Safety Data Sheet Dow Chemical Company Ltd

Safety Data Sheet Dow Chemical Company Ltd
Safety Data Sheet
Dow Chemical Company Ltd
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2010/10/22
Print Date: 24 Oct 2010
Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1.
Identification of the substance/preparation and of the company/undertaking
Product Name
GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Use of the substance/preparation
Cavity sealing foam.
COMPANY IDENTIFICATION
Dow Chemical Company Ltd
Diamond House, Lotus Park
Kingsbury Crescent
TW18 3AG Staines, Middlesex
United Kingdom
Customer Information Number:
0203 139 4000
For questions about this SDS, contact: [email protected]
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact:
Local Emergency Contact:
2.
+44 (0) 1553 761 251
00 44 155 37 61 251
Hazards Identification
Limited evidence of a carcinogenic effect.
Extremely flammable.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Irritating to eyes, respiratory system and skin.
May cause sensitization by inhalation and skin contact.
May cause slight temporary corneal injury. May stain skin. Material may stick to skin causing irritation
upon removal. Excessive exposure may cause irritation to upper respiratory tract (nose and throat)
and lungs. May cause pulmonary edema (fluid in the lungs.) Asthma-like symptoms may include
coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties
may be life threatening.
3.
Composition/information on ingredients
®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow
Page 1 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Component
Prepolymer of MDI and
polyol##
Diphenylmethane-4,4'-diisocyanate
Amount
Classification:
40.0 - 60.0 %
Not classified.
10.0 - 20.0 %
Carc.Cat.3: R40; Xn:
R20, R48/20; Xi:
R36/37/38; R42/43
Xn: R42
Revision Date: 2010/10/22
CAS #
Confidential
101-68-8
10.0 - 20.0 %
Methylenediphenyl
39310-05-9
diisocyanate,
homopolymer
Dimethyl ether
2.0 - 6.0 %
F+: R12
115-10-6
Isobutane
2.0 - 6.0 %
F+: R12
75-28-5
Propane
3.0 - 6.0 %
F+: R12
74-98-6
## Voluntarily disclosed component(s).
See Section 16 for full text of R-phrases.
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9 and of CAS 26447-40-5.
4.
EC #
Polymer
202-966-0
NLP
204-065-8
200-857-2
200-827-9
First-aid measures
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives
may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
Emergency Personnel Protection: First Aid responders should pay attention to self-protection and
use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
5.
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. Straight or direct water streams may not be
effective to extinguish fire. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Page 2 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2010/10/22
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in
extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location
or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition
sources. Move container from fire area if this is possible without hazard. Use water spray to cool fireexposed containers and fire-affected zone until fire is out.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire
from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to
the relevant sections.
Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire
can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are
heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash
back may occur. Dense smoke is produced when product burns.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride.
Carbon monoxide. Carbon dioxide. Hydrogen cyanide.
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Spills should be contained by, and covered
with large quantities of sand, earth or any other readily available absorbent material which is then
brushed in vigorously to assist absorption. The mixture can then be collected into drums and removed
for disposal. Wash area from residues with soap and water and rinse down.
Personal Precautions: Only trained and properly protected personnel must be involved in clean-up
operations. Keep unnecessary and unprotected personnel from entering the area. If available, use
foam to suppress vapors. Use appropriate safety equipment. For additional information, refer to
Section 8, Exposure Controls and Personal Protection. See Section 10 for more specific information.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information. Should the product enter sewers or drains, it
should be pumped into a covered, vented container; the cover should be placed loosely on the
container but not made pressure tight. Emergency services may need to be called to assist in the
cleanup operation.
7.
Handling and Storage
Handling
General Handling: Keep away from heat, sparks and flame. Use only with adequate ventilation.
Storage
Keep in a cool, well-ventilated place. Keep away from sources of ignition. See Section 10 for more
specific information.
Storage Period:
Storage temperature:
18 Months
15 - 25 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
Component
List
Type
Value
|
Page 3 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Diphenylmethane-4,4'-diisocyanate
Revision Date: 2010/10/22
ACGIH
TWA
0.005 ppm
UK WEL
TWA as
NCO
STEL as
NCO
TWA as
NCO
STEL as
NCO
0.02 mg/m3 SEN
Ireland OELV
TWA
AIHA WEEL
EU IOELV
UK WEL
UK WEL
TWA
TWA
TWA
STEL
1,920 mg/m3 1,000 ppm
Indicative OELV
1,880 mg/m3 1,000 ppm
1,920 mg/m3 1,000 ppm
766 mg/m3 400 ppm
958 mg/m3 500 ppm
Isobutane
ACGIH
TWA
1,000 ppm
Propane
ACGIH
UK WEL
TWA
Asphyxiant
1,000 ppm
UK WEL
Ireland OELV
Ireland OELV
0.07 mg/m3 SEN
0.02 mg/m3 SEN
0.07 mg/m3 SEN
|
Dimethyl ether
|
|
Included in the regulation but with no
data values. See regulation for
further details
A "SEN" notation following the exposure guideline refers to the potential to produce sensitization, as
confirmed by human or animal data.
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or
equivalent.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective
gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials
include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Examples of acceptable glove barrier materials include: Neoprene.
Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Avoid gloves made of: Polyvinyl chloride
("PVC" or "vinyl"). When prolonged or frequently repeated contact may occur, a glove with a
protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN
374) is recommended. When only brief contact is expected, a glove with a protection class of
3 or higher (breakthrough time greater than 60 minutes according to EN 374) is
recommended. NOTICE: The selection of a specific glove for a particular application and
duration of use in a workplace should also take into account all relevant workplace factors
such as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to glove
materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator
equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric
levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure
air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or
for situations where the atmospheric level is unknown, use an approved positive-pressure selfcontained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. In
confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive
pressure air line with auxiliary self-contained air supply. Use the following CE approved air-purifying
respirator: Organic vapor cartridge with a particulate pre-filter, type AP2.
Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in
the work area; wash hands and face before smoking or eating.
Page 4 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2010/10/22
Engineering Controls
Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some
operations. Provide general and/or local exhaust ventilation to control airborne levels below the
exposure guidelines. Exhaust systems should be designed to move the air away from the source of
vapor/aerosol generation and people working at this point. The odor and irritancy of this material are
inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor
ventilation.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Flash Point - Closed Cup
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in water (by
weight)
pH
Decomposition
Temperature
Partition coefficient, noctanol/water (log Pow)
Kinematic Viscosity
10.
Foam
Yellow
Mild
No test data available
Lower: No test data available
Upper: No test data available
No test data available
No test data available
No test data available.
No test data available
No test data available
No test data available
No test data available
reacts with water
Not applicable
No test data available
No data available for this product. See Section 12 for individual
component data.
No test data available
Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated
temperatures.
Conditions to Avoid: Avoid temperatures above 50 °C. Elevated temperatures can cause container
to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose.
Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal
compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many
materials to release heat. The reaction rate increases with temperature as well as with increased
contact; these reactions can become violent. Contact is increased by stirring or if the other material
acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and
will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a
layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.
Hazardous Polymerization
Can occur. Elevated temperatures can cause hazardous polymerization.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Toxic gases are released during decomposition.
Page 5 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
11.
Revision Date: 2010/10/22
Toxicological Information
Acute Toxicity
Ingestion
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling
operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
Observations in animals include: Gastrointestinal irritation.
As product: Single dose oral LD50 has not been determined.
Based on information for component(s): Estimated. LD50, Rat > 10,000 mg/kg
Aspiration hazard
Based on physical properties, not likely to be an aspiration hazard.
Dermal
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
Based on information for component(s): Estimated. LD50, Rabbit > 2,000 mg/kg
Inhalation
In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness
and death due to displacement of oxygen. Excessive exposure may cause irritation to upper
respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.)
Effects may be delayed. May cause central nervous system depression. Symptoms of excessive
exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed.
Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability
(irregular heartbeats). Decreased lung function has been associated with overexposure to
isocyanates.
As product: The LC50 has not been determined.
Eye damage/eye irritation
May cause eye irritation. May cause slight temporary corneal injury.
Skin corrosion/irritation
Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin
causing irritation upon removal. May stain skin.
Sensitization
Skin
Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with
isocyanates may play a role in respiratory sensitization.
Respiratory
May cause allergic respiratory response. MDI concentrations below the exposure guidelines may
cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may
include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing
difficulties may be life threatening.
Repeated Dose Toxicity
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols. For the minor component(s): In
animals, effects have been reported on the following organs: Kidney.
Chronic Toxicity and Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Developmental Toxicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother.
Reproductive Toxicity
No relevant information found.
Genetic Toxicology
For the minor component(s): In vitro genetic toxicity studies were negative. Genetic toxicity data on
MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were
negative. Animal mutagenicity studies were predominantly negative.
Page 6 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
12.
Revision Date: 2010/10/22
Ecological Information
ENVIRONMENTAL FATE
Data for Component: Prepolymer of MDI and polyol
Movement & Partitioning
No bioconcentration is expected because of the relatively high molecular weight (MW greater
than 1000).
Persistence and Degradability
Expected to degrade only slowly in the environment.
Data for Component: Diphenylmethane-4,4'-di-isocyanate
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: Methylenediphenyl diisocyanate, homopolymer
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: Dimethyl ether
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 9.78E-04 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 0.10 Measured
Partition coefficient, soil organic carbon/water (Koc): 1.29 - 14 Estimated.
Persistence and Degradability
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
10 Day Window
5%
28 d
OECD 301A Test
fail
Data for Component: Isobutane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 1.19E+00 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 2.76 Measured
Partition coefficient, soil organic carbon/water (Koc): 35 Estimated.
Persistence and Degradability
Biodegradation may occur under aerobic conditions (in the presence of oxygen).
Page 7 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2010/10/22
Data for Component: Propane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 7.07E-01 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 2.36 Measured
Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated.
Persistence and Degradability
No relevant information found.
ECOTOXICITY
Data for Component: Prepolymer of MDI and polyol
Material is not classified as dangerous to aquatic organisms.
Data for Component: Diphenylmethane-4,4'-di-isocyanate
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is not classified as dangerous to aquatic
organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/L in most sensitive species).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: Methylenediphenyl diisocyanate, homopolymer
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is not classified as dangerous to aquatic
organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/L in most sensitive species).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: Dimethyl ether
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50
greater than 100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, guppy (Poecilia reticulata), static renewal, 96 h: > 4,000 mg/l
Aquatic Invertebrate Acute Toxicity
LC50, water flea Daphnia magna, 48 h, immobilization: > 4,000 mg/l
Data for Component: Isobutane
Material is not classified as dangerous to aquatic organisms.
Data for Component: Propane
No relevant information found.
13.
Disposal Considerations
Contents under pressure. Do not puncture or incinerate container. Relieve all pressure prior to
disposal. Do not dump into any sewers, on the ground, or into any body of water. Any disposal
practice must be in compliance with all local and national laws and regulations. The generation of
waste should be avoided or minimized wherever possible. Refer to manufacturer/supplier for
information on recovery/recycling.
Page 8 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
14.
Revision Date: 2010/10/22
Transport Information
ROAD & RAIL
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
Environmental Hazard: No
OCEAN
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
EMS Number: F-D,S-U
Marine pollutant.: No
AIR
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203
Passenger Packing Instruction: 203
Environmental Hazard: No
INLAND WATERWAYS
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
Environmental Hazard: No
15.
Regulatory Information
European Inventory of Existing Commercial Chemical Substances (EINECS)
The components of this product are on the EINECS inventory or are exempt from inventory
requirements.
EC Classification and User Label Information
Hazard Symbol:
- Extremely flammable.
F+
- Harmful.
Xn
Risk Phrases :
R40 - Limited evidence of a carcinogenic effect.
R12 - Extremely flammable.
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R42/43 - May cause sensitization by inhalation and skin contact.
Safety Phrases :
S1/2 - Keep locked up out of reach of children.
S16 - Keep away from sources of ignition - no smoking.
S23 - Do not breathe spray.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Page 9 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Contains:
Revision Date: 2010/10/22
Diphenylmethane-4,4'-di-isocyanate
Methylenediphenyl diisocyanate, homopolymer
Contains isocyanates. See information supplied by the manufacturer.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 ºC.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
- Other regulations
Persons already sensitised to diisocyanates may develop allergic reactions when using this product.
Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal
contact, with this product.
This product should not be used under conditions of poor ventilation unless a protective mask with an
appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
16.
Other Information
Risk-phrases in the Composition section
R12
R20
R36/37/38
R40
R42
R42/43
R48/20
Extremely flammable.
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
Limited evidence of a carcinogenic effect.
May cause sensitization by inhalation.
May cause sensitization by inhalation and skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Revision
Identification Number: 1001245 / 3005 / Issue Date 2010/10/22 / Version: 4.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
Page 10 of 10
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