Sid Harvey item #'s 4135-06 & 4135-08 SDS # Z0355 Safety Data Sheet Issue Date: 22-Oct-2013 Revision Date: 28-Oct-2013 Version 1 1. IDENTIFICATION Product Identifier Product Name CalClean Other means of identification Part Number 4135-01, 4135-06, 4135-08. Recommended use of the chemical and restrictions on use Recommended Use Coil cleaner/degreaser. For professional use only. Details of the supplier of the safety data sheet Supplier Address Nu-Calgon 2008 Altom Court St. Louis, MO 63146 www.nucalgon.com Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) (314) 469-7000 (800) 554-5499 Chemtrec 1-800-424-9300 2. HAZARDS IDENTIFICATION Appearance Clear opal liquid Physical State Liquid Odor Fresh Classification Skin corrosion/irritation Serious eye damage/eye irritation Category 2 Category 1 Signal Word Danger Hazard Statements Causes skin irritation Causes serious eye damage Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection _____________________________________________________________________________________________ Page 1 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash it before reuse Unknown Acute Toxicity 5.6% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium metasilicate CAS No 6834-92-0 Weight-% <5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if necessary. Ingestion IF SWALLOWED: rinse mouth. Get medical attention if necessary. Most important symptoms and effects Symptoms Causes skin irritation. Causes serious eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical None known. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ Page 2 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face, hands, and any exposed skin thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep out of the reach of children. Incompatible Materials Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Sodium Tripolyphosphate 7758-29-4 Sodium metasilicate 6834-92-0 ACGIH TLV 3 15 mg/m 2 mg/m 3 OSHA PEL 3 15 mg/m 2 mg/m 3 NIOSH IDLH - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Wear approved safety goggles where a splash hazard exists. Skin and Body Protection Wear suitable protective clothing. Respiratory Protection Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilation wear respiratory protection. General Hygiene Considerations Wash contaminated clothing before reuse. Wash face, hands and any exposed skin thoroughly after handling. _____________________________________________________________________________________________ Page 3 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color Liquid Clear opal liquid Opal Property pH Values 11.3 (1% in water) 13.0 (concentrate) Not determined 100 °C / 212 °F None to boiling Equal to water Liquid-not applicable Not determined Not determined Not determined Not determined 1.08 Soluble in water Not determined Not determined Not determined Not determined Not determined Water thin (<5 cps) Not determined Not determined < 1%/wt 9.0 lb/gal Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties VOC Content (%) Density Odor Odor Threshold Fresh Not determined Remarks • Method IBP Tag Closed Cup 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep out of reach of children. Incompatible Materials Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners. Hazardous Decomposition Products None known based on information supplied. _____________________________________________________________________________________________ Page 4 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye damage. Skin Contact Causes skin irritation. Inhalation Avoid breathing vapors or mists. Ingestion Do not taste or swallow. Component Information Chemical Name Water 7732-18-5 Sodium Tripolyphosphate 7758-29-4 Sodium metasilicate 6834-92-0 Oral LD50 > 90 mL/kg ( Rat ) Dermal LD50 - Inhalation LC50 - = 3100 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) - = 600 mg/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined Unknown Acute Toxicity 5.6% of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Sodium Tripolyphosphate 7758-29-4 Sodium metasilicate 6834-92-0 Algae/aquatic plants Fish 1650: 48 h Leuciscus idus mg/L LC50 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 Toxicity to microorganisms Crustacea 216: 96 h Daphnia magna mg/L EC50 _____________________________________________________________________________________________ Page 5 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances _____________________________________________________________________________________________ Page 6 / 7 NUC-1630 - Revision Date: 28-Oct-2013 CalClean _____________________________________________________________________________________________ US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Sodium Tripolyphosphate 7758-29-4 New Jersey Massachusetts X Pennsylvania X 16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note: Health Hazards 2 Health Hazards 2 Flammability 0 Flammability 0 Instability 0 Physical Hazards 0 Special Hazards None Personal Protection X 22-Oct-2013 28-Oct-2013 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 7 / 7 MATERIAL SAFETY DATA SHEET SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Company Name Nu-Calgon Wholesaler, Inc. Street Address 2008 Altom Court Product Name Calclean Phone Number CHEMTREC (314) 469-7000 / (800) 554-5499 (800) 424-9300 City State Postal Code St. Louis MO 63146-4151 Product Number Product Use 4135 Cleaner/Degreaser Last Update 1/25/07 EPA Registration # N/A SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % By Wt. CAS Number TLV PEL Sodium Metasilicate 1-5% 6834-92-0 None Established None Established Nonionic Surfactant 1-5% Proprietary None Established None Established Sodium Tripolyphosphate 1-5% 7758-29-4 None Established None Established SECTION 3 – HAZARD IDENTIFICATION Emergency Overview: Alkaline detergent. Do not get in eyes, on skin or clothing. Avoid breathing spray or mist. Use only with adequate personal protection equipment. Potential Health Effects Eyes: Prolonged contact with eyes will cause severe irritation, possibly burns and permanent damage.. Skin: Prolonged or repeated contact with skin can cause moderate to severe irritation with pain; irritation may be delayed. Ingestion: Harmful if swallowed - may cause burns of the mouth, throat and stomach if ingested. Inhalation: Inhalation of generated mists or spray may cause respiratory irritation or chemical burn of mouth, throat, and stomach. Chronic Exposure: None currently known. Carcinogenicity: None Medical Conditions Aggravated be Exposure: An existing dermatitis. SECTION 4 – FIRST AID MEASURES Eyes: .Flush eyes with water for at least 30 minutes and call a physician immediately. Speed of action is essential. Skin: Remove contaminated clothing. Wash with large amounts of soap and water. If skin still feels slippery or if irritation persists, continue washing. Consult a physician in the case of any prolonged irritation Ingestion: Do not induce vomiting. Immediately give large quantities of water or (preferably) milk and call a physician. Speed of action is essential. Inhalation: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. SECTION 5 – FIREFIGHTING MEASURES Flash Point: None to Boiling °F Autoignition Temp: N/A°C/N/A°F Hazardous Products of Combustion: Burning may produce oxides of carbon and other substances. Flammable Limits in Air: N/A Extinguishing Media: Product is non-combustible. Water Spray (Fog), Dry Chemical; CO2; or Foam may be used where product is stored. Fire and Explosion Hazards: None Special Firefighting Procedures: Do not enter confined fire-spaces without protective clothing and self-contained air supply. SECTION 6 – ACCIDENTAL RELEASE MEASURES Spill or Leak: Before attempting clean up, refer to personal protection information. Do not touch or walk through spilled material. Stop leak if you can without risk. Dike ahead of large spills to prevent run-off. Mop, pump or take up with sand or other inert absorbent and reclaim into containers for reuse, recycle or proper disposal. SECTION 7 – HANDLING AND STORAGE Handling Procedures and Equipment: Avoid contact with corrosion sensitive metals, leather and wood. Do not get in eyes, on skin or clothing. Sprays and generated mists can be irritating. Use only according to dilution instructions and with adequate protective clothing. Storage Requirements: Keep container closed when not in use. Wash thoroughly after handling. D.O.T. Classification: Not Regulated SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection: Specific use conditions (spraying/confined spaces) may require local exhaust ventilation to prevent release of mist &/or vapors into work environment. If ventilation in not adequate, use NIOSH/MSHA approved respirator with alkaline mist/gas cartridge & full face piece. Eye Protection: Close fitting safety glasses/goggles/ face shield depending upon conditions of use. Protective Clothing: Impervious protective clothing appropriate to minimize contact (ie: rubber boots, apron, faceshield) especially where sprayback/misting conditions exist. Rubber protective gloves. Exposure Guidelines: No ingredients have an established exposure limit (TLV). Eye wash station and safety shower in handling area. Specific Engineering Controls (such as ventilation, enclosed process): Insure adequate ventilation to control any misting conditions. Eye wash station and safety shower in handling area. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Liquid Freezing Point: 0°C/32°F % Volatile by Weight: ~87% Color: Opal Vapor Density [air =1]: Not Determined Evaporation Rate: (vs. H2O):About the same. Odor: Mild, Pleasant Odor Vapor Pressure: Not Determinded Specific Gravity: (H2O=1): 1.08 (+/-0.005) Boiling Point: 100°C/212°F Solubility in Water: Complete pH (concentrate): 13.0 (=/-0.5) SECTION 10 – STABILITY AND REACTIVITY Chemical Stability: Stable Hazardous Polymerization: None Incompatibilities: Strong acids/oxidizers. Do not mix with chlorinated detergents (bleach). Reactive Conditions to avoid: Do not mix with chlorinated detergents (bleach) or any other chemicals. Decomposition Products: Burning may produce oxides of carbon and other substances. SECTION 11 – TOXICOLOGICAL INFORMATION LC50 of Ingredient (Specify Species) Not Determined Sodium Tripolyphosphate 7758-29-4 231-838-7 LD 50 of Ingredient (Specify Species) 3120 mg/kg (oral; Rat) Nonionic Surfactant Proprietary No Data. >5.0 g / kg (Oral ; Rat) Not Determined Sodium Metasilicate 6834-92-0 No Data. 1280 mg/kg (Oral; Rat) Not Determined Hazardous Ingredients CAS # EINECS # SECTION 12 – ECOLOGICAL INFORMATION Hazardous Ingredients Aquatic Toxicity Data Sodium Tripolyphosphate EC50 (48 hr) = >1,000 mg/l (Daphnia Magna) Nonionic Surfactant Not Determined Sodium Metasilicate LC50 (96 hr) = 247 mg/l (Daphnia Magna) SECTION 13 – DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in an approved waste facility according to Federal, State and local regulations. SECTION 14 – TRANSPORTATION INFORMATION Special Shipping Information: No Data. Purview DOT (Land) IMO (Water) ICAO (Air) Proper Shipping Name UN Number Packing Group Hazard Class Not Regulated No Data. No Data. SECTION 15 – REGULATIORY INFORMATION WHMIS Classification: (Workplace Hazardous Material Information System) SARA Title III: (Superfund Amendments & Reauthorization Act) OSHA: (Occupational Safety & Health Administration) TSCA: (Toxic Substance Control Act) Class E - Corrosive Material VOC: (volatile Organic Compounds) Less than 1% CPR: (Canadian Controlled Products Regulations) EINECS: (European Inventory of Existing Commercial Chemical Substances) DSL / NDSL: (Canadian Domestic Substance List)(Non-Domestic Substance List) CERCLA: (Comprehensive Response Compensation & Liability Act) IDL: (Canadian Ingredient Disclosure List) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. No Data. NFPA (HMIS) Rating: (Hazardous Materials Identification System) Contains no Section 313 listed substances subject to reporting requirement. OSHA Hazardous - Acute hazard All ingredients are TSCA registered. All ingredients are listed on the Canadian DSL. N/A Sodium metasilicate is listed. Health = 1 Flammability = 0 Reactivity = 0 SECTION 16 – OTHER INFORMATION No Data. The information contained herein is based on the data available to us and is believed to be correct. However, Nu-Calgon Wholesaler Inc. makes no warranty, expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu-Calgon Wholesaler Inc. assumes no liability for injury from the use of the product described herin.
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