable liquids. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate. Store away from incompatible materials (see Section 10, Stability and Reactivity). Containers should be separated from oxidizing materials by a minimum distance of 20 ft. or by a barrier of non-combustible material at least 5 ft. high having a fire-resistance rating of at least 0.5 hours. Storage areas should be made of fire resistant materials. Post warning and “NO SMOKING” signs in storage and use areas, as appropriate. Have appropriate extinguishing equipment in the storage area (e.g., sprinkler system, portable fire extinguishers). Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code, for additional information on storage.

Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with care.

Never perform any welding, cutting, soldering, drilling, or other hot work on an empty container or piping until all liquid, vapors, and residue have been cleared.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in

Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures and appropriate Canadian standards, or those of EU Member States.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below, if applicable. Use a non-sparking, grounded, explosion-proof ventilation system separate from other exhaust ventilation systems. Exhaust directly to the outside, taking necessary precautions for environmental protection. Ensure eyewash/safety shower stations are available near areas where this product is used.

EXPOSURE LIMITS/GUIDELINES:

CHEMICAL NAME CAS #

Solvent Naphtha

(Petroleum), Heavy

Aliphatic

(exposure limits are for kerosene)

64742-96-

7

Proprietary Organic Compounds

Mixture

EXPOSURE LIMITS IN AIR

NIOSH OTHER

TWA STEL TWA STEL TWA STEL IDLH TWA STEL mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

mg/m

3

200 (skin) as total hydrocarbon

(P)

TLV-A3

NE NE NE NE NE NE NE NE NE NE

NE = Not Established. P = Avoid prolonged and repeated skin contact to diesel fuels which can lead to dermal irritation and may be associated with an increased risk of skin cancer. See Section 16 for Definitions of Terms Used.

EYE PROTECTION: Splash goggles or safety glasses. Face-shields should be worn if operations will generate splashes or sprays. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, or the European Standard EN166.

RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed above, if applicable. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR

1910.134), applicable U.S. State regulations, the Canadian CSA Standard Z94.4-93, the European Standard EN149, or

Standards of EU member states. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHAs Respiratory Protection Standard (1910.134-1998). The following are NIOSH respiratory protective equipment for Kerosenes.

KEROSENE

CONCENTRATION RESPIRATORY

Up to 1000 mg/m

3

: Any chemical cartridge respirator with organic vapor cartridge(s), or any Supplied-Air Respirator

(SAR), or any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator

(PAPR) with organic vapor cartridge(s).

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8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)

RESPIRATORY PROTECTION (continued):

KEROSENE (continued)

CONCENTRATION RESPIRATORY

Up to 5000 mg/m

3

: Any Chemical Cartridge Respirator with a full facepiece and organic vapor cartridge(s), or any

Air-Purifying, Full-Facepiece Respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister, or any PAPR with a tight-fitting facepiece and organic vapor cartridge(s), or any Self-Contained Breathing Apparatus with a full facepiece, or any SAR.

Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination

Escape: with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.

Any Air-Purifying, Full-Facepiece Respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister, or any appropriate escape-type, SCBA.

HAND PROTECTION: Wear Nitrile rubber, Polyethylene, Viton ™ gloves (resistance to breakthrough longer than 8 hours when tested against a similar petroleum substance) for routine industrial use. Natural rubber and butyl rubber gloves are not recommended. Resistance of specific materials can vary from product to product. Evaluate resistance under conditions of use and maintain clothing carefully. Use triple gloves for spill response, as stated in Section 6 (Accidental

Release Measures) of this MSDS. If necessary, refer to U.S. OSHA 29 CFR 1910.138, appropriate Standards of Canada, or appropriate Standards of the European Union.

BODY PROTECTION: If operations will generate splashes or sprays, use body protection appropriate for task (e.g., coveralls or apron).

If necessary, refer to appropriate Standards of Canada or the European Union. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.

9. PHYSICAL and CHEMICAL PROPERTIES

SPECIFIC VAPOR DENSITY (air = 1): > 5.0

SPECIFIC GRAVITY @ 60

°F (water = 1): 0.804-0.815

SOLUBILITY IN WATER: Less than 0.01

VAPOR PRESSURE, mm Hg @ 20

°C (68°F): 0.010

ODOR THRESHOLD: Not established.

LIQUID DENSITY: 6.7 lb/gal @ 60

°F/0.804 lb/gal @ 16°C

EVAPORATION RATE (n-BuAc = 1): < 10

MELTING/FREEZING POINT: -42.7

°C (-45.0°F)

BOILING POINT @ 760 mmHg: IBP >400 (D86) F

°

>204

° pH: Not applicable.

% VOLATILES: 100%

DENSITY: 900 lb/ft

3

COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.

APPEARANCE, ODOR AND COLOR: This product is a clear, colorless liquid with a mild, paraffin-like odor.

HOW TO DETECT THIS SUBSTANCE (warning properties): The odor may act as a distinguishing characteristic of this product.

10. STABILITY and REACTIVITY

STABILITY: Normally stable.

DECOMPOSITION PRODUCTS: Thermal decomposition of this product can produce various hydrocarbons, carbon oxides and aldehydes.

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with strong oxidizers.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Avoid exposure to or contact with extreme temperatures and incompatible chemicals.

PART IV

Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION

TOXICITY DATA: Currently, there are no toxicological data available for components

SUSPECTED CANCER AGENT: Petroleum Distillates, Solvent, Aliphatic compounds, such as the main component of this product are listed as follows:

ACGIH TLV-A3 [Confirmed Animal Carcinogen with Unknown Relevance to Humans: The agent is carcinogenic in experimental animals at a relatively high dose, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) that may not be relevant to worker exposure. Available epidemiologic studies do not conform an increased risk of cancer in exposed humans. Available evidence does not suggest that the agent is likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure.] IARC-3 [Unclassifiable as to Carcinogenicity in

Humans: This category is used most commonly for agents, mixtures, and exposure circumstances for which the evidence of carcinogenicity is inadequate in humans and inadequate or limited in experimental animals. Exceptionally, agents (mixtures) for which the evidence of carcinogenicity is inadequate in humans but sufficient in experimental animals may be placed in this category when there is strong evidence that the mechanism of carcinogenicity in experimental does not operate in humans. Agents, mixtures, and exposure circumstances that do not fall into any other group are also placed in this category.]

The remaining component of this product is not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and

CAL/OSHA and therefore is neither considered to be nor suspected to be a cancer-causing agent by these agencies.

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11. TOXICOLOGICAL INFORMATION (Continued)

IRRITANCY OF PRODUCT: This product can be mildly irritating to eyes, skin, and other contaminated tissue.

SENSITIZATION TO THE PRODUCT: No component of this product is known to be a human skin or respiratory sensitizer.

REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system.

Mutagenicity: The components of this product are not reported to cause mutagenic effects in humans.

Embryotoxcity: The components of this product are not reported to cause embryotoxic effects in humans.

Teratogenicity: The components of this product are not reported to cause teratogenic effects in humans.

Reproductive Toxicity: The components of this product are not reported to cause adverse reproductive effects in humans.

A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process.

BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) determined for the components of this product.

12. ECOLOGICAL INFORMATION

ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.

ENVIRONMENTAL STABILITY: The components of this product are relatively stable under ambient, environmental conditions.

EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful or fatal to contaminated plant and animal life (especially if large quantities are released).

EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful or fatal to contaminated aquatic plant and animal life. This material floats on water, and can potentially form slicks that are capable of creating oxygen-deprived waterways and severely contaminate coastal and shore life.

13. DISPOSAL CONSIDERATIONS

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada or EU Member States. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.

EPA WASTE NUMBER: Wastes of this product should be tested to see if they are wastes as defined under EPA criteria for

D001 listed wastes (Waste Characteristic- Ignitabity).

14. TRANSPORTATION INFORMATION

NOTE: Due to the flash point, this material is only regulated as a hazardous material by the U.S. D.OT. It is not classified as dangerous goods under any other jurisdiction.

THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF

TRANSPORTATION.

PROPER SHIPPING NAME: Combustible liquid, n.o.s. (Solvent Naphtha (Petroleum), Heavy Aliphatic)

HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable

EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2004: 128

MARINE POLLUTANT: No component of this product is listed as a Marine Pollutant, per Appendix B to 49 CFR 172.101

TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT classified as Dangerous Goods, per regulations of Transport Canada.

INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This material is NOT classified as dangerous goods under rules of IATA and IMDG.

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD

(ADR): This product is NOT classified as Dangerous Goods by the United Nations Economic Commission for Europe to be dangerous goods.

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15. REGULATORY INFORMATION

ADDITIONAL U.S. REGULATIONS:

U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act.

U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs. (4,540 kg) therefore applies, per 40 CFR 370.20.

U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.

U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.

OTHER U.S. FEDERAL REGULATIONS: OSHA Standard for Flammable and Combustible Liquids (29 CFR 1910.106).

Depending on specific operations involving the use of this product, the regulations of the Process Safety Management of

Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation, the components of this product are/are not listed in Appendix A (provided Threshold Quantities for Listed Substances); however, any process that involves a flammable liquid on-site, in one location, in quantities of 10,000 lb. (4,553 kg) or greater is covered under this regulation unless it is used as a fuel. Vegetable Oils, such as the Linseed Oil components of this product, are considered OSHA

Table Z-1-A air contaminants.

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this product is on the California Proposition 65 lists.

LABELING (Precautionary Statements) ANSI LABELING (Z129.1): WARNING! COMBUSTIBLE LIQUID AND VAPOR.

MAY CAUSE ALLERGIC SKIN REACTION. HARMFUL IF INHALED. ASPIRATION HAZARD-INGESTION CAN CAUSE

LIFE-THREATENING LUNG DAMAGE. Keep away from heat, sparks, and flame. Avoid breathing mists or sprays. Avoid prolonged or repeated contact with skin. Use only with adequate ventilation. Keep container closed. Wash thoroughly after handling. Wear gloves and goggles. FIRST-AID: In case of contact, immediately flush skin or eyes for at least 15 minutes with large amounts of water. If inhaled, move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If ingested, do not induce vomiting. Get medical attention immediately. IN CASE OF FIRE: Use foam, dry chemical, or carbon dioxide. Liquid will float and may re-ignite on the surface of water. IN CASE OF SPILL: Absorb spill with inert material and place in suitable container. Refer to Material Safety Data Sheet for additional information on this product.

ADDITIONAL CANADIAN REGULATIONS:

CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.

OTHER CANADIAN REGULATIONS: Not applicable.

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this product are not on the CEPA Priority Substances Lists.

CANADIAN WHMIS CLASSIFICATION and SYMBOLS:

Class B3: Combustible Liquid

EUROPEAN UNION INFORMATION FOR PRODUCT:

EU LABELING AND CLASSIFICATION: This product meets the following definitions, per the European Union Council

Directives.

EU CLASSIFICATION: [Xn] Harmful.

EU RISK PHRASES: [R: 65]: Harmful; may cause lung damage if swallowed.

EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when

the substance or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container and label.

EU SAFETY PHRASES: [S(2–)*]: Keep out of reach of children. *This safety phrase can be omitted from the label when

the substance or preparation is sold for industrial use only. [S: 24]: Avoid contact with the skin. [S: 62]: Do not breathe fumes, vapour or spray (appropriate wording to be specified by the manufacturer).

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15. REGULATORY INFORMATION (Continued)

EUROPEAN UNION INFORMATION FOR PRODUCT:

EU LABELING AND CLASSIFICATION (continued):

EUROPEAN UNION ANNEX II HAZARD SYMBOL:

EUROPEAN UNION INFORMATION FOR CONSTITUENTS: The following information is available for primary constituents in the components of this product.

Solvent Naphtha (Petroleum), Heavy Aliphatic:

EU EINECS/ELINCS NUMBER: 265-200-4

EU CLASSIFICATION: Harmful. [Xn]

EU RISK PHRASES: [R: 65]: Harmful; may cause lung damage if swallowed.

EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when the

substance or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label.

16. OTHER INFORMATION

Po Box 36519, La Mesa, CA 91944-3519

The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Star brite assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Star brite assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.

DEFINITIONS OF TERMS

A large number of abbreviations and acronyms appear on an MSDS. Some of these, which are commonly used, include the following:

CAS #:

This is the Chemical Abstract Service Number that uniquely identifies each constituent.

EXPOSURE LIMITS IN AIR:

CEILING LEVEL: The concentration that shall not be exceeded during any part of the working exposure.

LOQ: Limit of Quantitation.

MAK: Federal Republic of Germany Maximum Concentration Values in the workplace.

NE: Not Established. When no exposure guidelines are established, an entry of NE is made for reference.

NIC: Notice of Intended Change.

NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at any time during a workday.

NIOSH RELs: NIOSH’s Recommended Exposure Limits.

PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure

Limits. This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule

(Federal Register: 58: 35338-35351 and 58: 40191). Both the current

PELs and the vacated PELs are indicated. The phrase, “Vacated 1989

PEL,” is placed next to the PEL that was vacated by Court Order.

SKIN: Used when a there is a danger of cutaneous absorption.

STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hr TWA is within the

TLV-TWA, PEL-TWA or REL-TWA.

TLV-Threshold Limit Value: An airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour.

EXPOSURE LIMITS IN AIR (continued):

TWA-Time Weighted Average: Time Weighted Average exposure concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek.

IDLH-Immediately Dangerous to Life and Health: This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury.

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD

RATINGS:

This rating system was developed by the National Paint and

Coating Association and has been adopted by industry to identify the degree of chemical hazards.

HEALTH HAZARD:

0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”.

Eye Irritation: Essentially non-irritating, or minimal effects which clear in <

24 hours [e.g. mechanical irritation]. Draize = “0”. Oral Toxicity LD

50

Rat: <

5000 mg/kg. Dermal Toxicity LD

50

Rat or Rabbit: < 2000 mg/kg. Inhalation

Toxicity 4-hrs LC

50

Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD

50

Rat: >

500-5000 mg/kg. Dermal Toxicity LD

50

Rat or Rabbit: > 1000-2000 mg/kg.

Inhalation Toxicity LC

50

4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard:

Temporary or transitory injury may occur. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation:

Moderately to severely irritating and/or corrosive; reversible corneal opacity; corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25.

Oral Toxicity LD

50

Rat: > 50-500 mg/kg. Dermal Toxicity LD

50

Rat or Rabbit:

> 200-1000 mg/kg. Inhalation Toxicity LC

50

4-hrs Rat: > 0.5-2 mg/L.);

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DEFINITIONS OF TERMS (Continued)

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD

RATINGS (continued):

HEALTH HAZARD (continued):

3 (Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given; high level of toxicity; corrosive. Skin Irritation:

Severely irritating and/or corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye

Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD

50

Rat: > 1-50 mg/kg.

Dermal Toxicity LD

50

Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity

LC

50

4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or permanent damage may result from single or repeated exposure.

Skin Irritation: Not appropriate. Do not rate as a “4”, based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a “4”, based on eye irritation alone. Oral Toxicity LD

50

Rat: < 1 mg/kg. Dermal Toxicity LD

50

Rat

or Rabbit: < 20 mg/kg. Inhalation Toxicity LC

50

4-hrs Rat: < 0.05 mg/L).

FLAMMABILITY HAZARD:

0 (Minimal Hazard-Materials that will not burn in air when exposure to a temperature of 815.5

°C [1500°F] for a period of 5 minutes.); 1 (Slight

Hazard-Materials that must be pre-heated before ignition can occur.

Material require considerable pre-heating, under all ambient temperature conditions before ignition and combustion can occur, Including: Materials that will burn in air when exposed to a temperature of 815.5

°C (1500°F) for a period of 5 minutes or less; Liquids, solids and semisolids having a flash point at or above 93.3

°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-

Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release vapor in sufficient quantities to produce hazardous atmospheres in air, Including:

Liquids having a flash-point at or above 37.8

°C [100°F]; Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp;

Solids and semisolids that readily give off flammable vapors.); 3 (Serious

Hazard- Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under almost all conditions, including: Liquids having a flash point below 22.8

°C [73°F] and having a boiling point at or above 38

°C [100°F] and below 37.8°C [100°F] [e.g. OSHA

Class IB and IC]; Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable liquids]; Materials that burn extremely rapidly, usually by reason of self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 (Severe Hazard-Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and which will burn readily, including:

Flammable gases; Flammable cryogenic materials; Any liquid or gaseous material that is liquid while under pressure and has a flash point below

22.8

°C [73°F] and a boiling point below 37.8°C [100°F] [e.g. OSHA Class IA;

Material that ignite spontaneously when exposed to air at a temperature of

54.4

°C [130°F] or below [e.g. pyrophoric]).

PHYSICAL HAZARD:

0 (Water Reactivity: Materials that do not react with water. Organic

Peroxides: Materials that are normally stable, even under fire conditions and will not react with water. Explosives: Substances that are Non-

Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No

Rating. Oxidizers: No “0” rating allowed. Unstable Reactives: Substances that will not polymerize, decompose, condense or self-react.); 1 (Water

Reactivity: Materials that change or decompose upon exposure to moisture.

Organic Peroxides: Materials that are normally stable, but can become unstable at high temperatures and pressures. These materials may react with water, but will not release energy. Explosives: Division 1.5 & 1.6 substances that are very insensitive explosives or that do not have a mass explosion hazard.

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM

HAZARD RATINGS (continued):

PHYSICAL HAZARD (continued):

1 (continued): Compressed Gases: Pressure below OSHA definition.

Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any material that in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid

(65%)/cellulose mixture and the criteria for Packing Group I and II are not met. Unstable Reactives: Substances that may decompose, condense or self-react, but only under conditions of high temperature and/or pressure and have little or no potential to cause significant heat generation or explosive hazard. Substances that readily undergo hazardous polymerization in the absence of inhibitors.); 2 (Water Reactivity:

Materials that may react violently with water. Organic Peroxides:

Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with water. Explosives: Division 1.4 – Explosive substances where the explosive effect are largely confined to the package and no projection of fragments of appreciable size or range are expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Compressed

Gases: Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1

°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing

Group II Solids: any material that, either in concentration tested, exhibits a mean burning time of less than or equal to the mean burning time of a

2:3 potassium bromate/cellulose mixture and the criteria for Packing

Group I are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing

Group I are not met. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure, but have a low potential for significant heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen at room temperature); 3 (Water Reactivity: Materials that may form explosive reactions with water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong initiating source, or must be heated under confinement before initiation; or materials that react explosively with water. Explosives: Division 1.2 –

Explosive substances that have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at

21.1

°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing

Group I Solids: any material that, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids: Any material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid

(50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a moderate potential to cause significant heat generation or explosion.); 4 (Water Reactivity: Materials that react explosively with water without requiring heat or confinement. Organic

Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures. Explosives:

Division 1.1 & 1.2-explosive substances that have a mass explosion hazard or have a projection hazard. A mass explosion is one that affects almost the entire load instantaneously. Compressed Gases: No Rating.

Pyrophorics: Add to the definition of Flammability “4”. Oxidizers: No “4” rating. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a high potential to cause significant heat generation or explosion.).

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DEFINITIONS OF TERMS (Continued)

NATIONAL FIRE PROTECTION ASSOCIATION HAZARD

RATINGS:

HEALTH HAZARD: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1

(materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury).

FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. 1 Materials that must be preheated before ignition can occur. Materials in this degree require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air. 3

Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and will burn readily.

INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions. 1 Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures. 2 Materials that readily undergo violent chemical change at elevated temperatures and pressures. 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation. 4

Materials that in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures.

FLAMMABILITY LIMITS IN AIR:

Much of the information related to fire and explosion is derived from the National Fire Protection Association

(NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition

Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.

TOXICOLOGICAL INFORMATION:

Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD

50

- Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC

50

- Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m

3

concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are:

IARC - the International Agency for Research on Cancer; NTP - the

National Toxicology Program, RTECS - the Registry of Toxic Effects of

Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other

Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV.

ECOLOGICAL INFORMATION:

EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter. TL

m

= median threshold limit; Coefficient of Oil/Water Distribution is represented by

log K

ow or log K

oc

and is used to assess a substance’s behavior in the environment.

REGULATORY INFORMATION:

U.S. and CANADA:

ACGIH: American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits.

This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration

(OSHA). WHMIS is the Canadian Workplace Hazardous Materials

Information System. DOT and TC are the U.S. Department of

Transportation and the Transport Canada, respectively. Superfund

Amendments and Reauthorization Act (SARA); the Canadian

Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic

Substance Control Act (TSCA); Marine Pollutant status according to the

DOT; the Comprehensive Environmental Response, Compensation, and

Liability Act (CERCLA or Superfund); and various state regulations.

This section also includes information on the precautionary warnings which appear on the material’s package label. OSHA - U.S.

Occupational Safety and Health Administration.

EUROPEAN and INTERNATIONAL:

The DFG: This is the Federal Republic of Germany’s Occupation Health

Agency, similar to the U.S. OSHA. EU is the European Union (formerly known as the EEC, European Economic Community). EINECS: This is the European Inventory of Now-Existing Chemical Substances. The ARD is the European Agreement Concerning the International Carriage of

Dangerous Goods by Road and the RID are the International Regulations

Concerning the Carriage of Dangerous Goods by Rail. AICS is the

Australian Inventory of Chemical Substances. MITI is the Japanese

Minister of International Trade and Industry

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