SAFETY DATA SHEET 1. Identification

SAFETY DATA SHEET 1. Identification
SAFETY DATA SHEET
1. Identification
Product identifier
Bloom and Root Plant Food 10-52-8
Other means of identification
Product code
31003
Recommended use
Agricultural /horticulture use - NPK fertilizer with micronutrients - refer to product label
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name
Address
Telephone
Website
E-mail
Emergency phone number
Lawn and Garden Products, Inc.
PO Box 35000
Fresno, CA 93745
Emergency Contact Number
1-559-994-9144
www.montereylawngarden.com
[email protected]
CHEMTREC (24 hours):
USA, Canada, Puerto Rico
1-800-424-3900
2. Hazard(s) identification
Physical hazards
Not classified.
Health hazards
Acute toxicity, oral
Environmental hazards
Not classified.
OSHA defined hazards
Not classified.
Category 4
Label elements
Signal word
Warning
Hazard statement
Harmful if swallowed.
Precautionary statement
Prevention
Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Response
If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth.
Storage
Store away from incompatible materials.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
96.53% of the mixture consists of component(s) of unknown acute oral toxicity.
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number
%
Potassium Nitrate
7757-79-1
3.3599664003
Manganese EDTA, disodium salt
15375-84-5
0.3859161408
EDTA, Disodium Copper(II) Salt
14025-15-1
0.3571164288
Sodium tetraborate pentahydrate
12179-04-3
0.099999
Sodium Molybdate, Dihydrate
10102-40-6
0.00099999
Other components below reportable levels
Material name: Bloom and Root Plant Food
715 Version #: 01 Issue date: 06-16-2015
Common name and synonyms
95.7960020397
SDS US
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*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Skin contact
If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a
physician if symptoms develop or persist.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Rinse with water. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
Direct contact with eyes may cause temporary irritation.
Inhalation
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.
5. Fire-fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
Use water spray to cool unopened containers.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at
levels exceeding the exposure limits. Wear appropriate protective equipment and clothing during
clean-up. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Avoid inhalation of dust from the spilled material. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Stop the flow of material, if this is without risk. Dike far ahead of spill for later disposal. If sweeping
of a contaminated area is necessary use a dust suppressant agent which does not react with the
product. Collect dust using a vacuum cleaner equipped with HEPA filter. Following product
recovery, flush area with water. Sweep up or vacuum up spillage and collect in suitable container
for disposal. Minimize dust generation and accumulation. Prevent entry into waterways, sewer,
basements or confined areas. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Minimize dust generation and accumulation. Provide appropriate exhaust ventilation at places
where dust is formed. Do not taste or swallow. Avoid breathing dust. Avoid contact with eyes.
Avoid prolonged exposure. Wear appropriate personal protective equipment. When using, do not
eat, drink or smoke. Wash hands thoroughly after handling. Observe good industrial hygiene
practices. Practice good housekeeping.
Store in original tightly closed container. Keep container tightly closed. Store in a well-ventilated
place. Store away from incompatible materials (see Section 10 of the SDS).
Material name: Bloom and Root Plant Food
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Manganese EDTA,
disodium salt (CAS
15375-84-5)
Sodium Molybdate,
Dihydrate (CAS
10102-40-6)
US. ACGIH Threshold Limit Values
Components
Sodium Molybdate,
Dihydrate (CAS
10102-40-6)
Sodium tetraborate
pentahydrate (CAS
12179-04-3)
Ceiling
5 mg/m3
PEL
5 mg/m3
Type
Value
Form
TWA
0.5 mg/m3
Respirable fraction.
STEL
6 mg/m3
Inhalable fraction.
TWA
2 mg/m3
Inhalable fraction.
Value
Form
TWA
1 mg/m3
Dust and mist.
STEL
3 mg/m3
Fume.
TWA
TWA
1 mg/m3
1 mg/m3
Fume.
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
EDTA, Disodium Copper(II)
Salt (CAS 14025-15-1)
Manganese EDTA,
disodium salt (CAS
15375-84-5)
Sodium tetraborate
pentahydrate (CAS
12179-04-3)
Value
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes
that may be generated during handling or thermal processing. If engineering measures are not
sufficient to maintain concentrations of dust particulates below the Occupational Exposure Limit
(OEL), suitable respiratory protection must be worn.
Individual protection measures, such as personal protective equipment
Face shield is recommended. Wear safety glasses with side shields (or goggles). Use tight fitting
Eye/face protection
goggles if dust is generated.
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear appropriate chemical resistant gloves.
Wear suitable protective clothing.
Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits. Respiratory protection not required.
Wear appropriate thermal protective clothing, when necessary.
Keep away from food and drink. Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Powder. Solid.
Physical state
Solid.
Form
Powder. Solid.
Color
Light blue
Odor
None.
Odor threshold
Not available.
pH
Not available.
Salt-Out / Crystallization Temp
Not available.
Material name: Bloom and Root Plant Food
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Melting point/freezing point
Not available.
Initial boiling point and boiling
range
Not available.
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Not available.
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Not available.
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Soluble
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid
Contact with incompatible materials. Avoid dispersal of dust in the air (i.e., clearing dust surfaces
with compressed air).
Strong oxidizing agents.
Incompatible materials
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Harmful if swallowed.
Ingestion
Inhalation
Prolonged inhalation may be harmful. Inhalation of dusts may cause respiratory irritation.
Skin contact
No adverse effects due to skin contact are expected.
Eye contact
Dust in the eyes will cause irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity
Product
Harmful if swallowed. Not known.
Species
Test Results
Bloom and Root Plant Food (CAS Mixture)
Acute
Inhalation
LD50
Rat
Material name: Bloom and Root Plant Food
715 Version #: 01 Issue date: 06-16-2015
2000.001 mg/l estimated
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Components
Species
Test Results
Rabbit
1166 mg/kg
Potassium Nitrate (CAS 7757-79-1)
Acute
Oral
LD50
Sodium tetraborate pentahydrate (CAS 12179-04-3)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg
Inhalation
LD50
Rat
> 2 mg/l
Oral
LD50
Rat
2660 mg/kg
* Estimates for product may be based on additional component data not shown.
Prolonged skin contact may cause temporary irritation.
Skin corrosion/irritation
Dust in the eyes will cause irritation.
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Not available.
Respiratory sensitization
This product is not expected to cause skin sensitization.
Skin sensitization
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is not expected to cause reproductive or developmental effects.
Reproductive toxicity
Specific target organ toxicity single exposure
Not classified.
Specific target organ toxicity repeated exposure
Not classified.
Aspiration hazard
Not available.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product
Species
Test Results
Fish
25913.4492 mg/l, 96 hr estimated
Species
Test Results
Bloom and Root Plant Food (CAS Mixture)
Aquatic
Acute
Fish
LC50
Components
EDTA, Disodium Copper(II) Salt (CAS 14025-15-1)
Aquatic
Fish
LC50
Channel catfish (Ictalurus punctatus)
838 mg/l, 96 hours
Fish
1378 - 3000 mg/l
Potassium Nitrate (CAS 7757-79-1)
Aquatic
Acute
Fish
LC50
Sodium Molybdate, Dihydrate (CAS 10102-40-6)
Aquatic
Crustacea
EC50
Material name: Bloom and Root Plant Food
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Tubificid worm (Tubifex tubifex)
42.48 - 65.64 mg/l, 48 hours
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Components
Fish
LC50
Species
Test Results
Striped bass (Morone saxatilis)
> 79.8 mg/l, 96 hours
Sodium tetraborate pentahydrate (CAS 12179-04-3)
Aquatic
Fish
LC50
Western mosquitofish (Gambusia affinis) 104 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
No data is available on the degradability of this product.
Persistence and degradability
Bioaccumulative potential
Not available.
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
One or more components are not listed on TSCA.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
EDTA, Disodium Copper(II) Salt (CAS 14025-15-1)
Listed.
Manganese EDTA, disodium salt (CAS 15375-84-5)
Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
Material name: Bloom and Root Plant Food
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SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Chemical name
Monoammonium Phosphate (MAP)
Potassium Nitrate
CAS number
% by wt.
7722-76-1
7757-79-1
79.5892041079
3.3599664003
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Manganese EDTA, disodium salt (CAS 15375-84-5)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Potassium Nitrate (CAS 7757-79-1)
Sodium tetraborate pentahydrate (CAS 12179-04-3)
US. New Jersey Worker and Community Right-to-Know Act
EDTA, Disodium Copper(II) Salt (CAS 14025-15-1)
Manganese EDTA, disodium salt (CAS 15375-84-5)
Potassium Nitrate (CAS 7757-79-1)
Sodium tetraborate pentahydrate (CAS 12179-04-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Potassium Nitrate (CAS 7757-79-1)
Sodium tetraborate pentahydrate (CAS 12179-04-3)
US. Rhode Island RTK
EDTA, Disodium Copper(II) Salt (CAS 14025-15-1)
Manganese EDTA, disodium salt (CAS 15375-84-5)
Potassium Nitrate (CAS 7757-79-1)
US. California Proposition 65
ATTENTION: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.
International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
On inventory (yes/no)*
No
Canada
Domestic Substances List (DSL)
No
Canada
Non-Domestic Substances List (NDSL)
No
China
Inventory of Existing Chemical Substances in China (IECSC)
No
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
No
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
No
Korea
Existing Chemicals List (ECL)
No
New Zealand
New Zealand Inventory
No
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
No
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
06-16-2015
Version #
01
Material name: Bloom and Root Plant Food
715 Version #: 01 Issue date: 06-16-2015
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Disclaimer
Revision Information
Brandt Consolidated, Inc. cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. While the
information contained herein are presented in good faith and believed to be accurate, it is provided
for your guidance only. Because many factors may affect processing or application, we
recommend that you make tests to determine the suitability of a product for your particular purpose
prior to use. No warranties of any kind, either expressed or implied, including warranties of
merchantability or fitness for a particular purpose, are made regarding products described or
information set forth, or that the products, or information may be used without infringing the
intellectual property rights of others. In no case shall the information provided be considered a
part of our terms and conditions of sale. Further, you expressly understand and agree that the
information furnished by our company hereunder are given gratis and we assume no obligation or
liability for the information given or results obtained, all such being given and accepted at your risk.
Product and Company Identification: Alternate Trade Names
GHS: Classification
Material name: Bloom and Root Plant Food
715 Version #: 01 Issue date: 06-16-2015
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