Safety Data Sheet 1/12

Safety Data Sheet 1/12

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

1/12

1. Identification of the substance/mixture and of the company/undertaking

Product name: Indicator Stop Bath

Product code: 5160346

Synonyms: PCD 2838

Relevant identified uses of the substance or mixture and uses advised against:

Identified uses: photographic processing chemical. For consumer and industrial use.

Supplier: Kodak Alaris Inc., 2400 Mount Read Boulevard, Rochester, NY 14615

IN EMERGENCY, telephone: 1-800-424-9300 or +1 703-527-3887.

For further information about this product, email [email protected]

2. Hazards identification

Classification of the chemical in accordance with paragraph (d) of 29 CFR 1910.1200:

Hazard class Hazard category Route of exposure

Flammable liquids

Corrosive to metals

Acute toxicity

Acute toxicity

Skin corrosion

Serious eye damage

Respiratory sensitisation

GHS-Labelling

Contains:

Acetic acid (64-19-7)

Symbol(s):

Category 3

Category 1

Category 4

Category 4

Category 1

Category 1

Category 1

--

--

Inhalation

Dermal

--

--

--

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

2/12

Safety Data Sheet

Signal word: Danger

Hazard statements:

Flammable liquid and vapour. May be corrosive to metals. Harmful if inhaled. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Hazard statements:

Precautionary statements:

Prevention: Keep container tightly closed. Keep only in original container. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Take precautionary measures against static discharge. Use only non-sparking tools. Use only outdoors or in a wellventilated area. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.

Response: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Absorb spillage to prevent material damage. Call a POISON CENTER or doctor/ physician. IF

INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON

SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Storage: Store in corrosive resistant container with resistant inliner. Store in a well-ventilated place. Keep container tightly closed.

Disposal: Dispose of contents/container in accordance with local/regional/national/international regulation.

HMIS III Hazard Ratings:

Health - 3, Flammability - 2, Physical Hazard - 0

NFPA Hazard Ratings: Health - 3, Flammability - 2, Instability - 0

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

3/12

NOTE: HMIS III and NFPA 704 (2007) hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. To adequately address safe handling, ALL information in this MSDS must be considered.

3. Composition/information on ingredients

Weight

percent

85 - 90

Components - (CAS-No.)

Acetic acid (64-19-7)

4. First aid measures

Inhalation:

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.

Eyes:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.

Skin: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before re-use. Immediately call a POISON CENTER or doctor/ physician.

Ingestion: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON

CENTER or doctor/ physician.

Most important symptoms and effects, both acute and delayed: No information available.

Indication of any immediate medical attention and special treatment needed:

Treatment: No information available.

5. Firefighting measures

Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Hazardous Combustion Products: Carbon oxides

Special Fire-Fighting Procedures: Use water spray to cool unopened containers. Wear self-contained breathing apparatus and protective clothing.

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

4/12

Unusual Fire and Explosion Hazards: Combustible Material contains a combustible solvent that may accumulate in the container headspace.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures: Refer to protective measures listed in sections 7 and 8.

Methods and materials for containment and cleaning up: Remove all sources of ignition.

Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.

Clean surface thoroughly to remove residual contamination.

Environmental precautions: No information available.

7. Handling and storage

Precautions for safe handling

Personal precautions: Do not breathe mist or vapour at concentrations greater than the exposure limits. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Use only with adequate ventilation. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Prevention of Fire and Explosion: Keep away from heat and sources of ignition. Keep from contact with oxidizing materials. Use only with adequate ventilation.

Conditions for safe storage, including any incompatibilities: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility section.)

8. Exposure controls/personal protection

Occupational exposure controls

Chemical Name Regulatory

Value Type Value

Acetic acid

Acetic acid

List

ACGIH

OSHA

Time weighted average

Short term exposure limit

Time weighted average 10 ppm

10 ppm

15 ppm

25 mg/m3

Appropriate engineering controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Controls should be sufficient so that applicable occupational exposure limits are not exceeded.

Individual protection measures, such as personal protective equipment

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

5/12

Eye protection:

Wear eye/face protection.

Hand protection: Wear protective gloves.

Respiratory protection:

If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator must be worn.

Respirator type: full-face organic vapour cartridge.

If respirators are used, a program should be instituted to assure compliance with applicable federal, state, commonwealth, provincial, or local laws and regulations.

9. Physical and chemical properties

Physical form: liquid

Colour: light yellow

Odour: sharp vinegar

Specific gravity: 1.07

Vapour pressure: 19.5 mbar (14.6 mm Hg)

Vapour density: 1.9

Boiling point/boiling range: 100.0 °C (212.0 °F)

Water solubility: complete

pH: 2

Flash point:

53.3 °C (127.9 °F)

Evaporation rate: No data available

Flammability (Solid; gas): No data available

Upper explosion limit: No data available

Lower explosion limit: No data available

Partition coefficient: n-octanol/water: No data available

Auto-ignition temperature: No data available

Decomposition temperature: No data available

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

6/12

Viscosity: No data available

Explosive properties: No data available

Oxidizing properties: No data available

10. Stability and reactivity

Reactivity: No data available

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: Hazardous polymerisation does not occur.

Conditions to avoid: No data available

Incompatible materials: Strong oxidizing agents, Bases, Amines, Metals.

Hazardous decomposition products: None under normal conditions of use.

11. Toxicological information

Effects of Exposure

General advice:

Contains: Acetic acid. Acute overexposure to extremely high airborne concentrations of respiratory irritants has been associated with development of an asthma-like reactive airways syndrome (RADS) in susceptible individuals. Extremely high airborne concentrations are not generated during normal conditions of use but may occur following a spill. The potential to generate extremely high airborne concentrations in a spill situation depends upon physical factors such as the concentration of the solution, the volume of the spill, the surface area of the spill, the size of the room where the spill occurred, and the ventilation rate in the room.

Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Harmful if inhaled.

Eyes: Causes serious eye damage.

Skin: Causes severe skin burns. Harmful in contact with skin.

Ingestion: May cause burns of the gastrointestinal tract if swallowed. May be harmful if swallowed.

Data for Acetic acid (CAS 64-19-7):

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

7/12

Acute Toxicity Data:

Oral LD50 (Rat): 3,320 mg/kg

Oral LD50 (Rat): 3,310 mg/kg

Inhalation LC50 (Rat): 11.4 mg/l / 4 hr

Dermal LD50 (Rabbit): 1,060 mg/kg

Skin irritation: severe

Eye irritation (washed eyes): severe

Eye irritation (unwashed eyes): severe

Carcinogenicity

American Conference of Governmental Industrial Hygienists

(ACGIH):

No component of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

International Agency for Research on Cancer (IARC):

U.S. National Toxicology Program (NTP):

U.S. Occupational Safety and Health Administration

(OSHA):

California Prop. 65

No component of this product present at levels greater than or equal to

0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

No component of this product present at levels greater than or equal to

0.1% is identified as a known or anticipated carcinogen by NTP.

No component of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or potential carcinogen by OSHA.

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other reproductive harm.

12. Ecological information

The following properties are ESTIMATED from the components of the preparations.

Potential Toxicity:

Toxicity to fish (LC50): 10 - 100 mg/l

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

8/12

Toxicity to daphnia (EC50):

Persistence and degradability:

Bioaccumulative potential

No data available

Mobility in soil

No information available.

13. Disposal considerations

10 - 100 mg/l

Readily biodegradable

Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local laws. Since emptied containers retain product residue, follow label warnings even after container is emptied.

14. Transport information

The information below is provided to assist in documentation. It represents the dangerous goods classification before any regulatory exceptions are taken (e.g. "limited quantity") and therefore may not represent the final classification. The final classification as it pertains to the product packaging configuration (including labeling, marking, and exceptions) may be obtained via the Dangerous Goods

Worksheet which can be found at www.kodak.com/go/ship.

IATA:

UN number: UN2789

Proper shipping name:

Class:

Sub-risks:

ACETIC ACID SOLUTION

8

3

Packaging group: II

IMDG: UN number: UN2789

Proper shipping name:

Class:

Sub-risks:

Packaging group:

US DOT: UN number:

Proper shipping name:

Class:

Sub-risks:

Packaging group:

ACETIC ACID SOLUTION

8

3

II

UN2789

ACETIC ACID SOLUTION

8

3

II

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

9/12

For more transportation information, go to: www.kodak.com/go/ship.

15. Regulatory information

Notification status

Regulatory List Notification status

TSCA All listed

DSL

NDSL

EINECS

ELINCS

All listed

None listed

All listed

None listed

NLP

AICS

IECS

ENCS

None listed

All listed

All listed

All listed

ECI

NZIoC

Not all listed

All listed

PICCS All listed

"Not all listed" indicates one or more component is either not on the public Inventory or is subject to exemption requirements. If additional information is needed contact Kodak.

Other regulations

U.S. - CERCLA/SARA (40 CFR § 302.4 Designation of hazardous substances):

Acetic acid

U.S. - CERCLA/SARA - Section 302 (40 CFR § 355

Appendices A and B - The List of Extremely Hazardous

Substances and Their Threshold Planning Quantities):

U.S. - CERCLA/SARA - Section 313 (40 CFR § 372.65

Toxic Chemical Release Reporting):

U.S. - California - 8 CCR Section 339 - Director's List of

Hazardous Substances:

No components of this product are subject to the SARA Section 302

(40 CFR 355) reporting requirements.

No components of this product are subject to the SARA Section 313

(40 CFR 372.65) reporting requirements.

Acetic acid

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

10/12

U.S. - California - 8 CCR Section 5200-5220 - Specifically

Regulated Carcinogens:

No components found on the California

Specifically Regulated

Carcinogens List.

U.S. - California - 8 CCR Section 5203 Carcinogens:

U.S. - California - 8 CCR Section 5209 Carcinogens:

No components found on the California

Section 5203 Carcinogens List.

No components found on the California

Section 5209 Carcinogens List.

Acetic acid U.S. - Massachusetts - General Law Chapter 111F (MGL c

111F) - Hazardous Substances Disclosure by

Employers (a.k.a. Right to Know Law):

U.S. - Minnesota Employee Right-to-Know (5206.0400,

Subpart 5. List of Hazardous Substances):

U.S. - New Jersey - Worker and Community Right to Know

Act (N.J.S.A. 34:5A-1):

U.S. - Pennsylvania - Part XIII. Worker and Community

Right-to-Know Act (Chapter 323 Hazardous Substance

List, Appendix A):

Acetic acid

Acetic acid

Acetic acid , Water

16. Other information

The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture.

US/Canadian Label Statements:

Indicator Stop Bath

Contains:

Acetic acid (64-19-7)

Symbol(s):

Signal word: Danger

Hazard statements:

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

11/12

Flammable liquid and vapour. May be corrosive to metals. Harmful if inhaled. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Hazard statements:

Precautionary statements:

Prevention: Keep container tightly closed. Keep only in original container. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Take precautionary measures against static discharge. Use only non-sparking tools. Use only outdoors or in a wellventilated area. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.

Response: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Absorb spillage to prevent material damage. Call a POISON CENTER or doctor/ physician. IF

INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON

SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Storage: Store in corrosive resistant container with resistant inliner. Store in a well-ventilated place. Keep container tightly closed.

Disposal: Dispose of contents/container in accordance with local/regional/national/international regulation.

FIRST AID: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before re-use. Immediately call a POISON CENTER or doctor/ physician. IF SWALLOWED: Rinse mouth.

Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. Keep out of reach of children. Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read and understood. Since emptied containers retain product residue, follow label warnings even after container is emptied. IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. IN CASE OF SPILL: Remove all sources of ignition. Absorb spill with vermiculite or other inert

Safety Data Sheet

Revision Date: 09/15/2015

Z17000000755/Version: 4.0

Print Date: 11/05/2015

Page:

12/12 material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination.

The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The information relating to the working solution is for guidance purposes only, and is based on correct mixing and use of the product according to instructions.

R-2, S-3, F-2, C-0

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

1/11

1. Identification of the substance/mixture and of the company/undertaking

Product name: Indicator Stop Bath, Working Solution

Product code: 5160346 - Working Solution

Synonyms: None.

Relevant identified uses of the substance or mixture and uses advised against:

Identified uses: photographic processing chemical. For industrial use only.

Supplier: Kodak Alaris Inc., 2400 Mount Read Boulevard, Rochester, NY 14615

IN EMERGENCY, telephone: 1-800-424-9300 or +1 703-527-3887.

For further information about this product, email [email protected]

2. Hazards identification

Classification of the chemical in accordance with paragraph (d) of 29 CFR 1910.1200:

Hazard class Hazard category Route of exposure

--

--

--

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 1

Respiratory sensitisation Category 1

GHS-Labelling

Contains:

Acetic acid (64-19-7)

Symbol(s):

Signal word: Danger

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

2/11

Hazard statements: Causes skin irritation. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary statements:

Prevention: Wear protective gloves/ eye protection/ face protection. In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Response: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash before reuse.

Storage: Store in a well-ventilated place. Keep cool.

Disposal: Dispose of contents/container in accordance with local/regional/national/international regulation.

HMIS III Hazard Ratings:

Health - 2, Flammability - 1, Physical Hazard - 0

NFPA Hazard Ratings: Health - 3, Flammability - 1, Instability - 0

NOTE: HMIS III and NFPA 704 (2007) hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. To adequately address safe handling, ALL information in this MSDS must be considered.

3. Composition/information on ingredients

Weight

percent

3 - 5

Components - (CAS-No.)

Acetic acid (64-19-7)

4. First aid measures

Inhalation:

IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician.

Eyes:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

3/11

Skin: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention.

Ingestion: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.

Most important symptoms and effects, both acute and delayed: No information available.

Indication of any immediate medical attention and special treatment needed:

Treatment: No information available.

5. Firefighting measures

Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Flush with plenty of water.

Special hazards arising from the substance or mixture

Hazardous Combustion Products: Carbon oxides, Sulphur oxides, Nitrogen oxides (NOx), (see also

Hazardous Decomposition Products sections.)

Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.

Fire or excessive heat may produce hazardous decomposition products.

Unusual Fire and Explosion Hazards: Dried product residue can act as a reducing agent. Reacts violently with oxidizing materials. May cause spontaneous heating and ignition when absorbed on combustible, porous material (e.g. rags, paper, sawdust, cotton, clothing).

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures: Refer to protective measures listed in sections 7 and 8.

Methods and materials for containment and cleaning up: Absorb spill with vermiculite or other inert material.

Collect in a noncombustible container for prompt disposal.

Clean surface thoroughly to remove residual contamination.

Environmental precautions: Flush with plenty of water.

For Large Spills: Flush with plenty of water.

7. Handling and storage

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

4/11

Precautions for safe handling

Personal precautions: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Prevention of Fire and Explosion: Keep from contact with oxidizing materials, highly oxygenated or halogenated solvents, organic compounds containing reducible functional groups. Remove and wash contaminated clothing promptly.

Conditions for safe storage, including any incompatibilities: Store in original container. Keep container tightly closed to prevent the loss of water. Keep away from incompatible substances (see

Incompatibility section.)

8. Exposure controls/personal protection

Occupational exposure controls

Chemical Name Regulatory

List

Value Type Value

Acetic acid

Acetic acid

ACGIH Time weighted average

Short term exposure limit

10 ppm

15 ppm

OSHA

Time weighted average

10 ppm 25 mg/m3

Appropriate engineering controls:

Good general ventilation should be used. Ventilation should be sufficient so that applicable occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in special circumstances.

Individual protection measures, such as personal protective equipment

Eye protection:

Wear eye/face protection.

Hand protection: Wear protective gloves.

Respiratory protection:

None should be needed.

If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator must be worn.

Respirator type: acid gas If respirators are used, a program should be instituted to assure compliance with applicable federal, state, commonwealth, provincial, or local laws and regulations.

9. Physical and chemical properties

Physical form: liquid

Colour: No data available

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

5/11

Odour: No data available

Specific gravity: No data available

Vapour pressure: No data available

Vapour density: No data available

Boiling point/boiling range: No data available

Water solubility: No data available

pH: No data available

Flash point:

No data available

Evaporation rate: No data available

Flammability (Solid; gas): No data available

Upper explosion limit: No data available

Lower explosion limit: No data available

Partition coefficient: n-octanol/water: No data available

Auto-ignition temperature: No data available

Decomposition temperature: No data available

Viscosity: No data available

Explosive properties: No data available

Oxidizing properties: No data available

10. Stability and reactivity

Reactivity: No data available

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: Hazardous polymerisation does not occur.

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

6/11

Conditions to avoid: No data available

Incompatible materials: Strong oxidizing agents, Bases, Amines, Metals.

Hazardous decomposition products: None under normal conditions of use.

11. Toxicological information

Effects of Exposure

General advice:

Contains: Acetic acid. Acute overexposure to extremely high airborne concentrations of respiratory irritants has been associated with development of an asthma-like reactive airways syndrome (RADS) in susceptible individuals. Extremely high airborne concentrations are not generated during normal conditions of use but may occur following a spill. The potential to generate extremely high airborne concentrations in a spill situation depends upon physical factors such as the concentration of the solution, the volume of the spill, the surface area of the spill, the size of the room where the spill occurred, and the ventilation rate in the room.

Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Eyes: Causes serious eye damage.

Skin: Causes skin irritation.

Ingestion: May be harmful if swallowed.

Data for Acetic acid (CAS 64-19-7):

Acute Toxicity Data:

Oral LD50 (Rat): 3,320 mg/kg

Oral LD50 (Rat): 3,310 mg/kg

Inhalation LC50 (Rat): 11.4 mg/l / 4 hr

Dermal LD50 (Rabbit): 1,060 mg/kg

Skin irritation: severe

Eye irritation (washed eyes): severe

Eye irritation (unwashed eyes): severe

Carcinogenicity

American Conference of Governmental Industrial Hygienists

(ACGIH):

No component of this product present at levels greater than or equal to

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

7/11

International Agency for Research on Cancer (IARC):

U.S. National Toxicology Program (NTP):

U.S. Occupational Safety and Health Administration

(OSHA):

California Prop. 65

12. Ecological information

The following properties are ESTIMATED from the components of the preparations.

Potential Toxicity:

Toxicity to fish (LC50): > 100 mg/l

Toxicity to daphnia (LC50):

Persistence and degradability:

> 100 mg/l

Readily biodegradable

Bioaccumulative potential

No data available

Mobility in soil

No information available.

13. Disposal considerations

0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

No component of this product present at levels greater than or equal to

0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

No component of this product present at levels greater than or equal to

0.1% is identified as a known or anticipated carcinogen by NTP.

No component of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or potential carcinogen by OSHA.

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other reproductive harm.

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

8/11

Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local laws. Since emptied containers retain product residue, follow label warnings even after container is emptied.

14. Transport information

Not regulated for all modes of transportation.

For more transportation information, go to: www.kodak.com/go/ship.

15. Regulatory information

Notification status

Regulatory List Notification status

TSCA

DSL

NDSL

EINECS

ELINCS

NLP

AICS

IECS

All listed

All listed

None listed

All listed

None listed

None listed

All listed

All listed

ENCS

ECI

All listed

Not all listed

NZIoC

PICCS

All listed

All listed

"Not all listed" indicates one or more component is either not on the public Inventory or is subject to exemption requirements. If additional information is needed contact Kodak.

Other regulations

U.S. - CERCLA/SARA (40 CFR § 302.4 Designation of hazardous substances):

Acetic acid

U.S. - CERCLA/SARA - Section 302 (40 CFR § 355

Appendices A and B - The List of Extremely Hazardous

Substances and Their Threshold Planning Quantities):

No components of this product are subject to the SARA Section 302

(40 CFR 355) reporting

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

9/11

U.S. - CERCLA/SARA - Section 313 (40 CFR § 372.65

Toxic Chemical Release Reporting): requirements.

No components of this product are subject to the SARA Section 313

(40 CFR 372.65) reporting requirements.

Acetic acid U.S. - California - 8 CCR Section 339 - Director's List of

Hazardous Substances:

U.S. - California - 8 CCR Section 5200-5220 - Specifically

Regulated Carcinogens:

U.S. - California - 8 CCR Section 5203 Carcinogens:

U.S. - California - 8 CCR Section 5209 Carcinogens:

No components found on the California

Specifically Regulated

Carcinogens List.

No components found on the California

Section 5203 Carcinogens List.

No components found on the California

Section 5209 Carcinogens List.

Acetic acid U.S. - Massachusetts - General Law Chapter 111F (MGL c

111F) - Hazardous Substances Disclosure by

Employers (a.k.a. Right to Know Law):

U.S. - Minnesota Employee Right-to-Know (5206.0400,

Subpart 5. List of Hazardous Substances):

U.S. - New Jersey - Worker and Community Right to Know

Act (N.J.S.A. 34:5A-1):

Acetic acid

Acetic acid

U.S. - Pennsylvania - Part XIII. Worker and Community

Right-to-Know Act (Chapter 323 Hazardous Substance

List, Appendix A):

Water , Acetic acid

16. Other information

The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture.

US/Canadian Label Statements:

Indicator Stop Bath, Working Solution

Contains:

Acetic acid (64-19-7)

Symbol(s):

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

10/11

Safety Data Sheet

Signal word: Danger

Hazard statements: Causes skin irritation. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary statements:

Prevention: Wear protective gloves/ eye protection/ face protection. In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Response: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash before reuse.

Storage: Store in a well-ventilated place. Keep cool.

Disposal: Dispose of contents/container in accordance with local/regional/national/international regulation.

FIRST AID: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN:

Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/ attention. IF

SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. Keep out of reach of children. Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read and understood. Since emptied containers retain product residue, follow label warnings even after container is emptied. IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Flush with plenty of water. IN CASE OF SPILL: Absorb spill with vermiculite or other inert material. Collect in a noncombustible container for prompt disposal. Clean surface thoroughly to remove residual contamination. For Large Spills: Flush with plenty of water.

Safety Data Sheet

Revision Date: 09/18/2015

000000055520/Version: 1.0

Print Date: 11/05/2015

Page:

11/11

The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The information relating to the working solution is for guidance purposes only, and is based on correct mixing and use of the product according to instructions.

R-1, S-2, F-1, C-1

Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement