Safety Data Sheet 1. IDENTIFICATION

Safety Data Sheet 1. IDENTIFICATION
Sid Harvey item #'s 4135-06 & 4135-08
SDS # Z0355
Safety Data Sheet
Issue Date: 22-Oct-2013
Revision Date: 28-Oct-2013
Version 1
1. IDENTIFICATION
Product Identifier
Product Name
CalClean
Other means of identification
Part Number
4135-01, 4135-06, 4135-08.
Recommended use of the chemical and restrictions on use
Recommended Use
Coil cleaner/degreaser. For professional use only.
Details of the supplier of the safety data sheet
Supplier Address
Nu-Calgon
2008 Altom Court
St. Louis, MO 63146
www.nucalgon.com
Emergency Telephone Number
Company Phone Number
Emergency Telephone (24 hr)
(314) 469-7000
(800) 554-5499
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Appearance Clear opal liquid
Physical State Liquid
Odor Fresh
Classification
Skin corrosion/irritation
Serious eye damage/eye irritation
Category 2
Category 1
Signal Word
Danger
Hazard Statements
Causes skin irritation
Causes serious eye damage
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
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Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a poison center or doctor/physician
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash it before reuse
Unknown Acute Toxicity
5.6% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Sodium metasilicate
CAS No
6834-92-0
Weight-%
<5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES
First Aid Measures
Eye Contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison center or
doctor/physician.
Skin Contact
IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/ attention. Take off contaminated clothing and wash it before reuse.
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical attention if necessary.
Ingestion
IF SWALLOWED: rinse mouth. Get medical attention if necessary.
Most important symptoms and effects
Symptoms
Causes skin irritation. Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
None known.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See
Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Use personal
protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face,
hands, and any exposed skin thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep out of
the reach of children.
Incompatible Materials
Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Chemical Name
Sodium Tripolyphosphate
7758-29-4
Sodium metasilicate
6834-92-0
ACGIH TLV
3
15 mg/m
2 mg/m
3
OSHA PEL
3
15 mg/m
2 mg/m
3
NIOSH IDLH
-
Appropriate engineering controls
Engineering Controls
Apply technical measures to comply with the occupational exposure limits. Eyewash
stations. Showers.
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Wear approved safety goggles where a splash hazard exists.
Skin and Body Protection
Wear suitable protective clothing.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilation
wear respiratory protection.
General Hygiene Considerations Wash contaminated clothing before reuse. Wash face, hands and any exposed skin
thoroughly after handling.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State
Appearance
Color
Liquid
Clear opal liquid
Opal
Property
pH
Values
11.3 (1% in water)
13.0 (concentrate)
Not determined
100 °C / 212 °F
None to boiling
Equal to water
Liquid-not applicable
Not determined
Not determined
Not determined
Not determined
1.08
Soluble in water
Not determined
Not determined
Not determined
Not determined
Not determined
Water thin (<5 cps)
Not determined
Not determined
< 1%/wt
9.0 lb/gal
Melting Point/Freezing Point
Boiling Point/Boiling Range
Flash Point
Evaporation Rate
Flammability (Solid, Gas)
Upper Flammability Limits
Lower Flammability Limit
Vapor Pressure
Vapor Density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition Coefficient
Auto-ignition Temperature
Decomposition Temperature
Kinematic Viscosity
Dynamic Viscosity
Explosive Properties
Oxidizing Properties
VOC Content (%)
Density
Odor
Odor Threshold
Fresh
Not determined
Remarks • Method
IBP
Tag Closed Cup
10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to Avoid
Keep out of reach of children.
Incompatible Materials
Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners.
Hazardous Decomposition Products
None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye Contact
Causes serious eye damage.
Skin Contact
Causes skin irritation.
Inhalation
Avoid breathing vapors or mists.
Ingestion
Do not taste or swallow.
Component Information
Chemical Name
Water
7732-18-5
Sodium Tripolyphosphate
7758-29-4
Sodium metasilicate
6834-92-0
Oral LD50
> 90 mL/kg ( Rat )
Dermal LD50
-
Inhalation LC50
-
= 3100 mg/kg ( Rat )
> 7940 mg/kg ( Rabbit )
-
= 600 mg/kg ( Rat )
-
-
Information on physical, chemical and toxicological effects
Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity
This product does not contain any carcinogens or potential carcinogens as listed by OSHA,
IARC or NTP.
Numerical measures of toxicity
Not determined
Unknown Acute Toxicity
5.6% of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent
spills can have a harmful or damaging effect on the environment.
Component Information
Chemical Name
Sodium Tripolyphosphate
7758-29-4
Sodium metasilicate
6834-92-0
Algae/aquatic plants
Fish
1650: 48 h Leuciscus idus
mg/L LC50
210: 96 h Brachydanio rerio
mg/L LC50 semi-static 210:
96 h Brachydanio rerio mg/L
LC50
Toxicity to
microorganisms
Crustacea
216: 96 h Daphnia magna
mg/L EC50
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Persistence/Degradability
Not determined.
Bioaccumulation
Not determined.
Mobility
Not determined
Other Adverse Effects
Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
14. TRANSPORT INFORMATION
Note
Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION
International Inventories
Not determined
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
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US Federal Regulations
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355).
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name
Sodium Tripolyphosphate
7758-29-4
New Jersey
Massachusetts
X
Pennsylvania
X
16. OTHER INFORMATION
NFPA
HMIS
Issue Date:
Revision Date:
Revision Note:
Health Hazards
2
Health Hazards
2
Flammability
0
Flammability
0
Instability
0
Physical Hazards
0
Special Hazards
None
Personal Protection
X
22-Oct-2013
28-Oct-2013
New format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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MATERIAL SAFETY DATA SHEET
SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Company Name
Nu-Calgon Wholesaler, Inc.
Street Address
2008 Altom Court
Product Name
Calclean
Phone Number
CHEMTREC
(314) 469-7000 / (800) 554-5499
(800) 424-9300
City
State
Postal Code
St. Louis
MO
63146-4151
Product Number
Product Use
4135
Cleaner/Degreaser
Last Update
1/25/07
EPA Registration #
N/A
SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients
% By Wt.
CAS Number
TLV
PEL
Sodium Metasilicate
1-5%
6834-92-0
None Established
None Established
Nonionic Surfactant
1-5%
Proprietary
None Established
None Established
Sodium Tripolyphosphate
1-5%
7758-29-4
None Established
None Established
SECTION 3 – HAZARD IDENTIFICATION
Emergency Overview: Alkaline detergent. Do not get in eyes, on skin or clothing. Avoid breathing spray or mist. Use only with adequate personal
protection equipment.
Potential Health Effects
Eyes: Prolonged contact with eyes will cause severe irritation, possibly burns and permanent damage..
Skin: Prolonged or repeated contact with skin can cause moderate to severe irritation with pain; irritation may be delayed.
Ingestion: Harmful if swallowed - may cause burns of the mouth, throat and stomach if ingested.
Inhalation: Inhalation of generated mists or spray may cause respiratory irritation or chemical burn of mouth, throat, and stomach.
Chronic Exposure: None currently known.
Carcinogenicity: None
Medical Conditions Aggravated be Exposure: An existing dermatitis.
SECTION 4 – FIRST AID MEASURES
Eyes: .Flush eyes with water for at least 30 minutes and call a physician immediately. Speed of action is essential.
Skin: Remove contaminated clothing. Wash with large amounts of soap and water. If skin still feels slippery or if irritation persists, continue washing.
Consult a physician in the case of any prolonged irritation
Ingestion: Do not induce vomiting. Immediately give large quantities of water or (preferably) milk and call a physician. Speed of action is essential.
Inhalation: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician.
SECTION 5 – FIREFIGHTING MEASURES
Flash Point: None to Boiling °F
Autoignition Temp: N/A°C/N/A°F
Hazardous Products of Combustion: Burning may produce oxides of carbon and other substances.
Flammable Limits in Air: N/A
Extinguishing Media: Product is non-combustible. Water Spray (Fog), Dry Chemical; CO2; or Foam may be used where product is stored.
Fire and Explosion Hazards: None
Special Firefighting Procedures: Do not enter confined fire-spaces without protective clothing and self-contained air supply.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Spill or Leak: Before attempting clean up, refer to personal protection information. Do not touch or walk through spilled material. Stop leak if you can
without risk. Dike ahead of large spills to prevent run-off. Mop, pump or take up with sand or other inert absorbent and reclaim into containers for reuse,
recycle or proper disposal.
SECTION 7 – HANDLING AND STORAGE
Handling Procedures and Equipment: Avoid contact with corrosion sensitive metals, leather and wood. Do not get in eyes, on skin or clothing. Sprays
and generated mists can be irritating. Use only according to dilution instructions and with adequate protective clothing.
Storage Requirements: Keep container closed when not in use. Wash thoroughly after handling. D.O.T. Classification: Not Regulated
SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: Specific use conditions (spraying/confined spaces) may require local exhaust ventilation to prevent release of mist &/or vapors into
work environment. If ventilation in not adequate, use NIOSH/MSHA approved respirator with alkaline mist/gas cartridge & full face piece.
Eye Protection: Close fitting safety glasses/goggles/ face shield depending upon conditions of use.
Protective Clothing: Impervious protective clothing appropriate to minimize contact (ie: rubber boots, apron, faceshield) especially where
sprayback/misting conditions exist. Rubber protective gloves.
Exposure Guidelines: No ingredients have an established exposure limit (TLV). Eye wash station and safety shower in handling area.
Specific Engineering Controls (such as ventilation, enclosed process): Insure adequate ventilation to control any misting conditions. Eye wash station and
safety shower in handling area.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Liquid
Freezing Point: 0°C/32°F
% Volatile by Weight: ~87%
Color: Opal
Vapor Density [air =1]: Not Determined
Evaporation Rate: (vs. H2O):About the same.
Odor: Mild, Pleasant Odor
Vapor Pressure: Not Determinded
Specific Gravity: (H2O=1): 1.08 (+/-0.005)
Boiling Point: 100°C/212°F
Solubility in Water: Complete
pH (concentrate): 13.0 (=/-0.5)
SECTION 10 – STABILITY AND REACTIVITY
Chemical Stability: Stable
Hazardous Polymerization: None
Incompatibilities: Strong acids/oxidizers. Do not mix with chlorinated detergents (bleach).
Reactive Conditions to avoid: Do not mix with chlorinated detergents (bleach) or any other chemicals.
Decomposition Products: Burning may produce oxides of carbon and other substances.
SECTION 11 – TOXICOLOGICAL INFORMATION
LC50 of Ingredient
(Specify Species)
Not Determined
Sodium Tripolyphosphate
7758-29-4
231-838-7
LD 50 of Ingredient
(Specify Species)
3120 mg/kg (oral; Rat)
Nonionic Surfactant
Proprietary
No Data.
>5.0 g / kg (Oral ; Rat)
Not Determined
Sodium Metasilicate
6834-92-0
No Data.
1280 mg/kg (Oral; Rat)
Not Determined
Hazardous Ingredients
CAS #
EINECS #
SECTION 12 – ECOLOGICAL INFORMATION
Hazardous Ingredients
Aquatic Toxicity Data
Sodium Tripolyphosphate
EC50 (48 hr) = >1,000 mg/l (Daphnia Magna)
Nonionic Surfactant
Not Determined
Sodium Metasilicate
LC50 (96 hr) = 247 mg/l (Daphnia Magna)
SECTION 13 – DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose of in an approved waste facility according to Federal, State and local regulations.
SECTION 14 – TRANSPORTATION INFORMATION
Special Shipping Information: No Data.
Purview
DOT
(Land)
IMO
(Water)
ICAO
(Air)
Proper Shipping Name
UN Number
Packing Group
Hazard Class
Not Regulated
No Data.
No Data.
SECTION 15 – REGULATIORY INFORMATION
WHMIS Classification: (Workplace
Hazardous Material Information System)
SARA Title III: (Superfund Amendments &
Reauthorization Act)
OSHA: (Occupational Safety & Health
Administration)
TSCA: (Toxic Substance Control Act)
Class E - Corrosive Material
VOC: (volatile Organic Compounds)
Less than 1%
CPR: (Canadian Controlled Products
Regulations)
EINECS: (European Inventory of Existing
Commercial Chemical Substances)
DSL / NDSL: (Canadian Domestic Substance
List)(Non-Domestic Substance List)
CERCLA: (Comprehensive Response
Compensation & Liability Act)
IDL: (Canadian Ingredient Disclosure List)
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations.
No Data.
NFPA (HMIS) Rating: (Hazardous Materials
Identification System)
Contains no Section 313 listed substances subject to reporting requirement.
OSHA Hazardous - Acute hazard
All ingredients are TSCA registered.
All ingredients are listed on the Canadian DSL.
N/A
Sodium metasilicate is listed.
Health = 1
Flammability = 0
Reactivity = 0
SECTION 16 – OTHER INFORMATION
No Data.
The information contained herein is based on the data available to us and is believed to be correct. However, Nu-Calgon Wholesaler Inc. makes no warranty,
expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu-Calgon Wholesaler Inc. assumes no liability
for injury from the use of the product described herin.
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